Products of the reaction of anabasine with phosgene
ConclusionsThe reaction of anabasine with phosgene has given the anabasinium salt of phosgene, anabasine-N-carbonyl chloride, and the urea derivative N,N′-carbonyldianabasine. In addition to the formation of these substances, the pyridine ring of anabasine is cleaved, giving the red substance 1-chloro-5-chloroformyl-amino-2-piperidin-2-yl)penta-1,3-diene.
Second-Generation Phosgene and Diphosgene Detection Tube
We have developed a second-generation detection tube for colorimetric and fluorescence detection of phosgene and diphosgene in air. The tube is packed with pellets made of a mixture of microcrystalline cellulose and magnesium aluminum metasilicate treated with a suitable monoterpene (camphor, menthol) to increase porosity and specific surface area. We impregnated the pellets with a specific o-phenylenediamine-pyronin (PY-OPD) based reagent. The detector with this novel indication charge enables phosgene or diphosgene to be selectively and sensitively detected at concentrations lower than as would those posing acute health risk. Owing to the analytical colorimetric and, at the same time, fluorescence signal, the detector is very robust while featuring good sensitivity and variability. The colorimetric limits of detection were 0.3 mg/m3 (tristimulus colorimeter), resp. 5 mg/m3 (with the naked eye), fluorescence detection limits of 0.3 mg/m3 (with the naked eye), all at an air sample volume of 1 dm3. The response was practically immediate, acid vapors and gases, or diethyl chlorophosphate as a simulant of nerve warfare chemical agents, were disruptive.
Variations of sulphur dioxide at the cloud top of Venus’s dynamic atmosphere
A pulse of sulphur dioxide in Venus’s upper atmosphere was observed by the Pioneer Venus spacecraft in the 1970s and 1980s and attributed to volcanism. Recent sulphur dioxide measurements from Venus Express indicate decadal-scale fluctuations in sulphur dioxide above Venus’s cloud tops in an atmosphere that is more dynamic than expected. Sulphur dioxide is a million times more abundant in the atmosphere of Venus than that of Earth, possibly as a result of volcanism on Venus within the past billion years1,2. A tenfold decrease in sulphur dioxide column density above Venus’s clouds measured by the Pioneer Venus spacecraft during the 1970s and 1980s has been interpreted as decline following an episode of volcanogenic upwelling from the lower atmosphere3,4. Here we report that the sulphur dioxide column density above Venus’s clouds decreased by an order of magnitude between 2007 and 2012 using ultraviolet spectrometer data from the SPICAV instrument onboard the Venus Express spacecraft. This decline is similar to observations during the 1980s. We also report strong latitudinal and temporal variability in sulphur dioxide column density that is consistent with supply fluctuations from the lower atmosphere. We suggest that episodic sulphur dioxide injections to the cloud tops may be caused either by periods of increased buoyancy of volcanic plumes, or, in the absence of active volcanism, by long-period oscillations of the general atmospheric circulation. The 30-year observational record from Pioneer Venus and Venus Express confirms that episodic injections of sulphur dioxide above the clouds recur on decadal timescales, suggesting a more variable atmosphere than expected.