[{"from": "human", "value": "Given SMILES, write its LUMO at room temperature and atmospheric pressure. ->  CC1=CC2=C(C3=C4C=C(C5=CC=C(C6=C(N=C(C7=CC=C(OCCCCCCCC)C=C7)C(C8=CC=C(OCCCCCCCC)C=C8)=N9)C9=C(C%10=CC=C(C)S%10)C=C6)S5)C=C3CC2)C(N4C(CCCCCCCC)CCCCCCCC)=C1\n"}, {"from": "gpt", "value": " 3.45\n"}]