[{"from": "human", "value": "Create a molecule that satisfies the conditions outlined in the description. The molecule is a natural product found in Ligularia atroviolacea with data available."}, {"from": "gpt", "value": "[C][C][=C][O][C][=C][Ring1][Branch1][C@H1][C@][Branch2][Ring1][Branch1][C@@H1][Branch1][Branch1][C][Ring1][=Branch1][=O][C][C][C][C@@H1][Ring1][Branch2][C][=Branch1][C][=O][O][Ring1][N][C]"}]