Experimental analysis on small-scale finger-jointed specimens at elevated temperatures
Finger joints have to meet strength performance requirements for the use in structural engineered wood products such as glued-laminated timber beams (glulam). Among these, the thermal stability of the adhesive used in the finger joint is an important criterion to determine the suitability of the connection. The influence of adhesives on the load-carrying capacity of glulam beams and finger-jointed members can be assessed by large-scale fire tests; however, there are obvious benefits in using small-scale specimens tested at elevated temperatures as an alternative. In Europe, there is currently no small-scale test available to test the fire performance of adhesives in structural timber members. The work presented in this paper addresses this issue and was supported by members of a European standardisation committee to develop such a small-scale test. This paper presents, as a first step, the results of a series of tensile tests on small-scale finger-jointed specimens tested at elevated temperatures. The tests were performed with different types of adhesives which are currently also tested in large-scale fire tests. In the small-scale tests here, structural adhesives showed nearly no weaknesses with increasing temperature up to 140 °C. Further, MUF and PRF adhesives showed mostly wood failure even up to temperatures of 220 °C. In the next step of this investigation, the results obtained from the small-scale tests at elevated temperature will be compared to large-scale fire test results in order to find a possible link between both testing methods.
Bench-scale fire tests of Dark Red Meranti and Spruce finger joints in tension
Abstract This study investigates the secondary failure of Malaysian Dark Red Meranti (Shorea spp.) and Spruce (Picea abies) finger joints in a glulam beam in a fire test using a bench-scale test set-up. Secondary failure is the occurrence of failure of the bond lines due to fire and the falling off of the outermost tension layers, exposing the uncharred inner layers to a sudden increase of fire intensity. The lack of published work and the difficulties in describing the behaviour of the finger joints after the secondary failure in a full-scale fire test has identified the need for a simple bench-scale method, incorporating the conditions of the standard fire test. This paper focusses on the performance of the finger joints which together with other defects such as knots and splits are generally the weakest component in the glulam beam. The finger joints were bonded with structural adhesives, specifically phenol resorcinol formaldehyde (PRF) and polyurethane (PUR). They were tested in tension to imitate the failure of finger joints on the tension side of a standard fire test of a glulam beam. Constant heat flux was introduced to the finger-jointed specimens to replicate the secondary failure of a glulam beam in the standard fire test. The results of this study indicate a relationship between the charring rate and density of the specimens, with higher density Dark Red Meranti showing lower charring rate compared to the lower density Spruce specimens. Factors such as constant heat flux as opposed to the time-increasing heat flux exposure and specimen size influenced the charring rate of the specimens. The char rate was measured at the early stages of the fire test, which is known to have higher values since the build-up of the charred layers was not sufficiently substantial to protect the inner unburnt wood. Overall, the bench-scale fire test set-up was able to differentiate the fire performance of the adhesives, with PRF showing better fire performance compared to the specimens finger-jointed with PUR adhesive. In addition, tensile tests at ambient temperature showed no significant difference in tensile strength between finger joints bonded with different adhesives for the same wood species. The tensile strengths of the finger joints bonded with different adhesives were influenced by the temperature profile through the joint. The proposed bench-scale fire test was used to compare the quality of the adhesives in a fire situation, specifically with respect to secondary failure. The PRF was selected as the reference adhesive.
The crystal structure of stilpnomelane. Part II. The full cell
Summary The structural formula of stilpnomelane averaged from 37 representative literature analyses and based on the determined structure is (Ca,Na,K)4(Ti0·1Al2·3Fe35·5Mn0·8Mg9·3)[Si63Al9](O,OH)216·nH2O. Ferrostilpnomelanes have up to 12 R 3+ cations in the octahedral sheet, ferristilpnomelanes commonly have between 24 and 30 R 3+ cations, rarely up to 37. The two groups can be distinguished by accurate X-ray powder diffraction, ferrostilpnomelanes having d 001 less and a greater than have ferristilpnomelanes. The unit cell is triclinic, a = b∼21·8 Å, γ = 120°, d 001∼12·2 Å, P . Hexagonal groups or ‘islands’ of 24 silicon-oxygen tetrahedra co-ordinate to the octahedral sheet, the centres of the ‘islands’ are displaced by 5a/12, 8b/12 on either side of the octahedral sheet as a result of warping of this sheet to permit articulation with the smaller tetrahedral sheet. The 24-tetrahedra ‘islands’ are linked laterally by 6-member rings of inverted tetrahedra, which in turn link at their apices to like rings connecting the next sheet of ‘islands’. Thus a single tetrahedral layer is 4 tetrahedra thick and has symmetry 6/m. The 6-member rings of tetrahedra act as hinges permitting up to 0·5 Å extension or contraction of the tetrahedral sheet to accommodate variations in the octahedral sheet dimensions with varying R 2+/R 3+ ratio.