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"text": "كما هو الحال بشكل عام في الـ heterocyclic chemistry أنه لازم تفكيركم يكون واسع يعني طالما أنا بأحكي عن insertion بين carbon و hydrogen بناء على ذلك، قداش الاحتمالات الممكنة؟ يعني مثلا بهذا الجزء اللي هو البروبين، كم احتمال ممكن عنده؟ كم نوع هيدروجين؟ اتخيلوا أن هذا الجزء في ال NMR حطته، كم بيك هتشوفه؟", "tokens": [4117, 15042, 31439, 21542, 6027, 4724, 8592, 28820, 6225, 10943, 8978, 2423, 39184, 20789, 31078, 66, 1050, 12558, 14739, 3224, 5296, 31377, 2304, 6055, 5172, 4117, 13546, 24793, 7251, 30544, 4032, 32277, 3615, 37495, 22653, 23032, 6027, 15042, 41850, 4724, 10721, 5016, 4117, 1829, 18871, 8969, 313, 49374, 5954, 4032, 12697, 44945, 16606, 15844, 29910, 23275, 12399, 12174, 3215, 33599, 42963, 33753, 2304, 6027, 9307, 9673, 43020, 3660, 22807, 37495, 22653, 50113, 15040, 39627, 15730, 25724, 11622, 38207, 13672, 1829, 31439, 2423, 26890, 37746, 9957, 12399, 9122, 2304, 1975, 33753, 2304, 6027, 3714, 43020, 43242, 3224, 22807, 9122, 2304, 8717, 45367, 8032, 25708, 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زي بعض و هدول ال CH2 زي بعض بمعنى لو أنا كان سؤالي draw all the possible insertion products for this reaction draw all the possible insertion products for this reaction هذا أحد ال insertion products اللي إجت فيه", "tokens": [28820, 2423, 3224, 25708, 2288, 29245, 9957, 9307, 13672, 1829, 34105, 46811, 7649, 10632, 29538, 2423, 5995, 18, 4032, 29538, 2423, 5995, 18, 30767, 1829, 45030, 11242, 4032, 8032, 3215, 12610, 2423, 5995, 17, 30767, 1829, 45030, 11242, 4724, 2304, 3615, 1863, 7578, 45164, 41850, 25961, 8608, 33604, 6027, 1829, 2642, 439, 264, 1944, 8969, 313, 3383, 337, 341, 5480, 2642, 439, 264, 1944, 8969, 313, 3383, 337, 341, 5480, 23758, 5551, 24401, 2423, 8969, 313, 3383, 13672, 1829, 11933, 7435, 2655, 8978, 3224], "avg_logprob": -0.17408088095047894, "compression_ratio": 1.8265306122448979, "no_speech_prob": 0.0, "words": [{"start": 324.34000000000003, "end": 325.22, "word": "كل", "probability": 0.47998046875}, {"start": 325.22, "end": 326.1, "word": " الهيدروجينات", 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"probability": 0.9482421875}, {"start": 339.3, "end": 339.6, "word": " the", "probability": 0.85498046875}, {"start": 339.6, "end": 340.4, "word": " possible", "probability": 0.90478515625}, {"start": 340.4, "end": 341.72, "word": " insertion", "probability": 0.953125}, {"start": 341.72, "end": 342.34, "word": " products", "probability": 0.82080078125}, {"start": 342.34, "end": 342.74, "word": " for", "probability": 0.94140625}, {"start": 342.74, "end": 343.12, "word": " this", "probability": 0.962890625}, {"start": 343.12, "end": 344.1, "word": " reaction", "probability": 0.91650390625}, {"start": 344.1, "end": 344.72, "word": " draw", "probability": 0.20263671875}, {"start": 344.72, "end": 345.1, "word": " all", "probability": 0.96240234375}, {"start": 345.1, "end": 345.34, "word": " the", "probability": 0.9208984375}, {"start": 345.34, "end": 345.74, "word": " possible", "probability": 0.962890625}, {"start": 345.74, "end": 346.46, "word": " insertion", "probability": 0.986083984375}, {"start": 346.46, "end": 346.86, "word": " products", "probability": 0.86279296875}, {"start": 346.86, "end": 347.12, "word": " for", "probability": 0.9541015625}, {"start": 347.12, "end": 347.36, "word": " this", "probability": 0.9619140625}, {"start": 347.36, "end": 347.88, "word": " reaction", "probability": 0.91650390625}, {"start": 347.88, "end": 348.68, "word": " هذا", "probability": 0.9345703125}, {"start": 348.68, "end": 349.54, "word": " أحد", "probability": 0.87939453125}, {"start": 349.54, "end": 349.72, "word": " ال", "probability": 0.95556640625}, {"start": 349.72, "end": 350.36, "word": " insertion", "probability": 0.956787109375}, {"start": 350.36, "end": 350.96, "word": " products", "probability": 0.72802734375}, {"start": 350.96, "end": 351.46, "word": " اللي", "probability": 0.97216796875}, {"start": 351.46, "end": 351.78, "word": " إجت", "probability": 0.7064615885416666}, {"start": 351.78, "end": 352.18, "word": " فيه", "probability": 0.98779296875}], "temperature": 1.0}, {"id": 14, "seek": 38023, "start": 353.95, "end": 380.23, "text": "ال CH2 هنا ال insertion product التاني وين بده يكون CH3 عادي وبناء على ذلك لو انا بده اتخيله هيكون حقيقة CH3 CH2 خليني اقول CH2 وهي ال H هذا اللي كان موجود اصلا و ايش هييجي عندى بال insertion ال CH2 اذا هنا لما احط", "tokens": [6027, 5995, 17, 34105, 2423, 8969, 313, 1674, 16712, 7649, 1829, 4032, 9957, 47525, 3224, 7251, 30544, 5995, 18, 6225, 995, 16254, 46599, 1863, 16606, 15844, 29910, 23275, 45164, 1975, 8315, 47525, 3224, 1975, 2655, 9778, 26895, 3224, 39896, 30544, 11331, 38436, 28671, 5995, 18, 5995, 17, 16490, 1211, 9957, 1829, 1975, 39648, 5995, 17, 37037, 1829, 2423, 389, 23758, 13672, 1829, 25961, 3714, 29245, 23328, 1975, 9381, 15040, 4032, 1975, 1829, 8592, 39896, 1829, 7435, 1829, 43242, 7578, 20666, 8969, 313, 2423, 5995, 17, 1975, 15730, 34105, 5296, 15042, 1975, 5016, 9566], "avg_logprob": -0.20362366767639808, "compression_ratio": 1.6376811594202898, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 353.95, "end": 354.21, "word": "ال", "probability": 0.67138671875}, {"start": 354.21, "end": 354.79, "word": " CH2", "probability": 0.62353515625}, {"start": 354.79, "end": 355.11, "word": " هنا", "probability": 0.927734375}, {"start": 355.11, "end": 355.59, "word": " ال", "probability": 0.86669921875}, {"start": 355.59, "end": 356.15, "word": " insertion", "probability": 0.9609375}, {"start": 356.15, "end": 356.59, "word": " product", "probability": 0.78369140625}, {"start": 356.59, "end": 357.07, "word": " التاني", "probability": 0.8875325520833334}, {"start": 357.07, "end": 357.29, "word": " وين", "probability": 0.7083740234375}, {"start": 357.29, "end": 357.53, "word": " بده", "probability": 0.4659423828125}, {"start": 357.53, "end": 357.89, "word": " يكون", "probability": 0.98486328125}, {"start": 357.89, "end": 358.87, "word": " CH3", "probability": 0.614013671875}, {"start": 358.87, "end": 360.47, "word": " عادي", "probability": 0.6422526041666666}, {"start": 360.47, "end": 361.21, "word": " وبناء", "probability": 0.8001302083333334}, {"start": 361.21, "end": 361.39, "word": " على", "probability": 0.53955078125}, {"start": 361.39, "end": 361.69, "word": " ذلك", "probability": 0.990478515625}, {"start": 361.69, "end": 361.85, "word": " لو", "probability": 0.8291015625}, {"start": 361.85, "end": 362.01, "word": " انا", "probability": 0.737548828125}, {"start": 362.01, "end": 362.19, "word": " بده", "probability": 0.79443359375}, {"start": 362.19, "end": 362.93, "word": " اتخيله", "probability": 0.9638671875}, {"start": 362.93, "end": 363.53, "word": " هيكون", "probability": 0.73779296875}, {"start": 363.53, "end": 364.13, "word": " حقيقة", "probability": 0.91455078125}, {"start": 364.13, "end": 365.67, "word": " CH3", "probability": 0.97265625}, {"start": 365.67, "end": 368.13, "word": " CH2", "probability": 0.9443359375}, {"start": 368.13, "end": 369.45, "word": " خليني", "probability": 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425.19, "text": "بفضل ال tertiary على ال secondary على ال primary بس مش هذا العامل الوحيد المؤثر بديش أنسى كمان أن حجم الحلقة الناتج أحياناً بيكون عامل مؤثر بالذات في ال ultra molecular reaction", "tokens": [3555, 5172, 11242, 1211, 2423, 38726, 29104, 15844, 2423, 11396, 15844, 2423, 6194, 4724, 3794, 37893, 23758, 18863, 10943, 1211, 2423, 2407, 5016, 25708, 9673, 33604, 49115, 47525, 1829, 8592, 14739, 3794, 7578, 9122, 2304, 7649, 14739, 11331, 7435, 2304, 21542, 1211, 28671, 2423, 8315, 2655, 7435, 5551, 5016, 1829, 7649, 995, 14111, 4724, 1829, 30544, 6225, 10943, 1211, 3714, 33604, 49115, 20666, 8848, 9307, 8978, 2423, 14808, 19046, 5480], "avg_logprob": -0.19817341171519856, "compression_ratio": 1.5303867403314917, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 408.91, "end": 409.89, "word": "بفضل", "probability": 0.82147216796875}, {"start": 409.89, "end": 410.19, "word": " ال", "probability": 0.69580078125}, {"start": 410.19, "end": 411.01, "word": " tertiary", 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"أنا في عندى ال flipping سريع على حرارة الغرفة عشانك ال Axial بيصير Equatorial و ال Equatorial Axial فبنقول أنه على حرارة الغرفة ال 12 زي بعض لإنه عندى ال flipping سريع لكن لو بردنا على درجة حرارة منخفضة جدا هيثبت بهذا الشكل و هنصير نشوف الهيدروجين نوعين مش نوع واحد", "tokens": [10721, 8315, 8978, 43242, 7578, 2423, 26886, 8608, 16572, 3615, 15844, 11331, 2288, 9640, 3660, 6024, 118, 28480, 3660, 6225, 8592, 7649, 4117, 2423, 20118, 831, 4724, 1829, 9381, 13546, 15624, 1639, 831, 4032, 2423, 15624, 1639, 831, 20118, 831, 6156, 3555, 1863, 39648, 14739, 3224, 15844, 11331, 2288, 9640, 3660, 6024, 118, 28480, 3660, 2423, 2272, 30767, 1829, 45030, 11242, 5296, 28814, 1863, 3224, 43242, 7578, 2423, 26886, 8608, 16572, 3615, 44381, 45164, 4724, 2288, 3215, 8315, 15844, 11778, 47341, 3660, 11331, 2288, 9640, 3660, 9154, 9778, 5172, 11242, 3660, 10874, 28259, 39896, 12984, 3555, 2655, 39627, 15730, 25124, 28820, 4032, 8032, 1863, 9381, 13546, 8717, 8592, 38688, 2423, 3224, 25708, 2288, 29245, 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"probability": 0.9459635416666666}, {"start": 838.27, "end": 838.99, "word": " الهيدروجين", "probability": 0.9733072916666666}, {"start": 838.99, "end": 840.05, "word": " وواجتشق", "probability": 0.6208902994791666}, {"start": 840.05, "end": 840.33, "word": " أنا", "probability": 0.54248046875}, {"start": 840.33, "end": 841.39, "word": " بقدر", "probability": 0.9376627604166666}, {"start": 841.39, "end": 841.89, "word": " فعلا", "probability": 0.9029947916666666}, {"start": 841.89, "end": 842.11, "word": " أن", "probability": 0.50927734375}, {"start": 842.11, "end": 842.69, "word": " أشوف", "probability": 0.8349609375}, {"start": 842.69, "end": 843.95, "word": " الهيدروجينات", "probability": 0.8720703125}, {"start": 843.95, "end": 844.35, "word": " في", "probability": 0.9736328125}, {"start": 844.35, "end": 845.29, "word": " الـcyclohexane", "probability": 0.888519287109375}, {"start": 845.29, "end": 846.07, "word": " نوعين", "probability": 0.98828125}, {"start": 846.07, "end": 846.29, 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{"start": 864.42, "end": 864.58, "word": " ال", "probability": 0.9677734375}, {"start": 864.58, "end": 865.44, "word": " insertion", "probability": 0.978271484375}, {"start": 865.44, "end": 866.06, "word": " طبعا", "probability": 0.96826171875}, {"start": 866.06, "end": 866.2, "word": " اللي", "probability": 0.962158203125}, {"start": 866.2, "end": 866.38, "word": " بدها", "probability": 0.497802734375}, {"start": 866.38, "end": 866.62, "word": " تشوف", "probability": 0.9972330729166666}, {"start": 866.62, "end": 866.76, "word": " ال", "probability": 0.91845703125}, {"start": 866.76, "end": 868.28, "word": " insertion", "probability": 0.99169921875}, {"start": 868.28, "end": 868.52, "word": " وين", "probability": 0.95458984375}, {"start": 868.52, "end": 868.66, "word": " ال", "probability": 0.9892578125}, {"start": 868.66, "end": 869.26, "word": " insertion", "probability": 0.994384765625}, {"start": 869.26, "end": 869.82, "word": " تتخيل", "probability": 0.8707275390625}, {"start": 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"word": " الكربون", "probability": 0.9777018229166666}], "temperature": 1.0}, {"id": 35, "seek": 89852, "start": 876.72, "end": 898.52, "text": "هيدروجينتين الان لما صار عليها التفاعل دلت هيدروجينة وين التانية؟ هايها ولذلك لما اقول وين اللي تم ال insertion هايه لاحظوا هذا الجزء دخل بين ال carbon هذي و ال H تبعيه", "tokens": [3224, 25708, 2288, 29245, 9957, 2655, 9957, 2423, 7649, 5296, 15042, 20328, 9640, 25894, 11296, 16712, 5172, 995, 30241, 11778, 1211, 2655, 8032, 25708, 2288, 29245, 9957, 3660, 4032, 9957, 16712, 7649, 10632, 22807, 8032, 47302, 11296, 35525, 8848, 23275, 5296, 15042, 1975, 39648, 4032, 9957, 13672, 1829, 46811, 2423, 8969, 313, 8032, 47302, 3224, 20193, 5016, 19913, 14407, 23758, 25724, 11622, 38207, 11778, 9778, 1211, 49374, 2423, 5954, 8032, 8848, 1829, 4032, 2423, 389, 6055, 3555, 3615, 1829, 3224], "avg_logprob": -0.3404706790123457, "compression_ratio": 1.7, "no_speech_prob": 0.0, "words": [{"start": 876.72, "end": 877.48, "word": "هيدروجينتين", "probability": 0.8225446428571429}, {"start": 877.48, "end": 878.04, "word": " الان", "probability": 0.50616455078125}, {"start": 878.04, "end": 878.2, "word": " لما", "probability": 0.7054443359375}, {"start": 878.2, "end": 878.56, "word": " صار", "probability": 0.65478515625}, {"start": 878.56, "end": 878.9, "word": " عليها", "probability": 0.98095703125}, {"start": 878.9, "end": 879.64, "word": " التفاعل", "probability": 0.9228515625}, {"start": 879.64, "end": 880.78, "word": " دلت", "probability": 0.6933186848958334}, {"start": 880.78, "end": 881.66, "word": " هيدروجينة", "probability": 0.8745930989583334}, {"start": 881.66, "end": 881.9, "word": " وين", "probability": 0.5806884765625}, {"start": 881.9, "end": 883.36, "word": " التانية؟", "probability": 0.8095703125}, {"start": 883.36, "end": 884.78, "word": " هايها", "probability": 0.37451171875}, {"start": 884.78, "end": 888.72, "word": " ولذلك", "probability": 0.7752278645833334}, {"start": 888.72, "end": 889.14, "word": " لما", "probability": 0.93994140625}, {"start": 889.14, "end": 889.44, "word": " اقول", "probability": 0.740966796875}, {"start": 889.44, "end": 889.76, "word": " وين", "probability": 0.900390625}, {"start": 889.76, "end": 890.0, "word": " اللي", "probability": 0.939697265625}, {"start": 890.0, "end": 890.26, "word": " تم", "probability": 0.99267578125}, {"start": 890.26, "end": 890.44, "word": " ال", "probability": 0.66552734375}, {"start": 890.44, "end": 891.3, "word": " insertion", "probability": 0.965087890625}, {"start": 891.3, "end": 891.76, "word": " هايه", "probability": 0.5284830729166666}, {"start": 891.76, "end": 893.96, "word": " لاحظوا", "probability": 0.9078369140625}, {"start": 893.96, "end": 894.32, "word": " هذا", "probability": 0.9453125}, {"start": 894.32, "end": 895.02, "word": " الجزء", "probability": 0.99072265625}, {"start": 895.02, "end": 896.36, "word": " دخل", "probability": 0.9931640625}, {"start": 896.36, "end": 896.64, "word": " بين", "probability": 0.96875}, {"start": 896.64, "end": 896.88, "word": " ال", "probability": 0.38525390625}, {"start": 896.88, "end": 897.24, "word": " carbon", "probability": 0.802734375}, {"start": 897.24, "end": 897.64, "word": " هذي", "probability": 0.6343587239583334}, {"start": 897.64, "end": 897.7, "word": " و", "probability": 0.7294921875}, {"start": 897.7, "end": 897.84, "word": " ال", "probability": 0.8212890625}, {"start": 897.84, "end": 898.08, "word": " H", "probability": 0.1707763671875}, {"start": 898.08, "end": 898.52, "word": " تبعيه", "probability": 0.765234375}], "temperature": 1.0}, {"id": 36, "seek": 92628, "start": 900.8, "end": 926.28, "text": "هذا الجزء من خلال الكاربين دخل بين الكاربون هذا والـ H تاعتها هاي ال insertion واضحة الفكرة؟ الآن بنجي على ال Nitrenes ال Nitrenes نفس التفاعلات", "tokens": [3224, 15730, 25724, 11622, 38207, 9154, 16490, 1211, 6027, 33251, 9640, 3555, 9957, 11778, 9778, 1211, 49374, 33251, 9640, 3555, 11536, 23758, 16070, 39184, 389, 6055, 995, 34268, 11296, 8032, 47302, 2423, 8969, 313, 4032, 46958, 5016, 3660, 27188, 4117, 25720, 22807, 6024, 48506, 44945, 7435, 1829, 15844, 2423, 37942, 1095, 279, 2423, 37942, 1095, 279, 8717, 36178, 16712, 5172, 995, 30241, 9307], "avg_logprob": -0.2951660044491291, "compression_ratio": 1.5389610389610389, "no_speech_prob": 0.0, "words": [{"start": 900.8, "end": 901.24, "word": "هذا", "probability": 0.91796875}, {"start": 901.24, "end": 901.7, "word": " الجزء", "probability": 0.9796549479166666}, {"start": 901.7, "end": 901.82, "word": " من", "probability": 0.97314453125}, {"start": 901.82, "end": 902.28, "word": " خلال", "probability": 0.986328125}, {"start": 902.28, "end": 903.06, "word": " الكاربين", "probability": 0.68353271484375}, {"start": 903.06, "end": 903.96, "word": " دخل", "probability": 0.8790690104166666}, {"start": 903.96, "end": 904.18, "word": " بين", "probability": 0.95263671875}, {"start": 904.18, "end": 904.78, "word": " الكاربون", "probability": 0.857666015625}, {"start": 904.78, "end": 905.12, "word": " هذا", "probability": 0.278076171875}, {"start": 905.12, "end": 905.62, "word": " والـ", "probability": 0.617919921875}, {"start": 905.62, "end": 905.82, "word": " H", "probability": 0.61865234375}, {"start": 905.82, "end": 906.4, "word": " تاعتها", "probability": 0.77349853515625}, {"start": 906.4, "end": 906.8, "word": " هاي", "probability": 0.32928466796875}, {"start": 906.8, "end": 906.88, "word": " ال", "probability": 0.9814453125}, {"start": 906.88, "end": 907.62, "word": " insertion", "probability": 0.88037109375}, {"start": 907.62, "end": 909.14, "word": " واضحة", "probability": 0.9393310546875}, {"start": 909.14, "end": 915.92, "word": " الفكرة؟", "probability": 0.83197021484375}, {"start": 915.92, "end": 921.96, "word": " الآن", "probability": 0.7001953125}, {"start": 921.96, "end": 922.5, "word": " بنجي", "probability": 0.7228190104166666}, {"start": 922.5, "end": 922.72, "word": " على", "probability": 0.85986328125}, {"start": 922.72, "end": 922.86, "word": 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1392.67, "word": " شابكة", "probability": 0.9893798828125}, {"start": 1392.67, "end": 1392.83, "word": " بال", "probability": 0.912109375}, {"start": 1392.83, "end": 1393.33, "word": " إيش؟", "probability": 0.75408935546875}, {"start": 1393.33, "end": 1393.87, "word": " بال", "probability": 0.95947265625}, {"start": 1393.87, "end": 1394.15, "word": " N", "probability": 0.56787109375}], "temperature": 1.0}, {"id": 55, "seek": 142346, "start": 1395.14, "end": 1423.46, "text": "طبعا البعض بيقول كيف تم هذا الكلام هذه rearrangement مشهورة جدا اسمها Cortes rearrangement هذه العملية اللي طلعت الناتج التاني اللي هنا rearrangement مشهورة شو اسمها Cortes rearrangement في ال Cortes rearrangement خلنا نقول كان عندنا C double bond O أزايد سخننا صارت C double bond O نيترين", "tokens": [9566, 3555, 3615, 995, 29739, 3615, 11242, 4724, 1829, 39648, 9122, 33911, 46811, 23758, 2423, 28820, 10943, 29538, 39568, 518, 37893, 3224, 13063, 3660, 10874, 28259, 24525, 2304, 11296, 28522, 279, 39568, 518, 29538, 18863, 42213, 10632, 13672, 1829, 23032, 1211, 34268, 28239, 9307, 7435, 16712, 7649, 1829, 13672, 1829, 34105, 39568, 518, 37893, 3224, 13063, 3660, 13412, 2407, 24525, 2304, 11296, 28522, 279, 39568, 518, 8978, 2423, 28522, 279, 39568, 518, 16490, 1211, 8315, 8717, 39648, 25961, 43242, 8315, 383, 3834, 6086, 422, 5551, 11622, 995, 25708, 8608, 9778, 1863, 8315, 20328, 9640, 2655, 383, 3834, 6086, 422, 8717, 36081, 2288, 9957], "avg_logprob": -0.19831730239093304, "compression_ratio": 1.9272727272727272, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1395.14, "end": 1395.58, "word": "طبعا", "probability": 0.902099609375}, {"start": 1395.58, "end": 1396.1, "word": " البعض", "probability": 0.91943359375}, {"start": 1396.1, "end": 1396.48, "word": " بيقول", "probability": 0.7926432291666666}, {"start": 1396.48, "end": 1397.34, "word": " كيف", "probability": 0.89599609375}, {"start": 1397.34, "end": 1397.58, "word": " تم", "probability": 0.978515625}, {"start": 1397.58, "end": 1397.9, "word": " هذا", "probability": 0.9365234375}, {"start": 1397.9, "end": 1398.46, "word": " الكلام", "probability": 0.9563802083333334}, {"start": 1398.46, "end": 1399.32, "word": " هذه", "probability": 0.34423828125}, {"start": 1399.32, "end": 1400.68, "word": " rearrangement", "probability": 0.6927490234375}, {"start": 1400.68, "end": 1401.56, "word": " مشهورة", "probability": 0.9755859375}, {"start": 1401.56, "end": 1402.02, "word": " جدا", "probability": 0.9951171875}, {"start": 1402.02, "end": 1402.9, "word": " اسمها", "probability": 0.9661458333333334}, {"start": 1402.9, "end": 1403.58, "word": " Cortes", "probability": 0.3189697265625}, {"start": 1403.58, "end": 1404.7, "word": " rearrangement", "probability": 0.78759765625}, {"start": 1404.7, "end": 1405.36, "word": " هذه", "probability": 0.88720703125}, {"start": 1405.36, "end": 1405.98, "word": " العملية", "probability": 0.9801432291666666}, {"start": 1405.98, "end": 1406.16, "word": " اللي", "probability": 0.796875}, {"start": 1406.16, "end": 1406.62, "word": " طلعت", "probability": 0.97900390625}, {"start": 1406.62, "end": 1407.24, "word": " الناتج", "probability": 0.7722981770833334}, {"start": 1407.24, "end": 1407.74, "word": " التاني", "probability": 0.8509114583333334}, {"start": 1407.74, "end": 1407.94, "word": " اللي", "probability": 0.92724609375}, {"start": 1407.94, "end": 1408.28, "word": " هنا", "probability": 0.92431640625}, {"start": 1408.28, "end": 1409.62, "word": " rearrangement", "probability": 0.918701171875}, {"start": 1409.62, "end": 1410.64, "word": " مشهورة", "probability": 0.981201171875}, {"start": 1410.64, "end": 1410.86, "word": " شو", "probability": 0.674560546875}, {"start": 1410.86, "end": 1411.5, "word": " اسمها", "probability": 0.9747721354166666}, {"start": 1411.5, "end": 1413.84, "word": " Cortes", "probability": 0.67626953125}, {"start": 1413.84, "end": 1415.06, "word": " rearrangement", "probability": 0.934814453125}, {"start": 1415.06, "end": 1415.46, "word": " في", "probability": 0.82470703125}, {"start": 1415.46, "end": 1415.6, "word": " ال", "probability": 0.375}, {"start": 1415.6, "end": 1416.1, "word": " Cortes", "probability": 0.852783203125}, {"start": 1416.1, "end": 1416.84, "word": " rearrangement", "probability": 0.943115234375}, {"start": 1416.84, "end": 1417.2, "word": " خلنا", "probability": 0.7452799479166666}, {"start": 1417.2, "end": 1417.48, "word": " نقول", "probability": 0.992431640625}, {"start": 1417.48, "end": 1417.76, "word": " كان", "probability": 0.908203125}, {"start": 1417.76, "end": 1418.54, "word": " عندنا", "probability": 0.980224609375}, {"start": 1418.54, "end": 1419.0, "word": " C", "probability": 0.357666015625}, {"start": 1419.0, "end": 1419.18, "word": " double", "probability": 0.426025390625}, {"start": 1419.18, "end": 1419.54, "word": " bond", "probability": 0.94091796875}, {"start": 1419.54, "end": 1419.8, "word": " O", "probability": 0.9287109375}, {"start": 1419.8, "end": 1420.38, "word": " أزايد", "probability": 0.79742431640625}, {"start": 1420.38, "end": 1421.04, "word": " سخننا", "probability": 0.71563720703125}, {"start": 1421.04, "end": 1421.34, "word": " صارت", "probability": 0.88671875}, {"start": 1421.34, "end": 1421.54, "word": " C", "probability": 0.87548828125}, {"start": 1421.54, "end": 1421.74, "word": " double", "probability": 0.8876953125}, {"start": 1421.74, "end": 1422.08, "word": " bond", "probability": 0.95947265625}, {"start": 1422.08, "end": 1422.54, "word": " O", "probability": 0.9833984375}, {"start": 1422.54, "end": 1423.46, "word": " نيترين", "probability": 0.8648681640625}], "temperature": 1.0}, {"id": 56, "seek": 144920, "start": 1424.06, "end": 1449.2, "text": "لاحظت أنا الكلام سليم ولا لأ؟ الآن بعد هيك هذه ال R بتعمل migration بال bond تبعتها على ال nitrogen فهتصير ايش؟ R عبر حلقة ثلاثية R N C O واضحة؟ يعني لما نكون راسمينها بهذا الشكل سهل عليكم أن تتخيلوا هذه الحلقة الثلاثية اللي تم من خلالها التفاعل؟", "tokens": [15040, 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0.2266845703125}, {"start": 1424.7, "end": 1425.14, "word": " الكلام", "probability": 0.9319661458333334}, {"start": 1425.14, "end": 1425.56, "word": " سليم", "probability": 0.8287760416666666}, {"start": 1425.56, "end": 1425.72, "word": " ولا", "probability": 0.69189453125}, {"start": 1425.72, "end": 1426.4, "word": " لأ؟", "probability": 0.8662109375}, {"start": 1426.4, "end": 1426.92, "word": " الآن", "probability": 0.6241455078125}, {"start": 1426.92, "end": 1427.52, "word": " بعد", "probability": 0.86767578125}, {"start": 1427.52, "end": 1428.04, "word": " هيك", "probability": 0.90771484375}, {"start": 1428.04, "end": 1428.48, "word": " هذه", "probability": 0.69677734375}, {"start": 1428.48, "end": 1428.62, "word": " ال", "probability": 0.88818359375}, {"start": 1428.62, "end": 1428.76, "word": " R", "probability": 0.401123046875}, {"start": 1428.76, "end": 1429.28, "word": " بتعمل", "probability": 0.939453125}, {"start": 1429.28, "end": 1429.96, "word": " migration", "probability": 0.72021484375}, {"start": 1429.96, "end": 1430.56, "word": " بال", "probability": 0.9453125}, {"start": 1430.56, "end": 1430.82, "word": " bond", "probability": 0.6572265625}, {"start": 1430.82, "end": 1431.28, "word": " تبعتها", "probability": 0.8504638671875}, {"start": 1431.28, "end": 1431.46, "word": " على", "probability": 0.84423828125}, {"start": 1431.46, "end": 1431.6, "word": " ال", "probability": 0.9140625}, {"start": 1431.6, "end": 1432.2, "word": " nitrogen", "probability": 0.87158203125}, {"start": 1432.2, "end": 1432.94, "word": " فهتصير", "probability": 0.8474609375}, {"start": 1432.94, "end": 1433.68, "word": " ايش؟", "probability": 0.781982421875}, {"start": 1433.68, "end": 1434.12, "word": " R", "probability": 0.77197265625}, {"start": 1434.12, "end": 1434.72, "word": " عبر", "probability": 0.8203125}, {"start": 1434.72, "end": 1435.1, "word": " حلقة", "probability": 0.9851888020833334}, {"start": 1435.1, "end": 1435.84, "word": " ثلاثية", "probability": 0.98603515625}, {"start": 1435.84, "end": 1437.66, "word": " R", "probability": 0.32421875}, {"start": 1437.66, "end": 1438.6, "word": " N", "probability": 0.4775390625}, {"start": 1438.6, "end": 1439.62, "word": " C", "probability": 0.80908203125}, {"start": 1439.62, "end": 1440.36, "word": " O", "probability": 0.9951171875}, {"start": 1440.36, "end": 1443.12, "word": " واضحة؟", "probability": 0.91943359375}, {"start": 1443.12, "end": 1443.38, "word": " يعني", "probability": 0.970947265625}, {"start": 1443.38, "end": 1443.5, "word": " لما", "probability": 0.75146484375}, {"start": 1443.5, "end": 1443.7, "word": " نكون", "probability": 0.966064453125}, {"start": 1443.7, "end": 1444.16, "word": " راسمينها", "probability": 0.76982421875}, {"start": 1444.16, "end": 1444.44, "word": " بهذا", "probability": 0.714111328125}, {"start": 1444.44, "end": 1444.86, "word": " الشكل", "probability": 0.994140625}, {"start": 1444.86, "end": 1445.44, "word": " سهل", "probability": 0.9617513020833334}, {"start": 1445.44, "end": 1445.82, "word": " عليكم", "probability": 0.710693359375}, {"start": 1445.82, "end": 1445.96, "word": " أن", "probability": 0.462646484375}, {"start": 1445.96, "end": 1446.46, "word": " تتخيلوا", "probability": 0.87236328125}, {"start": 1446.46, "end": 1446.66, "word": " هذه", "probability": 0.95068359375}, {"start": 1446.66, "end": 1447.06, "word": " الحلقة", "probability": 0.9881184895833334}, {"start": 1447.06, "end": 1447.6, "word": " الثلاثية", "probability": 0.9755045572916666}, {"start": 1447.6, "end": 1447.74, "word": " اللي", "probability": 0.76220703125}, {"start": 1447.74, "end": 1447.94, "word": " تم", "probability": 0.89306640625}, {"start": 1447.94, "end": 1448.08, "word": " من", "probability": 0.90771484375}, {"start": 1448.08, "end": 1448.44, "word": " خلالها", "probability": 0.9947509765625}, {"start": 1448.44, "end": 1449.2, "word": " التفاعل؟", "probability": 0.9509765625}], "temperature": 1.0}, {"id": 57, "seek": 147320, "start": 1449.92, "end": 1473.2, "text": "فصار عندى الكورتياس rearrangement بهذا الشكل وهذا من أشهر طرق بالمناسبة تحضير ال isocyanates يعني اللى بده isocyanates بياخد C double bond O أزايد بخلق C double bond O نيترين و عندها فرصة عالية تتحول لإيش", "tokens": [5172, 9381, 9640, 43242, 7578, 33251, 13063, 31371, 32277, 39568, 518, 39627, 15730, 25124, 28820, 37037, 15730, 9154, 5551, 8592, 3224, 2288, 23032, 2288, 4587, 20666, 2304, 8315, 35457, 3660, 6055, 5016, 11242, 13546, 2423, 307, 905, 6277, 1024, 37495, 22653, 13672, 7578, 47525, 3224, 307, 905, 6277, 1024, 4724, 1829, 47283, 3215, 383, 3834, 6086, 422, 5551, 11622, 995, 25708, 4724, 9778, 1211, 4587, 383, 3834, 6086, 422, 8717, 36081, 2288, 9957, 4032, 43242, 11296, 6156, 2288, 9381, 3660, 6225, 6027, 10632, 6055, 2655, 5016, 12610, 5296, 28814, 1829, 8592], "avg_logprob": -0.29449728163688077, "compression_ratio": 1.5169082125603865, "no_speech_prob": 0.0, "words": [{"start": 1449.92, "end": 1450.42, "word": "فصار", "probability": 0.633544921875}, {"start": 1450.42, "end": 1451.1, "word": " عندى", "probability": 0.6026611328125}, {"start": 1451.1, "end": 1452.4, "word": " الكورتياس", "probability": 0.6180267333984375}, {"start": 1452.4, "end": 1454.66, "word": " rearrangement", "probability": 0.631591796875}, {"start": 1454.66, "end": 1456.02, "word": " بهذا", "probability": 0.69287109375}, {"start": 1456.02, "end": 1456.38, "word": " الشكل", "probability": 0.98876953125}, {"start": 1456.38, "end": 1457.44, "word": " وهذا", "probability": 0.53955078125}, {"start": 1457.44, "end": 1457.58, "word": " من", "probability": 0.91552734375}, {"start": 1457.58, "end": 1458.02, "word": " أشهر", "probability": 0.9403076171875}, {"start": 1458.02, "end": 1458.36, "word": " طرق", "probability": 0.822265625}, {"start": 1458.36, "end": 1458.98, "word": " بالمناسبة", "probability": 0.93564453125}, {"start": 1458.98, "end": 1459.36, "word": " تحضير", "probability": 0.8829345703125}, {"start": 1459.36, "end": 1459.5, "word": " ال", "probability": 0.853515625}, {"start": 1459.5, "end": 1460.38, "word": " isocyanates", "probability": 0.7325439453125}, {"start": 1460.38, "end": 1461.14, "word": " يعني", "probability": 0.7998046875}, {"start": 1461.14, "end": 1461.28, "word": " اللى", "probability": 0.88134765625}, {"start": 1461.28, "end": 1461.58, "word": " بده", "probability": 0.857666015625}, {"start": 1461.58, "end": 1462.58, "word": " isocyanates", "probability": 0.8587646484375}, {"start": 1462.58, "end": 1464.32, "word": " بياخد", "probability": 0.9127197265625}, {"start": 1464.32, "end": 1466.02, "word": " C", "probability": 0.306884765625}, {"start": 1466.02, "end": 1466.2, "word": " double", "probability": 0.2685546875}, {"start": 1466.2, "end": 1466.6, "word": " bond", "probability": 0.9169921875}, {"start": 1466.6, "end": 1467.1, "word": " O", "probability": 0.91796875}, {"start": 1467.1, "end": 1467.86, "word": " أزايد", "probability": 0.6717529296875}, {"start": 1467.86, "end": 1468.22, "word": " بخلق", "probability": 0.637451171875}, {"start": 1468.22, "end": 1468.42, "word": " C", "probability": 0.68896484375}, {"start": 1468.42, "end": 1468.58, "word": " double", "probability": 0.85595703125}, {"start": 1468.58, "end": 1468.82, "word": " bond", "probability": 0.94775390625}, {"start": 1468.82, "end": 1468.98, "word": " O", "probability": 0.96337890625}, {"start": 1468.98, "end": 1469.64, "word": " نيترين", "probability": 0.908203125}, {"start": 1469.64, "end": 1470.5, "word": " و", "probability": 0.86669921875}, {"start": 1470.5, "end": 1471.3, "word": " عندها", "probability": 0.5146484375}, {"start": 1471.3, "end": 1471.72, "word": " فرصة", "probability": 0.994384765625}, {"start": 1471.72, "end": 1472.02, "word": " عالية", "probability": 0.96875}, {"start": 1472.02, "end": 1472.68, "word": " تتحول", "probability": 0.827880859375}, {"start": 1472.68, "end": 1473.2, "word": " لإيش", "probability": 0.8299560546875}], "temperature": 1.0}, {"id": 58, "seek": 148587, "start": 1474.69, "end": 1485.87, "text": "عشانك في هذا التفاعل صح هذا ال نيترين عمل ال insertion لكن عمل كمان تفاعل الأساسي اللي هو ال courtesary arrangement", "tokens": [3615, 8592, 7649, 4117, 8978, 23758, 16712, 5172, 995, 30241, 20328, 5016, 23758, 2423, 8717, 36081, 2288, 9957, 6225, 42213, 2423, 8969, 313, 44381, 6225, 42213, 9122, 2304, 7649, 6055, 5172, 995, 30241, 16247, 3794, 32277, 1829, 13672, 1829, 31439, 2423, 4753, 279, 822, 17620], "avg_logprob": -0.35054346465546155, "compression_ratio": 1.3533834586466165, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 1474.6899999999998, "end": 1475.57, "word": "عشانك", "probability": 0.6363525390625}, {"start": 1475.57, "end": 1475.71, "word": " في", "probability": 0.76611328125}, {"start": 1475.71, "end": 1475.99, "word": " هذا", "probability": 0.81103515625}, {"start": 1475.99, "end": 1476.69, "word": " التفاعل", "probability": 0.9306640625}, {"start": 1476.69, "end": 1477.51, "word": " صح", "probability": 0.885009765625}, {"start": 1477.51, "end": 1477.77, "word": " هذا", "probability": 0.7939453125}, {"start": 1477.77, "end": 1477.91, "word": " ال", "probability": 0.6181640625}, {"start": 1477.91, "end": 1478.43, "word": " نيترين", "probability": 0.721832275390625}, {"start": 1478.43, "end": 1478.83, "word": " عمل", "probability": 0.91845703125}, {"start": 1478.83, "end": 1478.99, "word": " ال", "probability": 0.73779296875}, {"start": 1478.99, "end": 1479.97, "word": " insertion", "probability": 0.97119140625}, {"start": 1479.97, "end": 1480.71, "word": " لكن", "probability": 0.73193359375}, {"start": 1480.71, "end": 1481.43, "word": " عمل", "probability": 0.978759765625}, {"start": 1481.43, "end": 1481.81, "word": " كمان", "probability": 0.7716471354166666}, {"start": 1481.81, "end": 1482.35, "word": " تفاعل", "probability": 0.9349365234375}, {"start": 1482.35, "end": 1483.01, "word": " الأساسي", "probability": 0.7542724609375}, {"start": 1483.01, "end": 1483.05, "word": " اللي", "probability": 0.72216796875}, {"start": 1483.05, "end": 1483.25, "word": " هو", "probability": 0.97412109375}, {"start": 1483.25, "end": 1483.37, "word": " ال", "probability": 0.40380859375}, {"start": 1483.37, "end": 1485.43, "word": " courtesary", "probability": 0.3167317708333333}, {"start": 1485.43, "end": 1485.87, "word": " arrangement", "probability": 0.67138671875}], "temperature": 1.0}, {"id": 59, "seek": 150380, "start": 1486.62, "end": 1503.8, "text": "و في اكتر من rearrangement حوالين Cortias يعني لو كتبتوا انتوا في google search Cortias rearrangement الأشياء الشبيهة مع تغيرات في نوع ال R و إشي هتلاقوا حوالي ستة سبعة rearrangements كلهم نفس فكرة ال Cortias باسماء مختلفة", "tokens": [2407, 8978, 1975, 4117, 2655, 2288, 9154, 39568, 518, 11331, 2407, 6027, 9957, 28522, 4609, 37495, 22653, 45164, 9122, 2655, 3555, 2655, 14407, 16472, 2655, 14407, 8978, 20742, 3164, 28522, 4609, 39568, 518, 16247, 8592, 1829, 16606, 25124, 21292, 3224, 3660, 20449, 6055, 17082, 13546, 9307, 8978, 8717, 45367, 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بتكون", "probability": 0.60333251953125}, {"start": 1561.04, "end": 1561.54, "word": " بتكون", "probability": 0.70654296875}, {"start": 1561.54, "end": 1562.06, "word": " بنسب", "probability": 0.915771484375}, {"start": 1562.06, "end": 1562.86, "word": " قليلة", "probability": 0.9488932291666666}], "temperature": 1.0}, {"id": 62, "seek": 158833, "start": 1564.85, "end": 1588.33, "text": "و ال insertion يعني هي مثلا هنا مثال اتطلعوا عليه مباشرة any three بالتسخين شو هتصير؟ نيتريل الان وين ال H القريبة؟ هيا ولذلك هذه هتيجي هنا و ال H؟ وين هتصير؟ عن نيتروجين نشطط", "tokens": [2407, 2423, 8969, 313, 37495, 22653, 39896, 50113, 15040, 34105, 50113, 6027, 1975, 2655, 9566, 1211, 3615, 14407, 47356, 3714, 3555, 33599, 25720, 604, 1045, 20666, 2655, 3794, 9778, 9957, 13412, 2407, 8032, 2655, 9381, 13546, 22807, 8717, 36081, 16572, 1211, 2423, 7649, 4032, 9957, 2423, 389, 25062, 16572, 49401, 22807, 8032, 25528, 35525, 8848, 23275, 29538, 8032, 31371, 7435, 1829, 34105, 4032, 2423, 389, 22807, 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"word": " عليه", "probability": 0.93359375}, {"start": 1569.27, "end": 1569.87, "word": " مباشرة", "probability": 0.98828125}, {"start": 1569.87, "end": 1570.13, "word": " any", "probability": 0.1612548828125}, {"start": 1570.13, "end": 1570.59, "word": " three", "probability": 0.677734375}, {"start": 1570.59, "end": 1571.83, "word": " بالتسخين", "probability": 0.8931640625}, {"start": 1571.83, "end": 1572.01, "word": " شو", "probability": 0.901611328125}, {"start": 1572.01, "end": 1573.53, "word": " هتصير؟", "probability": 0.8509765625}, {"start": 1573.53, "end": 1574.59, "word": " نيتريل", "probability": 0.7298583984375}, {"start": 1574.59, "end": 1575.41, "word": " الان", "probability": 0.56500244140625}, {"start": 1575.41, "end": 1575.83, "word": " وين", "probability": 0.913818359375}, {"start": 1575.83, "end": 1575.97, "word": " ال", "probability": 0.95849609375}, {"start": 1575.97, "end": 1576.17, "word": " H", "probability": 0.158203125}, {"start": 1576.17, "end": 1577.93, "word": " القريبة؟", "probability": 0.9417724609375}, {"start": 1577.93, "end": 1578.19, "word": " هيا", "probability": 0.3494873046875}, {"start": 1578.19, "end": 1580.29, "word": " ولذلك", "probability": 0.791015625}, {"start": 1580.29, "end": 1580.65, "word": " هذه", "probability": 0.54296875}, {"start": 1580.65, "end": 1581.15, "word": " هتيجي", "probability": 0.965087890625}, {"start": 1581.15, "end": 1581.37, "word": " هنا", "probability": 0.958984375}, {"start": 1581.37, "end": 1581.51, "word": " و", "probability": 0.76220703125}, {"start": 1581.51, "end": 1581.63, "word": " ال", "probability": 0.869140625}, {"start": 1581.63, "end": 1583.99, "word": " H؟", "probability": 0.7098388671875}, {"start": 1583.99, "end": 1584.61, "word": " وين", "probability": 0.960693359375}, {"start": 1584.61, "end": 1586.45, "word": " هتصير؟", "probability": 0.9869140625}, {"start": 1586.45, "end": 1586.77, "word": " عن", "probability": 0.76123046875}, {"start": 1586.77, "end": 1587.53, "word": " نيتروجين", "probability": 0.8486328125}, {"start": 1587.53, "end": 1588.33, "word": " نشطط", "probability": 0.74090576171875}], "temperature": 1.0}, {"id": 63, "seek": 161855, "start": 1594.01, "end": 1618.55, "text": "لاحظوا الـ Nitrene دخل بين الـ Carbon و الـ H ولا لأ؟ هاي ال Nitrene هذه كانت Carbon-H صارت Carbon-Nitrene-H واضحت فكرة ال insertion كذلك الحال هنا في هذا المثال الحقيقة اللي هنا تم برضه insertion على الـ H اللي هنا اللي جاب ال double bond مش reaction على ال double bond", "tokens": [15040, 5016, 19913, 14407, 2423, 39184, 37942, 32252, 11778, 9778, 1211, 49374, 2423, 39184, 31453, 4032, 2423, 39184, 389, 49429, 5296, 10721, 22807, 8032, 47302, 2423, 37942, 32252, 29538, 25961, 2655, 31453, 12, 39, 20328, 9640, 2655, 31453, 12, 45, 270, 32252, 12, 39, 4032, 46958, 5016, 2655, 6156, 4117, 25720, 2423, 8969, 313, 9122, 8848, 23275, 21542, 6027, 34105, 8978, 23758, 9673, 12984, 6027, 21542, 38436, 28671, 13672, 1829, 34105, 46811, 4724, 43042, 3224, 8969, 313, 15844, 2423, 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ولذلك هنا لما بدأ أطلع في النهاية، إيش كان عندي هنا؟ H أصار نيترين، هاي هنا H أصار نيترين، إجت الـ Nitrene هنا، والـH مع الـNitrogen، إذا هذا التفاعل insertion ولا addition؟", "tokens": [1211, 33456, 45164, 23758, 4724, 16254, 5551, 25957, 1211, 5480, 15844, 6024, 114, 2407, 38207, 20666, 2304, 35473, 12399, 4724, 16254, 5551, 25957, 1211, 11331, 1211, 28671, 38637, 1211, 5718, 104, 10632, 35525, 8848, 23275, 34105, 5296, 15042, 47525, 10721, 5551, 9566, 1211, 3615, 8978, 28239, 11296, 10632, 12399, 11933, 1829, 8592, 25961, 18871, 16254, 34105, 22807, 389, 5551, 9381, 9640, 8717, 36081, 2288, 9957, 12399, 8032, 47302, 34105, 389, 5551, 9381, 9640, 8717, 36081, 2288, 9957, 12399, 11933, 7435, 2655, 2423, 39184, 37942, 32252, 34105, 12399, 16070, 39184, 39, 20449, 2423, 39184, 45, 270, 7747, 12399, 11933, 15730, 23758, 16712, 5172, 995, 30241, 8969, 313, 49429, 4500, 22807], "avg_logprob": -0.22826704504815015, "compression_ratio": 1.7025862068965518, "no_speech_prob": 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