Electrical and thermal transport properties of icosahedral Al70Pd22.5(Re1−xMnx)7.5 quasicrystals
This work presents measurements of the electrical resistivity (ρ), Seebeck coefficient, and thermal conductivity (κ) of icosahedral Al70Pd22.5(Re1−xMnx)7.5 quasicrystals from 10to300K. A series of quasicrystals was prepared with x=0, 0.1, 0.2, 0.3, 0.5, 0.6, 0.8, and 1.0 to systematically study the effect of substitution. The electrical resistivity increases as the temperature decreases, suggesting a semiconductinglike behavior in these alloys. The room-temperature values of the Seebeck coefficient vary from −5μV∕K to +65μV∕K, showing a significant dependence on the value of x. However, κ exhibits a rather weak composition dependence in the temperature range investigated. The room-temperature dimensionless thermoelectric figure of merit (ZT) of this system is optimized at x=0.1. With further appropriate heat treatments, high ZT is presumably available at elevated temperatures in the Al70Pd22.5(Re0.9Mn0.1)7.5 sample.
Figure of merit of quasicrystals: the case of Al-Cu-Fe
Quasicrystals exhibit low thermal and moderate electrical conductivity, accompanied by a relatively high absolute magnitude of thermopower, which makes them suitable candidates for use as thermoelectric devices. Theoretical explanations of electrical and thermal conductivity and thermopower of two representative members of the Al-Cu-Fe icosahedral quasicrystal family (i-Al62Cu25.5Fe12.5 and i-Al63Cu25Fe12) are given. Their figures of merit are relatively low compared with the best-known thermoelectric materials.
Clinical chemical values and variations in Rasa Aragonesa ewes and lambs
Reference values of biochemical parameters in serum of Rasa Aragonesa ewes and their physiological variations were determined. Total proteins were 53.0–80.0 g/l, glucose 2.17–5.13 mmol/l, cholesterol 0.83–2.31 mmol/l, total bilirubin 1.85–6.49 μmol/l, urea 3.15–10.39 mmol/l, GGT 36–93 U/l (37°C), ALAT 11–33 U/l (37°C) and ASAT 71–209 U/l (37°C). Ewes were divided into three groups: A, 1- and 2-year-old ewes; B, ewes 3 and 4 years old; C, older ewes. Age had significant influence (P<0.05) on ASAT only during pregnancy, with higher levels for younger ewes. Blood parameters in lambs were determined at 5–10 d of life (nursing), 25 to 30 d of life receiving their mother's milk and 80–90 g of feed; and 45 to 50 d of life, weaned, receiving only solid feed. Serum urea and ALAT tended to increase with age, whereas total protein, globulins, cholesterol and GGT decreased with age. These values are of practical importance in the diagnosis of diseases and metabolic disorders in Rasa Aragonesa ewes and lambs under field conditions.