[{"from": "human", "value": "Given SMILES, write its HOMO at room temperature and atmospheric pressure. ->  CC1=C(/C=C/C2=CC=CS2)C=C(S1)C(S3)=CC4=C3C(OCC(CCCC)CC)=C(C=C(C)S5)C5=C4OCC(CCCC)CC\n"}, {"from": "gpt", "value": " 5.22\n"}]