SELECT MIN("#") FROM table_73323 WHERE "U.S. viewers (million)" = '10.14'
What episode had 10.14 million viewers (U.S.)?
CREATE TABLE table_73323 (
    "No." real,
    "#" real,
    "Title" text,
    "Directed by" text,
    "Written by" text,
    "U.S. viewers (million)" text,
    "Original air date" text,
    "Production code" real
)