Electric Field Heat Transfer Augmentation During Condensation of Nonconducting Fluids on a Horizontal Surface
Experiments were carried out to determine the heat transfer coefficient during condensation on the underside of a horizontal plate with and without an electric field applied perpendicular to the plate. An expression is presented, correlating the augmentation of the heat transfer coefficient to the most unstable wavelength of the electrohydrodynamical instability of the condensate-vapor interface.
A new set of correlations for EHD enhanced condensation heat transfer of tubular systems
Abstract An improved set of correlations for evaluating the heat transfer coefficient of EHD assisted condensation heat transfer for tubular systems is presented in this paper. The correlations were developed by curve fitting a wide range of experimental data and then optimising the empirical constants so that the percentage deviation is less than ±30%. The experimental data was classified in four categories: (I) condensation outside horizontal smooth tubes, (II) condensation inside horizontal smooth tubes, (III) condensation outside vertical tubes and (IV) condensation inside vertical tubes. The experimental data in each category included results obtained using various refrigerants and various electrode systems. The improved correlations were used to predict a total of 166 experimental data points. A comprehensive literature review of all available correlations for EHD assisted condensation heat transfer is also described in this paper. Two correlations that were identified to be simple were used to predict the above-mentioned data bank. These are the correlations of Choi and Reynolds and Didkovesky and Bologa. The Choi and Reynolds correlation was found to successfully predict heat transfer rates of condensation outside horizontal and vertical tubes and of condensation inside vertical tubes when high intensity electric field is applied. However, the Didkovesky and Bologa correlation was found to successfully predict only the results of condensation heat transfer outside vertical surfaces.
Diagnosis of the σ-, π- and (σ+π)-Aromaticity by the Shape of the NICSzz-Scan Curves and Symmetry-Based Selection Rules
The NICSzz-scan curves of aromatic organic, inorganic and “all-metal” molecules in conjunction with symmetry-based selection rules provide efficient diagnostic tools of the σ-, π- and/or double (σ + π)-aromaticity. The NICSzz-scan curves of σ-aromatic molecules are symmetric around the z-axis, having half-band widths approximately less than 3 A with the induced diatropic ring current arising from Tx,y-allowed transitions involving exclusively σ-type molecular orbitals. Broad NICSzz-scan curves (half-band width approximately higher than 3 A) characterize double (σ + π)-aromaticity, the chief contribution to the induced diatropic ring current arising from Tx,y-allowed transitions involving both σ- and π-type molecular orbitals. NICSzz-scan curves exhibiting two maxima at a certain distance above and below the molecular plane are typical for (σ + π)-aromatics where the π-diatropic ring current overwhelms the σ-type one. In the absence of any contribution from the σ-diatropic ring current, the NICSzz(0) value is close to zero and the molecule exhibits pure π-aromaticity.