Multifunctional co poly(amic acid) A new binder for Si based micro composite anode of lithium ion battery
Abstract Multifunctional co poly(amic acid) (PAmA) containing pyrene and carboxylic acid side chains is developed as a binder for the recycled kerf loss Si Ni SiC composite anode. The capacity retention performance of the lithium ion battery can be apparently enhanced. In a long cycle test of 300 lithiation/delithiation cycles, 79% of capacity retention is achieved. In considering that the recycled kerf loss Si sample contains 38 wt% inactive micro sized SiC abrasive particles, the achieved capacity of 648 mAh g 1 is reasonably high in comparison to other reported values. Small anode thickness expansion of 43% is found in a 100 cycle test, reflecting that the use of the PAmA binder can create strong interconnection among the silicon particles, conductive carbons and copper electrode.