Spectral control development for thermophotovoltaics
Gallium Antimonide (GaSb) infrared photovoltaic cells are light weight whereas batteries are heavy. The specific energy in a hydrocarbon fuel is high at 12,900 W-hr per kg but a lithium ion rechargeable battery has a specific energy of only 145 W-hr per kg. A 10% efficient portable lightweight thermophotovoltaic (TPV) cylindrical generator when compared with a battery can have 6.5 times higher specific energy, operates 7 times longer, and be quickly refueled. The key is the 10% efficiency goal. This efficiency goal depends on matching the spectrum from a combustion heated ceramic IR emitter to the response band of the IR PV cell. Herein, spectral measurements are presented for a propane burner and ceramic IR emitter assembly surrounded by a fused silica glass envelope. The cylindrical IR ceramic emitter consists of an array of NiO doped MgO rods or slats. The Ni ion emission line is centered at 1.6 microns and it matches the GaSb IR response band extending out to 1.8 microns. The ceramic IR emitter is combustion heated to approximately 1200 C. The fuel and air combustion efficiency and hot gas coupling efficiency to the IR emitter are also important parameters.
Spectral filtering of sub-bandgap radiation using all-dielectric gratings for thermophotovoltaic applications
Abstract. Filtering of the sub-band spectral radiation is an attractive technique to overcome the lower efficiencies of direct conversion thermophotovoltaic technology. The poor performance of these systems is due to the relatively small portion of the incident energy being above the bandgap of photovoltaic cell. To effectively filter the majority of the sub-bandgap radiation and re-employ it as regenerative heat, a viable solution is to design an efficient spectrally selective filter ideally matched to the photovoltaic cell’s bandgap. Here, we have explored a high contrast amorphous silicon grating on a quartz substrate. Quartz due to its inherent nature inhibits transmission of sub-band gap radiation in the infrared (IR) region (>4.75  μm), whereas gratings further filter radiation above 1.8  μm suitable for GaSb photovoltaic cell. The optimized filter is fabricated using direct write laser lithography, and optical characterization result shows that 72% of incident radiation in unconvertible region (>1.80  μm) is filtered and recycled. Further, the thermal characterization results of IR filter carried out using a ceramic heater has shown the drop in effective temperature from 1074.9 to 813.2 K in above bandgap region. This suppressed radiation has contributed to an absolute increase in source body temperature by 16.0 K resulting in increase in the above bandgap radiation available for thermophotovoltaic conversion. The proposed spectral filtering design can be tailored to solar cells of any bandgap and is scalable for employment in various thermophotovoltaic applications.
Analysis of the stress wave effect during coal breakage by a high-pressure abrasive air jet
In view of the defects of borehole collapse, inhibition of gas desorption and migration of gas existing in hydraulic fracturing and other hydraulic permeability–increasing measures for soft coal seams with low-permeability technology is proposed for coal breakage by a high-pressure abrasive gas jet for relieving pressure and increasing permeability. The comparative analysis of gas jet flow field structure between convergent nozzle and Laval nozzle has been given by numerical simulation. For Laval nozzle, the expansion wave and compression wave alternate and move forward steadily in gas jet and vanish when potential core length reaches maximum. So, the Laval nozzle can form more stable flow filed structure of gas jet and avoid shock wave in gas jet. Furthermore, a high-speed camera is adopted to analyze the jet structure and verify the conclusion of numerical simulation. Based on thermodynamic theory, this article calculates and analyzes the critical local sound velocity and pressure generated from the stress wave during the process of coal breakage by the gas jet. Furthermore, experimental coal breakage by a high-pressure abrasive gas jet is carried out. The high-pressure abrasive gas jet impacts the coal body as a quasi-static load and a dynamic load and forms corrosion pits on the surface of the coal body. Penetrating cracks are formed within the coal in the pattern of the loaded stress wave which leads to coal breakage. The effects of porosity and permeability on the propagation of the stress wave in coal are analyzed by establishing the dispersion equation for the spread of the stress wave in coal. The results show that porosity has a significant effect on wave velocity and that the attenuation of the stress wave is intensified with an increase in porosity. Moreover, the stress wave attenuation is more obvious at high frequency. The effect of permeability on the wave velocity is not significant at low frequencies. In contrast, at high frequency and relatively low permeability, the wave velocity increases with the permeability, and the attenuation of the wave velocity initially increases and then decreases. When the permeability is greater than 10−11 m2, the wave velocity is not affected by the permeability. However, the stress wave is not attenuated.