Growth and optical properties of transition metal oxides single crystal solid solutions
Abstract NiO, CoO, MnO single crystals and single crystal solid solutions of Ni c Mg 1− c O, Co c Mg 1− c O and Mn c Mg 1− c O were grown by the method of chemical transport reaction (the “sandwich” technique). The nature of the observed absorption and luminescence bands is explained in terms of the electronic transition of bivalent nickel, cobalt and manganese. The fine structure of the observed bands in NiO and MnO are connected to the pure exciton transition and to the exciton-magnon excitation.
Phase diagram and magnetic properties of the diluted fcc system NipMg1-pO.
Starting from Ni and Mg nitrates, about 20 samples of ${\mathrm{Ni}}_{\mathit{p}}$${\mathrm{Mg}}_{1\mathrm{\ensuremath{-}}\mathit{p}}$O samples (with 0.06\ensuremath{\le}p\ensuremath{\le}0.86) were prepared and x-ray-diffraction studies showed the samples to have the NaCl structure with the lattice constant fitting the expression a(p)=4.2115-0.0340p \AA{}. Temperature-dependent magnetic-susceptibility (\ensuremath{\chi}) studies of the samples were carried out between 1.8 and 600 K using a superconducting-quantum-interference-device magnetometer and N\'eel temperatures ${\mathit{T}}_{\mathit{N}}$'s were determined from the peak in \ensuremath{\partial}(\ensuremath{\chi}T)/\ensuremath{\partial}T. The variation of t=${\mathit{T}}_{\mathit{N}}$(p)/${\mathit{T}}_{\mathit{N}}$(1) vs p is compared with that of ${\mathrm{Co}}_{\mathit{p}}$${\mathrm{Mg}}_{1\mathrm{\ensuremath{-}}\mathit{p}}$O. For both systems, the variations for pg0.31 are found to fit the predicted values for a simple-cubic Heisenberg antiferromagnet and a theoretical basis for this anomalous result is advanced. The experimental percolation threshold ${\mathit{p}}_{\mathit{c}}$=0.15\ifmmode\pm\else\textpm\fi{}0.01 and for ${\mathit{p}}_{\mathit{c}}$p0.31, \ensuremath{\chi} below ${\mathit{T}}_{\mathit{N}}$ shows irreversible behavior for the zero-field-cooled and field-cooled cases, suggestive of spin-glass-like behavior also observed in other diluted fcc antiferromagnets, such as ${\mathrm{Co}}_{\mathit{p}}$${\mathrm{Mg}}_{1\mathrm{\ensuremath{-}}\mathit{p}}$O and ${\mathrm{Eu}}_{\mathit{p}}$${\mathrm{Sr}}_{1\mathrm{\ensuremath{-}}\mathit{p}}$Te. It is suggested that the differences in the t-vs-p variations for p0.31 in ${\mathrm{Ni}}_{\mathit{p}}$${\mathrm{Mg}}_{1\mathrm{\ensuremath{-}}\mathit{p}}$O, ${\mathrm{Co}}_{\mathit{p}}$${\mathrm{Mg}}_{1\mathrm{\ensuremath{-}}\mathit{p}}$O, and ${\mathrm{Eu}}_{\mathit{p}}$${\mathrm{Sr}}_{1\mathrm{\ensuremath{-}}\mathit{p}}$Te may be related to the differences in the ratio of the next-nearest-neighbor to nearest-neighbor exchange constants in these systems.
EXAFS and XANES Studies of CoxMg1−xO Solid Solutions Using a Laboratory EXAFS Spectrometer
Studies of the local electronic structure and the short-range order in solid solutions CoxMg1−xO with x varying from 0.02 to 1.00 are carried out on the CoK-edge X-ray absorption spectra using a laboratory EXAFS spectrometer. A non-monotonous change of the CoO distance in the first coordination shell with a bent at about x = 0.5 is established. The second coordination shell of cobalt is formed by cobalt and magnesium atoms with a distribution close to a statistical one. 
 
 
 
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