When was cobalt first used for blue paint?
1182639#1
Cobalt blue in impure forms had long been used in Chinese porcelain, but it was independently discovered as a pure alumina-based pigment by Louis Jacques Thénard in 1802. Commercial production began in France in 1807. The first recorded use of "cobalt blue" as a color name in English was in 1777. The leading world manufacturer of cobalt blue in the 19th century was Benjamin Wegner's Norwegian company Blaafarveværket ("blue colour works" in Dano-Norwegian). Germany was also famous for production, especially the blue colour works ("Blaufarbenwerke") in the Ore Mountains of Saxony.
Cobalt blue
24580536#1
Cobalt-based blue pigments (cobalt blue) have been used since ancient times for jewelry and paints, and to impart a distinctive blue tint to glass, but the color was later thought by alchemists to be due to the known metal bismuth. Miners had long used the name "kobold ore" (German for "goblin ore") for some of the blue-pigment producing minerals; they were so named because they were poor in known metals, and gave poisonous arsenic-containing fumes when smelted. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), and this was ultimately named for the "kobold".
Cobalt
24580536#48
Before the 19th century, cobalt was predominantly used as a pigment. It has been used since the Middle Ages to make smalt, a blue-colored glass. Smalt is produced by melting a mixture of roasted mineral smaltite, quartz and potassium carbonate, which yields a dark blue silicate glass, which is finely ground after the production. Smalt was widely used to color glass and as pigment for paintings. In 1780, Sven Rinman discovered cobalt green, and in 1802 Louis Jacques Thénard discovered cobalt blue. Cobalt pigments such as cobalt blue (cobalt aluminate), cerulean blue (cobalt(II) stannate), various hues of cobalt green (a mixture of cobalt(II) oxide and zinc oxide), and cobalt violet (cobalt phosphate) are used as artist's pigments because of their superior chromatic stability. Aureolin (cobalt yellow) is now largely replaced by more lightfast yellow pigments.
Cobalt
324222#76
Blue and white porcelain artifacts decorating white porcelain with paintings and designs in underglaze by using natural cobalt pigment are another example of popular wares of the Joseon period. Many of these items were created by court painters employed by the royal family. During this period, the popular style of landscape paintings is mirrored in the decoration of ceramics. Initially developed by the Chinese at the Jingdezhen kilns in the mid-14th century, Joseon began to produce this type of porcelain from the 15th century under Chinese influence. The first cobalt imported from China was used by Korean artists. In 1463 when sources of cobalt were discovered in Korea, artists and their buyers found the material was inferior in quality and preferred the more expensive imported cobalt. Korean porcelain with imported cobalt decoration contradict the emphasis of an orderly, frugal and moderate life in Neo-Confucianism.
Joseon
4543#42
The introduction of oil painting changed the way colours looked and how they were used. Ultramarine pigment, for instance, was much darker when used in oil painting than when used in tempera painting, in frescoes. To balance their colours, Renaissance artists like Raphael added white to lighten the ultramarine. The sombre dark blue robe of the Virgin Mary became a brilliant sky blue. Titian created his rich blues by using many thin glazes of paint of different blues and violets which allowed the light to pass through, which made a complex and luminous colour, like stained glass. He also used layers of finely ground or coarsely ground ultramarine, which gave subtle variations to the blue.
In about the 9th century, Chinese artisans abandoned the Han blue colour they had used for centuries, and began to use cobalt blue, made with cobalt salts of alumina, to manufacture fine blue and white porcelain, The plates and vases were shaped, dried, the paint applied with a brush, covered with a clear glaze, then fired at a high temperature. Beginning in the 14th century, this type of porcelain was exported in large quantity to Europe where it inspired a whole style of art, called Chinoiserie. European courts tried for many years to imitate Chinese blue and white porcelain, but only succeeded in the 18th century after a missionary brought the secret back from China.
Blue
2299975#3
The earliest known example of cobalt aluminate glass dates to a lump from about 2000 BC in ancient Mesopotamia, very possibly intended for use as a pigment; it was rare until the modern era. Cobalt oxide smalt appears as a pigment in Egyptian pottery about five centuries later, and soon after in the Aegean region, and this is the pigment normally known as "smalt". In paintings, smalt has a tendency to lose its colour over a long period, and is little used today. However, when used in ceramics for underglaze decoration, it keeps its colour well, and is the main blue used in blue and white pottery from a wide range of dates and areas, including Chinese blue and white porcelain from the Yuan and Ming dynasties, Renaissance Italian maiolica and Delftware.
Chinese porcelain used smalt glazes from the Tang dynasty onwards, though Chinese cobalt glass is found from the Zhou dynasty (1122–221 BC). Cobalt was used as a pigment in Central Asia from the 13th century. A fragment of a mud painting in the ancient Tangut city of Khara-Khoto has been found to contain smalt, judged to be dated between the 11th and 13th centuries. A large quantity of smalt was purchased for the decoration of the gallery of Francis I of France at Fontainebleau in 1536. Smalt, normally now discoloured, is common in European paintings from the 15th to 17th centuries. For example, it is found in Hans Holbein the Younger's portrait of Sir William Butts (ca. 1540), in Michael Pacher's painting "The Early Fathers' Altar" (ca. 1483), and in the frescos of Domenico Ghirlandaio (1449–1494).
Cobalt glass
24580536#3
Cobalt is primarily used in the manufacture of magnetic, wear-resistant and high-strength alloys. The compounds cobalt silicate and cobalt(II) aluminate (CoAlO, cobalt blue) give a distinctive deep blue color to glass, ceramics, inks, paints and varnishes. Cobalt occurs naturally as only one stable isotope, cobalt-59. Cobalt-60 is a commercially important radioisotope, used as a radioactive tracer and for the production of high energy gamma rays.
Cobalt
24580536#20
During the 19th century, a significant part of the world's production of cobalt blue (a dye made with cobalt compounds and alumina) and smalt (cobalt glass powdered for use for pigment purposes in ceramics and painting) was carried out at the Norwegian Blaafarveværket. The first mines for the production of smalt in the 16th century were located in Norway, Sweden, Saxony and Hungary. With the discovery of cobalt ore in New Caledonia in 1864, the mining of cobalt in Europe declined. With the discovery of ore deposits in Ontario, Canada in 1904 and the discovery of even larger deposits in the Katanga Province in the Congo in 1914, the mining operations shifted again. When the Shaba conflict started in 1978, the copper mines of Katanga Province nearly stopped production. The impact on the world cobalt economy from this conflict was smaller than expected: cobalt is a rare metal, the pigment is highly toxic, and the industry had already established effective ways for recycling cobalt materials. In some cases, industry was able to change to cobalt-free alternatives.
Cobalt
1182639#0
Cobalt blue is a blue pigment made by sintering cobalt(II) oxide with alumina at 1200 °C. Chemically, cobalt blue pigment is cobalt(II) oxide-aluminium oxide, or cobalt(II) aluminate, CoAlO. Cobalt blue is lighter and less intense than the (iron-cyanide based) pigment Prussian blue. It is extremely stable and has historically been used as a coloring agent in ceramics (especially Chinese porcelain), jewelry, and paint. Transparent glasses are tinted with the silica-based cobalt pigment smalt.
Cobalt blue
11829480#18
Its best-known pattern, "cobalt net", first appeared in 1949. The design is based on a blue net pattern that was painted on raised lines cast into the porcelain dinnerware pieces of Catherine the Great. The factory has actual examples of Catherine's dinnerware with this design. The new design pattern is a combination of intersecting lines of cobalt blue with inverted tear drops of cobalt blue (made from mineral cobalt) and 22 karat gold accents.
Imperial Porcelain Factory, Saint Petersburg