On the solubility of radium sulfate and carbonate
Radium is one of the most toxic elements and its concentration in different human activities and migration from man-made wastes provokes a strong interest in environmental science. To be able to model the migration process, reliable experimental thermodynamic data of radium compounds are needed.
In this work details of the safe radium source disassembly which were previously used in brachytherapy are described and different methods for conversion of RaSO4 into aqueous solution are reviewed. The method of choice included three cycles of RaSO4 heating in 1.5 M Na2CO3 up to 85 oC, cooling and subsequent removal of supernatant. X-ray diffraction studies showed that the method allows the synthesis of amorphous RaCO3, which can be dissolved in mineral acid. Gamma spectrometric measurements showed that most of the initial RaSO4 was converted into solution and that 7 ± 1 % of the initial 210Pb was co-precipitated with RaCO3. Synthesized RaCO3 was dissolved in HCl to prepare a radium stock solution. 
The radium stock solution was used to determine the solubility of pure RaSO4 and RaCO3 from oversaturation using Na2SO4 and Na2CO3 as a source of sulfate and carbonate ions. The solubility was determined at 25.1 oC as a function of ionic strength using NaCl media. The concentration of radium was measured by gamma spectrometry after separation of the aqueous phase from the solid phase using ultracentrifugation. The extended specific ion interaction theory was used to extrapolate solubility product constants to zero ionic strength (log10 Ksp° = -10.16 ± 0.05 for RaSO4 and log10 Ksp° = -7.73 ± 0.56 for RaCO3) and to calculate ion interaction coefficients.
A comparison of the shapes of the radium solubility curves for both anions with the shapes of corresponding barium solubility curves demonstrates the similarity of the behaviour of radium and barium salts in saline solutions. It can be supposed that due to the similarity of the radium and barium effective ionic radii, and the same charge, these ions undergo similar specific ion interactions in NaCl media.
On the solubility of radium and other alkaline earth sulfate and carbonate phases at elevated temperature
Solubility constant data for alkaline earth sulfate and carbonate phases were collated. Thermodynamic data for these phases were determined by assuming that the solubility (log K-s) of each phase is a function of the inverse of absolute temperature with a constant, but non-zero, heat capacity change. The solubility for all phases, both sulfate and carbonate, exhibits a maximum at a particular temperature, with the temperature at which the maximum solubility occurs increasing as the alkaline earth metals become heavier (for both sulfate and carbonate phases). The heat capacity change was found to be a quadratic function of the square root of the ionic radius. The enthalpy of reaction, at 25 degrees C, is related to the temperature at which the maximum solubility occurs. Combination of these behaviours allows the solubility of the alkaline earth sulfate and carbonate phases to be determined across a temperature range of 0 to 300 degrees C. These relationships allow solubility data to be determined for the same temperature range for radium sulfate and carbonate for which very few literature data are available, particularly for radium carbonate.
Prophets praying for, or preying on people’s faith: A reflection on prophetic ministry in the South African context
In mainline churches, the ministry of prophecy or the prophetic ministry involves the proclamation of the gospel. This, in turn, is related to the every-believer ministry. However, there is now a resurgence of the prophetic ministry as a special office as evidenced by the establishment of neo-prophetic churches. This article argues that neo-prophetic churches are tapping into people’s longing for the fresh divine word to speak directly into their personal situations. The article also probes whether neo-prophets in the prophetic activities are not also preying on people’s faith.