Switching properties of fluorescent photochromic poly(methyl methacrylate) with spironaphthoxazine and D-π-A type pyran-based fluorescent dye.
Fluorescent photochromic poly(methyl methacrylate) (PMMA) with spironaphthoxazine (SPO) and D-π-A type pyran-base fluorescent dye as a fluorophore was synthesized by typical free radical copolymerization. The poly(MMA-co-SPO-co-fluorophore) in both solution and solid film exhibited excellent photoregulated fluorescence switching behavior and reversible modulation of fluorescence intensity using alternating irradiation with UV and visible light. The poly(MMA-co-SPO-co-fluorophore) also showed viscosity and conductivity switching behaviors along with photoresponse.
Fluorescent monomers as building blocks for dye labeled polymers: synthesis and application in energy conversion, biolabeling and sensors.
This review focuses on side-chain functionalized polymers derived from direct (co)polymerization of fluorescent dyes. This overview about polymerizable dyes includes 1,8-naphthalimides, fluoresceins, rhodamines, coumarins, azo-dyes, oxadiazoles, diverse aromatic dyes as well as selected other dyes that cannot be classified within these groups. The discussed dyes have been functionalized with a polymerizable unit in order to apply straight-forward polymerization procedures. Therefore, the center of attention is set to the optical properties of the polymerizable dyes and the applicable polymerization techniques. Furthermore, the various applications (i.e., in biomedicine and pharmacy, as thermo-responsive materials and energy transfer materials, for dispersion of carbon nanotubes and others) of each polymer are discussed.
Point-to-point and point-to-multipoint communications
A network, such as wired and/or wireless LAN, is configured to have both point-to-point and point-to-multipoint connections. The point-to-multipoint connection(s) is used to communicate information between a plurality of the stations (or modem, or transceivers) in the network, whereas the point-to-point connection(s) are used to communicate information between only 2 stations in the network with the ability to, for example, maximize performance (rate/reach/BER/latency/etc) between those two stations. A master station allocates one or more frequency bands to the various point-to-multipoint and point-to-point connections.