Analysis of total metals in waste molding and core sands from ferrous and non-ferrous foundries.
Waste molding and core sands from the foundry industry are successfully being used around the world in geotechnical and soil-related applications. Although waste foundry sands (WFSs) are generally not hazardous in nature, relevant data is currently not available in Argentina. This study aimed to quantify metals in waste molding and core sands from foundries using a variety of metal-binder combinations. Metal concentrations in WFSs were compared to those in virgin silica sands (VSSs), surface soils and soil guidance levels. A total analysis for Ag, Al, Ba, Be, Cd, Co, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Te, Tl, V, and Zn was conducted on 96 WFSs and 14 VSSs collected from 17 small and medium-sized foundries. The majority of WFSs analyzed, regardless of metal cast and binder type, contained metal concentrations similar to those found in VSSs and native soils. In several cases where alkyd urethane binder was used, Co and Pb concentrations were elevated in the waste sands. Elevated Cr, Mo, Ni, and Tl concentrations associated with VSSs should not be an issue since these metals are bound within the silica sand matrix. Because of the naturally low metal concentrations found in most WFSs examined in this study, they should not be considered hazardous waste, thus making them available for encapsulated and unencapsulated beneficial use applications.
Geotechnical and leaching properties of flowable fill incorporating waste foundry sand.
Waste foundry sand (WFS) can be converted into flowable fill for geotechnical applications. In this study, WFS samples were obtained from 17 independent metal casting facilities with different casting processes, thus representing a good range of WFS properties. The laboratory studies include physical, geotechnical and leaching properties of flowable fills consisting of WFS, cement, and fly ash mixed to different water contents. The main properties measured include WFS physical properties (density, particle gradation, grain shape, and fine content), WFS flowable fill geotechnical properties (unconfined compressive strength, hydraulic conductivity, setting time, and bleeding), and the fill's leaching properties (heavy metals and organics in the bleed water and the leachate extracted from hardened WFS flowable fills). The test results indicate that in terms of the physical properties, most of the data fall within narrow ranges, although data from the copper/aluminum-based WFS samples might fall beyond the ranges. Geotechnical properties of WFS flowable fills in both fresh and hardened phases were verified conforming to the features of specified flowable fills. Material leaching analyses indicate that the toxicity of WFS flowable fills is below regulated criteria. A mix formulation range originated from this study is proposed for the design of WFS made flowable fill.
Morpho-biometric Relationship, Relative Condition Factor and Meat Yield of Distant Scallop Bractechlamys vexillum (Reeve, 1853) in Asid Gulf, Philippines
Understanding the relationships of morphometric and biometric characters of a species allows the prediction of one trait from the other and generate a measure of relative condition. These relationships were studied for the Distant scallop Bratechlamys vexillum (Reeve, 1853) in Asid Gulf. Representative samples collected during the dry season (May 2018, n = 99) and wet season (September 2018, n = 100) were used to analyse these relationships through models of simple linear and power regression analyses, revealing allometric growth patterns. For both periods, it was revealed that shell width (SW) is a slightly better predictor than the height (SH) for total weight (TW) (R2 = 0.90 and 0.92) and the adductor muscle weight (AW) (R2 = 0.78 and 0.80). The strong functional relationship was also observed between TW and AW (R2 = 0.80 and 0.81). The relative condition factors (Kn) were high in both seasons. High meat yields were also observed in May (12.77 %) and September (14.26 %). The significant difference in meat yields (P < 0.05) can be a result of the seasonal difference manifested by the dynamics of energy partitioning during gametogenesis and spawning. These biological metrics are vital inputs in analysing mariculture prospects for the resource and a contribution to the scarce information on the biology of the species.