Simulation of coating -visco-elastic liquid in the Micro-nip of metering size press
For a set of operating conditions and coating color formulations, undesirable phenomena like color spitting and coating ribs may be triggered in the Micro-nip during the coating process. Therefore, our interest in this work focus on another parameter affect on the undesirable phenomena as the vortices in the Micro-nip. The problem deals with the flow through the Micro-nip of metering size press. The flow enters and exits at a tangential velocity of 20 m/s between two rollers with diameter 80 cm and 60 mum apart. In the upper and bottom part of the domain the angular velocity is 314 rad /s. It has one sub-domain. Previous studies focus on the Micro-nip without considering the inertia and the viscoelasticity of the material. Roll coating is a technique commonly used in the coating industry to meter a thin fluid film on a moving substrate. During the film formation, the fluid is subjected to very high shear and extensional rates over a very short period of time. The fluid domain changes as a function of the hydrodynamic pressure within the nip as a result of the deformable cover usually used on one of the rolls. The free surface also adds more complexity to the flow due to the force equilibrium in the fluid gas interface. Last of all, the rheological behavior of the coating fluid is usually non-Newtonian, so the metering flow hydrodynamics is finally very difficult to describe. It is concluded that the normal forces of micro-nip increases with increasing the inhibitors. Therefore, it affects on the smoothness and creates defects. On the other hand, it can be concluded that the creation of big vortex in the middle of micro-nip affects on the coating liquid behavior.
The fluid dynamics of reverse roll coating
The flow in the metering gap of a reverse roll coater is examined by experiments and finite element solutions of the Navier-Stokes equations. At high speed ratios and capillary numbers, the metered film flow deviates strongly from predictions of lubrication theory: the wetting line moves through the gap center and the metered film thickness passes through a minimum. The two flow instabilities found are ribbing, a sinusoidal cross-web waviness extending smoothly down-web; and cascade, an irregular V-shaped cross-web wave, repeated quasiperiodically down-web. Experimental operability diagrams define parameter ranges where these instabilities and the steady two-dimensional flow are encountered. Ribbing behavior is understood by consideration of the pressure gradient at the free surface. The mechanism of cascade is the intrusion through the gap of the wetting line, which causes the metered film to thicken and eventually reattach to the metering roll in a cyclical manner.
A bifunctional Cr/Yb/Tm:Ca3Ga2Ge3O12 phosphor with near-infrared long-lasting phosphorescence and upconversion luminescence.
Currently, upconversion nanocrystals and long-lasting phosphorescent particles have attracted extensive research interest for their possible applications as bioimaging probes. However, there are few reports concerning the achievement of both upconversion luminescence of lanthanide ions and long-lasting phosphorescence of transition metal ions in a sole host so far. Herein, we demonstrate a novel calcium gallium germanium garnet (Ca3Ga2Ge3O12) host where lanthanide ions such as Tm(3+)/Yb(3+) and transition metal ions such as Cr(3+) can be easily incorporated through substituting the Ca(2+) and Ga(3+) respectively. This Cr/Yb/Tm:Ca3Ga2Ge3O12 phosphor exhibits both broadband near-infrared long-lasting phosphorescence of Cr(3+) with an afterglow time of more than 7000 s and near-infrared to near-infrared upconversion luminescence of Tm(3+). Impressively, it is evidenced that the addition of Yb(3+)/Tm(3+) into Cr:Ca3Ga2Ge3O12 not only results in Tm(3+) upconversion luminescence but also greatly increases Cr(3+) afterglow time. Based on excitation/emission, three-dimensional thermoluminescence, and time-resolved luminescence spectra, the related long-lasting phosphorescence and upconversion luminescent mechanisms are systematically discussed as well.