Air monitoring: Research needs.
Sampling and analyses difficulties encountered in the ambient, source and exposure monitoring areas of environmental data sampling of inorganic particulate matter, inorganic gases, organic particulate matter, and organic gases are discussed. Attention is given to instrumentation such as tunable lasers, ion chromatography, optical emission spectroscopy, fiber glass filters, dichotomous samplers, Teflon and other polymeric membrane filters, and electrostatic samplers. A lack of species-tailored devices is noted, as is a need to develop numerical and statistical models that will decrease the required sampling volume for reliable estimates. Finally, better characterizations of the effects that sampling has on the medium sampled are recommended. 8 references.
Considerations for design of source apportionment studies
This report recommends procedures for source and ambient sampling and analysis in source apportionment studies. The recommendations are based on the results of receptor model studies of atmospheric particles in urban areas, especially a recent study of Houston, TX, undertaken as part of the Mathematical and Empirical Receptor Models Workshop (Quail Roost II). The recommendations are presented at three levels of increasing cost and detail of information obtained. Existing mass emissions inventories combined with chemically resolved test data from similar sources (not necessarily in the same locale) can be used to initially estimate the sources of elements present on ambient particles. To aid local users in construction of chemically resolved emission estimates, the U.S. Environmental Protection Agency (EPA) is compiling a library of compositions and size distributions of particulate emissions from major source types. More reliable source characterization can be achieved if the actual sources are tested directly. EPA should develop and publish detailed procedures for source sampling that would be more appropriate for receptor model use than are existing standard methods. Source and ambient sampling should be conducted by similar methods. If possible, particles from sources should be collected in a way that simulates changes that would normally occur before they reach distant receptors (e.g. by diluting and cooling the particles from hot sources). It is recommended that particulate samples be routinely collected in two size fractions by use of virtual impactors and that all samples be subjected, at a minimum, to mass and X-ray fluorescence analyses. Additional measurements are suggested for obtaining more detailed information: neutron activation analysis; X-ray diffraction; automated particle classification by electron microscopy; analyses for classes of organic species, ^(14)C and thermally released carbonaceous species; and real-time observation of several gases during sample collection. Methods for collecting meteorological data in parallel with ambient samples are described, as are methods for incorporating such data into the source identification process.
Ocean predictive skill assessments in the South Atlantic: Crowd-sourcing of student-based discovery
Autonomous Underwater Gliders have over a decade long history of successful regional deployments serving scientific, societal and security needs in application areas ranging from pole to pole and including the full range of water depths from shallow coastal seas to the deep ocean. Glider deployments covering the basin scale are much fewer, but are a growing capacity as demonstrated by the Woods Hole to Bermuda line that crosses the Gulf Stream, the Atlantic Crossing line that follows the Gulf Stream, and the basin circling flights now being conducted as part of the Challenger Glider Mission. The next step in the evolution of the global Challenger mission is to enable an ensemble of modelers from different institutions and agencies to participate in a meaningful way. This process with be formalized in 2014 by leveraging the data management tools of the U.S. Integrated Ocean Observing System (IOOS) and the education tools of the U.S. National Science Foundation's (NSF) Ocean Observing Initiative (OOI). The Education Visualization (EV) tools developed by the OOI's Education and Public Engagement (EPE) Implementing Organization (IO) are currently being configured through the cyber OOI net to display real time OOI glider data with intuitive interactive browser-based tools, reducing the barriers for student participation in sea exploration and discovery. Through U.S. IOOS, forecast ocean data will be harvested from the ephemeral ocean snapshots produced by an ensemble of ocean models along the same glider tracks as Challenger. The parallel observed and forecast datasets, both evolving in real time, will be accessible through the same OOI EV tools, enabling student participation in a crowd-sourced ocean predictive skill experiment. The result will satisfy one of the important goals of the Challenger mission by enabling students to assess of the quality of the ensemble of available global scale ocean models. Student research team projects that use the new model data comparison capabilities will be conducted during the summer of 2014. Students will compare an ensemble of the global ocean models along the high velocity transport pathways by gliders on basin-scale missions, such as one that traverses the northern side of the South Atlantic gyre along the Brazilian shelfbreak. The lasting impact of the Challenger mission will be a global fleet available to respond to events, an assessment of the ocean models along the fastest ocean transport pathways, and the establishment of a network of gliderports for global response.