[{"from": "human", "value": "Synthesize a molecule that matches the given characteristics. The molecule is the D-enantiomer of tryptophan. It has a role as a bacterial metabolite. It is a tryptophan and a D-alpha-amino acid. It is a conjugate base of a D-tryptophanium. It is a conjugate acid of a D-tryptophanate. It is an enantiomer of a L-tryptophan. It is a tautomer of a D-tryptophan zwitterion."}, {"from": "gpt", "value": "[C][=C][C][=C][C][=Branch1][Ring2][=C][Ring1][=Branch1][C][=Branch1][Branch1][=C][N][Ring1][=Branch1][C][C@H1][Branch1][=Branch1][C][=Branch1][C][=O][O][N]"}]