Effects of annealing on phase evolution, microstructure and magnetic properties of mechanically synthesized nickel-ferrite
Abstract The influence of milling and subsequent annealing on nickel-ferrite phase formation was investigated by X-ray diffraction (XRD). Microstructure and magnetic properties of NiFe 2 O 4 were determined by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and vibration sample magnetometry (VSM). Single phase nanosized nickel-ferrite was obtained by 30 h mechanical alloying (MA) and subsequent annealing at 600 °C for 1 h. Magnetic properties of the milled powder were extensively affected by the annealing temperature. Considerable growth of the particles and necking by sintering resulted from annealing at 1000 °C.
Evaluation of dielectric breakdown strength of transformer oil with BaTiO3 and NiFe2O4 nanoparticles
In this paper, the dielectric characteristics of the power transformer oil are enhanced by dispersing newly synthesized nanoparticles. Two nanocrystalline powders, barium titanate (BaTiO3) and nickel ferrite (NiFe2O4), are synthesized via the tartaric acid precursor method. The change in the crystal structure, crystalline size, and microstructure of the synthesized nanoparticles as a function of annealing temperatures are characterized using X-ray diffraction and transmission electron microscope. These nanoparticles are mixed with the transformer oil considering different concentrations such as 25, 50, and 75 mg/l where the sonicator is used to disperse the nanoparticles in the oil samples. The dielectric breakdown strength is tested based on IEC standard. The results confirm the efficiency of the NiFe2O4 than BaTiO3 for enhancing the dielectric characteristics of the power transformer oils.
Preparation of functional materials via non-conventional routes
Abstract An overview is given on the non-conventional solid-state processes for the preparation of functional materials. Emphasis is laid on the formation of heterogeneous bridging bonds (HBB) across the boundary between two dissimilar solids under mechanical stressing. Loss of the coordination number for the near surface atoms and/or disturbance of the symmetry of the crystal field or the ligand field are discussed in conjunction with the HBB formation. Case studies on complex oxides, ferrous coordination compounds and some organic - inorganic composites are given.