[{"from": "human", "value": "Given SMILES, write its LUMO at normal measurement conditions.. ->  CC1=CC2=C(C(C3=CC=C(CC(CC)CCCC)S3)=C(C=C(C4=C(C(N(CCCCCCCC)C5=O)=O)C5=C(C)S4)S6)C6=C2C7=CC=C(CC(CC)CCCC)S7)S1\n"}, {"from": "gpt", "value": " 3.46\n"}]