Use of portable FTIR spectrometers for detecting greenhouse gas emissions of the megacity Berlin – Part 2: Observed time series of &amp;lt;I&amp;gt;X&amp;lt;/I&amp;gt;CO&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt; and &amp;lt;I&amp;gt;X&amp;lt;/I&amp;gt;CH&amp;lt;sub&amp;gt;4&amp;lt;/sub&amp;gt;