[{"from": "human", "value": "Create a molecule that satisfies the conditions outlined in the description. The molecule is a natural product found in Ligularia sagitta with data available."}, {"from": "gpt", "value": "[C][/C][=C][Branch1][C][\\C][/C][=Branch1][C][=O][O][C@H1][C][C@@H1][C@][Branch1][Ring2][O][Ring1][Ring1][C][C@][Branch2][Ring2][C][C][=Branch1][N][=C][Branch1][Branch2][C][=Branch1][C][=O][O][Ring1][=Branch1][C][C@H1][Branch1][O][C@@][Ring1][N][Branch1][Branch1][C@H1][Ring1][S][C][C][O][C][=Branch1][C][=O][C][O]"}]