Selective removal of cesium and strontium using porous frameworks from high level nuclear waste.
Efficient and cost effective removal of radioactive (137)Cs and (90)Sr found in spent fuel is an important step for safe, long term storage of nuclear waste. Solid state materials such as resins and titanosilicate zeolites have been assessed for the removal of Cs and Sr from aqueous solutions, but there is room for improvement in terms of capacity and selectivity. Herein, we report the Cs( and Sr(2+ exchange potential of an ultra stable MOF, namely, MIL 101 SO3H, as a function of different contact times, concentrations, pH levels, and in the presence of competing ions. Our preliminary results suggest that MOFs with suitable ion exchange groups can be promising alternate materials for cesium and strontium removal.
Chemical communications