
 Possibilities for compositional tailoring of Norway spruce (Picea abies
 L. Karst.) wood using a hydrophobic oil impregnation process

ZusammenfassungImpregnation with hydrophobic oils offers non-toxic options for preserving Norway spruce (Picea abies L. Karst) wood that could potentially be used to tailor the properties
 of wood products, especially those used in exposed conditions. The objective of this study was to quantify
 the effects of the water-filled porosity and density of Norway spruce wood and treatments (applied to set
 the wood’s water contents at desired test levels) prior to impregnation with the linseed oil derivative
 Linogard by the Linotech process on its oil retention. Retention of oil differed significantly between
 tissue types. Dried specimens always retained less oil than corresponding undried or rewetted specimens.
 Furthermore, water-filled porosity and density had significant effects on oil retention levels within tissue
 types, allowing linear regression equations to be developed that gave good predictions of oil retention
 parameters for different tissues, with R2 values ranging from 0.66 for mature
 heartwood to 0.85 for mature sapwood. Thus there is scope to use hydrophobic oil impregnation processes
 for producing compositionally tailored wood materials with specified properties.

Near-infrared spectroscopy for the quantification of linseed oil uptake in Scots pine (Pinus sylvestris L.)
Abstract Eighteen sapwood and 18 heartwood samples from three Scots pine (Pinus sylvestris L.) trees were used to identify correlations between the features of their near-infrared spectra (400–2500 nm) measured before and after impregnation with linseed oil (Linogard®) and (1) the amount of oil taken up by the samples at three different longitudinal positions; and (2) the tissue type of sample. Calibration models were cross-validated and oil uptake models were also validated on separate test sets. Partial least squares regression models for the prediction of uptake and tissue type in non-impregnated wood were promisingly accurate, having coefficients of multiple determination (Q 2) values of > 0.8, 0.8 and 0.75 for predictions of tissue type, oil taken up as a percentage of sample mass and total mass of oil taken up, respectively. The models developed for linseed oil-impregnated samples were better still, generating Q 2 values of > 0.9, > 0.8 and 0.8 for the three key properties. In general, models based on spectra acquired along two directions of measurement (longitudinal and tangential) were more accurate than models based on only one. Tandem models consisting of two submodels, one for sapwood and one for heartwood, were more successful than single models applicable to both tissue types.
Experimental investigation of the geotechnical properties and microstructure of lime-stabilized saline soils under freeze-thaw cycling
Abstract The Song-Nen Plain in northeastern China holds one of the three largest expanses of soda saline-alkali soil in the world. Due to its disadvantageous geotechnical properties, the saline soil in this area is unable to meet the needs of construction projects. This study evaluates the stabilizing effect of adding lime to such soils. Specifically, it investigates how the physicochemical and mechanical properties and microstructure of soda saline-alkali soil are altered by lime and how these changes are affected by both freeze-thaw cycling and the duration of curing. The results reveal that adding lime to saline soil transforms clay particles into sand and silt particles and causes the pore size distribution (PSD) to become bimodal, with small-pore and macropore populations. An increase in lime content leads to an increase in the unconfined compressive strength (UCS) but a gradual decrease in both the cation exchange capacity (CEC) and plastic index. Freeze-thaw cycles break up coarse particles and aggregate finer particles, increasing the diameter of macropores and decreasing the USC; however, the effect on specimens with >9% lime is negligible. It is further shown that the geotechnical properties of the soil change immediately after the addition of lime, indicating that the cation exchange reaction takes place very quickly. Furthermore, the pozzolanic reaction leads to an increase in the percentage of sand-sized particles and a decrease in porosity after 28 days of curing. Overall, these results indicate that it is feasible to use lime to improve the engineering properties of soda saline-alkali soil in this area.