Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]nickel(II) tetrahydrate
In the title complex, [Ni(C11H9ClN3O2)2]·4H2O, the Ni atom is coordinated by four N atoms and two O atoms derived from two tridentate 3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands. The cis-N4O2 donor set defines a distorted octahedral geometry. In the crystal structure, the complex and water molecules are linked by O—H⋯O hydrogen bonds.
Bis[6-(3,5-dimethyl-1 H -pyrazol-1-yl-κ N 2 )picolinato-κ 2 N , O ]zinc(II) trihydrate
In the title compound, [Zn(C11H10N3O2)2]·3H2O, the ZnII atom is coordinated by four N and two O atoms in a distorted octa­hedral geometry. One water molecule is disordered equally over two positions.
Air scrubbing techniques for ammonia and odor reduction at livestock operations : review of on-farm research in the Netherlands
Acid scrubbers and biotrickling filters have been developed for ammonia (NH3) removal at pig and poultry houses 
in The Netherlands over the last 20 years to prevent acidification and eutrophication of soils. Because of growing 
suburbanization, odor removal is increasingly considered important as well. In this review, we report the results of the on-farm 
research on full-scale operated scrubbers for treatment of exhaust air from animal houses with regard to NH3 and odor 
removal in The Netherlands. The NH3 removal of acid scrubbers ranged from 40% to 100% with an overall average of 96%. 
The NH3 removal of biotrickling filters ranged from -8% to +100% with an overall average of 70%. Minimum empty bed air 
residence times (EBRTs) were 0.4 to 1.1 s. For acid scrubbers, process control with pH measurement and automatic water 
discharge is sufficient to guarantee sufficient NH3 removal. For biotrickling filters, however, improvement of process control 
is necessary to guarantee sufficient NH3 removal. The odor removal of acid scrubbers ranged from 3% to 51% with an overall 
average of 27%. The odor removal of biotrickling filters ranged from -29% to +87% with an overall average of 51%. 
Minimum EBRTs were 0.5 to 2.3 s. Further research is necessary to explain this variation and to improve the odor removal 
efficiency of both acid scrubbers and biotrickling filters.