Blood samples will be collected on the date of Photodynamic Therapy. A total of 13.5mL of blood will be collected between 2 tubes (3.5mL gold top tube and a 10 mL lavendar top Vacutainer tube with EDTA). The biomarkers to be examined include serum VitD levels at the time of PDT, and the presence/absence of gene alleles that correlate with expression of several proteins involved in VitD and 5FU metabolism.