Clay mineralogy and unconventional hydrocarbon shale reservoirs in the USA. I. Occurrence and interpretation of mixed layer R3 ordered illite/smectite
Abstract The mineralogy of many of the major unconventional hydrocarbon shale reservoirs in the USA, which span practically the whole spectrum of Phanerozoic time, is reviewed from a survey of relevant published literature. This survey reveals that there is a remarkable uniformity in the mineralogy of these shales, both with regard to non clay minerals but particularly to the clay minerals. It was found that the clay mineralogy of practically all of the shale reservoirs older than the Upper Cretaceous are dominated by illitic clays, both in discrete form and as illite dominated, mixed layer, illite smectite (I/S) The layer stacking arrangement of the latter is of the long range type described as R3, such that every smectite layer tends to be preceded and succeeded by three illite layers in a sequence like IIISIIIS. Such material is conventionally interpreted (a) as having formed from a smectite precursor, (b) as existing in MacEwan type crystallites consisting of about 5 to 15 unit layers in thickness where there is three dimensional regularity across the smectite interlayers, and (c) as having interlayers of a truly smectitic character. Using evidence from the fundamental particle concept of Nadeau et al. (1984b) this interpretation is rejected. Instead, it is proposed that R3 type I/S (a) forms de novo, crystallizing from pore waters of appropriate chemical composition in a particular pressure and temperature stability field, as it does in conventional sandstone reservoirs, (b) consists primarily of thin illite crystallites or crystals