# Thermodynamics

## Zeroth Law of Thermodynamics: Thermal Equilibrium


### Section Key Terms

We learned in the previous chapter that when two objects (or systems) are in contact with one another, heat will transfer thermal energy from the object at higher temperature to the one at lower temperature until they both reach the same temperature. The objects are then in thermal equilibrium, and no further temperature changes will occur if they are isolated from other systems. The systems interact and change because their temperatures are different, and the changes stop once their temperatures are the same. Thermal equilibrium is established when two bodies are in thermal contact with each other—meaning heat transfer (i.e., the transfer of energy by heat) can occur between them. If two systems cannot freely exchange energy, they will not reach thermal equilibrium. (It is fortunate that empty space stands between Earth and the sun, because a state of thermal equilibrium with the sun would be too toasty for life on this planet!)
If two systems, A and B, are in thermal equilibrium with each other, and B is in thermal equilibrium with a third system, C, then A is also in thermal equilibrium with C. This statement may seem obvious, because all three have the same temperature, but it is basic to thermodynamics. It is called the zeroth law of thermodynamics.
You may be wondering at this point, why the wacky name? Shouldn’t this be called the first law of thermodynamics rather than the zeroth? The explanation is that this law was discovered after the first and second laws of thermodynamics but is so fundamental that scientists decided it should logically come first.
As an example of the zeroth law in action, consider newborn babies in neonatal intensive-care units in hospitals. Prematurely born or sick newborns are placed in special incubators. These babies have very little covering while in the incubators, so to an observer, they look as though they may not be warm enough. However, inside the incubator, the temperature of the air, the cot, and the baby are all the same—that is, they are in thermal equilibrium. The ambient temperature is just high enough to keep the baby safe and comfortable.

### Check Your Understanding


### Section Summary

1. Systems are in thermal equilibrium when they have the same temperature.
2. Thermal equilibrium occurs when two bodies are in contact with each other and can freely exchange energy.
3. The zeroth law of thermodynamics states that when two systems, A and B, are in thermal equilibrium with each other, and B is in thermal equilibrium with a third system, C, then A is also in thermal equilibrium with C.

### Concept Items


### Critical Thinking


### Test Prep Multiple Choice


### Test Prep Short Answer


### Test Prep Extended Response
