[{"from": "human", "value": "Given SMILES, write its LUMO at normal measurement conditions.. ->  CC1=C2C(C(N(CC(CCCCCC)CCCC)C2=O)=O)=C(C3=C(OCCCCCCCCCCCC)C=C(C4=CC(OCCCCCCCCCCCC)=C(C)S4)S3)S1\n"}, {"from": "gpt", "value": " 3.53\n"}]