NUMERICAL SIMULATION OF FIRE SPREAD ON POLYURETHANE FOAM SLABS | NIST
Computational Fluid Dynamics (CFD) models are used extensively by fire protection engineers for performance based design and forensic analysis. The equations of motion describing the gas phase are relatively well known and the approximations in the various gas phase sub-models have been extensively studied. However, coupling of the gas phase and the condensed phase to describe flame spread over a burning solid, has proven to be difficult to model. This is due to a lack of understanding of the underlying physical phenomena that take place during the decomposition of the solid as well as poor characterization of the fundamental material properties that control the burning process. The overall goal of this project is to improve the capability of the fire models to predict flame spread over materials that typically burn in a compartment fire. In this paper, we attempt to simulate fire growth and spread on 10 cm thick slabs of polyurethane foam. A multi-layered, multi-material model was developed to simulate flame spread, and material properties were obtained from various small scale experiments. Model predictions were compared with large scale experiments on polyurethane foam slabs, ignited on one edge. Results indicate that the model is capable of qualitatively predicting the observed trends in heat release rate, flame spread rate and heat fluxes measured in the experiments. This report will describe the progress that has been made to date on modeling fire growth and spread on polyurethane foam slabs and the comparison of these results with experimental data.
Sensitivity of Heat of Reaction for Polyurethane Foams
The heat of reaction for the decomposition of polyurethane foam and its melt are determined from the heat flow measurements obtained through simultaneous differential scanning calorimetry and thermogravimetric analysis. Under nitrogen environment, the decomposition of foam experiences two endothermic pyrolysis reactions based on the experimental results. Through the investigation on the sensitivity of heat of reaction to heating rate and sample mass, a region where the heat of reaction remains constant is found for the melt samples tested. This consistent region includes heating rate from 5 to 20 °C/min and sample mass between ~20 and ~50 mg. No consistent region is found for the foam samples because of the reduced accuracy in the heat flow measured. For the foams and melts tested, the consistent heat of reaction for the second reaction ranges from endothermic 164 ‐ 295 J/g while the recommended heat of reaction for the first reaction ranges from endothermic 610 ‐ 1023 J/g.
Effect of Calcium Glycerophosphate on Demineralization in an in vitro Biofilm Model
The aim was to investigate the anti-caries properties of calcium glycerophosphate (CaGP) using an in vitro bacterial flow cell model. Four flow cells, inoculated from a chemostat containing a seven-organism bacterial consortium, were pulsed with sucrose twice daily, to provide an acidic challenge and pH-cycling conditions. Blocks of enamel and dentine were mounted in each flow cell. In a study on the effect of CaGP concentration, CaGP was pulsed into three of the flow cells, at the same time as the sucrose, to give concentrations of 0.10, 0.25 and 0.50%. Water was pulsed into the fourth flow cell with the sucrose. Microradiography revealed a significant dose response of decreasing demineralization as CaGP concentration increased. Reductions at 0.25 and 0.5% were significant when compared to the control. A second study investigated the effect of timing of CaGP pulsing, relative to sucrose, on enamel and dentine demineralization. CaGP (flow cell concentration 0.2%), was pulsed 1 h before, during or 1 h after the sucrose pulse; a water control was employed. In enamel, pulsing CaGP before the sucrose reduced demineralization significantly compared to concurrent pulsing, which in turn gave a significant reduction compared to pulsing after sucrose, which did not reduce demineralization significantly compared to the water control. In dentine, CaGP reduced demineralization significantly only when pulsed before the sucrose. The findings suggest that in vivo, the anti-caries potential of CaGP may be greater if it is applied before a cariogenic challenge.