[{"from": "human", "value": "Create a molecule that satisfies the conditions outlined in the description. The molecule is an isoquinoline alkaloid that is 4,4a-dihydro-3H,6H-5,10b-ethanophenanthridin-3-one carrying additional hydroxy and methoxy substituents at positions 8 and 9 respectively (the 4aR,10bS-diastereomer). It has a role as a plant metabolite. It is an aromatic ether, a bridged compound, a cyclic ketone, an enone, an isoquinoline alkaloid, a member of phenols, a tertiary amino compound and an organic heterotetracyclic compound. It is a conjugate base of a (4aR,10bS)-noroxomaritidine(1+). It is an enantiomer of a (4aS,10bR)-noroxomaritidine."}, {"from": "gpt", "value": "[C][O][C][=C][Branch2][Ring1][N][C][=C][C][N][C][C][C@@][Branch1][=N][C@H1][Ring1][Branch1][C][C][=Branch1][C][=O][C][=C][Ring1][#Branch1][C][Ring1][=N][=C][Ring1][P][O]"}]