Preparation and properties of gradient structure concrete member
Based on the dense packing powder theory, the refining and self-healing principles, and hydrophobic treatment, the special surface-layer materials and design are proposed in gradient structure concrete (GSC) member. According to service behavior, the GSC member is divided into serial structure and parallel structure. And it is fabricated corresponding to structural parameters by stacked press process, or pulled clapboard method, or suspended nets method. Use of small and full scale specimens for testing, the results are shown that: 1) the surface-layer strength of the GSC component improved by 30%, compared to that of a conventional single-layer component; 2) the width of the crack ranges from 0 to 0.1mm in the GSC component, whereas a conventional single-layer component are distributed with visible cracks(0.2–0.5mm);3) The permeating depth and chloride diffusion coefficient of the GSC component is respectively 0mm and 6.3×10–13 m2/s, whereas a conventional single-layer component is 15mm and 12.8×10–13 m2/s.
EFFECT OF THE COMPONENT GRADIENT DISTRIBUTION ON THE STRENGTH OF CEMENT-BASED COMPOSITE MATERIALS
A structural model of cement - based functional gradient materials is put forward based on the concept of gradient structure. The relationships between the gradient distributions of the components and fibers in the cement-based materials were investigated. The results indicate that the continuous gradient change in the components can be obtained using multi-layer vibration method. The bending and compressive strengths of concrete and mortar (FGDCM) reinforced with fibers with gradient distribution were greatly increased in comparison with homogeneous distribution.
Intentional poisoning cases of animals with anticholinesterase pesticide-carbofuran in Sri Lanka.
Carbofuran is a broad spectrum insecticide and nematicide which inhibits acetyl cholinesterase. Several intentional poisoning cases of animals and birds including crows, dogs, cow, and elephant, using carbofuran were reported in Sri Lanka. Qualitative analysis of carbofuran in biological specimens was carried out using T.L.C and GC-MS. The quantitative analysis was carried out by HPLC using Zorbax Eclips XDB-C18 (150 x 4.6 mm I.D x 5 microm particle size) column with acetonitrile: water 25:75 v/v mobile phase and UV detection at 210 nm. The liquid-liquid extraction with chloroform was reproducible and sensitive. The procedure was validated in terms of linearity (0.996<r<0.999) for concentrations ranging from 1 to 200 microg/ml, repeatability (RSD 4.4% at 100 microg/ml, n=10) extraction recovery (91.7% at 100 microg/g, 77.3% at 20 microg/g), limit of detection (S/N ratio=3, 0.7 microg/ml) and limit of quantification (S/N ratio=10, 2.4 microg/ml). The method was found satisfactory and successfully applied in fatal cases of animals and birds due to carbofuran poisoning. The fatal carbofuran levels detected were in the range of 42-910 microg/g in crow's gizzard and contents, 50-800 microg/g in dog's stomach contents, 13-20 microg/g in dog's liver, 0.9 microg/g in cow's stomach and contents, 35 microg/g in elephant's stomach and contents.