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Goodyear, Ariz.: Indians outfielder Lonnie Chisenhall will start the season on the 10-day disabled list, opening the door for Abraham Almonte to make the Opening Day roster.
Chisenhall sustained a mild sprain of the AC joint in his right shoulder when he crashed into an outfield wall last week, and the club wanted to let him rest for three days before evaluating him. He is nearing a return but won�t have enough at-bats to be ready for the Indians� April 3 season opener against the Texas Rangers in Arlington, Texas.
The Indians hope to have Chisenhall activated for their April 11 home opener against the Chicago White Sox. It�s the second consecutive season Chisenhall will open on the disabled list.
�He feels a heck of a lot better than he did last year at this time,� Indians manager Terry Francona said. �But he was probably going to get two at-bats on Friday. That�s just not ready. And I think he understands that.�
Almonte has had a strong spring, hitting .383 with three home runs, three doubles and 12 RBI heading into Wednesday�s game.
�I think everybody who�s seen Abe this spring is happy the way it works, because he really is deserving,� Francona said. �He�s done a terrific job.�
Almonte joins Tyler Naquin, Brandon Guyer and Austin Jackson as players securely in the Opening Day outfield.
The remaining question mark is Michael Brantley, who has played well in his recent, limited Cactus League action, going 7-for-19 with three extra-base hits. He played in back-to-back games for the third time on Wednesday and is slated to play in a third consecutive game on Thursday.
His swing has him looking like the Brantley of old, but the question remains as to what kind of workload his shoulder can handle.
Brantley�s status is in part what has kept the Indians from finalizing their Opening Day roster, along with their pending decision of whom to play at third base, assuming Jose Ramirez slides to second base during Jason Kipnis� absence.
�What I did tell Brant this morning was, �Don�t read anything into this,�?� Francona said of Brantley. ��There�s no pressure on you. Every decision is for the person, and we�ll figure out the team part of it.� I wanted to make sure that he understood that [there�s no] pressure on him.
�He has to be ready. He�s done such a good job. What we really care about is him continuing to be healthy, whether that�s the first day, the third day, the fifth day.�
The Indians� plan is for Ramirez to not become a part of the outfield picture. After he spent last year at left field and third base, the club would like to keep him in the infield. Ramirez is slated to start at second base for the first few weeks of the season with Kipnis dealing with shoulder inflammation.
�He could do it, but I just think for who we have, he�s such a good infielder,� Francona said. �Wherever you put him in the infield, he�s a pretty good defender. � You just don�t want to weaken yourself too much if you can help it.�
Ryan Lewis can be reached at email@example.com. Read the Indians blog at www.ohio.com/indians. Follow him on Twitter at www.twitter.com/RyanLewisABJ.

subset: commoncrawl


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Metals 2018, 8(5), 347; https://doi.org/10.3390/met8050347
Template-Assisted Fabrication of Nanostructured Tin (β-Sn) Arrays for Bulk Microelectronic Packaging Devices
Department of Materials Science and Engineering and Department of Energy Systems Research, Ajou University, Suwon 16499, Korea
Department of Metallurgical and Materials Engineering, SOE, OP Jindal University, Raigarh 496109, India
Department of Mechanical Engineering, Ajou University, Suwon 16499, Korea
Author to whom correspondence should be addressed.
Received: 23 March 2018 / Accepted: 8 May 2018 / Published: 11 May 2018
In this study, uniform and ordered nanostructured arrays of pure tin (Sn) were produced by the chemical pulse plating method in potentiostatic mode. Bottom metalized anodic aluminium oxide templates were used as the substrates for holding nanostructures during deposition. The plating bath consists of stannous sulfate (SnSO4), sulfuric acid (H2SO4), polyethylene glycol (PEG), and glutaraldehyde as a surfactant. The effect of potentiostatic potential ranging from −0.5 to −3.2 V vs. Ag/AgCl electrode was studied on the growth morphology of nanostructures that were formed. The characterization studies were accomplished by X-ray diffraction (XRD), field emission electron microscopy, and energy dispersive spectroscopy. It was found that several nanostructures were of different shapes and size when the potential was varied. Nanorods were prominent at the deposition potentials of −0.5 and −1.1 V, while a combination of nanostructures (nanorods, nanoplates, and nanoparticles) was predominant at −3.2 V. XRD results show that the nanostructures that were obtained consisted of tetragonal (Sn) structure with a crystallite size of about 20 nm. This process is economically viable and it can be scaled to produce various nanostructures through a careful control of deposition parameters.
Keywords:nanostructure; deposition; plating; bulk; nanorods; template; pores
1. Introduction
Materials that were prepared on the nanoscale often exhibit many different properties as compared to the same material in their bulk-state. As a result, there has been a tremendous amount of research activities on nanocrystalline materials among engineers and scientists in the past few decades, and the synthesis of bulk nanocrystalline materials is an important topic of recent research on nanocrystalline materials. For example, wire-shaped one-dimensional (1D) nanostructures in microelectronics as chip interconnections as well as fundamental units in functional devices. Especially, the excellent magnetic properties of metallic (Ni-, Fe-, and Co-based) nanostructures have opened new dimensions for next-generation memory devices with a high information storage capacity [1,2,3,4]. The production and the development of metallic or nonmetallic nanostructures are of significant interests due to their advanced application areas, such as microelectronics, optics, sensors, catalysis, fuel cells, solar cells, water purification, thermoelectrics, and bio-implants [5,6,7,8,9,10]. Various nanostructures, 1D or two-dimensional (2D) are synthesized by different routes, such as physical evaporation methods, atomic layer deposition, sonochemical treatment, chemical precipitation methods, polyol methods, ion implantation, and template assisted chemical plating methods [11,12,13,14,15,16,17,18,19,20]. Chemical plating methods where nanostructures are grown in a supporting membrane kind of structure, called templates, are the most popular and simplest methods. The size of the nanowires is generally predetermined by the diameter of the pores inside the templates. In addition, the template-based approach is one of the direct and quick methods to produce nanostructures at the industrial scale [21,22,23]. When compared to chemical methods, physical methods require a great deal of care and handling because they are operated at a fixed temperature and sensitive environment [24,25,26,27]. They are, therefore, not suitable to fill the channels of the templates. In addition, the top-down approach, like physical evaporation or chemical vapor deposition and physical vapor deposition are not desirable to fill up the template pores. This is because of the fact that as soon as the thickness of sputtered atoms rises over the channel openings, most of the pores of the template get blocked. Therefore, a chemical plating method where the nucleation and growth occur from inside the pore walls and bottom is the most suitable for the template based techniques to avoid any kind of pore blockage and high filling efficiency. Among the chemical method, and pulse plating offers many advantages. The pulse plating method is most suitable in view of its various benefits, such as simple and economic procedure as compared to other popular precipitation and sol-gel methods that require processing at high temperatures. The efficiency of plating process can be achieved up to more than 95–99% [12,23]. However, there is a scarcity of literature on Sn nanostructure formation by template-assisted pulse deposition. This may be due to the lack of database and understanding of the various roles of pulse and bath parameters inside the template pores. In addition, high aspect ratio nanostructures can be achieved by changing the template-assisted plating parameters at our will [10,21,22,23,24,25]. Among nanostructures, a more convincing impact of wire-shaped 1D nanosystems is in microelectronics, especially, in chip interconnections and as elemental building blocks in advanced functional devices. Particularly, the remarkable properties of Sn-based nanowires have opened new perspectives to fabricate the next generation of packaging devices [4,5,26,27,28]. For example, the optical transparency of Sn nanowires lies in the range 85–90% and it can be applied as transparent electrodes in electronic devices [28]. Double side tin nanowire arrays have already been tried as advanced thermal interface materials and have possibility for use in future electronic packaging materials [29]. Nanowire-based Sn and Sn-3.5Ag solders have been shown to have better joining characteristics at the nanoscale [30,31]. Therefore, in this work, we have fabricated Sn nanostructures (nanowires, nanorods, nanoplatelets, nanoparticles) in view of their potential applications in recent microelectronic packaging devices. We have used the pulse plating method for nanostructure fabrication using aqueous sulfate bath and an anodic aluminium oxide (AAO) template membrane as cathodic substrate. Further, the effect of varying potential from −0.5 to −3.2 V vs. Ag/AgCl on Sn nanostructure morphology during potentiosatic deposition has been also addressed.
2. Experimental Details
2.1. AAO Template Preparation
Anodic aluminium oxide (AAO) templates (Anodiscs, 60 µm height, Whatmann, Sigma Aldrich, St. Louis, MO, USA) having average pore diameter of 100 nm were used as templates. Prior to deposition, the template was cleaned with distilled water and ethyl alcohol to remove any dirt and grease that is present in the pores, and dried in open air.
2.2. Bath Preparation
The plating bath was prepared for the deposition process by adding the following chemicals procured from Sigma Aldrich (St. Louis, MO, USA) in the composition:
- Stannous Sulfate, SnSO4 (50 g/L, 99.9% pure);
- Sulfuric Acid, H2SO4 (170 g/L, 99.999% pure);
- Polyethylene glycol (PEG), H–(O–CH2–CH2)n–OH, n = 10,000 (g/L, 99.99% pure);
- Glutaraldehyde, OCH(CH2)3CHO (0.025 g/L, 99.99% pure).
The sulfuric acid acts as a supporting electrolyte in the plating bath, while PEG acts as a bath stabilizer. The glutaraldehyde acts as a surfactant additive to provide uniform current distribution and deposition throughout the channels. The surfactant also minimizes the internal stresses in the nanostructures inside the template pores. The bath pH was determined by using a digital pH meter. The bath pH value was around 0.6 ± 0.1 and was operated at room temperature (~26 °C) using an infra-red (IR, ST652, Qingdao Tlead International Co, Ltd., Qingdao, China) thermometer. The plating bath was also kept on stirring at 200 rpm during deposition to have a more uniform distribution of ions in the solution by a SPINOT magnetic stirrer.
2.3. The Plating Cell
The plating cell was composed three-electrode cell configuration (Figure 1a). AAO template was used as a cathode substrate. Platinum rod was used as a non-consumable anode and an Ag/AgCl that was stabilized with 1 M KCl was used as a standard reference electrode in the plating cell. AAO template was metallized with a thin Au seed layer (150 nm) followed by a Cu layer (500 nm) by a magnetron sputtering inside the channels of the template on one side, as shown in Figure 1b.
The electrode contacts were made by using an Al foil (10 mm) and a conducting silver paste through the template Cu layer. A small area of the Al foil (20 mm × 20 mm) was exposed to the bath solution to complete the circuit among the three-electrode cell.
2.4. The Pulse Plating Experiment
Pulse plating experiment was carried out using the plating bath and immersing the electrodes in it. The electric potential was supplied through Pulse Plater (EPP-4000, Biologic Science Instruments, Seyssinet-Pariset, France). The deposition was carried out under varying potential from −0.5 to −3.2 V vs. Ag/AgCl electrode for a duration of 3 h. Typical current profiles at various potentiostatic potentials are shown in Figure 2, and the corresponding electrical parameters are presented in Table 1. The non-vanishing current at 0 V is due to the side reactions, like hydrogen evolution and/or dissolution of the nanostructures, the current may not reach exactly zero during the off-cycle.
2.5. Recovery of Nanostructures
The AAO template was taken out of the plating bath and was rinsed with distilled water and alcohol and dried. After that, the AAO template was immediately immersed into a 6 M hot solution of KOH for a few minutes. In due course of time, the AAO template was preferentially etched and dissolved out, leaving behind the free-standing array of nanostructures.
3. Microstructural Characterization
3.1. Phase Analysis
The phase analysis of nanostructure arrays was done by X-ray diffraction (XRD) instrument (D2 Phaser Benchtop XRD System, Bruker AXS GmbH, Karlsruhe, Germany) with Co-target operating at 40 kV and 40 mA current. The various peaks obtained in the XRD spectrum were identified by comparison of the peaks with the International Center for Diffraction Data (ICDD) database using TOPAS software module (Version 6, Bruker-AXS, Karlsruhe, Germany) under Pseudo-Voigt profile fitting.
3.2. Nanostructure Morphology
The structure and evolution of Sn nanostructures inside the AAO template were examined using field emission scanning electron microscope (FESEM) (Hitachi 4800, Tokyo, Japan). The compositional analysis was accomplished by using energy dispersive X-ray spectrometer (EDS) that was attached to the FESEM instrument, which was used to identify the elemental compositions that were present in the sample.
4. Results and Discussion
4.1. Phase Evolution
The various phases that are present in the Sn nanostructure arrays after the deposition was analyzed from the XRD spectrum, as shown in Figure 3. The intense peak was noticed at 37.4°, which matches with the (200) plane of the β-Sn lattice. There is another peak at 65.2°, which corresponds to the (301) β-Sn plane. No other peaks of any impurity elements were found in the XRD spectrum, further indicating no contamination from either contact electrodes (Cu, Au, or Al) of the AAO templates.
4.2. Compositional Analysis
The elemental composition of the nanostructures was estimated by the EDS analysis, as shown in Figure 4.
The EDS analysis shows that un-etched sample contains O, Al, and Sn in the spectrum. Al and O are coming from the adhering AAO template while Sn is from the nanostructures inside and on the walls of the AAO (Figure 3a,c,d). The presence of Au is also noticed, which may be from the metalized layer at the bottom that is used as a seed layer. After etching of the AAO template in KOH, there was no trace of elements from metallization layer Cu or Al (Figure 3b,e). This confirms the purity of the obtained free-standing nanostructures by template deposition.
4.3. Morphology of Nanostructures
We divided the range of potential investigated into three categories: (−0.5, −1.1, and −3.2 V), and observed the change in the shape and size of the nanostructures formed. Figure 5 shows the SEM image of the surface morphology of Sn nanostructures that were formed at different potentiostatic potentials. Various types of nanostructures of different shapes and sizes were formed, as shown.
4.3.1. Formation of Short Nanorods (−0.5 V)
Following SEM images show the type and morphology of the Sn nanostructures that were plated at very low potential −0.5 V (Figure 5). The bright nanostructures are visible inside the template pores (Figure 5a–d).
Most of the pores were not filled completely and uneven filing was noticed (Figure 5a). Some of the template pores were half filled and random filling was observed. It can be easily correlated to the very small amount of potential that was fed to the template channels, causing a weaker deposition rate. As a consequence, poor filling of the pores and non-uniform nanorods were produced into the pores. The network of short and fine nanorods was obtained, being aligned along the large axis (Figure 5b). After etching, most of the template material was dissolved, leaving behind few standing nanorods, as shown in (Figure 5c,d). The average diameter of these rod-shaped nanostructures lie within 140–160 nm and the length is rather short in the range of 1–2 µm. This may be due to the poor deposition at this condition rate, as most of the pores are not utilized [21,22,23,24].
4.3.2. Formation of Large Nanorods/Nanowires (−1.1 V)
The formation of thicker and larger nanorods was noticed when the potential was −1.1 V. Figure 6 shows the well-defined nanorods, which are fully occupied within template pores (Figure 6a,b). A top view of the templates shows the maximum filling of the pores, the white region represents the filled up pores and black spots show the empty pores (Figure 6a). The diameter and length of the nanorods lie in the range of 200 nm and 4–7 µm (Figure 6b–d). The pores are densely filled in most of the cases. The mean diameters of nanorods are larger than the pore diameters of the AAO. This may be due to the fact that these AAO membranes can be slightly dissolved in highly acidic or basic medium solutions [32,33]. Most of the plating baths are highly acidic or basic; the walls of the AAO can be slightly dissolved at higher potentials that are used by electroplating baths.
In addition, the population density of nanostructures also rises with an increase of potential from −0.5 to −1.1 V. The full-fledged nanorods obtained in this potential region are due to the fact that the deposition thickness is enhanced at higher potentials [21]. The nucleation density and the growth rate of nanorods are in proper balance.
4.3.3. Formation of Nano-Rods, Nanoparticles, and Nanoplates (−3.2 V)
In this case, the deposition potential was further extended to −3.2 V and the morphology was observed, as shown in Figure 7. It can be noticed that a network of various types of nanostructures was formed, being oriented in different directions. We can see nanoparticles, nanoplates, and nanorods (Figure 7a–f) in this case. This can be explained in view of the fact that, an increase in potential to a sufficiently high value, the cathodic polarization increases due to a greater electron movement and reduction in the vicinity of the cathodic layer. A localized deposition triggers the formation of dendrite structures, which may result in fine nanoparticles and nanoplates. The size of the nanoparticles lays around 20–30 nm. The nanorods are 1 μm long and 20 nm wide. At this stage, the electron transfer rate is severe and random, causing a loss of orientation and shape. The nucleation rate rises quickly as compared to growth rate, and multiple nanostructures are noticed.
It can also be noted that the template pores are of fixed dimension and are rigid. Theoretically, the deposition parameters should not affect the size and shape of nanostructures inside the template. The nanostructures are supposed to be confined to the wall surface of the template pores. According to Asli et al. when the pore diameter is below a critical size, layer by layer growth of nanorods occurs, regardless of current density due to a smaller surface area at pore bottom as compared to pore wall [34,35]. Shin et al. commented that, under diffusion limited conditions, the growth of nanowires is independent of system parameters. As the nanowires length increases, the metal ions diffusion into the template pores rises, which make the unstable growth front causing over-deposit and blockage of pores [36,37,38]. Thierry et al. have described that unstable growth of these nanostructures occurs on account of the "tip effect". The "tip effect" at a higher deposition potential leads to a very high current flow at the tip of the Sn nuclei, which promotes the rapid growth of nanostructures [19].
It is to be noted that, though the deposition takes place inside the pores of AAO template, yet the evolution of hydrogen gas is not prevented in chemical baths during plating. At such higher potential, the inherent hydrogen gas screens the AAO template pores, and hence a number of nanostructures are generated. Top view of the AAO template is shown in Figure 7a, which shows that a maximum amount of pores are filled and the top surface is coated with a Sn layer at higher deposition potential. This is related to the high rates of deposition as well as hydrogen evolution combined to produce the tip effect, and hence multiple nanostructures are formed [19,20,21,36,37,38].
5. Conclusions
There are various conclusions drawn from this study as summarized below:
- 1D Sn nanostructures arrays were produced successfully via the template assisted plating approach from aqueous sulfate bath.
- It was found that the nanostructure shape, size, and morphology were severely affected in response to various deposition potential.
- Low deposition potential of −0.5 V causes formation of very short nanowires (1–2 µm, dia 140–160 nm) and incomplete filling of the AAO template pores is found.
- At a medium deposition potential, −1.1 V, the growth rate of nanostructures was further increased to (4–7 µm length, dia 200 nm). Most of the template pores were filled completely
- As the deposition potential was raised to a sufficiently high value, −3.2 V, multiple nanostructures were formed. The nanoparticles were formed due to the dendritic deposition of Sn inside the AAO template pores (20 nm).
- The multiple nanostructures (nanoplates, nanorods, and nanoparticles) were formed on account of the tip effect of Sn nuclei inside the AAO template. It can be suggested that an optimum deposition potential is needed to exploit the use of each kind of nanostructure and can be potentially controlled for mass production.
Author Contributions
A.S. and B.A. formulated the idea and wrote the manuscript. A.S. performed materials synthesis. A.K.S. and Y.J. performed characterizations. All authors participated in discussion and review of manuscript.
This research was funded by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (NRF-2015R1A2A2A01002387). This research was also supported by the Ajou University research fund.
This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (NRF-2015R1A2A2A01002387). This research was also supported by the Ajou University research fund.
Conflicts of Interest
The authors declare no conflict of interest.
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Figure 1. (a) Pulse plating experimental set up and (b) schematic illustration for template assisted plating.
Figure 2. The current profile used for the various potentiostatic potential (a) −0.5 V; (b) −1.1 V; and (c) −3.2 V.
Figure 4. Energy dispersive X-ray spectrometer (EDS) Spectrum of Sn nanostructures array (a) secondary electron (SE) image of the top view of the template before etching; (b) SE image of the side view of the nanostructure after template etching; (c) EDS spectrum with anodic aluminium oxide (AAO) template with empty pores before etching; (d) EDS spectrum of the AAO template where the pores were filled before etching; (e) EDS spectrum of the nanostructure after template etching.
Figure 5. Field emission scanning electron microscope (FESEM) micrograph of random oriented nanorods at potential of −0.5 V (a) top view of the AAO template; (b) cross section of the AAO template; (c) cross-section of AAO template at another location; and (d) higher resolution image of (c).
Figure 6. FESEM micrograph of highly ordered nanorods at potential of −1.1 V (a) top view of the AAO template; (b) Another top view of un-even deposits of nanostructures; (c) cross-section of the AAO template showing dense array of nanorods; and (d) a higher resolution image of the (c).
Figure 7. FESEM micrograph of randomly oriented multiple nanostructures at potential of −3.2 V (a) top view of the AAO template; (b) high resolution of the (a); (c) high resolution image of (b) showing a cluster of nanoparticles; (d) formation of nanoplates and nanoparticles inside the template at few locations, tilted view of (d); (e) a close view of the nanoplates in (d); and (f) formation of random nanorods of uneven thickness.
|Applied potential
|Off time potential
|On-time, Off-time
|0.001 s, 0.01 s
|Duty Cycle
|100 Hz
© 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).


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Click on a thumbnail to go to Google Books.
xXxHoLic, Volume 2
by CLAMP
No current Talk conversations about this book.
Watanuki finds out some more about Yuuko. Also finds out that Domeki and he are tied together, and Watanuki can't stand that idea.
We are now getting to the meat of the story. In this volume Watanuki's spiritual eyes do not cause him much trouble but Yuko makes up for that. In this volume we also meet more of the main cast of character's. Watanuki's rival is only a rival because Watanuki thinks that he is. In truth Domeki is a friend who likes to give Watnuki trouble. The ghost stories are fun, especially if you like mythology like I do. Again that index in the back of the book is very useful because it explains the finer details about Japan and its very unique culture. Of course the art is just wonderful. I love that in DEL REY gives full color inserts for the first couple of pages. It just makes the art really pop. More ghost stuff coming up soon!
I give this volume a Five out of Five stars.
I loved how Watanuki's employment with Yuuko is transcending. It just proves that there's more to their employee-employer relationship. But the "more" is not what you're thinking of. They're really like good friends. And their relationship will blossom more in the upcoming volumes.
In the beginning of this manga we get to see the rest of how the Tsubasa characters are brought together and sent on their way to find the memories of Sakura leaving the over-excitiable Watanuki to cope with the concept of alternate versions of himself in an infinite universe. The story then moves on and we get to discover more about Watanuki's family and school.
I did find the story interesting if not terribly exciting although it does seem to be building up to something exciting. I am curious to see how things progress and will be picking up additional volumes to read in the future. Although Yuri is a sexy character, she's not really inappropriate and I would certainly continue to suggest this manga for ages 12 and up.
Is contained in
Has as a reference guide/companion
References to this work on external resources.
Wikipedia in English (4)
Amazon.com Product Description (ISBN 0345471199, Paperback)WATCH OUT FOR WITCHES
Kimihiro Watanuki thought he had signed up with a bunch of weirdoes, and he was right! He became the unfortunate indentured servant of a woman known as Yûko Ichihara, who was widely rumored to be the time-space witch. Now his voyage through the worlds of the occult are off and running, as he and Yûko go visiting fortune tellers and horoscope readers. But can the future really be told?
Meanwhile, the romance is heating up between Kimihiro and cute Himawari-chan. Then fate throws Kimihiro's old rival back into his life. Now Yûko invites all three to a temple to tell scary stories throughout the night. Is it just for fun or is there some deeper reason?
See the other side of the Tsubasa story in xxxHOLiC volume two! Don't miss it!
(retrieved from Amazon Thu, 12 Mar 2015 18:11:37 -0400)
Kimihiro visits a fortune teller while romance blossoms with Himawari-chan.
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Lies, Deceit, & Levin
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Published: 10 months ago
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1.Kira Camping Hammock By Freeport Park
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Gaby Witt
About Gaby:
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Gaby's Friends
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Milk a cow
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for Brands and Retail Buyers
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For Cathedrals and Chaucer wards.
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Limestone and Its Uses
Everything you ever wanted to know about limestone fills these 15 slides. Its properties, uses, and reactions with other materials are all explained. Most likely, this would be useful in a high school geology class as an example of sedimentary rocks. Be aware that it contains some British spellings of words, and is somewhat rustic in appearance.
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The Effect of Acid Rain on Limestone
Pupils investigate the pH of rain water in this earth science instructional activity. They collect rain water from their area and explore the pH when lime stone is added, then they will use the data collected to conjecture as to the...
6th - 9th Science CCSS: Designed


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Lawson 4-Piece Rattan Sectional Seating Group with Cushions By Birch Lane_ Heritage
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List Of The Best Adirondack Chairs In 2019
1. Mooresville Family Steel Garden Bench By Winston Porter
Read more about Mooresville Family Steel Garden Bench By Winston Porter
The Bridgewater is a sofa style that is primarily casual and definitely comfy. This design may be the darling of many an artist simply because you can use it to create a informal, pleasant room. Bridgewater sofas are flexible, with respect to the furniture you select. Completed in a neutral fabric, this style of couch doesnt compete with other elements within the room that may be more remarkable, such as artwork or other big functions. Much more official fabric will yield a far more grand type of sofa. A number of qualities differentiate Bridgewater sofas: Usually they've low arms along with a higher back, which plays a role in the sporadic appear. Most also have a customized skirt that conceals the legs and loose cushions for that chair and back. This specific design was designed to accommodate slipcovers, which also lend a casual air towards the couch.
2. Tropez Patio Chair with Cushion By Elle Decor
Read more about Tropez Patio Chair with Cushion By Elle Decor
The Lawson could be called quintessential United states sofa design. It's comfy and straightforward: The boxy shape is large and usually has 3 back again soft cushions as well as 3 chair cushions. The traditional Lawson also offers A taller back again and box-formed cushions which have welts at the edges, as do the back pillows. Well suited for snuggling and sleeping, this sofa design was designed for Jones Lawson, an American copper tycoon at the turn from the hundred years. He desired a settee that was quite different from the picky Victorian styles that were typical at that time. Current versions from the Lawson may also incorporate metal or wood contained in the arms. Most significantly, this couch style is the one that will morph its feel with the fabric you select for that furniture. The shape is so versatile that it may be attractive, luxurious, industrial, informal or formal based on your fabric choice.
3. Cotton Chair Hammock By Blue Sky Hammocks
Read more about Cotton Chair Hammock By Blue Sky Hammocks
This group of RTA sofas comes in different upholstery textures. A number of them include glued leather-based, linen, corduroy, linen consistency, rayon. All you need is to find the correct tapestry in significance for your well balanced requirements. Obtainable supplies provide an easy-to-thoroughly clean component. A attribute that implies its versatility to resist drinks and food. The luxurious chair and back soft cushions election in support of a reducing-advantage look. The square molded arm that begins just above them improves the elegance. You will find the comforts and soft styles that hit your entry.
4. Curacao 3 Piece Rocker Conversation Set By Sol 72 Outdoor
Read more about Curacao 3 Piece Rocker Conversation Set By Sol 72 Outdoor
While the rear of this sofa hints at the Chesterfield, with its rows of tufting, a tuxedo couch has cleaner, more angular lines. It is said to have been the bellwether more contemporary designs within the 1920s. Although some say this sofa style took its title from Tuxedo Park in New York, it's also considered called after the classic fancy men's match. You are able to determine a tuxedo sofa by its hands that are the same height as the back again. The tufting on the back of the sofa and its rectangular silhouette are also traditional qualities. Soft cushions include comfort to this higher-armed style. Also, while the couch over from Upcountry is upholstered in leather-based, this well-liked style is usually completed in textiles of all types, including the very trendy velvet.
5. Palmview Patio Chair with Cushion (Set of 2) By Fleur De Lis Living
Read more about Palmview Patio Chair with Cushion (Set of 2) By Fleur De Lis Living
This established is padded in a drive and comfortable textured padded velvet. This gives it the amazing comfort and ease that its cherished for. Once again it facilitates chaise style seats for sufficient comfort. Moreover, the sinus springtime base adds to the durability and comfort. Furthermore, the couch has hard wood structures that increase its toughness and durability. The sofa has cushions on the seat and the back. Yet still, the couch can move from a sitting placement to a lying down position effortlessly. Having said that, simply to repeat, the couch is extremely gentle and provides exceptional comfort and ease.
6. Vineyard Park Bench By POLYWOOD�
Read more about Vineyard Park Bench By POLYWOOD�
Whilst the back of this sofa shows the Chesterfield, using its rows of tufting, a tux couch has cleaner, much more angular outlines. It is stated to have been the bellwether of more modern styles in the 1920s. While some say this sofa design took its name from Tuxedo Recreation area in New York, it is also said to be named after the traditional fancy mens match. You are able to identify a tux sofa by its arms that are identical peak as the back. The tufting on the rear of the sofa and it is rectangle-shaped outline are also traditional characteristics. Soft cushions add comfort and ease to this high-equipped style. Also, while the sofa above from Upcountry is upholstered in leather, this popular style is often completed in textiles of all types, including the really trendy purple velvet.
7. Leone Wooden Garden Bench By Breakwater Bay
Read more about Leone Wooden Garden Bench By Breakwater Bay
Does your room show room needs? Are you currently inclined to throw a sleep party within the light of the absence of room to sleep? This DHP Futon mattress would be ideal for you in this situation. This Futon mattress sofa by DHP includes the functionality of a couch bed having a contemporary and elegant appearance. Place it in your family room to attain an extra tired bed at night. A microfiber ground that took off in the middle would be a ideal combination. This amazing sofa accompanies a tapestry with shiny stainless hair and legs. Consolidating these outcomes together inside a comfortable well-liked design sofa. You can choose to have it in Faux Leather-based, Purple velvet or Bed linen. An element that's worth specifying is its back again style. In light of the different seats, DHP encourages the alteration from the couch to your comfort and ease amounts. You are able to gain levels to have an animated babble, or for quiet moving image night.
8. Miami 7 Piece Sectional Seating Group with Cushions By TK Classics
Read more about Miami 7 Piece Sectional Seating Group with Cushions By TK Classics
This luxurious group of urban-chic sofas is made to supply an adorned domain. Actually, even your modest areas may have you required to have an immaculate movie evening. Place him down to obtain a completely changed mattress. This avant-garde sleeper futon is accessible in different tones. This includes some vibrant shades unmanageable such as Lemon, Mild Azure, and Light Purple. Put them inside your inventive studies or loft to evaluate the exuberance. It's also accessible in lowering shades such as darkish, darkish and dark. These nuances, once more, printing a respectable aspect of the upper class. Using the splitting component of your back, you are able to relaxation for your preferred position. This sofa appears rich with tufted material texture furniture. Fortunately that it is personalized with hypoallergenic filling. A conclusive result supplies a comfortable relaxation.
9. Fehi Outdoor Patio Armless Chair with Cushion By Orren Ellis
Read more about Fehi Outdoor Patio Armless Chair with Cushion By Orren Ellis
Much like its namesake, the camelback sofa includes a difficulty or possibly two that highlights the main outline of this couch design. This can be a traditional design which was made popular in the 1700s by Chippendale and families who desired aristocratic, formal Fehi Outdoor Patio Armless Chair with Cushion By Orren Ellis often opted for this style. These days, this sofa style lends a more official atmosphere to the room, especially when upholstered in a formal fabric. A more casual fabric option will make it appropriate for a household room that does not require a lot of custom. Either way, the camelback couch has some elements that define the design and style. The thighs are usually uncovered, the couch has no back cushions also it normally has square or rolled hands.
10. Coronado Sofa with Sunbrella Cushions By Sunset West
Read more about Coronado Sofa with Sunbrella Cushions By Sunset West
Using the current boost in popularity of the Mid-Century Contemporary design genre, this couch design is a warm item. Regardless of whether accurate classic items, reproductions or new styles that incorporate Middle-Hundred years Contemporary elements, they are really flexible couches. Most often utilized in a minimalist or middle-century style scheme, they're fantastic for adding a vintage really feel to some space. The distinguishing components include the exposed thighs and straight line framework. Most mid-hundred years sofas but not all of them will have some tufting around the back again.
Where to Find Lawson 4-Piece Rattan Sectional Seating Group with Cushions
You might feel you could get the exact same quality of furniture in your Big Box stores but that's not the situation. To put it differently, you don't find high-end clothing & apparel in JC Penny. {You'd need to go to Dolce & Gabanna or Neiman Marcus because of that.
To conclude, there are a number of great different garden furniture focused on their list. However, this will depend in your design and concept of what you should want to achieve when choosing the best one. If you are searching for a powerful sturdy set that does not need to move about a lot, the teams of rattan furniture might be a wise decision. Should you be searching for mobility and comfort then your solitary chairs would be a much better fit for those searching for on the run patio furniture. The last option would be if you are searching for a mixture of each sturdy and portability, then the seats and models with Zero The law of gravity may be the best match for you personally. Go and see now, which one will match your distinctive style and comfort and get outside to lastly get that necessary to unwind time.


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- AUD/USD remains on the back foot near 0.6880 following the release of Australian construction data.
- The Construction Work Done (Q1), which directly flows into the GDP, missed estimates, strengthening the case for an RBA rate cut in June.
The AUD/USD pair may have a hard time cheering a potential risk reset in the financial markets, as the Construction Work Done (Q1) - a key metric that flows directly into the GDP - has missed estimates.
The amount of construction work contracted 1.9% in the first three months of 2019, the data released by the Australian Bureau of Statistics soon before press time showed. The markets were expecting no change following a 3.1% drop in the final three months of 2018.
The below-forecast GDP input comes a day after the RBA Governor Lowe almost pre-announced a June rate cut, sending the Australian government bond yields to record lows. The data released today will likely boost the probability of the central bank lowering interest rates next month.
The financial markets, however, have fully priced for the RBA to deliver two 25 basis point rate cuts by November. As a result, the AUD may not suffer big losses during the day ahead due to the weaker-than-expected construction data.
The AUD may even pick up a bid if the oversold Chinese Yuan's starts recovering ground, however, the upside will likely be capped by the strengthening case for an RBA rate cut in June.
As of writing, the AUD/USD is trading at 0.6880, representing marginal losses on the day, having hit a low of 0.6873 a few minutes ago.
Pivot levels
Information on these pages contains forward-looking statements that involve risks and uncertainties. Markets and instruments profiled on this page are for informational purposes only and should not in any way come across as a recommendation to buy or sell in these assets. You should do your own thorough research before making any investment decisions. FXStreet does not in any way guarantee that this information is free from mistakes, errors, or material misstatements. It also does not guarantee that this information is of a timely nature. Investing in Open Markets involves a great deal of risk, including the loss of all or a portion of your investment, as well as emotional distress. All risks, losses and costs associated with investing, including total loss of principal, are your responsibility.
Latest Forex News
Editors' Picks
EUR/USD rises above 1.1200 amid some USD weakness
EUR/USD is trading above 1.1200, recovering some of the losses. Earlier, ECB officials expressed concern about global growth President Draghi speaks later. Tension is rising toward the Fed decision.
GBP/USD pressured below 1.2600, Conservative contest in focus
GBP/USD is trading below 1.2600, consolidating the losses seen on Friday after US retail sales beat expectations. The Conservative contest is heating up ahead of tomorrow's second vote.
USD/JPY: wait-and-see continues ahead of Fed
The dollar consolidates its gains against most rival, and scarce data exacerbates the quietness. USD/JPY bullish above 108.90, bearish below 108.10.
Gold: Flirting with daily lows, around 200-hour SMA
A follow-through selling below 200-hour SMA will reinforce the negative outlook and accelerate the slide towards 38.2% Fibo. level support near the $1325 region ahead of Wednesday's FOMC policy update.
Gold: Signs of bullish exhaustion ahead of the Fed
Gold's rally seems to have run its course with signs of bullish exhaustion emerging on technical charts ahead of Wednesday's FOMC (Federal Open Market Committee) rate decision.


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Bird-inspired robot transforms itself in mid-air to slip through gaps
Image credit: Dreamstime
Researchers based at Aix-Marseille Université have developed a robot capable of morphing in flight in order to fly through tight spaces. This could pave the way for exploration and search and rescue robots with the ability to travel unimpeded through small spaces.
Sign up to the E&T News e-mail to get great stories like this delivered direct to your inbox every day.


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For Muslims, the Hajj is the fifth and final pillar of Islam. It occurs in the month of Dhul Hijjah which is the twelfth month of the Islamic lunar calendar. It is the journey that every sane adult Muslim must undertake at least once in their lives if they can afford it and are physically able..
In my own cricket watching sweet spot between the ages of five and 16, Pakistan toured Australia seven times. At the beginning of that stretch they visited three times in five summers between 1988 89 and 1992 93. It's why when you speak to Australian cricket fans in their thirties and forties about Pakistani cricket, they are much more likely to recall an obscure fact about Qasim Umar, Abdul Qadir, Ijaz Ahmed or Ata ur Rehman than they are to tell you much about Shoaib Malik, Ahmed Shehzad or Sohaib Maqsood other than the way they face when they bat, and even then Pakistan's T20 captain, Mohammad Hafeez, could probably walk through Melbourne's Bourke Street mall without being recognised..
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Cemetery information and mortuary documents related to Tomiclock, a member of the Alaskan (Eskimo) Nation.
Student information card of Tomiclock, a member of the Alaskan Nation, who entered the school on November 14, 1897 and died there on April 8, 1900. She was buried in the cemetery on the school grounds.
Repository: National Archives and Records Administration


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Bepps Puffs Sweet Chilli
We believe snacks should put a bounce in your step. Our sweet chilli BEPPS are not just big on flavour, they're naturally packed full of protein and fibre. And, with no added nasties, these are finger-licking snacks that everyone can enjoy.
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- Ingredients
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Additional information
|0.50 kg
|39.5 × 30 × 16 cm
|Case Size
24 x 22g
|Product Code
Organic Black Eyed Pea Flour* (36%), Organic Whole Rice Flour*, Organic Sunflower Oil*, Organic Sweet Chilli Flavour Seasoning* (15%) (Rice Flour*, Unrefined Cane Sugar*, Spices* (Paprika*, Chilli*, Pepper*, Ginger*), Onions*, Tomatoes*, Sea Salt, Garlic*, Yeast Powder*, Natural Flavouring, Acid: Citric Acid E330, Sunflower Oil*), Organic Rice Protein*, * = from certified Organic ingredients
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Career Center
Register for the June 5th AUSA Job Fair in Arlington, VA – www.ausa.org/jobfair.
MAINTENANCE & OPERATIONS SUPERVISOR - SEWER UTILITY (Open Until filled)
Kitsap County
Kitsap County Public Works Department is dedicated to making our communities better and safer places to live, work, and play.
If you are innovative, problem solver and someone that has proven leadership ability this may just be the perfect job for you! Kitsap County Public Works is looking for someone with these attributes along with strong construction/maintenance background in sanitary sewer to join their team!
The Maintenance & Operations (M&O) Supervisor is responsible with managing and providing supervision to crew supervisors overseeing multiple crews for the Sewer Utility Division of Kitsap County Public Works (KCPW). The position provides technical expertise and oversees the planning, organizing, and scheduling of the operations, maintenance, and repair for the County's sewer collection/conveyance systems. Responsible for the completion of preventative maintenance duties and construction projects in accordance with county, state and federal regulations and requirements and industry standards. Knowledgeable in all aspects of constructing sewer system piping including planning, scheduling, equipment operation, trench safety and excavation, road construction, and other underground utilities. Develops and maintains annual budgets, manages resources, and assists in the planning and forecasting of asset repair and replacement. The position is responsible for the safety, training, evaluating, and coaching of crews to meet program objectives and performance goals. The M&O Supervisor coordinates activities and works closely with all divisions within KCPW and outside agencies.
Required Education and Experience
Preferred Education, Experience or Other Qualifications.
Driving Requirements
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Author: Andreas Broeckmann
Publisher: MIT Press
Category: Art
Page: 392
View: 8856An investigation of artists' engagement with technical systems, tracing art historical lineages that connect works of different periods.
Author: Andreas Broeckmann
Publisher: MIT Press
Category: Art
Page: 392
View: 8856An investigation of artists' engagement with technical systems, tracing art historical lineages that connect works of different periods.
Programs, Processes, and Performances
Author: Daniel A. Barber,Martin Bressani,Carlotta Darò,Tobias Erb,Kijan Espahangizi,Sabine von Fischer,John Harwood,Julian Jachmann,Susanne Jany,Reinhold Martin,Jacqueline Maurer,Spyros Papapetros,Caspar Schärer,Georg Vrachliotis
Publisher: Schwabe AG
Category: Architecture
Page: 180
View: 9224Architektur und Maschine sind zentrale Gegenstände menschlicher Gestaltung. Wie funktioniert ihr Zusammenspiel? In thematischer Breite und historischer Tiefe gehen die Beiträge des Bandes dem vielfältigen Wechselspiel dieser Phänomene nach, vor allem im Hinblick auf drei Aspekte: Maschinen, die dem Entwurf und der Errichtung von Gebäuden dienen, solche, die ihrer Arbeit innerhalb der Wände und Strukturen von Bauten verrichten und - insbesondere - Maschinen, die als Modelle und Bilder des architektonischen Denkens fungieren. Dabei zeigt sich, dass die Thematik der Maschine im Rahmen der Architektur bis heute nicht nur an konkrete technische Fragen, sondern vielmehr an allgemeine Programme, Prozesse und Performanzen und damit an grundlegende Kategorien des gebauten Raumes rührt. What is the nature of the interaction between architecture and machines as key objects in human design and how does this interplay work? The contributors to the volume explore this multifaceted interchange in its broad thematic manifestations and historical depth, focusing above all on three aspects: machines that assist in the design and construction of buildings, those that perform their tasks inside the walls and structures of buildings, and - in particular - machines that act as models and images of architectural thought. What emerges is that the subject of machines within the architectural framework has been rooted, up until the present day, not simply in concrete technical questions, but rather to a far greater extent in general programs, processes, and performances, and thus in fundamental categories of built space.
Sex, Drugs, and Biopolitics in the Pharmacopornographic Era
Author: Paul B. Preciado
Publisher: The Feminist Press at CUNY
Category: Social Science
Page: 432
View: 6137What constitutes a "real" man or woman in the twenty-first century? Since birth control pills, erectile dysfunction remedies, and factory-made testosterone and estrogen were developed, biology is definitely no longer destiny. In this penetrating analysis of gender, Paul B. Preciado shows the ways in which the synthesis of hormones since the 1950s has fundamentally changed how gender and sexual identity are formulated, and how the pharmaceutical and pornography industries are in the business of creating desire. This riveting continuation of Michel Foucault's The History of Sexuality also includes Preciado's diaristic account of his own use of testosterone every day for one year, and its mesmerizing impact on his body as well as his imagination.
Author: Wolfgang Jacobsen,Helga Belach,Norbert Grob
Publisher: N.A
Page: 311
View: 1036
Author: Michael Hardt,Antonio Negri
Publisher: Oxford University Press
Category: Democracy
Page: 336
View: 507In recent years "leaderless" social movements have proliferated around the globe, from North Africa and the Middle East to Europe, the Americas, and East Asia. Some of these movements have led to impressive gains: the toppling of authoritarian leaders, the furthering of progressive policy, and checks on repressive state forces. They have also been, at times, derided by journalists and political analysts as disorganized and ineffectual, or suppressed by disoriented and perplexed police forces and governments who fail to effectively engage them. Activists, too, struggle to harness the potential of these horizontal movements. Why have the movements, which address the needs and desires of so many, not been able to achieve lasting change and create a new, more democratic and just society? Some people assume that if only social movements could find new leaders they would return to their earlier glory. Where, they ask, are the new Martin Luther Kings, Rudi Dutschkes, and Stephen Bikos? With the rise of right-wing political parties in many countries, the question of how to organize democratically and effectively has become increasingly urgent. Although today's leaderless political organizations are not sufficient, a return to traditional, centralized forms of political leadership is neither desirable nor possible. Instead, as Michael Hardt and Antonio Negri argue, familiar roles must be reversed: leaders should be responsible for short-term, tactical action, but it is the multitude that must drive strategy. In other words, if these new social movements are to achieve meaningful revolution, they must invent effective modes of assembly and decision-making structures that rely on the broadest democratic base. Drawing on ideas developed through their well-known Empire trilogy, Hardt and Negri have produced, in Assembly, a timely proposal for how current large-scale horizontal movements can develop the capacities for political strategy and decision-making to effect lasting and democratic change. We have not yet seen what is possible when the multitude assembles.
Roman Von Bernhard Kellermann
Author: Bernhard Kellermann
Publisher: N.A
Category: Science fiction, German
Page: 402
View: 1204
Author: N.A
Publisher: N.A
Page: N.A
View: 9246
Aufsätze jugendlicher zur Zeit
Author: Erna Stahl
Publisher: N.A
Category: History
Page: 112
View: 9623
Ausg. A.
Author: N.A
Publisher: N.A
Category: Electric engineering
Page: N.A
View: 879
Author: Cornelia (ART) Sollfrank
Publisher: Hatje Cantz Pub
Category: Art
Page: 143
View: 8770Text by Sabine Himmelsbach, Jacob Lillemose, Rahel Puffert, Gerald Raunig.


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York traditional 600mm vanity unit with ceramic basin and mirror cabinet in oak.
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Product Code: U-YORK-PK4O
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