Synthesis and Crystal Structure of Hexakis(imidazole) nickel (II) O,O′-diphenyldithiophosphate [Ni(Im)6](Ph2O2PS2)2
The crystal and molecular structures of [Ni(Im)6](dtp)2 (Im = imidazole, dtp = O,O′-diphenyldithiophosphate) have been determined by X-ray crystallography. It crystallizes in the triclinic system, space group Pī, with cell parameters a = 9.375 (2), b = 12.324(3), c = 13.285(3) Å, α = 107.86(3), β = 102.28(3), γ = 109.24(3), and Z = 1. The crystal structure of the title compound is built up of discrete monomeric molecules of [Ni(Im)6](dtp)2. The nickel (II) ion is hexacoordinated by six imidazole molecules and the coordination environment of Ni (II) is of octahedral geometry. In the solid state, a network of N-H∙∙∙S intermolecular hydrogen bonds connect the Ni(Im)6 moieties and O,O′-diphenyl- dithiophosphate molecules, forming a three-dimensional structure.
Imidazole complexes with cobalt(II) salts
A number of tetrahedral and octahedral complexes formed by cobalt(II) salts with imidazole are described and the physical evidence for their structures is discussed.
Phytochemical and FT-IR Spectral Analysis of Certain Bamboo Species of SouthIndia
Bamboo with its varied uses has historically been an integral part of livelihoods and lifestyles in India. The present study was carried out to characterize the bioactive constituents present in the leaf extracts of certain bamboo species using Fourier transform infrared spectroscopic analysis (FT-IR). The various solvent extracts of various bamboo leaves subjected to qualitative analysis showed the availability of phytoconstituents including alkaloids, phenolic compounds, flavonoids, saponins, glycosides, terpenoids, steroids, coumarins and phytosterols. Quinones were completely absent in all the five bamboo species. The FT-IR spectrum confirmed the presence of sulphides (SS), phenols (C-O), aromatic compounds, thiols (S-H), aliphatic compounds (C-Cl) and amines (NH) in different bamboo species. The present investigation has also opened avenues for further research into the development of potent phytomedicines from different bamboo species.