Growth Mechanism and Crystal Form of Potassium Dichromate
The structure of potassium dichromate (P1, Z = 4) consists of two layers parallel to (001), between which no crystallographic symmetry relation exists. These layers are nearly coincident with each other when rotated through 90° about c * . One question remained unanswered: do the crystals grow parallel to {001} with d(002) or d(001) layers? The pseudo-fourfold axis does not run parallel to a crystallographic direction and acts only between two layers. This means that crystal growth parallel to {001} occurs in d(001) layers, which corresponds to the occurrence of one-sided intergrowths on (001). The layers are also nearly coincident with each other through pseudo-twofold axes parallel to [110] and [110], These axes do not act in the (100) or (010) projections. In the projections along the [110] and [110] directions, the lattice directions are then extended by a factor of approximately √2, and the formula units in the cell of the d(002) layer are doubled. This indicates a further possible growth mechanism. The theoretical growth forms of the crystals were calculated with the Fourier transform method of morphology.
Phase transitions in K2Cr2O7 and structural redeterminations of phase II.
Crystals of phase II K2Cr2O7, potassium dichromate, space group P1 , grown from aqueous solution undergo a first-order transition to phase I, space group reportedly P21/n, at a phase-transition temperature, TPT, of 544 (2) K on first heating; the corresponding transition on cooling is at 502 (2) K. The endotherm on subsequent heatings occurs reproducibly at TPT = 531 (2) K. Mass loss between ca 531 and 544 K, identified as included water, is rapid and continues more slowly to higher temperatures for a total loss of ca 0.20%. The higher TPT on first heating is associated with the increasing pressure of superheated water occupying inclusion defects. The latent diagonal glide plane in phase II allows the structure of phase I to be inferred. The triclinic structure at 296 K has been independently redetermined. Normal probability analysis shows high consistency between the resulting and previous atomic coordinates, but with uncertainties reduced by a factor of ca 2. The earlier uncertainties are systematically underestimated by a comparable factor. The structure of phase IIb, space group A2/a on transposing axes, was determined at ca 300 K by Krivovichev et al. [Acta Cryst. (2000), C56, 629-630]. The first-order transition between phases I and II arises from the ca 60 degrees relative rotation of terminal O atoms in each tetrahedron as the n glide plane is gained or lost. A transition between phases IIb and I, also of first order, is likely but not between phases II and IIb. An intermediate phase may exist between phases IIb and I.
Image Projection in Immersive 3D Visualization Laboratory
In recent years, many centers in the world attempted to build a virtual reality laboratory. The main idea of such laboratory is to allow the user to “immerse” into and move in a computer-generated virtual world. In the paper, the underlying principles of the system of virtual reality (VR) are described. The selected implementations constructed by the research centers of the world are also presented. The cave automatic virtual environment (CAVE) installation is planned to be implemented at the Gdansk University of Technology. In this solution, the images will be projected on flat screens arranged in the form of a cube. The user will be located inside a transparent sphere freely rotating inside a cube, which allows simulation of free movement without changing the position of the screens. A walking motion of the user will trigger changes in the computer-generated images on screens surrounding the sphere thus creating an illusion of motion. The problems of visualization in the planned installation are outlined and discussed.