The magnetic and thermal properties of tetraammine copper (II) sulfate monohydrate have been extensively studied and have been interpreted as those of a substance containing a magnetic linear chain structure.
In 1967, Saito & Kanda conducted proton nuclear magnetic resonance studies on this material in the paramagnetic and ordered state.
Unfortunately, the lack of proton positions prevented a quantitative interpretation of these data.
Since the early crystallographic study by Mazzi (1955) reported a structure based on projected data and indicated an unusual coordination about the copper ion, a detail structure determination was considered necessary for any future quantitative interpretation of the observed resonance data.
The magnetic and thermal properties of tetraammine copper (II) sulfate monohydrate have been extensively studied and have been interpreted as those of a substance containing a magnetic linear chain structure. In 1967, Saito & Kanda conducted proton nuclear magnetic resonance studies on this material in the paramagnetic and ordered state. Unfortunately, the lack of proton positions prevented a quantitative interpretation of these data. Since the early crystallographic study by Mazzi (1955) reported a structure based on projected data and indicated an unusual coordination about the copper ion, a detail structure determination was considered necessary for any future quantitative interpretation of the observed resonance data.
Tetraamminecopper(II) sulfate