Magneto-resistance, stress effects, and a self-similar expansion model for the magnetization processes in amprphous wires
The outer shell magnetization process was investigated from the point of view of its effects on longitudinal and transverse magnetoresistance (MR), magnetization, and domain structure observations as well as their stress effects for a Fe/sub 77.5/Si/sub 7.5/B/sub 15/ amorphous wire with a diameter of 125 mu m prepared by rapid quenching in rotating water. The unusual behavior of the initial negative slope observed in the longitudinal MR is explained in terms of a realistic domain structure. A self-similar expansion model is proposed to explain the dynamical response of such a structure under applied fields and/or tensile stresses. It is suggested that the zig-zag domains of the outer shell are stabilized by a square closure domain which expands uniformly while maintaining a self-similar shape up to a threshold field of about 20 Oe and then deforms towards the saturation magnetization. However, this domain structure was destroyed or much deformed by a tensile stress along the wire axis of about 170 MPa in the sample. Such a critical stress depends on the diameter, quenching conditions, alloy composition, etc. This behavior and stabilization of the zig-zag domain by the closure domains give a novel mechanism for the magnetization processes which follow the re-entrant reversal, and are thus useful for the understanding of re-entrant reversal phenomena themselves. >
Effects of longitudinal currents and torsion on the magnetization process in amorphous wires
The effects of longitudinal currents and torsion on the magnetization process of positive, negative, and nearly zero magnetostrictive Co- and Fe-based amorphous wires were studied. With a DC current flowing through the wire, a shift in the bistable magnetic response was observed which was dependent on the sign of the magnetostriction. The well-known bistable magnetic switching character was also observed in inverse Wiedemann effect (IWE) studies of these wires. It is concluded that the observed effects appear to be quite promising for applications in sensors and in a wide range of new active and passive elements. >
Development of new analytical methods for the determination of caffeine content in aqueous solution of green coffee beans
BackgroundThis study was conducted to develop fast and cost effective methods for the determination of caffeine in green coffee beans. In the present work direct determination of caffeine in aqueous solution of green coffee bean was performed using FT-IR-ATR and fluorescence spectrophotometry. Caffeine was also directly determined in dimethylformamide solution using NIR spectroscopy with univariate calibration technique.ResultsThe percentage of caffeine for the same sample of green coffee beans was determined using the three newly developed methods. The caffeine content of the green coffee beans was found to be 1.52 ± 0.09 (% w/w) using FT-IR-ATR, 1.50 ± 0.14 (% w/w) using NIR and 1.50 ± 0.05 (% w/w) using fluorescence spectroscopy. The means of the three methods were compared by applying one way analysis of variance and at p = 0.05 significance level the means were not significantly different. The percentage of caffeine in the same sample of green coffee bean was also determined by using the literature reported UV/Vis spectrophotometric method for comparison and found to be 1.40 ± 0.02 (% w/w).ConclusionNew simple, rapid and inexpensive methods were developed for direct determination of caffeine content in aqueous solution of green coffee beans using FT-IR-ATR and fluorescence spectrophotometries. NIR spectrophotometry can also be used as alternative choice of caffeine determination using reduced amount of organic solvent (dimethylformamide) and univariate calibration technique. These analytical methods may therefore, be recommended for the rapid, simple, safe and cost effective determination of caffeine in green coffee beans.