Biebsanin — A new susquiterpene lactone fromAchillea biebersteinii andA. santolina
Continuing a study of the lactones of Achillea biebersteinii [i] and A. santolina, from the mother liquors [2, 3] by means of the systems chloroform-ethanol (30:1) and benzene--ethyl acetate (1:1) we have isolated a new chlorine-containing sesquiterpene lactone with the composition C15HzgO~CI (ethyl acetate), mp 258-259°C (in a preheated metal block), [u]~ ° --34 ° (c 1.0; pyridine), M + 330, which we have called biebsanin (I).
Rupicolin-A and -B, rupin-A and -B, and cumambrin-B oxide from Artemisia tripartita ssp. Rupicola
Abstract Five new sesquiterpene Iactones have been isolated from Artemisia tripartita Rydb. ssp. rupicola Beetle. The compounds, all guaianolides, are structurally related in what appears to be a sequence in which epoxidation plays the principal role.
Acetylation analysis of saccharides. 2. Microanalysis of neutral glycosphingolipids by means of acetylation with radioactive acetic anhydride.
Abstract The quantitative analysis of mixtures of glycosphingolipids by acetylation with radioactive acetic anhydride and separation by thin-layer chromatography is described. The method was primarily developed for screening of glycosphingolipid composition of tissues, cultured cells, and virus preparations. The sensitivity and linearity of the method is demonstrated. Although theoretically a much higher sensitivity is achievable, in practive about 10 −9 g of glycosphingolipid can be detected and tentatively identified. As an example, the acetylation pattern of lipids from a preparation of herpes simplex virus is demonstrated.