cryospectrokinetic studies of zinc and cobalt carboxypeptidase a disclosed two intermediates in the hydrolysis of both peptides and depsipeptides and furnished all the rate and equilibrium constants for the reaction scheme e + s in equilibrium es1 in equilibrium es2 -- -e + p [ auld , d. s. , galdes , a. , geoghegan , k. f. , holmquist , b. , martinelli , r. a. , & vallee , b. l. ( 1984 ) proc . natl . acad . sci . u.s.a. 81 , 5041-5045 ] .
C0020291
hydrolysis
C1418943
proc