History and development.

The motivation for creating the PNG format was the realization, in early 1995, that the Lempel–Ziv–Welch (LZW) data compression algorithm used in the Graphics Interchange Format (GIF) format was patented by Unisys. There were also other problems with the GIF format that made a replacement desirable, notably its limit of 256 colors at a time when computers with far more advanced displays were becoming common.  A January 1995 precursory discussion thread, on the usenet newsgroup "comp.graphics" with the subject "Thoughts on a GIF-replacement file format", had many propositions which would later be part of the PNG file format. In that thread, Oliver Fromme, author of the popular JPEG viewer QPEG, proposed the PING name, eventually becoming PNG, a recursive acronym meaning "PING is not GIF", and also the codice_4 extension.  Although GIF allows for animation, it was decided that PNG should be a single-image format. In 2001, the developers of PNG published the Multiple-image Network Graphics (MNG) format, with support for animation. MNG achieved moderate application support, but not enough among mainstream web browsers and no usage among web site designers or publishers. In 2008, certain Mozilla developers published the Animated Portable Network Graphics (APNG) format with similar goals. APNG is a format that is natively supported by Gecko- and Presto-based web browsers and is also commonly used for thumbnails on Sony's PlayStation Portable system (using the normal PNG file extension). However, as of 2017, usage of APNG remains minimal despite being supported by all major browsers but Microsoft Edge.

PNG Working Group.

The original PNG specification was authored by an ad-hoc group of computer graphics experts and enthusiasts. Discussions and decisions about the format were conducted by email. The original authors listed on RFC 2083 are:

File format.

File header.

A PNG file starts with an 8-byte signature (refer to hex editor image on the right):

"Chunks" within the file.

After the header comes a series of chunks, each of which conveys certain information about the image. Chunks declare themselves as "critical" or "ancillary", and a program encountering an ancillary chunk that it does not understand can safely ignore it. This chunk-based storage layer structure, similar in concept to a container format or to Amigas IFF, is designed to allow the PNG format to be extended while maintaining compatibility with older versions—it provides forward compatibility, and this same file structure (with different signature and chunks) is used in the associated MNG, JNG, and APNG formats.  A chunk consists of four parts: length (4 bytes, big-endian), chunk type/name (4 bytes), chunk data (length bytes) and CRC (cyclic redundancy code/checksum; 4 bytes). The CRC is a network-byte-order CRC-32 computed over the chunk type and chunk data, but not the length.  Chunk types are given a four-letter case sensitive ASCII type/name; compare FourCC. The case of the different letters in the name (bit 5 of the numeric value of the character) is a bit field that provides the decoder with some information on the nature of chunks it does not recognize.  The case of the first letter indicates whether the chunk is critical or not. If the first letter is uppercase, the chunk is critical; if not, the chunk is ancillary. Critical chunks contain information that is necessary to read the file. If a decoder encounters a critical chunk it does not recognize, it must abort reading the file or supply the user with an appropriate warning.  The case of the second letter indicates whether the chunk is "public" (either in the specification or the registry of special-purpose public chunks) or "private" (not standardised). Uppercase is public and lowercase is private. This ensures that public and private chunk names can never conflict with each other (although two private chunk names could conflict).  The third letter must be uppercase to conform to the PNG specification. It is reserved for future expansion. Decoders should treat a chunk with a lower case third letter the same as any other unrecognised chunk.  The case of the fourth letter indicates whether the chunk is safe to copy by editors that do not recognize it. If lowercase, the chunk may be safely copied regardless of the extent of modifications to the file. If uppercase, it may only be copied if the modifications have not touched any critical chunks.

Critical chunks.

A decoder must be able to interpret critical chunks to read and render a PNG file. The codice_6 chunk is essential for color type 3 (indexed color). It is optional for color types 2 and 6 (truecolor and truecolor with alpha) and it must not appear for color types 0 and 4 (grayscale and grayscale with alpha).

Ancillary chunks.

Other image attributes that can be stored in PNG files include gamma values, background color, and textual metadata information. PNG also supports color management through the inclusion of ICC color space profiles.  The lowercase first letter in these chunks indicates that they are not needed for the PNG specification. The lowercase last letter in some chunks indicates that they are safe to copy, even if the application concerned does not understand them.

Pixel format.

Pixels in PNG images are numbers that may be either indices of sample data in the palette or the sample data itself. The palette is a separate table contained in the PLTE chunk. Sample data for a single pixel consists of a tuple of between one and four numbers. Whether the pixel data represents palette indices or explicit sample values, the numbers are referred to as channels and every number in the image is encoded with an identical format.  The permitted formats encode each number as an unsigned integer value using a fixed number of bits, referred to in the PNG specification as the "bit depth". Notice that this is not the same as color depth, which is commonly used to refer to the total number of bits in each pixel, not each channel. The permitted bit depths are summarized in the table along with the total number of bits used for each pixel.  The number of channels depends on whether the image is grayscale or color and whether it has an alpha channel. PNG allows the following combinations of channels, called the "color type". The color type is specified as an 8-bit value however only the low 3 bits are used and, even then, only the five combinations listed above are permitted. So long as the color type is valid it can be considered as a bit field as summarized in the adjacent table:  With indexed color images, the palette always stores trichromatic colors at a depth of 8 bits per channel (24 bits per palette entry). Additionally, an optional list of 8-bit alpha values for the palette entries may be included; if not included, or if shorter than the palette, the remaining palette entries are assumed to be opaque. The palette must not have more entries than the image bit depth allows for, but it may have fewer (for example, if an image with 8-bit pixels only uses 90 colors then it does not need palette entries for all 256 colors). The palette must contain entries for all the pixel values present in the image.  The standard allows indexed color PNGs to have 1, 2, 4 or 8 bits per pixel; grayscale images with no alpha channel may have 1, 2, 4, 8 or 16 bits per pixel. Everything else uses a bit depth per channel of either 8 or 16. The combinations this allows are given in the table above. The standard requires that decoders can read all supported color formats, but many image editors can only produce a small subset of them.

Transparency of image.

PNG offers a variety of transparency options. With true-color and grayscale images either a single pixel value can be declared as transparent or an alpha channel can be added (enabling any percentage of partial transparency to be used). For paletted images, alpha values can be added to palette entries. The number of such values stored may be less than the total number of palette entries, in which case the remaining entries are considered fully opaque.  The scanning of pixel values for binary transparency is supposed to be performed before any color reduction to avoid pixels becoming unintentionally transparent. This is most likely to pose an issue for systems that can decode 16-bits-per-channel images (as is required for compliance with the specification) but only output at 8 bits per channel (the norm for all but the highest end systems).  Alpha "storage" can be "associated" ("premultiplied") or "unassociated", but PNG standardized on "unassociated" ("non-premultiplied") alpha, which means that imagery is not alpha "encoded"; the emissions represented in RGB are not the emissions at the pixel level. This means that the over operation will multiply the RGB emissions by the alpha, and cannot represent emission and occlusion properly.

Compression.

PNG uses a 2-stage compression process:  PNG uses DEFLATE, a non-patented lossless data compression algorithm involving a combination of LZ77 and Huffman coding. Permissively-licensed DEFLATE implementations, such as zlib, are widely available.  Compared to formats with lossy compression such as JPG, choosing a compression setting higher than average delays processing, but often does not result in a significantly smaller file size.

Filtering.

Before DEFLATE is applied, the data is transformed via a prediction method: a single "filter method" is used for the entire image, while for each image line, a "filter type" is chosen to transform the data to make it more efficiently compressible. The filter type used for a scanline is prepended to the scanline to enable inline decompression.  There is only one filter method in the current PNG specification (denoted method 0), and thus in practice the only choice is which filter type to apply to each line. For this method, the filter predicts the value of each pixel based on the values of previous neighboring pixels, and subtracts the predicted color of the pixel from the actual value, as in DPCM. An image line filtered in this way is often more compressible than the raw image line would be, especially if it is similar to the line above, since the differences from prediction will generally be clustered around 0, rather than spread over all possible image values. This is particularly important in relating separate rows, since DEFLATE has no understanding that an image is a 2D entity, and instead just sees the image data as a stream of bytes.  There are five filter types for filter method 0; each type predicts the value of each byte (of the image data before filtering) based on the corresponding byte of the pixel to the left ("A"), the pixel above ("B"), and the pixel above and to the left ("C") or some combination thereof, and encodes the "difference" between the predicted value and the actual value. Filters are applied to byte values, not pixels; pixel values may be one or two bytes, or several values per byte, but never cross byte boundaries. The filter types are: The Paeth filter is based on an algorithm by Alan W. Paeth. Compare to the version of DPCM used in lossless JPEG, and to the discrete wavelet transform using 1×2, 2×1, or (for the Paeth predictor) 2×2 windows and Haar wavelets.  Compression is further improved by choosing filter types adaptively on a line-by-line basis. This improvement, and a heuristic method of implementing it commonly used by PNG-writing software, were created by Lee Daniel Crocker, who tested the methods on many images during the creation of the format; the choice of filter is a component of file size optimization, as discussed below.  If interlacing is used, each stage of the interlacing is filtered separately, meaning that the image can be progressively rendered as each stage is received; however, interlacing generally makes compression less effective.

Interlacing.

PNG offers an optional 2-dimensional, 7-pass interlacing scheme—the Adam7 algorithm. This is more sophisticated than GIF's 1-dimensional, 4-pass scheme, and allows a clearer low-resolution image to be visible earlier in the transfer, particularly if interpolation algorithms such as bicubic interpolation are used.  However, the 7-pass scheme tends to reduce the data's compressibility more than simpler schemes.

Animation.

PNG itself does not support animation. MNG is an extension to PNG that does; it was designed by members of the PNG Group. MNG shares PNG's basic structure and chunks, but it is significantly more complex and has a different file signature, which automatically renders it incompatible with standard PNG decoders.  The complexity of MNG led to the proposal of APNG by developers of the Mozilla Foundation. It is based on PNG, supports animation and is simpler than MNG. APNG offers fallback to single-image display for PNG decoders that do not support APNG. However, neither of these formats is currently widely supported. APNG is supported in Firefox 3.0 and up, Pale Moon (all versions), and Opera 9.5, but since Opera changed its layout engine to Blink, support was dropped. The latest version of Safari on iOS 8 and Safari 8 for OS X Yosemite support APNG. Chromium 59.0 has added APNG support, then Opera added back in 46.0. The PNG Group decided in April 2007 not to embrace APNG. Several alternatives were under discussion, ANG, aNIM/mPNG, "PNG in GIF" and its subset "RGBA in GIF".

Examples.

Displayed in the fashion of hex editors, with on the left side byte values shown in hex format, and on the right side their equivalent characters from ISO-8859-1 with unrecognized and control characters replaced with periods. Additionally the PNG signature and individual chunks are marked with colors. Note they are easy to identify because of their human readable type names (in this example PNG, IHDR, IDAT, and IEND).

Advantages.

Reasons for which we use this International Standard are:

Comparison with other file formats.

Graphics Interchange Format (GIF).

PNG images are less widely supported by older browsers. In particular, IE6 has limited support for PNG.

JPEG.

The JPEG (Joint Photographic Experts Group) format can produce a smaller file than PNG for photographic (and photo-like) images, since JPEG uses a lossy encoding method specifically designed for photographic image data, which is typically dominated by soft, low-contrast transitions, and an amount of noise or similar irregular structures. Using PNG instead of a high-quality JPEG for such images would result in a large increase in filesize with negligible gain in quality. In comparison, when storing images that contain text, line art, or graphics – images with sharp transitions and large areas of solid color – the PNG format can compress image data more than JPEG can. Additionally, PNG is lossless, while JPEG produces visual artifacts around high-contrast areas. (Such artifacts depend on the settings used in the JPG compression; they can be quite noticeable when a low-quality [high-compression] setting is used.) Where an image contains both sharp transitions and photographic parts, a choice must be made between the two effects. JPEG does not support transparency.  JPEG's lossy compression also suffers from generation loss, where repeatedly decoding and re-encoding an image to save it again causes a loss of information each time, degrading the image. This does not happen with repeated viewing or copying, but only if the file is edited and saved over again. Because PNG is lossless, it is suitable for storing images to be edited. While PNG is reasonably efficient when compressing photographic images, there are lossless compression formats designed specifically for photographic images, lossless WebP and Adobe DNG (digital negative) for example. However these formats are either not widely supported, or are proprietary. An image can be stored losslessly and converted to JPEG format only for distribution, so that there is no generation loss.  While the PNG specification does not explicitly include a standard for embedding Exif image data from sources such as digital cameras, the preferred method for embedding EXIF data in a PNG is to use the non-critical ancillary chunk label codice_13.  Early web browsers did not support PNG images; JPEG and GIF were the main image formats. JPEG was commonly used when exporting images containing gradients for web pages, because of GIF's limited color depth. However, JPEG compression causes a gradient to blur slightly. A PNG format reproduces a gradient as accurately as possible for a given bit depth, while keeping the file size small. PNG became the optimal choice for small gradient images as web browser support for the format improved. No images at all are needed to display gradients in modern browsers, as gradients can be created using CSS.

JPEG-LS.

JPEG-LS is an image format by the Joint Photographic Experts Group, though far less widely known and supported than the other lossy JPEG format discussed above. It is directly comparable with PNG, and has a standard set of test images. On the Waterloo Repertoire ColorSet, a standard set of test images (unrelated to the JPEG-LS conformance test set), JPEG-LS generally performs better than PNG, by 10–15%, but on some images PNG performs substantially better, on the order of 50–75%. Thus, if both of these formats are options and file size is an important criterion, they should both be considered, depending on the image.

TIFF.

Tagged Image File Format (TIFF) is a format that incorporates an extremely wide range of options. While this makes TIFF useful as a generic format for interchange between professional image editing applications, it makes adding support for it to applications a much bigger task and so it has little support in applications not concerned with image manipulation (such as web browsers). The high level of extensibility also means that most applications provide only a subset of possible features, potentially creating user confusion and compatibility issues.  The most common general-purpose, lossless compression algorithm used with TIFF is Lempel–Ziv–Welch (LZW). This compression technique, also used in GIF, was covered by patents until 2003. TIFF also supports the compression algorithm PNG uses (i.e. Compression Tag 0008 'Adobe-style') with medium usage and support by applications. TIFF also offers special-purpose lossless compression algorithms like CCITT Group IV, which can compress bilevel images (e.g., faxes or black-and-white text) better than PNG's compression algorithm.  PNG supports non-premultiplied alpha only whereas TIFF also supports "associated" (premultiplied) alpha.

Software support.

The official reference implementation of the PNG format is the programming library "libpng". It is published as free software under the terms of a permissive free software license. Therefore, it is usually found as an important system library in free operating systems.

Bitmap graphics editor support for PNG.

The PNG format is widely supported by graphics programs, including Adobe Photoshop, Corel's Photo-Paint and Paint Shop Pro, the GIMP, GraphicConverter, Helicon Filter, ImageMagick, Inkscape, IrfanView, Pixel image editor, Paint.NET and Xara Photo & Graphic Designer and many others. Some programs bundled with popular operating systems which support PNG include Microsoft's Paint and Apple's Photos/iPhoto and Preview, with the GIMP also often being bundled with popular Linux distributions.  Adobe Fireworks (formerly by Macromedia) uses PNG as its native file format, allowing other image editors and preview utilities to view the flattened image. However, Fireworks by default also stores metadata for layers, animation, vector data, text and effects. Such files should not be distributed directly. Fireworks can instead export the image as an optimized PNG without the extra metadata for use on web pages, etc.

Web browser support for PNG.

PNG support first appeared in Internet Explorer 4.0b1 (32-bit only for NT) and in Netscape 4.04.  Despite calls by the Free Software Foundation and the World Wide Web Consortium (W3C), tools such as gif2png, and campaigns such as Burn All GIFs, PNG adoption on websites was fairly slow due to late and buggy support in Internet Explorer, particularly regarding transparency.  PNG compatible browsers include: Apple Safari, Google Chrome, Mozilla Firefox, Opera, Camino, Internet Explorer 7 (still numerous issues), Internet Explorer 8 (still some issues), Internet Explorer 9 and many others. For the complete comparison, see Comparison of web browsers (Image format support).  Especially versions of Internet Explorer (Windows) below 9.0 have numerous problems which prevent it from correctly rendering PNG images.

Operating system support for PNG icons.

PNG icons have been supported in most distributions of Linux since at least 1999, in desktop environments such as GNOME. In 2006, Microsoft Windows support for PNG icons was introduced in Windows Vista. PNG icons are supported in AmigaOS 4, AROS, macOS, iOS and MorphOS as well. In addition, Android makes extensive use of PNGs.

File size and optimization software.

PNG file size can vary significantly depending on how it is encoded and compressed; this is discussed and a number of tips are given in "PNG: The Definitive Guide."

Compared to GIF.

Compared to GIF files, a PNG file with the same information (256 colors, no ancillary chunks/metadata), compressed by an effective compressor is normally smaller than a GIF image. Depending on the file and the compressor, PNG may range from somewhat smaller (10%) to significantly smaller (50%) to somewhat larger (5%), but is rarely significantly larger for large images. This is attributed to the performance of PNG's DEFLATE compared to GIF's LZW, and because the added precompression layer of PNG's predictive filters take account of the 2-dimensional image structure to further compress files; as filtered data encodes differences between pixels, they will tend to cluster closer to 0, rather than being spread across all possible values, and thus be more easily compressed by DEFLATE. However, some versions of Adobe Photoshop, CorelDRAW and MS Paint provide poor PNG compression, creating the impression that GIF is more efficient.

File size factors.

PNG files vary in size due to a number of factors: There is thus a filesize trade-off between high color depth, maximal metadata (including color space information, together with information that does not affect display), interlacing, and speed of compression, which all yield large files, with lower color depth, fewer or no ancillary chunks, no interlacing, and tuned but computationally intensive filtering and compression. For different purposes, different trade-offs are chosen: a maximal file may be best for archiving and editing, while a stripped down file may be best for use on a website, and similarly fast but poor compression is preferred when repeatedly editing and saving a file, while slow but high compression is preferred when a file is stable: when archiving or posting. Interlacing is a trade-off: it dramatically speeds up early rendering of large files (improves latency), but may increase file size (decrease throughput) for little gain, particularly for small files.

Lossy PNG compression.

Although PNG is a lossless format, PNG encoders can preprocess image data in a lossy fashion to improve PNG compression. For example, quantizing a truecolor PNG to 256 colors allows the indexed color type to be used for a likely reduction in file size.

Image editing software.

Some programs are more efficient than others when saving PNG files, this relates to implementation of the PNG compression used by the program.  Many graphics programs (such as Apple's Preview software) save PNGs with large amounts of metadata and color-correction data that are generally unnecessary for Web viewing. Unoptimized PNG files from Adobe Fireworks are also notorious for this since they contain options to make the image editable in supported editors. Also CorelDRAW (at least version 11) sometimes produces PNGs which cannot be opened by Internet Explorer (versions 6–8).  Adobe Photoshop's performance on PNG files has improved in the CS Suite when using the Save For Web feature (which also allows explicit PNG/8 use).  Adobe's Fireworks saves larger PNG files than many programs by default. This stems from the mechanics of its "Save" format: the images produced by Fireworks' save function include large, private chunks, containing complete layer and vector information. This allows further lossless editing. When saved with the "Export" option, Fireworks' PNGs are competitive with those produced by other image editors, but are no longer editable as anything but flattened bitmaps. Fireworks is unable to save size-optimized vector-editable PNGs.  Other notable examples of poor PNG compressors include:  Poor compression increases the PNG file size but does not affect the image quality or compatibility of the file with other programs.  When the color depth of a truecolor image is reduced to an 8-bit palette (as in GIF), the resulting image data is typically much smaller. Thus a truecolor PNG is typically larger than a color-reduced GIF, although PNG could store the color-reduced version as a palettized file of comparable size. Conversely, some tools, when saving images as PNGs, automatically save them as truecolor, even if the original data use only 8-bit color, thus bloating the file unnecessarily. Both factors can lead to the misconception that PNG files are larger than equivalent GIF files.

Optimizing tools.

Various tools are available for optimizing PNG files; they do this by:

Tool list.

A simple comparison of their features is listed below. Before zopflipng was available, a good way in practice to perform a png optimization is to use a combination of 2 tools in sequence for optimal compression: one which optimizes filters (and removes ancillary chunks), and one which optimizes DEFLATE. Although pngout offers both, only one type of filter can be specified in a single run, therefore it can be used with a wrapper tool or in combination with optipng or pngcrush, acting as a re-deflater, like advdef.

Ancillary chunk removal.

For removing ancillary chunks, most PNG optimization tools have the ability to remove all color correction data from PNG files (gamma, white balance, ICC color profile, standard RGB color profile). This often results in much smaller file sizes. For example, the following command line options achieve this with pngcrush:  codice_28  Ancillary chunks can also be losslessly removed using the free Win32 program PNGExtra.

Filter optimization.

OptiPNG, pngcrush, pngout, and zopflipng all offer options applying one of the filter types 0–4 globally (using the same filter type for all lines) or with a "pseudo filter" (numbered 5), which for each line chooses one of the filter types 0–4 using an adaptive algorithm. Zopflipng offers 3 different adaptive method, including a brute-force search that attempts to optimize the filtering.  pngout and zopflipng provide an option to preserve/reuse the line-by-line filter set present in the input image.  OptiPNG, pngcrush and zopflipng provide options to try different filter strategies in a single run and choose the best. The freeware command line version of pngout doesn't offer this, but the commercial version, pngoutwin, does.

DEFLATE optimization.

zopfli and the LZMA SDK employ DEFLATE implementations that produce higher compression ratios than the zlib reference implementation at the cost of performance. AdvanceCOMP's codice_29 and codice_30 can use either of these libraries to re-compress PNG files. Additionally, PNGOUT contains its own proprietary DEFLATE implementation.  advpng doesn't have an option to apply filters and always uses filter 0 globally (leaving the image data unfiltered); therefore it should not be used where the image benefits significantly from filtering. By contrast, advdef from the same package doesn't deal with PNG structure and acts only as a re-deflater, retaining any existing filter settings.

Icon optimization.

Since icons intended for Windows Vista and later versions may contain PNG subimages, the optimizations can be applied to them as well. At least one icon editor, Pixelformer, is able to perform a special optimization pass while saving ICO files, thereby reducing their sizes. FileOptimizer (mentioned above) can also handle ICO files.  Icons for macOS may also contain PNG subimages, yet there isn't such tool available.

Portable Network Graphics (PNG, officially pronounced, more commonly pronounced ) is a raster-graphics file format that supports lossless data compression. PNG was developed as an improved, non-patented replacement for Graphics Interchange Format (GIF).

便携式网络图形(英语:Portable Network Graphics,PNG)是一种支持无损压缩的位图图形格式,支持索引、灰度、RGB三种颜色方案以及Alpha通道等特性。PNG的开发目标是改善并取代GIF作为适合网络传输的格式而不需专利许可,所以被广泛应用于互联网及其他方面上。


Geographic reach.

PAL was adopted by most European countries, by all African countries that had never been a Belgian or French colony, by Argentina, Brazil, Paraguay, and Uruguay, by most of Asia, and by Oceania.  There were some countries in those regions that did not adopt PAL. They were France, countries that once were part of the Soviet Union, Japan, Myanmar, the Philippines, and Taiwan.

History.

The Phase Alternating Line (PAL) was discovered in 1938 by the German Reichs-Rundfunk-Gesellschaft (RRG) Research and Development Division to resolve the conflicts between companies over the introduction of a nationwide analog television system in Nazi Germany.  In the 1950s, the Western European countries began plans to introduce colour television, and were faced with the problem that the NTSC standard demonstrated several weaknesses, including colour tone shifting under poor transmission conditions, which became a major issue considering Europe's geographical and weather-related particularities. To overcome NTSC's shortcomings, alternative standards were devised, resulting in the development of the PAL and SECAM standards. The goal was to provide a colour TV standard for the European picture frequency of 50 fields per second (50 hertz), and finding a way to eliminate the problems with NTSC.  PAL was developed by Walter Bruch at Telefunken in Hanover, West Germany, with important input from Dr. Kruse and. The format was patented by Telefunken in 1962, citing Bruch as inventor, and unveiled to members of the European Broadcasting Union (EBU) on 3 January 1963. When asked why the system was named "PAL" and not "Bruch" the inventor answered that a "Bruch system" would probably not have sold very well ("Bruch" is the German word for "breakage"). The first broadcasts began in the United Kingdom in June 1967, followed by West Germany later that year. The one BBC channel initially using the broadcast standard was BBC2, which had been the first UK TV service to introduce "625-lines" in 1964. Telefunken PALcolour 708T was the first PAL commercial TV set. It was followed by Loewe-Farbfernseher S 920 & F 900.  Telefunken was later bought by the French electronics manufacturer Thomson. Thomson also bought the "Compagnie Générale de Télévision" where Henri de France developed SECAM, the first European Standard for colour television. Thomson, now called Technicolour SA, also owns the RCA brand and licences it to other companies; Radio Corporation of America, the originator of that brand, created the NTSC colour TV standard before Thomson became involved.  The term PAL was often used informally and somewhat imprecisely to refer to the 625-line/50 Hz (576i) television system in general, to differentiate from the 525-line/60 Hz (480i) system generally used with NTSC. Accordingly, DVDs were labelled as PAL or NTSC (referring to the line count and frame rate) even though technically the discs carry neither PAL nor NTSC encoded signal. CCIR 625/50 and EIA 525/60 are the proper names for these (line count and field rate) standards; PAL and NTSC on the other hand are methods of encoding colour information in the signal.

Colour encoding.

Both the PAL and the NTSC system use a quadrature amplitude modulated subcarrier carrying the chrominance information added to the luminance video signal to form a composite video baseband signal. The frequency of this subcarrier is 4.43361875 MHz for PAL and NTSC 4.43, compared to 3.579545 MHz for NTSC 3.58. The SECAM system, on the other hand, uses a frequency modulation scheme on its two line alternate colour subcarriers 4.25000 and 4.40625 MHz.  The name "Phase Alternating Line" describes the way that the phase of part of the colour information on the video signal is reversed with each line, which automatically corrects phase errors in the transmission of the signal by cancelling them out, at the expense of vertical frame colour resolution. Lines where the colour phase is reversed compared to NTSC are often called PAL or phase-alternation lines, which justifies one of the expansions of the acronym, while the other lines are called NTSC lines. Early PAL receivers relied on the human eye to do that cancelling; however, this resulted in a comb-like effect known as Hanover bars on larger phase errors. Thus, most receivers now use a chrominance analogue delay line, which stores the received colour information on each line of display; an average of the colour information from the previous line and the current line is then used to drive the picture tube. The effect is that phase errors result in saturation changes, which are less objectionable than the equivalent hue changes of NTSC. A minor drawback is that the vertical colour resolution is poorer than the NTSC system's, but since the human eye also has a colour resolution that is much lower than its brightness resolution, this effect is not visible. In any case, NTSC, PAL, and SECAM all have chrominance bandwidth (horizontal colour detail) reduced greatly compared to the luminance signal.  The 4.43361875 MHz frequency of the colour carrier is a result of 283.75 colour clock cycles per line plus a 25 Hz offset to avoid interferences. Since the line frequency (number of lines per second) is 15625 Hz (625 lines × 50 Hz ÷ 2), the colour carrier frequency calculates as follows: 4.43361875 MHz = 283.75 × 15625 Hz + 25 Hz. The frequency 50 Hz is the optional refresh frequency of the monitor to be able to create an illusion of motion, while 625 lines means the vertical lines or resolution that the PAL system supports. The original colour carrier is required by the colour decoder to recreate the colour difference signals. Since the carrier is not transmitted with the video information it has to be generated locally in the receiver. In order that the phase of this locally generated signal can match the transmitted information, a 10 cycle burst of colour subcarrier is added to the video signal shortly after the line sync pulse, but before the picture information, during the so-called back porch. This colour burst is not actually in phase with the original colour subcarrier, but leads it by 45 degrees on the odd lines and lags it by 45 degrees on the even lines. This swinging burst enables the colour decoder circuitry to distinguish the phase of the R-Y vector which reverses every line.

PAL vs. NTSC.

PAL usually has 576 visible lines compared with 486 lines with NTSC, meaning that PAL has a 20% higher resolution, in fact it even has a higher resolution than Enhanced Definition standard (854x486). Most TV output for PAL and NTSC use interlaced frames meaning that even lines update on one field and odd lines update on the next field. Interlacing frames gives a smoother motion with half the frame rate. NTSC is used with a frame rate of 60i or 30p whereas PAL generally uses 50i or 25p; both use a high enough frame rate to give the illusion of fluid motion. This is due to the fact that NTSC is generally used in countries with a utility frequency of 60 Hz and PAL in countries with 50 Hz, although there are many exceptions. Both PAL and NTSC have a higher frame rate than film which uses 24 frames per second. PAL has a closer frame rate to that of film, so most films are sped up 4% to play on PAL systems, shortening the runtime of the film and, without adjustment, slightly raising the pitch of the audio track. Film conversions for NTSC instead use 3:2 pull down to spread the 24 frames of film across 60 interlaced fields. This maintains the runtime of the film and preserves the original audio, but may cause worse interlacing artefacts during fast motion.  NTSC receivers have a tint control to perform colour correction manually. If this is not adjusted correctly, the colours may be faulty. The PAL standard automatically cancels hue errors by phase reversal, so a tint control is unnecessary yet Saturation control can be more useful. Chrominance phase errors in the PAL system are cancelled out using a 1H delay line resulting in lower saturation, which is much less noticeable to the eye than NTSC hue errors.  However, the alternation of colour information—Hanover bars—can lead to picture grain on pictures with extreme phase errors even in PAL systems, if decoder circuits are misaligned or use the simplified decoders of early designs (typically to overcome royalty restrictions). In most cases such extreme phase shifts do not occur. This effect will usually be observed when the transmission path is poor, typically in built up areas or where the terrain is unfavourable. The effect is more noticeable on UHF than VHF signals as VHF signals tend to be more robust.  In the early 1970s some Japanese set manufacturers developed decoding systems to avoid paying royalties to Telefunken. The Telefunken licence covered any decoding method that relied on the alternating subcarrier phase to reduce phase errors. This included very basic PAL decoders that relied on the human eye to average out the odd/even line phase errors. One solution was to use a 1H analogue delay line to allow decoding of only the odd or even lines. For example, the chrominance on odd lines would be switched directly through to the decoder and also be stored in the delay line. Then, on even lines, the stored odd line would be decoded again. This method effectively converted PAL to NTSC. Such systems suffered hue errors and other problems inherent in NTSC and required the addition of a manual hue control.  PAL and NTSC have slightly divergent colour spaces, but the colour decoder differences here are ignored.

PAL vs. SECAM.

The SECAM patents predate those of PAL by several years (1956 vs. 1962). Its creator, Henri de France, in search of a response to known NTSC hue problems, came up with ideas that were to become fundamental to both European systems, namely: 1) colour information on two successive TV lines is very similar and vertical resolution can be halved without serious impact on perceived visual quality 2) more robust colour transmission can be achieved by spreading information on two TV lines instead of just one 3) information from the two TV lines can be recombined using a delay line.  SECAM applies those principles by transmitting alternately only one of the U and V components on each TV line, and getting the other from the delay line. QAM is not required, and frequency modulation of the subcarrier is used instead for additional robustness (sequential transmission of U and V was to be reused much later in Europe's last "analog" video systems: the MAC standards).  SECAM is free of both hue and saturation errors. It is not sensitive to phase shifts between the colour burst and the chrominance signal, and for this reason was sometimes used in early attempts at colour video recording, where tape speed fluctuations could get the other systems into trouble. In the receiver, it did not require a quartz crystal (which was an expensive component at the time) and generally could do with lower accuracy delay lines and components.  SECAM transmissions are more robust over longer distances than NTSC or PAL. However, owing to their FM nature, the colour signal remains present, although at reduced amplitude, even in monochrome portions of the image, thus being subject to stronger cross colour.  One serious drawback for studio work is that the addition of two SECAM signals does not yield valid colour information, due to its use of frequency modulation. It was necessary to demodulate the FM and handle it as AM for proper mixing, before finally remodulating as FM, at the cost of some added complexity and signal degradation. In its later years, this was no longer a problem, due to the wider use of component and digital equipment.  PAL can work without a delay line, but this configuration, sometimes referred to as "poor man's PAL", could not match SECAM in terms of picture quality. To compete with it at the same level, it had to make use of the main ideas outlined above, and as a consequence PAL had to pay licence fees to SECAM. Over the years, this contributed significantly to the estimated 500 million francs gathered by the SECAM patents (for an initial 100 million francs invested in research).  Hence, PAL could be considered as a hybrid system, with its signal structure closer to NTSC, but its decoding borrowing much from SECAM.  There were initial specifications to use colour with the French 819 line format (system E). However, "SECAM E" only ever existed in development phases. Actual deployment used the 625 line format. This made for easy interchange and conversion between PAL and SECAM in Europe. Conversion was often not even needed, as more and more receivers and VCRs became compliant with both standards, helped in this by the common decoding steps and components. When the SCART plug became standard, it could take RGB as an input, effectively bypassing all the colour coding formats' peculiarities.  When it comes to home VCRs, all video standards use what is called "colour under" format. Colour is extracted from the high frequencies of the video spectrum, and moved to the lower part of the spectrum available from tape. Luminance then uses what remains of it, above the colour frequency range. This is usually done by heterodyning for PAL (as well as NTSC). But the FM nature of colour in SECAM allows for a cheaper trick: division by 4 of the subcarrier frequency (and multiplication on replay). This became the standard for SECAM VHS recording in France. Most other countries kept using the same heterodyning process as for PAL or NTSC and this is known as MESECAM recording (as it was more convenient for some Middle East countries that used both PAL and SECAM broadcasts). Another difference in colour management is related to the proximity of successive tracks on the tape, which is a cause for chroma crosstalk in PAL. A cyclic sequence of 90° chroma phase shifts from one line to the next is used to overcome this problem. This is not needed in SECAM, as FM provides sufficient protection.  Regarding early (analogue) videodiscs, the established Laserdisc standard supported only NTSC and PAL. However, a different optical disc format, the Thomson transmissive optical disc made a brief appearance on the market. At some point, it used a modified SECAM signal (single FM subcarrier at 3.6 MHz). The media's flexible and transmissive material allowed for direct access to both sides without flipping the disc, a concept that reappeared in multi-layered DVDs about fifteen years later.

PAL signal details.

For PAL-B/G the signal has these characteristics.  After 0.9 μs a colourburst of cycles is sent. Most rise/fall times are in range. Amplitude is 100% for white level, 30% for black, and 0% for sync. The CVBS electrical amplitude is Vpp and impedance of 75 Ω.  The vertical timings are:  As PAL is interlaced, every two fields are summed to make a complete picture frame.  Luminance, formula_1, is derived from red, green, and blue (formula_2) signals:  formula_4 and formula_5 are used to transmit chrominance. Each has a typical bandwidth of 1.3 MHz.  Composite PAL signal formula_8timing where formula_9.  Subcarrier frequency formula_10 is 4.43361875 MHz (±5 Hz) for PAL-B/D/G/H/I/N.

PAL broadcast systems.

PAL-B/G/D/K/I.

Many countries have turned off analogue transmissions, so the following does not apply anymore, except for using devices which output broadcast signals, such as video recorders.  The majority of countries using or having used PAL have television standards with 625 lines and 50 fields per second, differences concern the audio carrier frequency and channel bandwidths. The variants are:  Systems B and G are similar. System B specifies 7 MHz channel bandwidth, while System G specifies 8 MHz channel bandwidth. Australia used System B for VHF and UHF channels. Similarly, Systems D and K are similar except for the bands they use: System D is only used on VHF (except in mainland China), while System K is only used on UHF. Although System I is used on both bands, it has only been used on UHF in the United Kingdom.

PAL-M (Brazil).

In Brazil, PAL is used in conjunction with the 525 line, 59.94 field/s system M, using (very nearly) the NTSC colour subcarrier frequency. Exact colour subcarrier frequency of PAL-M is 3.575611 MHz. Almost all other countries using system M use NTSC.  The PAL colour system (either baseband or with any RF system, with the normal 4.43 MHz subcarrier unlike PAL-M) can also be applied to an NTSC-like 525-line (480i) picture to form what is often known as "PAL-60" (sometimes "PAL-60/525", "Quasi-PAL" or "Pseudo PAL"). PAL-M (a broadcast standard) however should not be confused with "PAL-60" (a video playback system—see below).

PAL-N (Argentina, Paraguay and Uruguay).

In Argentina, Paraguay and Uruguay the PAL-N variant is used. It employs the 625 line/50 field per second waveform of PAL-B/G, D/K, H, and I, but on a 6 MHz channel with a chrominance subcarrier frequency of 3.582056 MHz (917/4*H) very similar to NTSC (910/4*H).  PAL-N uses the YDbDr colour space.  VHS tapes recorded from a PAL-N or a PAL-B/G, D/K, H, or I broadcast are indistinguishable because the downconverted subcarrier on the tape is the same. A VHS recorded off TV (or released) in Europe will play in colour on any PAL-N VCR and PAL-N TV in Argentina, Paraguay and Uruguay. Likewise, any tape recorded in Argentina, Paraguay or Uruguay off a PAL-N TV broadcast can be sent to anyone in European countries that use PAL (and Australia/New Zealand, etc.) and it will display in colour. This will also play back successfully in Russia and other SECAM countries, as the USSR mandated PAL compatibility in 1985—this has proved to be very convenient for video collectors.  People in Argentina, Paraguay and Uruguay usually own TV sets that also display NTSC-M, in addition to PAL-N. Direct TV also conveniently broadcasts in NTSC-M for North, Central, and South America. Most DVD players sold in Argentina, Paraguay and Uruguay also play PAL discs—however, this is usually output in the European variant (colour subcarrier frequency 4.433618 MHz), so people who own a TV set which only works in PAL-N (plus NTSC-M in most cases) will have to watch those PAL DVD imports in black and white (unless the TV supports RGB SCART) as the colour subcarrier frequency in the TV set is the PAL-N variation, 3.582056 MHz.  In the case that a VHS or DVD player works in PAL (and not in PAL-N) and the TV set works in PAL-N (and not in PAL), there are two options:  Some DVD players (usually lesser known brands) include an internal transcoder and the signal can be output in NTSC-M, with some video quality loss due to the system's conversion from a 625/50 PAL DVD to the NTSC-M 525/60 output format. A few DVD players sold in Argentina, Paraguay and Uruguay also allow a signal output of NTSC-M, PAL, or PAL-N. In that case, a PAL disc (imported from Europe) can be played back on a PAL-N TV because there are no field/line conversions, quality is generally excellent.  Extended features of the PAL specification, such as Teletext, are implemented quite differently in PAL-N. PAL-N supports a modified 608 closed captioning format that is designed to ease compatibility with NTSC originated content carried on line 18, and a modified teletext format that can occupy several lines.  Some special VHS video recorders are available which can allow viewers the flexibility of enjoying PAL-N recordings using a standard PAL ( 625/50 Hz ) colour TV, or even through multi-system TV sets. Video recorders like Panasonic NV-W1E (AG-W1 for the US), AG-W2, AG-W3, NV-J700AM, Aiwa HV-M110S, HV-M1U, Samsung SV-4000W and SV-7000W feature a digital TV system conversion circuitry.

PAL-L.

The PAL L (Phase Alternating Line with L-sound system) standard uses the same video system as PAL-B/G/H (625 lines, 50 Hz field rate, 15.625 kHz line rate), but with 6 MHz video bandwidth rather than 5.5 MHz. This requires the audio subcarrier to be moved to 6.5 MHz. An 8 MHz channel spacing is used for PAL-L.

System A.

The BBC tested their pre-war 405 line monochrome system with all three colour standards including PAL, before the decision was made to abandon 405 and transmit colour on 625/System I only.

PAL interoperability.

The PAL colour system is usually used with a video format that has 625 lines per frame (576 visible lines, the rest being used for other information such as sync data and captioning) and a refresh rate of 50 interlaced fields per second (compatible with 25 full frames per second), such systems being B, G, H, I, and N (see broadcast television systems for the technical details of each format).  This ensures video interoperability. However, as some of these standards (B/G/H, I and D/K) use different sound carriers (5.5 MHz, 6.0 MHz 6.5 MHz respectively), it may result in a video image without audio when viewing a signal broadcast over the air or cable. Some countries in Eastern Europe which formerly used SECAM with systems D and K have switched to PAL while leaving other aspects of their video system the same, resulting in the different sound carrier. Instead, other European countries have changed completely from SECAM-D/K to PAL-B/G.  The PAL-N system has a different sound carrier, and also a different colour subcarrier, and decoding on incompatible PAL systems results in a black-and-white image without sound. The PAL-M system has a different sound carrier and a different colour subcarrier, and does not use 625 lines or 50 frames/second. This would result in no video or audio at all when viewing a European signal.

Multisystem PAL support and "PAL 60".

Recently manufactured PAL television receivers can typically decode all of these systems except, in some cases, PAL-M and PAL-N. Many of receivers can also receive Eastern European and Middle Eastern SECAM, though rarely French-broadcast SECAM (because France used a quasi-unique positive video modulation, system L) unless they are manufactured for the French market. They will correctly display plain CVBS or S-video SECAM signals. Many can also accept baseband NTSC-M, such as from a VCR or game console, and RF modulated NTSC with a PAL standard audio subcarrier (i.e., from a modulator), though not usually broadcast NTSC (as its 4.5 MHz audio subcarrier is not supported). Many sets also support NTSC with a 4.43 MHz subcarrier.  Many 1990s-onwards videocassette recorders sold in Europe can play back NTSC tapes. When operating in this mode most of them do not output a true (625/25) PAL signal, but rather a hybrid consisting of the original NTSC line standard (525/30), but with colour converted to PAL 4.43 MHz—this is known as "PAL 60" (also "quasi-PAL" or "pseudo-PAL") with "60" standing for 60 Hz (for 525/30), instead of 50 Hz (for 625/25). Some video game consoles also output a signal in this mode. Notably, the PlayStation 2 did not actually offer a true PAL 60 mode; while many PlayStation 2 games did offer a "PAL 60" mode as an option, the console would in fact generate an NTSC signal during 60 Hz operation. Most newer television sets can display such a signal correctly, but some will only do so (if at all) in black and white and/or with flickering/foldover at the bottom of the picture, or picture rolling (however, many old TV sets can display the picture properly by means of adjusting the V-Hold and V-Height knobs—assuming they have them). Some TV tuner cards or video capture cards will support this mode (although software/driver modification can be required and the manufacturers' specs may be unclear). A "PAL 60" signal is similar to an NTSC (525/30) signal, but with the usual PAL chrominance subcarrier at 4.43 MHz (instead of 3.58 as with NTSC and South American PAL variants) and with the PAL-specific phase alternation of the red colour difference signal between the lines.  Some DVD players offer a choice of PAL vs NTSC output for NTSC discs.

Countries and territories using PAL.

Below countries and territories currently use or once used the PAL system. Many of these have converted or are currently converting PAL to DVB-T (most countries), DVB-T2 (most countries), DTMB (China, Hong Kong and Macau) or ISDB (Sri Lanka, Maldives, Botswana and part of South America).

Countries that have formerly used PAL.

The following countries no longer use PAL for terrestrial broadcasts, and are in process of converting from PAL (cable) to DVB-T.

Digital PAL/PAL 2.0.

The PAL system is analog. There was an attempt to manufacture equipment that digitizes the PAL signal in the 1980s, but it was not commercially successful. Digital devices such as digital television, modern game consoles, computers, etc., use color component systems where the R, G, and B signals are transmitted over three different cables, or Y (luminance), RY, and BY (difference from color). In these cases only the number of total horizontal lines is taken into account—625 in digital PAL and 525 in NTSC—and the frame rate—25 frames/s in PAL Digital and 30 frames/s in digital NTSC. Systems using the MPEG-2 standard, such as DVD and satellite television, cable television, or digital terrestrial television (DTT) have practically nothing to do with PAL.</div

Phase Alternating Line (PAL) is a colour encoding system for analogue television used in broadcast television systems in most countries broadcasting at 625-line / 50 field (25 frame) per second (576i). It was one of three major analogue colour television standards, the others being NTSC and SECAM.

PAL制式是电视广播中色彩调频的一种方法,全名为逐行倒相(Phase Alternating Line)。除了北美、东亚部分地区使用NTSC制式,中东、法国及东欧采用SECAM制式以外,世界上大部分地区都是采用PAL制式。PAL于1963年由德国人沃尔特·布鲁赫提出,当时他为德律风根(Telefunken)工作。


Types of phase transition.

Examples of phase transitions include:  Phase transitions occur when the thermodynamic free energy of a system is non-analytic for some choice of thermodynamic variables (cf. phases). This condition generally stems from the interactions of a large number of particles in a system, and does not appear in systems that are too small. It is important to note that phase transitions can occur and are defined for non-thermodynamic systems, where temperature is not a parameter. Examples include: quantum phase transitions, dynamic phase transitions, and topological (structural) phase transitions. In these types of systems other parameters take the place of temperature. For instance, connection probability replaces temperature for percolating networks.  At the phase transition point (for instance, boiling point) the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred.  It is sometimes possible to change the state of a system diabatically (as opposed to adiabatically) in such a way that it can be brought past a phase transition point without undergoing a phase transition. The resulting state is metastable, i.e., less stable than the phase to which the transition would have occurred, but not unstable either. This occurs in superheating, supercooling, and supersaturation, for example.

Classifications.

Ehrenfest classification.

Paul Ehrenfest classified phase transitions based on the behavior of the thermodynamic free energy as a function of other thermodynamic variables. Under this scheme, phase transitions were labeled by the lowest derivative of the free energy that is discontinuous at the transition. "First-order phase transitions" exhibit a discontinuity in the first derivative of the free energy with respect to some thermodynamic variable. The various solid/liquid/gas transitions are classified as first-order transitions because they involve a discontinuous change in density, which is the (inverse of the) first derivative of the free energy with respect to pressure. "Second-order phase transitions" are continuous in the first derivative (the order parameter, which is the first derivative of the free energy with respect to the external field, is continuous across the transition) but exhibit discontinuity in a second derivative of the free energy. These include the ferromagnetic phase transition in materials such as iron, where the magnetization, which is the first derivative of the free energy with respect to the applied magnetic field strength, increases continuously from zero as the temperature is lowered below the Curie temperature. The magnetic susceptibility, the second derivative of the free energy with the field, changes discontinuously. Under the Ehrenfest classification scheme, there could in principle be third, fourth, and higher-order phase transitions.  The Ehrenfest classification implicitly allows for continuous phase transformations, where the bonding character of a material changes, but there is no discontinuity in any free energy derivative. An example of this occurs at the supercritical liquid–gas boundaries.

Modern classifications.

In the modern classification scheme, phase transitions are divided into two broad categories, named similarly to the Ehrenfest classes:  First-order phase transitions are those that involve a latent heat. During such a transition, a system either absorbs or releases a fixed (and typically large) amount of energy per volume. During this process, the temperature of the system will stay constant as heat is added: the system is in a "mixed-phase regime" in which some parts of the system have completed the transition and others have not. Familiar examples are the melting of ice or the boiling of water (the water does not instantly turn into vapor, but forms a turbulent mixture of liquid water and vapor bubbles). Imry and Wortis showed that quenched disorder can broaden a first-order transition. That is, the transformation is completed over a finite range of temperatures, but phenomena like supercooling and superheating survive and hysteresis is observed on thermal cycling.  Second-order phase transitions are also called ""continuous phase transitions"". They are characterized by a divergent susceptibility, an infinite correlation length, and a power law decay of correlations near criticality. Examples of second-order phase transitions are the ferromagnetic transition, superconducting transition (for a Type-I superconductor the phase transition is second-order at zero external field and for a Type-II superconductor the phase transition is second-order for both normal-state—mixed-state and mixed-state—superconducting-state transitions) and the superfluid transition. In contrast to viscosity, thermal expansion and heat capacity of amorphous materials show a relatively sudden change at the glass transition temperature which enables accurate detection using differential scanning calorimetry measurements. Lev Landau gave a phenomenological theory of second-order phase transitions.  Apart from isolated, simple phase transitions, there exist transition lines as well as multicritical points, when varying external parameters like the magnetic field or composition.  Several transitions are known as "infinite-order phase transitions". They are continuous but break no symmetries. The most famous example is the Kosterlitz–Thouless transition in the two-dimensional XY model. Many quantum phase transitions, e.g., in two-dimensional electron gases, belong to this class.  The liquid–glass transition is observed in many polymers and other liquids that can be supercooled far below the melting point of the crystalline phase. This is atypical in several respects. It is not a transition between thermodynamic ground states: it is widely believed that the true ground state is always crystalline. Glass is a "quenched disorder" state, and its entropy, density, and so on, depend on the thermal history. Therefore, the glass transition is primarily a dynamic phenomenon: on cooling a liquid, internal degrees of freedom successively fall out of equilibrium. Some theoretical methods predict an underlying phase transition in the hypothetical limit of infinitely long relaxation times. No direct experimental evidence supports the existence of these transitions.

Characteristic properties.

Phase coexistence.

A disorder-broadened first-order transition occurs over a finite range of temperatures where the fraction of the low-temperature equilibrium phase grows from zero to one (100%) as the temperature is lowered. This continuous variation of the coexisting fractions with temperature raised interesting possibilities. On cooling, some liquids vitrify into a glass rather than transform to the equilibrium crystal phase. This happens if the cooling rate is faster than a critical cooling rate, and is attributed to the molecular motions becoming so slow that the molecules cannot rearrange into the crystal positions. This slowing down happens below a glass-formation temperature Tg, which may depend on the applied pressure. If the first-order freezing transition occurs over a range of temperatures, and Tg falls within this range, then there is an interesting possibility that the transition is arrested when it is partial and incomplete. Extending these ideas to first-order magnetic transitions being arrested at low temperatures, resulted in the observation of incomplete magnetic transitions, with two magnetic phases coexisting, down to the lowest temperature. First reported in the case of a ferromagnetic to anti-ferromagnetic transition, such persistent phase coexistence has now been reported across a variety of first-order magnetic transitions. These include colossal-magnetoresistance manganite materials, magnetocaloric materials, magnetic shape memory materials, and other materials. The interesting feature of these observations of Tg falling within the temperature range over which the transition occurs is that the first-order magnetic transition is influenced by magnetic field, just like the structural transition is influenced by pressure. The relative ease with which magnetic fields can be controlled, in contrast to pressure, raises the possibility that one can study the interplay between Tg and Tc in an exhaustive way. Phase coexistence across first-order magnetic transitions will then enable the resolution of outstanding issues in understanding glasses.

Critical points.

In any system containing liquid and gaseous phases, there exists a special combination of pressure and temperature, known as the critical point, at which the transition between liquid and gas becomes a second-order transition. Near the critical point, the fluid is sufficiently hot and compressed that the distinction between the liquid and gaseous phases is almost non-existent. This is associated with the phenomenon of critical opalescence, a milky appearance of the liquid due to density fluctuations at all possible wavelengths (including those of visible light).

Symmetry.

Phase transitions often involve a symmetry breaking process. For instance, the cooling of a fluid into a crystalline solid breaks continuous translation symmetry: each point in the fluid has the same properties, but each point in a crystal does not have the same properties (unless the points are chosen from the lattice points of the crystal lattice). Typically, the high-temperature phase contains more symmetries than the low-temperature phase due to spontaneous symmetry breaking, with the exception of certain accidental symmetries (e.g. the formation of heavy virtual particles, which only occurs at low temperatures).

Order parameters.

An order parameter is a measure of the degree of order across the boundaries in a phase transition system; it normally ranges between zero in one phase (usually above the critical point) and nonzero in the other. At the critical point, the order parameter susceptibility will usually diverge.  An example of an order parameter is the net magnetization in a ferromagnetic system undergoing a phase transition. For liquid/gas transitions, the order parameter is the difference of the densities.  From a theoretical perspective, order parameters arise from symmetry breaking. When this happens, one needs to introduce one or more extra variables to describe the state of the system. For example, in the ferromagnetic phase, one must provide the net magnetization, whose direction was spontaneously chosen when the system cooled below the Curie point. However, note that order parameters can also be defined for non-symmetry-breaking transitions.  Some phase transitions, such as superconducting and ferromagnetic, can have order parameters for more than one degree of freedom. In such phases, the order parameter may take the form of a complex number, a vector, or even a tensor, the magnitude of which goes to zero at the phase transition.  There also exist dual descriptions of phase transitions in terms of disorder parameters. These indicate the presence of line-like excitations such as vortex- or defect lines.

Relevance in cosmology.

Symmetry-breaking phase transitions play an important role in cosmology. As the universe expanded and cooled, the vacuum underwent a series of symmetry-breaking phase transitions. For example, the electroweak transition broke the SU(2)×U(1) symmetry of the electroweak field into the U(1) symmetry of the present-day electromagnetic field. This transition is important to understanding the asymmetry between the amount of matter and antimatter in the present-day universe (see electroweak baryogenesis).  Progressive phase transitions in an expanding universe are implicated in the development of order in the universe, as is illustrated by the work of Eric Chaisson and David Layzer.  See also relational order theories and order and disorder.

Critical exponents and universality classes.

Continuous phase transitions are easier to study than first-order transitions due to the absence of latent heat, and they have been discovered to have many interesting properties. The phenomena associated with continuous phase transitions are called critical phenomena, due to their association with critical points.  It turns out that continuous phase transitions can be characterized by parameters known as critical exponents. The most important one is perhaps the exponent describing the divergence of the thermal correlation length by approaching the transition. For instance, let us examine the behavior of the heat capacity near such a transition. We vary the temperature of the system while keeping all the other thermodynamic variables fixed, and find that the transition occurs at some critical temperature "T". When is near "T", the heat capacity typically has a power law behavior,  The heat capacity of amorphous materials has such a behaviour near the glass transition temperature where the universal critical exponent α = 0.59 A similar behavior, but with the exponent instead of, applies for the correlation length.  The exponent is positive. This is different with. Its actual value depends on the type of phase transition we are considering.  It is widely believed that the critical exponents are the same above and below the critical temperature. It has now been shown that this is not necessarily true: When a continuous symmetry is explicitly broken down to a discrete symmetry by irrelevant (in the renormalization group sense) anisotropies, then some exponents (such as formula_2, the exponent of the susceptibility) are not identical.  For −1 < α < 0, the heat capacity has a "kink" at the transition temperature. This is the behavior of liquid helium at the lambda transition from a normal state to the superfluid state, for which experiments have found = -0.013±0.003. At least one experiment was performed in the zero-gravity conditions of an orbiting satellite to minimize pressure differences in the sample. This experimental value of α agrees with theoretical predictions based on variational perturbation theory.  For 0 < < 1, the heat capacity diverges at the transition temperature (though, since < 1, the enthalpy stays finite). An example of such behavior is the 3D ferromagnetic phase transition. In the three-dimensional Ising model for uniaxial magnets, detailed theoretical studies have yielded the exponent ∼ +0.110.  Some model systems do not obey a power-law behavior. For example, mean field theory predicts a finite discontinuity of the heat capacity at the transition temperature, and the two-dimensional Ising model has a logarithmic divergence. However, these systems are limiting cases and an exception to the rule. Real phase transitions exhibit power-law behavior.  Several other critical exponents,, and, are defined, examining the power law behavior of a measurable physical quantity near the phase transition. Exponents are related by scaling relations, such as It can be shown that there are only two independent exponents, e.g. and.  It is a remarkable fact that phase transitions arising in different systems often possess the same set of critical exponents. This phenomenon is known as "universality". For example, the critical exponents at the liquid–gas critical point have been found to be independent of the chemical composition of the fluid.  More impressively, but understandably from above, they are an exact match for the critical exponents of the ferromagnetic phase transition in uniaxial magnets. Such systems are said to be in the same universality class. Universality is a prediction of the renormalization group theory of phase transitions, which states that the thermodynamic properties of a system near a phase transition depend only on a small number of features, such as dimensionality and symmetry, and are insensitive to the underlying microscopic properties of the system. Again, the divergence of the correlation length is the essential point.

Critical slowing down and other phenomena.

There are also other critical phenomena; e.g., besides "static functions" there is also "critical dynamics". As a consequence, at a phase transition one may observe critical slowing down or "speeding up". The large "static universality classes" of a continuous phase transition split into smaller "dynamic universality" classes. In addition to the critical exponents, there are also universal relations for certain static or dynamic functions of the magnetic fields and temperature differences from the critical value.

Percolation theory.

Another phenomenon which shows phase transitions and critical exponents is percolation. The simplest example is perhaps percolation in a two dimensional square lattice. Sites are randomly occupied with probability p. For small values of p the occupied sites form only small clusters. At a certain threshold p a giant cluster is formed and we have a second-order phase transition. The behavior of P near p is, P~(p-p), where β is a critical exponent.

Phase transitions in biological systems.

Phase transitions play many important roles in biological systems. Examples include the lipid bilayer formation, the coil-globule transition in the process of protein folding and DNA melting, liquid crystal-like transitions in the process of DNA condensation, and cooperative ligand binding to DNA and proteins with the character of phase transition.  In "biological membranes", gel to liquid crystalline phase transitions play a critical role in physiological functioning of biomembranes. In gel phase, due to low fluidity of membrane lipid fatty-acyl chains, membrane proteins have restricted movement and thus are restrained in exercise of their physiological role. Plants depend critically on photosynthesis by chloroplast thylakoid membranes which are exposed cold environmental temperatures. Thylakoid membranes retain innate fluidity even at relatively low temperatures because of high degree of fatty-acyl disorder allowed by their high content of linolenic acid, 18-carbon chain with 3-double bonds. Gel-to-liquid crystalline phase transition temperature of biological membranes can be determined by many techniques including calorimetry, fluorescence, spin label electron paramagnetic resonance and NMR by recording measurements of the concerned parameter by at series of sample temperatures. A simple method for its determination from 13-C NMR line intensities has also been proposed.  It has been proposed that some biological systems might lie near critical points. Examples include neural networks in the salamander retina, bird flocks gene expression networks in Drosophila, and protein folding. However, it is not clear whether or not alternative reasons could explain some of the phenomena supporting arguments for criticality. It has also been suggested that biological organisms share two key properties of phase transitions: the change of macroscopic behavior and the coherence of a system at a critical point.  The characteristic feature of second order phase transitions is the appearance of fractals in some scale-free properties. It has long been known that protein globules are shaped by interactions with water. There are 20 amino acids that form side groups on protein peptide chains range from hydrophilic to hydrophobic, causing the former to lie near the globular surface, while the latter lie closer to the globular center. Twenty fractals were discovered in solvent associated surface areas of > 5000 protein segments. The existence of these fractals proves that proteins function near critical points of second-order phase transitions.  In groups of organisms in stress (when approaching critical transitions), correlations tend to increase, while at the same time, fluctuations also increase. This effect is supported by many experiments and observations of groups of people, mice, trees, and grassy plants.

Experimental.

A variety of methods are applied for studying the various effects. Selected examples are:

The term phase transition (or phase change) is most commonly used to describe transitions between solid, liquid, and gaseous states of matter, as well as plasma in rare cases. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change, often discontinuously, as a result of the change of external conditions, such as temperature, pressure, or others. For example, a liquid may become gas upon heating to the boiling point, resulting in an abrupt change in volume. The measurement of the external conditions at which the transformation occurs is termed the phase transition. Phase transitions commonly occur in nature and are used today in many technologies.

相变(又称物态变化,英语:Phase Transition)是指物质在外部参数(如:温度、压力、磁场等等)连续变化之下,从一种相(态)忽然变成另一种相,最常见的是冰变成水和水变成蒸气。然而,除了物体的三相变化(固态、液态、气态)自然界还存在许许多多的相变现象,例如日常生活中另一种较常见的相变是加热一块磁铁,磁铁的铁磁性忽然消失。其他在物理学中重要相变列举如下:


Description.

There are many aspects of quality in a business context, though primary is the idea the business produces something, whether it be a physical good or a particular service. These goods and/or services and how they are produced involve many types of processes, procedures, equipment, personnel, and investments, which all fall under the quality umbrella. Key aspects of quality and how it's diffused throughout the business are rooted in the concept of quality management:  While quality management and its tenets are relatively recent phenomena, the idea of quality in business is not new. In the early 1900s, pioneers such as Frederick Winslow Taylor and Henry Ford recognized the limitations of the methods being used in mass production at the time and the subsequent varying quality of output, implementing quality control, inspection, and standardization procedures in their work. Later in the twentieth century, the likes of William Edwards Deming and Joseph M. Juran helped take quality to new heights, initially in Japan and later (in the late '70s and early '80s) globally.  Customers recognize that quality is an important attribute in products and services, and suppliers recognize that quality can be an important differentiator between their own offerings and those of competitors (the quality gap). In the past two decades this quality gap has been gradually decreasing between competitive products and services. This is partly due to the contracting (also called outsourcing) of manufacturing to countries like China and India, as well internationalization of trade and competition. These countries, among many others, have raised their own standards of quality in order to meet international standards and customer demands. The ISO 9000 series of standards are probably the best known international standards for quality management, though specialized standards such as ISO 15189 (for medical laboratories) and ISO 14001 (for environmental management) also exist.

Notable definitions.

The definition of "quality" has changed over time, and even today some variance is found in how it is described. However, some commonality can still be found. The common element of the business definitions is that the quality of a product or service refers to the perception of the degree to which the product or service meets the customer's expectations. Quality has no specific meaning unless related to a specific function and/or object.  The business meanings of "quality" have developed over time. Various interpretations are given below:

Market sector perspectives.

Operations management.

Traditionally, quality acts as one of five operations/project performance objectives dictated by operations management policy. Operations management, by definition, focuses on the most effective and efficient ways for creating and delivering a good or service that satisfies customer needs and expectations. As such, its ties to quality are apparent. The five performance objectives which give business a way to measure their operational performance are:  Based on an earlier model called the sand cone model, these objectives support each other, with quality at the base. By extension, quality increases dependability, reduces cost, and increases customer satisfaction.

Manufacturing.

The early 1920s saw a slow but gradual movement among manufacturers away from a "maximum production" philosophy to one aligned more closely with "positive and continuous control of quality to definite standards in the factory." That standardization, further pioneered by Deming and Juran later in the twentieth century, has become deeply integrated into how manufacturing businesses operate today. The introduction of the ISO 9001, 9002, and 9003 standards in 1987 — based off work from previous British and U.S. military standards — sought to "provide organizations with the requirements to create a quality management system (QMS) for a range of different business activities." Additionally, good manufacturing practice (GMP) standards became more common place in countries around the world, laying out the minimum requirements manufacturers in industries including food and beverages, cosmetics, pharmaceutical products, dietary supplements, and medical devices must meet to assure their products are consistently high in quality. Process improvement philosophies such as Six Sigma and Lean Six Sigma have further pushed quality to the forefront of business management and operations. At the heart of these and other efforts is often the QMS, a documented collection of processes, management models, business strategies, human capital, and information technology used to plan, develop, deploy, evaluate, and improve a set of models, methods, and tools across an organization for the purpose of improving quality that aligns with the organization's strategic goals.

Service sector.

The push to integrate the concept of quality into the functions of the service industry takes a slightly different path from manufacturing. Where manufacturers focus on "tangible, visible, persistent issues," many — but not all — quality aspects of the service provider's output are intangible and fleeting. Other obstacles include management's perceptions not aligning with customer expectations due to lack of communication and market research and the improper or lack of delivery of skill-based knowledge to personnel. Like manufacturing, customer expectations are key in the service industry, though the degree with which the service interacts with the customer definitely shapes perceived service quality. Perceptions such as being dependable, responsive, understanding, competent, and clean (which are difficult to describe tangibly) may drive service quality, somewhat in contrast to factors that drive measurement of manufacturing quality.

In business, engineering, and manufacturing, quality has a pragmatic interpretation as the non-inferiority or superiority of something; it's also defined as being suitable for its intended (fitness for purpose) while satisfying customer expectations. Quality is a perceptual, conditional, and somewhat subjective attribute and may be understood differently by different people. Consumers may focus on the specification quality of a product/service, or how it compares to competitors in the marketplace. Producers might measure the conformance quality, or degree to which the product/service was produced correctly. Support personnel may measure quality in the degree that a product is reliable, maintainable, or sustainable.

-{zh-tw:品质; zh-cn:品质;}-(英语:Quality),香港通常沿用古语称为质素,可指物品的特征、品性、本质,也可指商品或服务的水准、品质。