Plant-controlled supratidal anhydrite from Al-Khiran, Kuwait
We report here that in the supratidal zone of the Al-Khiran sabkha, diagenetic anhydrite occurs exclusively in association with the living halophyte Halocnemum strobilaceum (Pallas) M .B. This anhydrite has a hair cream-like consistency and the bulk of it has formed as pseudomorphs after gypsum crystals. On the death of the plant at the end of its life cycle, the anhydrite is hydrated back to gypsum. This two-way transformation results in a series of characteristic textures, whose preservation could be due to the comparative ‘youth’ of the sabkha, which is in the very earliest stages of evaporite diagenesis.
Conversion of gypsum to anhydrite in aqueous salt solutions
Abstract Gypsum in contact with aqueous salt solutions was converted to natural anhydrite at 90.5°C. The mechanism of the reaction is the conversion of gypsum first to the hemihydrate then to natural anhydrite. Thermodynamic calculations and experimental evidence substantiate the reaction mechanism. It is demonstrated that the previous value of 42°C for the transition temperature of the gypsum-anhydrite system is in error. Gypsum will not be converted to anhydrite in pure calcium sulfate solutions at temperatures less than 97°C.
The crystal structure of stilpnomelane. Part II. The full cell
Summary The structural formula of stilpnomelane averaged from 37 representative literature analyses and based on the determined structure is (Ca,Na,K)4(Ti0·1Al2·3Fe35·5Mn0·8Mg9·3)[Si63Al9](O,OH)216·nH2O. Ferrostilpnomelanes have up to 12 R 3+ cations in the octahedral sheet, ferristilpnomelanes commonly have between 24 and 30 R 3+ cations, rarely up to 37. The two groups can be distinguished by accurate X-ray powder diffraction, ferrostilpnomelanes having d 001 less and a greater than have ferristilpnomelanes. The unit cell is triclinic, a = b∼21·8 Å, γ = 120°, d 001∼12·2 Å, P . Hexagonal groups or ‘islands’ of 24 silicon-oxygen tetrahedra co-ordinate to the octahedral sheet, the centres of the ‘islands’ are displaced by 5a/12, 8b/12 on either side of the octahedral sheet as a result of warping of this sheet to permit articulation with the smaller tetrahedral sheet. The 24-tetrahedra ‘islands’ are linked laterally by 6-member rings of inverted tetrahedra, which in turn link at their apices to like rings connecting the next sheet of ‘islands’. Thus a single tetrahedral layer is 4 tetrahedra thick and has symmetry 6/m. The 6-member rings of tetrahedra act as hinges permitting up to 0·5 Å extension or contraction of the tetrahedral sheet to accommodate variations in the octahedral sheet dimensions with varying R 2+/R 3+ ratio.