X-RAY DIFFRACTION A N A L Y S I S OF THIN CLAY FILMS FROM DILUTE SUSPENSIONS USING G L A N C I N G INCIDENCE DIFFRACTION
-X-ray diffraction (XRD) analysis of small quantities of clay mounted on glass slides using conventional Bragg-Brentano geometry generally produces unsatisfactory low-intensity reflections masked by amorphous substrate scatter. Glancing-incidence asymmetric Bragg diffraction, an alternative uncoupled geometry, uses a fixed low-incidence angle and parallel-beam optics to increase path length through the sample and decrease X-ray penetration into the substrate. To evaluate this technique on thin soil clay films, results from conventional Bragg-Brentano and glancing-incidence diffraction (GID) were compared for progressively diluted clay suspensions separated from 2 southeastern soils with typical mineral assemblages. Patterns produced by GID showed overall higher reflection intensities and reduced substrate scatter, especially at higher 20 angles within the amorphous glass region, Using GID, positive identification of clay minerals was obtained from sample quantities as small as 0.005 mg cm 2 and suspensions as dilute as 29 mg L 1. Key Words--GID, Thin Films, XRD.
A new scheme for x‐ray grazing incidence diffraction
A new scheme for x‐ray grazing incidence diffraction (GID) under total external reflection conditions is presented. This simple scheme allows the grazing angles and the scattering angles to be adjusted independently so that the structural and/or the chemical profiles of materials can be determined at controlled depths. As an example, Si1−xGex/Si superlattice materials were studied. Both commensurate and incommensurate growths between the two quantum wells in the strained‐layer superlattice were observed by the GID technique.
Socially responsible enterprise in Cuba: a positive role model for Corporate Social Responsibility?’
This article examines the unique institutional environment of socialist Cuba, where currently a process of controlled marketization and expansion of private enterprise is taking place. The article investigates business behaviour in Cuba with particular reference to implicit assumptions relating to socially responsible enterprise, or Corporate Social Responsibility (CSR) as the term is understood in Western Liberal Democracies. It draws upon a series of interviews with business practitioners and business commentators (both Cuban and non-Cuban residents on the island). The interviews focused on the participants’ awareness of business ethics and socially responsible enterprise, and the cultural differences in assumptions and expectations relating to the concept of CSR between the Cuban and non-Cuban interviewees. We find that Cuba at this early stage of tentative marketization presents a positive role model of socially responsible enterprise. Both the highly regulated State economy and the embedded norms and values of social equity that have emerged as a consequence of Cuba’s socialist revolution facilitate business social responsibility. The relevance of this research to current debates in relation to CSR is discussed and it is argued that capitalist economies may similarly benefit from tighter regulatory control and by cultivating more pro-social business norms that prioritise ethical over economic concerns.