Light scattering spectroscopy of the liquid-glass transition : comparison with idealized and extended mode coupling theory
Light scattering experiments were performed on several fragile glass-forming materials at temperatures ranging from above the melting temperature T, to below the calorimetric glass transition temperature T, in the frequency range 0.2 GHz to 4000 GHz. The experimental susceptibility spectra x”(o) exhibit both the form and the scaling properties predicted by the idealized mode coupling theory. In particular, the scaling frequency o, was found to obey the power law w, a 1 T T,_jzO for three different materials, confirming the predicted “critical slowing down” as T+ Tc from either above or below. At low frequencies and temperatures the spectra deviate from the predictions due to the neglect of ergodicity-restoring activated transport (hopping) processes. We have therefore reanalyzed the data using the extended version of the theory, including activated transport.
Light scattering spectroscopy of the liquid-glass transition
Supercooled liquids approaching the liquid-glass transition exhibit unusual properties associated with structural relaxation. The mode-coupling theory (MCT) of supercooled liquid dynamics shows that non-linear interactions among density fluctuation modes can produce effects resembling these observations. MCT produces detailed predictions for the dynamics of density fluctuations in supercooled liquids, including a crossover from liquid to glassy dynamics at a critical temperature Tc. Recent light scattering studies of supercooled CaKNO3 are described that have provided detailed tests of MCT both above and below Tc, including a cusp in the scaling time at Tc=105+or-5 degrees C. These experiments are reviewed, and comparisons with both the idealized and extended versions of MCT are described.
The effect of collimation on image quality and radiation safety in digital radiography of small animals
Collimating the primary x-ray beam to the specific area of anatomic interest has traditionally been strongly recommended to produce high quality radiographic images, even though some small animal patients can fit their entire torso on a single radiographic casette or detector. However, modern digital radiography may allow for whole-body projections for these patients at similar quality to specific collimated projections. Lateral and ventrodorsal projections of 31 small dogs were obtained to evaluate the effect of collimation on the quality of the resulting digital radiograph. Each projection was performed using both a collimated and whole-body technique. Scatter radiation was detected during each exposure as well to determine the effect of collimation on radiation safety for veterinary personnel. The resulting images were cropped to portray only the thorax, and were evaluated by five radiologists blinded to the procedure used for each image. Visual grading characteristics analysis was performed. An overall trend towards higher image quality was found in the collimated approach compared to the whole-body, but in most cases this change was not significant. Overall image quality for the ventrodorsal images was found to be significantly better in the collimated approach compared to the whole-body. Evaluation of image histograms suggests that the application of digital processing and the look-up table differs between them, and this may account for a large portion of any quality difference. Over twice as much scatter radiation was detected during the whole-body images as during the collimated images. Overall image quality was rated as adequate to high for almost all images with both approaches. Adequate collimation remains recommended to provide the highest quality images with the lowest exposure to veterinary personnel.