Uraninite and Thorianite
WASSERSTEIN1 suggested that the generation by radioactive decay of Pb4+ of smaller ionic radii within the crystal lattice of uraninite caused a shrinkage in the unit cell proportionate to the geological age and the shrinkage was of the order of 0.0025–0.0041 Å. per hundred million years. The anomaly in the relation of cell dimensions of Bisundni and Gaya uraninites with the age, reported by Holmes2, was explained by Wasserstein3 by classifying uraninites into two different types—α-type for Bisundni uraninite and γ-type for Gaya uraninite, the latter being apparently anomalous and requiring heat treatment under oxidizing conditions in order to reduce the cell size to correspond to that of an α-type analogue. Wasserstein did not, however, state the temperature and period of heating and the conditions under which the cell size of γ-uraninite was reduced to correspond to age values consistent with those of the α-type.
Cube-Edges of Uraninites as a Criterion of Age
I HAVE suggested that there is a progressive reduction in the size of the unit cell of uraninite-thorianites with time1. The ionic radius of Pb4+ is appreciably smaller than those of U4+ and Th4+. The decay of the parent element causes its substitution by radiogenic lead within the crystal lattice; because of the differences in sizes of the ions, a shrinkage results. It is therefore likely that this factor can be utilized for indicating the relative ages of uraninites after these have been subjected to an X-ray powder examination. No great accuracy can be envisaged, but such a method would be more accessible to geologists than the highly refined mass-spectrographic one, which can be practised in very few laboratories in the world.
The Inca Occupation of the South Coast of Peru
like the others, however; it forks into several nearly parallel ravines of which the largest are Huayuri, Rio Grande-Palpa, Ingenio (called Collao in ancient times), Nasca proper (the ancient Caxamarca), Taruga, and Poroma. Due to peculiarities of the local topography, the irrigated areas in Ica and the ravines of Nasca are located inland, at the foot of the mountains, rather than at the mouths of the rivers as is more usual in Peruvian coastal valleys. No sharp natural or cultural boundary separates the valley of Chincha from the valleys of Cafiete (ancient Huarco and Runahuana), Asia, and Mala, the next valleys going up the coast to the northwest. At the other end of the area we are considering, however, there is a sharp break; beyond Yauca the Andean foothills reach out to the sea, natural conditions are quite different, and there are important differences in the archaeological picture as well. The historical sources which mention the south coast are not particularly helpful, except in so far as they provide us with a few dates. To begin with, no chronicler gives an explicit account of the political organization of the south coast at the time it came into contact with the Incas. It can, perhaps, be inferred from Cabello Balboa's statements about common policy toward the Inca invaders that there was some sort of political connection between the valleys of Mala, Cafiete, and Chincha, but the connection need have been no more than a temporary military alliance. Cabello makes no mention at all of Pisco. The valleys of Ica, Nasca, and 125