[{"from": "human", "value": "Design a molecule that meets the criteria outlined in the description. The molecule is a natural product found in Daphniphyllum calycinum with data available."}, {"from": "gpt", "value": "[C][C@@H1][C][N+1][Branch2][Ring2][O][C@@H1][C@H1][Branch1][N][C][C][C@@H1][C][Ring1][=Branch1][=C][C][C][Ring1][Branch1][C@@][Branch2][Ring1][#Branch1][C@][Branch1][O][C@@H1][Ring1][=N][C@@H1][Ring1][S][C][C][Ring1][Branch1][C][C][C][=Branch1][C][=O][O][Ring1][O][C][O-1]"}]