Evaluation of Joint Resistance Between Bi-2223/Ag Superconducting Tapes
We fabricated Bi-2223/Ag jointed tape and evaluated its current carrying capacity and joint resistance at 77.3 K as a function of the contact length. The tapes were jointed by the conventional resistive joint method with 40Pb-60Sn solder as an insert material and their joint resistance was measured by two different techniques, i.e., the standard four-probe and field decay methods. It was observed that the current carrying capacity and joint resistance were significantly dependent on the contact length. As the contact length increased, the current carrying capacity improved and increased to the level of critical current in the unjoined tape at the contact length of 5 cm. On the other hand, the joint resistance linearly decreased as the contact length increased. In addition, the joint resistances measured by the two methods were similar to each other (7.3times10-9 Omega~8.0times10-9 Omega), indicating that the standard four-probe method maintained a moderate degree of accuracy at the level of resistance of 10-9 Omega
Development and characteristics of persistent mode in HTS magnet
Abstract We fabricated a high-temperature superconducting (HTS) magnet with a persistent current switch (PCS) and evaluated the decay characteristics of persistent mode and joint resistance at 77 K. To make the HTS magnet, BSCCO(2223) tapes were wound into a double-pancake coil and connected to the PCS by soldering. Field decay behavior was remarkably dependent on operating current. At an operating current of 50% of the critical current ( I c ), decay behavior showed two distinct regimes: initial fast decay and subsequent linear decay. By contrast, there was a linear decay regime of only 13% of I c . Total circuit resistance was approximately 2.0 × 10 −8 Ω at an operating current of 6 A. Measured decay behavior was closely consistent with the calculated decay behavior obtained from both the index resistance and joint resistance components.
An Ultrasensitive Analytical Method Based on Chemiluminescence Sensing Electrochemical Parallel Catalytic Reaction Event
An ultrasensitive electrochemiluminescence (ECL) method on the combination of electrochemical parallel catalytic reaction and chemiluminesence signal sensing was proposed for improving ECL analytical characteristics using vanadate(V) as a representative. Vanadate(V) could be electrochemically reduced to generate vanadate(II) which could be chemically oxidized by potassium periodate to regenerate vanadate(V) and give parallel catalytic wave effect. Then, the reduced product of potassium periodate could react with butyl-rhodamine B to emit a sensitive chemiluminescence signal. The chemiluminescence intensity was correlative with vanadate(V) concentration. The investigation on the electrochemical reaction rate constant (k0) confirmed that the speed of electrochemical reaction was faster than that of the subsequent chemiluminescence reaction. The possibility of the combination of electrochemical parallel catalytic reaction with chemiluminescence signal sensing was proved. The similar ECL behaviors could be observed at zirconia nanowires-Nafion modified electrode. Because of the separation and enrichment effect of the modified electrode on vanadate(V), the selectivity and sensitivity was further improved greatly. Based on these findings, a new concept on the combination of electrochemical parallel catalytic reaction and chemiluminesence signal sensing was proposed and an ultrasensitive ECL method for the determination of vanadate(V) was developed at zirconia nanowires-Nafion modified electrode. Under the optimum experimental conditions, the ECL intensity was linear with the concentration of vanadate(V) in the range of 2.0×10−12 mol/L–2.0×10−10 mol/L. The detection limit was 8.0×10−13 mol/L, which was more than 6 orders of magnitude lower than that observed by electrochemical current transduction for electrochemical parallel catalytic reaction at zirconia nanowires-Nafion modified electrode.