On the structural integrity of the spinel block in the β"-alumina structure.
The β''-alumina structure is examined in detail and an analysis is presented of the three-dimensional integrity of the lattice. The layer structure that is responsible for the very high sodium conduction rate is the specific focus. Rigid layers that are derived from the cubic spinel structure are interleaved by more open honeycomb pathways where rapid ion diffusion takes place. The three-dimensional rigidity of the spinel block in this structure makes it possible to accurately quantify the conduction layer thickness based only on the hexagonal unit-cell dimensions, as suggested originally by Harbach [(1983), J. Mater. Sci. 18, 2437-2452]. His calculation is tested rigorously against the many single-crystal structure determinations that have been made on the β''-alumina family compounds and excellent correlation is found.
Molecular dynamics simulations of Mg-doped beta″-alumina with potential models fitted for accurate structural response to thermal vibrations
Abstract A new interatomic potential model has been developed for Mg-doped beta″-alumina, using free energy optimization. By including the thermal expansion during potential fitting, the new potentials allow for an improved description of the structural behavior at different temperatures in molecular dynamics (MD) simulations. The new model was applied to study the detailed structural responses to temperature and transport properties of Mg-doped beta″-alumina. Results suggest that the sodium diffusion in beta″-alumina is highly correlated, and reliable electrical conductivity of beta″-alumina can only be extracted from molecular dynamics with substantial simulation duration and resolution, which may be best provided by long time scale classical simulations with accurate potentials.
Pig Vocalizations Under Selected Husbandry Practices
Acoustical characteristics of vocalizations of sows, piglets, and nursery pigs under selected husbandry practices were analyzed with a digital signal processing system. The duration (D) and major energy-resonance frequency (P) for each call were determined as follows: a) processing of piglets (D = 0.81 s and f* = 3 700 Hz); b) food anticipation of breeding-gest ation sows (2.50 s and 3 000 Hz); c) isolation of piglet (0.34 s and 500, 3 500 Hz); d) startling of nursery pigs (0.29 s and 900 Hz); e) sows in heat (3.07 s and 1 375 Hz); f) farrowing (0.10 s and 3 000 Hz); g) sow nursing (0.15 s and 1 000 Hz); and h) mate greeting of sow (0.13 s and 1 000 Hz). Calls a) to d) are responses to human generated stressors, and calls e) through h) responses to social and physiological states of the pigs. Thus, vocalizations can be segmented for different pig production situations.