Defect chemistry and transport properties of BaxCe 0 . 85 M 0 . 15 O 3 -
The site-incorporation mechanism of M dopants into ABO3 perovskites controls the overall defect chemistry and thus their transport properties. For charge-balance reasons, incorporation onto the A-site would require the creation of negatively charged point defects (such as cation vacancies), whereas incorporation onto the B-site is accompanied by the generation of positively charged defects, typically oxygen vacancies. Oxygen-vacancy content, in turn, is relevant to proton-conducting oxides in which protons are introduced via the dissolution of hydroxyl ions at vacant oxygen sites. We propose here, on the basis of x-ray powder diffraction studies, electron microscopy, chemical analysis, thermal gravimetric analysis, and alternating current impedance spectroscopy, that nominally B-site doped barium cerate can exhibit dopant partitioning as a consequence of barium evaporation at elevated temperatures. Such partitioning and the presence of significant dopant concentrations on the A-site negatively impact proton conductivity. Specific materials examined are BaxCe0.85M0.15O3(x 0.85 − 1.20; M Nd, Gd, Yb). The compositional limits for the maximum A-site incorporation are experimentally determined to be: (Ba0.919Nd0.081)(Ce0.919Nd0.081)O3, (Ba0.974Gd0.026)(Ce0.872Gd0.128)O2.875, and Ba(Ce0.85Yb0.15)O2.925. As a consequence of the greater ability of larger cations to exist on the Ba site, the H2O adsorption and proton conductivities of large-cation doped barium cerates are lower than those of small-cation doped analogs.
11. Ionic Conduction and Applications
Solid state ionic conductors are crucial to a number of major technological developments, notably in the domains of energy storage and conversion and in environmental monitoring (such as battery, fuel cell and sensor technologies). Solid state ionic membranes based on fast ion conductors potentially provide important advantages over liquid electrolytes, including the elimination of sealing problems improved stability and the ability to miniaturize electrochemical devices using thin films. This chapter reviews methods of optimizing ionic conduction in solids and controlling the ratio of ionic to electronic conductivity in mixed conductors. Materials are distinguished based on whether they are characterized by intrinsic versus extrinsic disorder, amorphous versus crystalline structure, bulk versus interfacial control, cation versus anion conduction and ionic versus mixed ionic–electronic conduction. Data for representative conductors are tabulated. A number of applications that rely on solid state electrolytes and/or mixed ionic–electronic conductors are considered, and the criteria used to choose such materials are reviewed. Emphasis is placed on fuel cells, sensors and batteries, where there is strong scientific and technological interest. The chapter concludes by considering how solid 11.1 Conduction in Ionic Solids ................. 248
Investigation of scatter radiation of non-circular X-ray scan trajectories
Modern interventional X-ray devices are highly maneuverable and allow complex 3D imaging trajectories. New scan trajectories enable not only optimized object sampling but also introduce new approaches for dynamic 3D imaging. In this paper, we investigated the scatter radiation of two different scan trajectories. The scatter radiation was sampled by a rail setup with dosimeters at defined positions. After data analysis, contour maps were generated which show for four exemplary heights the scatter radiation distribution. The alternative scan trajectory showed smaller dose exposures at heights correlated to upper torso and head areas of a model physician. Keywords—Image acquisition, alternative scan trajectory, circular tomosynthesis, scatter radiation distribution