A comparative simulation study of power generation plants involving chemical looping combustion systems
Abstract This work presents a simulation study on both energy and economics of power generation plants with inherent CO 2 capture based on chemical looping combustion technologies. Combustion systems considered include a conventional chemical looping system and two extended three-reactor alternatives (exCLC and CLC3) for simultaneous hydrogen production. The power generation cycles include a combined cycle with steam injected gas turbines, a humid air turbine cycle and a simple steam cycle. Two oxygen carriers are considered in our study, iron and nickel. We further analyze the effect of the pressure reaction and the turbine inlet temperature on the plant efficiency. Results show that plant efficiencies as high as 54% are achieved by the chemical looping based systems with competitive costs. That value is well above the efficiency of 46% obtained by a conventional natural gas combined cycle system under the same conditions and simulation assumptions.
Thermodynamic analysis of H2 production from CaO sorption‐enhanced methane steam reforming thermally coupled with chemical looping combustion as a novel technology
In this novel paper, a technique for hydrogen production route of CaO sorption‐enhanced methane steam reforming (SEMSR) thermally coupled with chemical looping combustion (CLC) was presented (CLC‐SEMSR), which perceived as an improvement of previous methane steam reforming (MSR) thermally coupled with CLC technology (CLC‐MSR). The application of CLC instead of furnace achieves the inherent separation of CO2 from flue gas without extra energy required. The required heat for the reformer is provided by thermally coupling CLC. The addition of CaO sorbents can capture CO2 as it is formed from the reformer gas to the solid phase, displacing the normal MSR equilibrium restrictions and obtaining higher purity of H2. The Aspen Plus was used to simulate this novel process on the basis of thermodynamics. The performances of this system examined included the composition of reformer gas, yield of reformer gas (YRg), methane conversion (αM), the overall energy efficiency (η), and exergy efficiency (φ) of this process. The effects of the molar ratio of CaO to methane for reforming (Ca/M) in the range of 0–1.2, the molar ratio of methane for combustion to methane for reforming (M(fuel)/M) in the range of 0.1–0.3, and the molar ratio of NiO to methane for reforming (Ni/M) in the range of 0.4–1.2 were investigated. It has been found to be favored by operating under the conditions of Ca/M = 1, M(fuel)/M = 0.2, and Ni/M = 0.8. The most excellent advantage of CLC‐SEMSR was that it could obtain higher purity of H2 (95%) at lower operating temperature (655 °C), as against H2 purity of 77.1% at higher temperature (900 °C) in previous CLC‐MSR. In addition, the energy efficiency of this process could reach 83.3% at the optimal conditions. Copyright © 2014 John Wiley & Sons, Ltd.
Effects of reservoir volume on performance of pulse tube cooler.
A pulse tube cooler has the advantages of long-life and low-vibration over conventional cryocoolers such as G-M and Stirling coolers because of the absence of moving parts at low temperature. On the other hand, the combination of a reservoir and orifice is indispensable to optimize the performance of pulse tube coolers. In order to make the pulse tube cooler compact for practical applications, the volume of reservoir should be minimized. This paper analyzes the effects of the reservoir volume on the thermodynamic performance of various components in a simple orifice and a double-inlet pulse tube cooler by combining a linearized model with a thermodynamic analysis. Expressions of entropy production for those components are presented. The results show that the reservoir volume has a significant influence on the entropy production in the various components when the reservoir to pulse tube volume ratio is smaller than about 5. The ratio is important to determine the minimum reservoir volume for a pulse tube cooler. Optimum settings for a double-inlet pulse tube cooler are also discussed.