[{"from": "human", "value": "Synthesize a molecule that matches the given characteristics. The molecule is an angucycline antibiotic that consists of a tetrangomycin skeleton linked to deoxy sugars through C-glycosidic and O-glycosidic bonds at positions 9 and 3 respectively. It is isolated from Streptomyces sp.KY002 and exhibits cytotoxicity against human lung cancer and MCF-7 human breast cancer cells. It has a role as an antineoplastic agent. It is a C-glycosyl compound, a glycoside and an angucycline antibiotic. It is functionally related to a tetrangomycin."}, {"from": "gpt", "value": "[C][C@H1][C@H1][Branch2][#Branch1][=Branch2][C][C][C@@H1][Branch1][Ring2][O][Ring1][=Branch1][O][C@@][Branch2][=Branch1][O][C][C][=C][Branch1][Branch2][C][=Branch1][C][=O][C][Ring1][#Branch1][C][=C][Branch1][Branch1][C][=C][Ring1][=Branch2][C][=Branch1][C][=O][C][=C][Branch1][Branch1][C][Ring1][=Branch2][=O][C][=C][C][=Branch1][Branch1][=C][Ring1][Branch2][O][C@H1][C][C@@H1][C@@H1][Branch1][Branch2][C@H1][Branch1][Ring2][O][Ring1][=Branch1][C][O][C@H1][C@@H1][Branch1][Ring2][O][Ring1][=Branch2][C][C][=Branch1][C][=O][C@@H1][Branch1][Ring2][O][Ring1][Branch2][C][C][O][C@H1][C][=C][C][=Branch1][C][=O][C@@H1][Branch1][Ring2][O][Ring1][#Branch1][C]"}]