[{"from": "human", "value": "Synthesize a molecule that matches the given characteristics. The molecule is the tosylate form of umbralisib, an orally bioavailable, selective inhibitor of the delta isoform of the 110 kDa catalytic subunit of class I phosphoinositide-3 kinases (PI3K) with potential antineoplastic activity.  umbralisib inhibits PI3K and prevents the activation of the PI3K/AKT kinase signaling pathway. This decreases proliferation and induces cell death in susceptible tumor cells.  Unlike other isoforms of PI3K, PI3K-delta is expressed primarily in tumor cells and cells of the hematopoietic lineage. The targeted inhibition of PI3K-delta allows for PI3K signaling in normal, non-neoplastic cells. PI3K, an enzyme often overexpressed in cancer cells, plays a crucial role in tumor cell regulation and survival."}, {"from": "gpt", "value": "[C][C][=C][C][=C][Branch1][Branch1][C][=C][Ring1][=Branch1][S][=Branch1][C][=O][=Branch1][C][=O][O].[C][C@@H1][Branch2][Ring2][Branch1][C][=C][Branch2][Ring1][Branch1][C][=Branch1][C][=O][C][=C][Branch1][Ring2][O][Ring1][#Branch1][C][=C][C][=Branch1][Ring2][=C][Ring1][#Branch1][F][C][=C][C][=Branch1][=Branch1][=C][C][=C][Ring1][=Branch1][F][N][C][=N][C][=N][C][=Branch2][Ring1][=N][=C][Ring1][=Branch1][C][=Branch1][Ring2][=N][Ring1][=Branch2][C][=C][C][=Branch1][=C][=C][Branch1][Branch1][C][=C][Ring1][=Branch1][O][C][Branch1][C][C][C][F][N]"}]