Vapor Compression and Thermoelectric Heat Pumps for a Cascade Distillation Subsystem: Design and Experiment
Humans on a spacecraft require significant amounts of water for drinking, food, hydration, and hygiene. Maximizing the reuse of wastewater while minimizing the use of consumables is critical for long duration space exploration. One of the more promising consumable-free methods of reclaiming wastewater is the distillation/condensation process used in the Cascade Distillation Subsystem (CDS). The CDS heats wastewater to the point of vaporization then condenses and cools the resulting water vapor. The CDS wastewater flow requires heating for evaporation and the product water flow requires cooling for condensation. Performing the heating and cooling processes separately would require two separate units, each of which would demand large amounts of electrical power. Mass, volume, and power efficiencies can be obtained by heating the wastewater and cooling the condensate in a single heat pump unit. The present work describes and compares two competing heat pump methodologies that meet the needs of the CDS: 1) a series of mini compressor vapor compression cycles and 2) a thermoelectric heat exchanger. In the paper, the CDS system level requirements are outlined, the designs of the two heat pumps are described in detail, and the results of heat pump analysis and performance tests are provided. The mass, volume, and power requirement for each heat pump option is compared and the advantages and disadvantages of each system are listed.
Design, Simulation and Test of Thermal Control System of Centrifuge for Space Utilization
Taking centrifuge system for space utilization as the research object, an active air-cooling thermal control system is put forward. Physical models of the centrifuge thermal control system are built on the basis of simplifying assumptions under actual conditions. A numerical calculation model of centrifuge system is established by using the sliding mesh technique and flow resistance model of heat exchanger is introduced based on the porous medium theory. A numerical analysis of the dynamic heat exchange performance of the centrifuge is carried out and the results show the flow and heat exchange characteristics of each part of the system in the dynamic equilibrium state. Also, the centrifuge system and its heat exchange performance test platform are designed and built, and the monitoring probes are placed at the key position. The curves of the whole equilibrium process of key points are obtained and the test condition is consistent with numerical simulation condition. The equilibrium temperatures of the test are in agreement with that of the numerical analysis, which proves that the numerical model and calculation method are accurate. Meanwhile, the test and numerical analysis results can also improve each other to provide data and supporting techniques for in-orbit engineering utilization of manned space station in future.
Highly enantio- and diastereoselective synthesis of β-methyl-γ-monofluoromethyl-substituted alcohols.
Enanatiopure β-methyl-γ-monofluoromethyl alcohols were prepared from the allylic alkylation between fluorobis(phenylsulfonyl)methane with Morita-Baylis-Hillman carbonates. The reaction was catalyzed by using the Cinchona alkaloid derivative, (DHQD)(2)AQN. The origin of the stereoselectivity was verified by DFT methods. Calculated geometries and relative energies of various transition states strongly support the observed stereoselectivity.