The chemical process accompanying the hydrogenation of fats I. Geometrical isomerization
Summary1. It has been shown for numerous examples that the catalytic hydrogenation of fats is accompanied by the cis-trans isomerization of the radicals of the unsaturated acids.2. A scheme is proposed which explains the mechanism of the isomerization through a process of the hydrogenation-dehydrogenation of the olefinic compounds.
Modern State of the Multiplet Theor of Heterogeneous Catalysis
Publisher Summary This chapter reviews the modern state of the multiplet theory of heterogeneous catalysis. The multiplet theory deals with numerical values of bond lengths and bond energies, as well as with the geometrical form of reacting molecules and the crystal lattices of catalysts. This allows definite results to be obtained for many reactions on an atomic level. This is how the multiplet theory differs from a number of other theories on catalysis. The theory of the structure of matter is based on both electronic theory and quantum mechanics—the basis for the multiplet theory. Bond lengths and energies represent a stable complex of electronic properties essential for catalysis. The multiplet theory proceeds from the premise that catalysis is a chemical phenomenon and that covalent bonds require catalytic activation.
Code switching in Ahdaf Soueif's The Map of Love
This article examines the phenomenon of code switching in The Map of Love (1999) by the Egyptian—British writer Ahdaf Soueif. Though she chooses English as a medium for her creative expression, Soueif deploys Arabic in her narrative to represent different aspects of the linguistic and cultural norms of Egyptian society. The article's methodology is informed by Kachru's framework on contact literature and his categorization of the occurrence of literary code switching or bilingual creativity into different strategies that encompass cultural and linguistic processes. The results indicate the predominance in The Map of Love of the discourse strategies of employing lexical borrowing, culture-bound references and translational transfer. Finally, the article analyzes the functional motivation of code switching in the postcolonial context of the novel and how the use of certain creative strategies might enhance or diminish the narrative's effectiveness and readability.