Analysis of deterioration by partial discharge of XLPE using GCMS and FTIR
Deterioration of polymeric dielectrics by partial discharge (PD) might occur at defects in an insulation layer. To elucidate the mechanism of deterioration by PD, measurements were conducted of the gas components produced during deterioration and the substances created on the surface of cross-linked polyethylene (XLPE) samples subjected to PD. Gas component measurements were performed using an experimental apparatus including GC-MS. Results of gas analyses showed that carbon dioxide (CO2) was produced when the XLPE sample is subjected to the PD in a N2+O2 gas atmosphere. The amount of generated CO2 was confirmed to increase concomitantly with the period of voltage application. The FTIR spectroscopic analysis of substances on the surface of deteriorated XLPE revealed carbonyl compounds on the surface of the deteriorated samples. The deterioration was suppressed when a phenolic antioxidant was added: 44-thiobis-3methyl-6tert butyl phenol. The process of deterioration by PD and the effect of the antioxidant on the deterioration by PD were also discussed.
Evolution of pd patterns in polyethylene insulation cavities under AC voltage
In the framework of developing defect-based life models, in which breakdown is explicitly associated with partial discharge (PD)-induced damage growth from a defect, ageing tests and PD measurements were carried out in the laboratory on polyethylene (PE) layered specimens containing artificial cavities. PD activity was monitored continuously during aging. A quasi-deterministic series of stages can be observed in the behavior of the main PD parameters (i.e. discharge repetition rate and amplitude). The evolution of the parameters reflects the physicalchemical changes taking place at the dielectric/cavity interface during the aging process. PD activity shows similar time behavior under constant cavity gas volume and constant cavity gas pressure conditions, suggesting that the variation of PD parameters may not be attributed to the variation of the gas pressure. It is speculated that the change of PD activity is related to the composition of the cavity gas, as well as to the properties of dielectric/cavity interface.
La inseguridad jurídica en normas de contratación estatal
It is established by different studies that the issue of government procurement has been marred by several factors, the test objective to publicize these factors, we take as starting point the constant conflict between the branches of government to try and organize this subject; will collect and analyze diverse regulatory and case material in order to achieve evidence and demonstrate the different concepts of constant change that produces excessive regulation of the subject procurement and is in turn causing rapid changes that result in legal uncertainty for our law on the Contract Status.