Scale and Corrosion Prevention in Cooling Water Systems Part II: Calcium Sulphate
This paper describes an experimental study on calcium sulphate scaling and prevention by newly treated poly- acrylamide in a laboratory model. In order to study the inhibiting capacity of the chemical used, experiments were per- formed in solutions involving treatment of synthetic sea water with different concentrations of the polymer. Polyacryla- mide gave significantly lower precipitation rate compared to the treatment in absence of inhibitor. The inhibitor probably is adsorbed on the active growth sites of the initially formed crystals. The performances of scale inhibitor with different concentrations were analyzed in terms of the amount of soluble calcium ions in solution. The results showed that the amount of scale was reduced to 0.00%, with, 10-15 ppm polymer additions, after 1 day incubation at 90°C. Antiscale agents specific to calcium sulphate deposits have recently been developed and tested on a laboratory scale. The work was also extended to study the corrosion inhibition of polyacrylamide to both C-steel and copper specimens in contact with synthetic cooling water environment. Electrochemical polarization techniques reveal that the inhibitor acts as anodic type with respect to C-steel and mixed type for copper. Corrosion current jcorr and corrosion rate CR were reduced and inhibi- tion efficiency IE% increases with polymer additions. The inhibition effects are due to the formation of protective film. Morphological investigation for CaSO4. 2H2O gypsum crystals formed in synthetic sea water indicate reduction of cal- cium sulphate crystals in the presence of the polymer as indicated by scanning electron microscopic (SEM) studies.
The Influence of Recirculating Water Impurities on the Performance of Calcium Phosphate Inhibiting Polymers
Many factors, including pH, temperature, make-up water quality, and heat exchanger metallurgy, influence the performance of polymeric inhibitors in treating recirculating cooling water systems. The availability of good quality make-up water and the imposition of stringent wastewater discharge regulations have forced many cooling systems to operate at increasingly higher cycles of concentration. The severity of these operating conditions often results in waters that have higher scale formation potential. Presented here is information regarding the influence of impurities, such as suspended matter and metal ions, on the performance of polymeric inhibitors used in phosphate-based treatment programs.
The risk of Listeria monocytogenes infection in beef cattle operations
Aim:  To determine the prevalence of Listeria monocytogenes and associated risk factors among beef operations (cow‐calf and feedlot) in central and southern California.