[{"from": "human", "value": "Synthesize a molecule that matches the given characteristics. The molecule is a nicotinamide dinucleotide that is NAD(+) in which the anomeric centre of the ribosylnicotinamide moiety has alpha- rather than beta-configuration It is a conjugate acid of an alpha-NAD(1-)."}, {"from": "gpt", "value": "[C][=C][C][=Branch2][=Branch1][=N][=C][N+1][=Branch1][Ring2][=C][Ring1][=Branch1][C@@H1][C@@H1][Branch2][Branch1][S][C@@H1][Branch2][Branch1][O][C@H1][Branch1][Ring2][O][Ring1][Branch1][C][O][P][=Branch1][C][=O][Branch1][C][O][O][P][=Branch1][C][=O][Branch1][C][O][O][C][C@@H1][C@H1][Branch2][Ring1][N][C@H1][Branch2][Ring1][#Branch1][C@@H1][Branch1][Ring2][O][Ring1][Branch1][N][C][=N][C][=C][Branch1][=Branch2][N][=C][N][=C][Ring1][=Branch1][Ring1][=Branch2][N][O][O][O][O][C][=Branch1][C][=O][N]"}]