Water and Salt Migration with Phase Change in Saline Soil during Freezing and Thawing Processes
Water and salt transfer coupled with phase change may cause serious damage to engineering structures in saline soil regions. In this study, the migration of water and salt in silty clay collected from the Qinghai‐Tibet Plateau is explored experimentally and numerically during freezing and thawing processes. The results revealed that there are significant differences in the variations of liquid water content and solution concentration for different initial salt contents, due to salt crystallization and dissolution. The temperature‐induced water migration is determined by the soil properties, which can be well explained by the thermodynamics of mass transfer. The amount of salt migrated upward during cooling is slightly larger than that transported downward in the warming period, implying that salt may be accumulated in the surface soil after a large number of circulations and finally result in soil salinization.
Modelling of cryogenic processes in permafrost and seasonally frozen soils
This paper investigates the thermo-hydro-mechanical (THM) behaviour of soils subjected to seasonal temperature variations in both permafrost and seasonally frozen conditions. Numerical modelling of soil freezing and ice segregation processes is presented, and compared against small-scale physical modelling experiments. The coupled THM model presented, which is solved by way of a transient finite element approach, considers a number of processes, including conduction, convection, phase change, the movement of moisture due to cryogenic suctions, and the development of ice lenses. Two seasonal freezing scenarios are considered: (a) for soils with no permafrost, where freezing is from the surface downward (one-sided freezing); and (b) for soils underlain by permafrost, where large thermal gradients in the uppermost permafrost layer can cause active layer freezing in two directions, from the permafrost table upwards and from the ground surface downwards (two-sided freezing). In the case of one-sided freezing, ice lens formation occurs as the freezing front advances downwards from the surface, and is limited by water supply. However, during two-sided freezing, ice segregation takes place in a closed system, with ice lenses accumulating at the base of the active layer and near the ground surface, leaving an intervening ice-poor zone. Numerical modelling is able to represent the development of both the thermal field and ice segregation observed in the physical models. The significance of this contrasting ground ice distribution is considered in the context of thaw-related slow mass movement processes (solifluction).
Crystallisation kinetics with nucleation phenomenon: Ice slurry system
In this paper a physical model is built to investigate the non-isothermal freezing kinetic in ice slurry systems. The global Nakamura-type kinetics is adopted to describe the nucleation rate during the freezing process. A genetic algorithm is used to determine the nucleation probability of ice slurry. The finite difference method is utilized to solve the heat transfer problem, and the source term method is employed to handle the absorbed latent heat. An experimental example of a cylindrical cell is used to test this model. From a comparison with the experimental result, the computed cooling curve is found to be very close to the experimental one.