Epoxy systems for low temperature applications
Epoxy-based formulated products are finding increased utility in a wide variety of structural and electrical applications that are required to operate in low temperature environments. Cryogenic technology is accelerating the growth in these fields. This versatile thermosetting polymer offers many attractive features such as high mechanical strength, outstanding dielectric characteristics, excellent adhesive properties, very good chemical resistance and excellent thermal endurance. Such features make them materials of choice for high and medium voltage electrical apparatus that operate in below zero Celsius environments. At lower operating temperatures, many factors come into play affecting overall performance. Among these factors are: speed and effectiveness of cure, fracture toughness characteristics, and thermal expansion properties.
Electrical aging tests on epoxy insulators in GIS
Due to the relatively small insulator dimensions in gas-insulated switchgear (GIS), the electrical stressing is high by comparison to that of insulators for conventional switchgear. Aging tests on a large number of full-sized insulators in several vessels in an outdoor test station have been carried out to determine the stress limits. The tests, with voltages of several hundred kilovolts, last for several years. The aim is to work out conditions (by extrapolation) for a trouble-free switchgear operating life of at least 50 years. The most important test objects are postinsulators weighing 2 kg each. It has been confirmed that partial discharges have a major effect on the failure probability. The life curve obtained from the test results of six batches of partial-discharge-free insulators is compared with the required reliability data. >
Heavy metal adsorption from industrial wastewater by PAMAM/TiO2 nanohybrid: Preparation, characterization and adsorption studies
Abstract This study investigates the removal of heavy metals from industrial wastewater using TiO 2 nanoparticles modified with poly-amidoamine dendrimer (PAMAM, G 4 ). The metal ions Cu 2 + , Pb 2 + , and Cd 2 + were selected as model pollutants. FTIR, SEM, BET surface area and Zeta potential measurements, and Dispersion Observing methods have been employed for characterizing the synthetic nanohybrid and these techniques indicated that the PAMAM loaded on to TiO 2 have been favorably synthesized. The effects of several parameters including initial metal ion concentration, temperature, pH solution, the nanohybrid dosage and contact time were studied. The experimental data were analyzed using equilibrium isotherm and kinetics models. The adsorption process was studied using isotherm, kinetics, and thermodynamics models. The analysis shows that the Langmuir isotherm and pseudo-second-order kinetics are appropriate models for the adsorption process. The thermodynamic parameters illustrate that the absorption is endothermic and spontaneous. The findings suggest that the nanohybrid is a good super absorbent for the removal of heavy metals from industrial effluents.