Crystallization, morphology and magnetic properties of melt-spun (Nd,Pr,Dy)/sub 2/(Fe,Co,Mo)/sub 14/B//spl alpha/-Fe nanocomposites
Crystallization, phase evolution, nanostructure, exchange coupling, and hard magnetic properties of melt-spun Nd/sub 2.4/Pr/sub 5.6/Dy/sub 1/Fe/sub 85/B/sub 6/ and Nd/sub 2.4/Pr/sub 5.6/Dy/sub 1/Fe/sub 78/Co/sub 6/Mo/sub 1/B/sub 6/ nanocomposites have been studied. All the Nd/sub 2.4/Pr/sub 5.6/Dy/sub 1/Fe/sub 85/B/sub 6/ alloys annealed for 30 s at 565/spl deg/C or above contain nanostructured /spl alpha/-Fe and Nd/sub 2/Fe/sub 14/B-type (2:14:1) phases, whereas Nd/sub 2.4/Pr/sub 5.6/Dy/sub 1/Fe/sub 78/Co/sub 6/Mo/sub 1/B/sub 6/ alloys annealed at 600/spl deg/C or below are mainly composed of /spl alpha/-Fe and a metastable 1:7 phase. A small amount of 2:14:1 phase forms after annealing at 600/spl deg/C. When annealed at 640/spl deg/C or above, the hard phase in Nd/sub 2.4/Pr/sub 5.6/Dy/sub 1/Fe/sub 78/Co/sub 6/Mo/sub 1/B/sub 6/ alloys is the 2:14:1 phase rather than the 1:7 phase. The differences in magnetic properties of the Nd/sub 2.4/Pr/sub 5.6/Dy/sub 1/Fe/sub 85/B/sub 6/ and Nd/sub 2.4/Pr/sub 5.6/Dy/sub 1/Fe/sub 78/Co/sub 6/Mo/sub 1/B/sub 6/ nanocomposites at different anneal temperatures result from the different nanostructures, exchange coupling and phase components present in the alloys, in particular from the different amount of the 1:7 phase.
Magnetic properties of (Nd,Pr,Dy)2Fe14B/α-Fe nanocomposite magnets crystallized in a magnetic field
The effect of applying a magnetic field during the crystallization process of a melt-spun Nd2.4Pr5.6Dy1Fe85B6 alloy on the nanostructure, crystallographic texture, exchange coupling, and magnetic properties has been studied. Compared with samples annealed without magnetic field, there was a noticeable improvement in the intrinsic coercivity iHc, the remanence Br, and the maximum magnetic energy product (BH)max for Nd2.4Pr5.6Dy1Fe85B6 alloys annealed in a 12 kOe field. The magnetic performance improved with an increase in the magnetic fields applied up to 9 kOe. Crystallographic alignment and magnetically anisotropic behavior were found in the samples crystallized in the magnetic field. The improvement in magnetic properties after magnetic crystallization is considered to be the result of both magnetic-field-induced crystallite alignment and enhanced exchange coupling due to a reduction of grain size.
Nonenzymatically galactosylated serum albumin in a galactosemic infant.
Galactosemia is a molecular disease of genetic origin that is characterized by a deficiency of galactose-1-phosphate uridyltransferase.1 , 2 The resulting severe impairment of galactose metabolism ...