Analysis of total metals in waste molding and core sands from ferrous and non-ferrous foundries.
Waste molding and core sands from the foundry industry are successfully being used around the world in geotechnical and soil-related applications. Although waste foundry sands (WFSs) are generally not hazardous in nature, relevant data is currently not available in Argentina. This study aimed to quantify metals in waste molding and core sands from foundries using a variety of metal-binder combinations. Metal concentrations in WFSs were compared to those in virgin silica sands (VSSs), surface soils and soil guidance levels. A total analysis for Ag, Al, Ba, Be, Cd, Co, Cr, Cu, Fe, Mg, Mn, Mo, Ni, Pb, Sb, Te, Tl, V, and Zn was conducted on 96 WFSs and 14 VSSs collected from 17 small and medium-sized foundries. The majority of WFSs analyzed, regardless of metal cast and binder type, contained metal concentrations similar to those found in VSSs and native soils. In several cases where alkyd urethane binder was used, Co and Pb concentrations were elevated in the waste sands. Elevated Cr, Mo, Ni, and Tl concentrations associated with VSSs should not be an issue since these metals are bound within the silica sand matrix. Because of the naturally low metal concentrations found in most WFSs examined in this study, they should not be considered hazardous waste, thus making them available for encapsulated and unencapsulated beneficial use applications.
Ecotoxicological evaluation of foundry sands and cosmetic sludges using new earthworm biomarkers
The management and final disposal of industrial wastes are a matter of considerable human concern. The present study evaluates the cyto/genotoxic effects and changes of the coelomic cell formulas exerted by aqueous leachates and solid waste (SW) of two industrial residues using coelomocytes extruded from Eisenia fetida. The assayed wastes corresponded to industrial foundry and cosmetic activities. After 14 days of exposure, we obtained a group of endpoints that reflect the toxicity/genotoxicity, coelomocyte formula and indexes; and the mortality classical value (LC50-14d). Among the variables measured, total coelomocytes formula (eleocytes + amebocytes + granulocytes) appears as a single and easy parameter to assess the toxicity of eluates at short exposure times. We applied a set of assays using earthworms as test organism that would allow evaluating SW as well as its aqueous leachates. It is easy to run trials combining exposures of 1 h to 14 days, which can be integrated into the implementation of the traditional test for evaluating acute toxicity.
Experimental study of water fluxes in a residential area: 2. Road infiltration, runoff and evaporation
Lack of accurate data has led some hydrologists and city planners to assume that urban infiltration is zero and runoff is 100% of the rainfall. These assumptions lead to an over estimation of road runoff volume and an underestimation of direct recharge to groundwater, which is already rising under some UK cities. This study investigates infiltration and runoff processes and quantifies the percentage of rainfall that contributes to storm drainage, and that which infiltrates through different types of road surface. Access tubes were installed for measuring soil water content using a neutron probe in three car parks, a road and a grass site at the Centre for Ecology and Hydrology, Crowmarsh Gifford, Wallingford. Storm drainage was recorded at the exit of the Thamesmead Estate in Crowmarsh Gifford, just before the drain joins the River Thames at Wallingford. Rainfall and water table depth were also recorded. Weekly measurements of soil moisture content indicated that the top 40 cm layer is not influenced by water‐table fluctuations and, therefore, positive changes in soil moisture could be attributed to infiltration of rainfall through the surface. Depending on the nature of the surface, subsurface layers, level of traffic, etc., between 6 and 9% of rainfall was found to infiltrate through the road surfaces studied. The storm drainage generated by road runoff revealed a flow pattern similar to that of the receiving watercourse (River Thames) and increased with the increase of infiltration and soil water content below the road surface. The ratio of runoff to rainfall was 0·7, 0·9 and 0·5 for annual, winter (October–March) and summer (April–September) respectively. As the results of the infiltration indicated that 6 to 9% of annual rainfall infiltrates through the road surface, this means that evaporation represents, 21–24% of annual rainfall, with more evaporation taking place during summer than winter. Copyright © 2003 John Wiley & Sons, Ltd.