What is an alkali?
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In chemistry, an alkali (; from Arabic: "al-qaly" "ashes of the saltwort") is a basic, ionic salt of an alkali metal or alkaline earth metal chemical element. An alkali also can be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The adjective alkaline is commonly, and alkalescent less often, used in English as a synonym for basic, especially for bases soluble in water. This broad use of the term is likely to have come about because alkalis were the first bases known to obey the Arrhenius definition of a base, and they are still among the most common bases.
Alkali
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The word "alkali" is derived from Arabic "al qalīy" (or "alkali"), meaning "the calcined ashes" (see calcination), referring to the original source of alkaline substances. A water-extract of burned plant ashes, called potash and composed mostly of potassium carbonate, was mildly basic. After heating this substance with calcium hydroxide ("slaked lime"), a far more strongly basic substance known as "caustic potash" (potassium hydroxide) was produced. Caustic potash was traditionally used in conjunction with animal fats to produce soft soaps, one of the caustic processes that rendered soaps from fats in the process of saponification, one known since antiquity. Plant potash lent the name to the element potassium, which was first derived from caustic potash, and also gave potassium its chemical symbol K (from the German name Kalium), which ultimately derived from alkali.
Alkali
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The alkali metals are all shiny, soft, highly reactive metals at standard temperature and pressure and readily lose their outermost electron to form cations with charge +1. They can all be cut easily with a knife due to their softness, exposing a shiny surface that tarnishes rapidly in air due to oxidation by atmospheric moisture and oxygen (and in the case of lithium, nitrogen). Because of their high reactivity, they must be stored under oil to prevent reaction with air, and are found naturally only in salts and never as the free elements. Caesium, the fifth alkali metal, is the most reactive of all the metals. In the modern IUPAC nomenclature, the alkali metals comprise the group 1 elements, excluding hydrogen (H), which is nominally a group 1 element but not normally considered to be an alkali metal as it rarely exhibits behaviour comparable to that of the alkali metals. All the alkali metals react with water, with the heavier alkali metals reacting more vigorously than the lighter ones.
Alkali metal
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Alkali basalt or alkali olivine basalt is a fine-grained, dark-coloured, volcanic rock characterized by phenocrysts of olivine, titanium-rich augite, plagioclase feldspar and iron oxides. For similar SiO concentrations, alkali basalts have a higher content of the alkalis, NaO and KO, than other basalt types such as tholeiites. They are also characterized by the development of modal nepheline in their groundmass (visible at highest magnification on a petrographic microscope) and normative nepheline in their CIPW norms. Alkali basalts are typically found on updomed and rifted continental crust, and on oceanic islands such as Hawaii, Madeira and Ascension Island.
Alkali basalt
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Alkali is a ghost town located in Esmeralda County, Nevada. Alkali is the site of Alkali Hot Spring, which was operated as a spa by Geni and Joe Guisti in the 1930s.
During Goldfield's peak, the site included an indoor wooden swimming pool with a separate area for children and a large building containing a dining room, kitchen, dance hall and bar. In front of the dining room were tall tamarisk trees and a large picnic table where visitors could either order from the dining room or bring their own lunches. The Guisti residence was at the rear of the dining room. Geni Guisti served young folks grape juice over ice at the bar, which was considered a real treat. Friday and Saturday night dances were attended by Tonopah residents.
Alkali, Nevada
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Alkali, or Alkaline, soils are clay soils with high pH (> 8.5), a poor soil structure and a low infiltration capacity. Often they have a hard calcareous layer at 0.5 to 1 metre depth. Alkali soils owe their unfavorable physico-chemical properties mainly to the dominating presence of sodium carbonate, which causes the soil to swell and difficult to clarify/settle. They derive their name from the alkali metal group of elements, to which sodium belongs, and which can induce basicity. Sometimes these soils are also referred to as "alkaline sodic soils".
Alkaline soils are basic, but not all basic soils are alkaline.
The causes of soil alkalinity can be natural or man-made:
Alkali soil
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The Alkali Lakes are a series of three large playas located in the Surprise Valley of northeastern California, United States. From north to south they are known as Upper, Middle and Lower Alkali Lake. Upper Alkali Lake is often known simply as Upper Lake, and Lower Alkali Lake as Lower Lake. Although mostly located in Modoc County, California, the eastern edges of Middle and Lower Lakes touch Washoe County, Nevada. The Warner Mountains are located to the west of the three lakes. The lake beds are typically flooded with shallow water in the winter but dry up during most summers.
Alkali Lakes (California)
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The alkali metals are a group (column) in the periodic table consisting of the chemical elements lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr). This group lies in the s-block of the periodic table of elements as all alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in their having very similar characteristic properties. Indeed, the alkali metals provide the best example of group trends in properties in the periodic table, with elements exhibiting well-characterised homologous behaviour.
Alkali metal
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The alkali metals are among the most electropositive elements on the periodic table and thus tend to bond ionically to the most electronegative elements on the periodic table, the halogens (fluorine, chlorine, bromine, iodine, and astatine), forming salts known as the alkali metal halides. The reaction is very vigorous and can sometimes result in explosions. All twenty stable alkali metal halides are known; the unstable ones are not known, with the exception of sodium astatide, because of the great instability and rarity of astatine and francium. The most well-known of the twenty is certainly sodium chloride, otherwise known as common salt. All of the stable alkali metal halides have the formula MX where M is an alkali metal and X is a halogen. They are all white ionic crystalline solids that have high melting points. All the alkali metal halides are soluble in water except for lithium fluoride (LiF), which is insoluble in water due to its very high lattice enthalpy. The high lattice enthalpy of lithium fluoride is due to the small sizes of the Li and F ions, causing the electrostatic interactions between them to be strong: a similar effect occurs for magnesium fluoride, consistent with the diagonal relationship between lithium and magnesium.
Alkali metal
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An alkalide is a chemical compound in which alkali metal atoms are anions (negative ions) with a charge or oxidation state of –1. Until the first discovery of alkalides in the 1970s, alkali metals were only known to appear in salts only as cations (positive ions) with a charge or oxidation state of +1. These types of compounds are of theoretical interest due to their unusual stoichiometry and low ionization potentials. Alkalide compounds are chemically related to the electrides, salts in which trapped electrons are effectively the anions.
Alkalide