Life Fraction Hardening Applied to a Modified Theta Projection Creep Model for a Nickel-Based Super-Alloy
This paper presents the application of a life fraction hardening rule to the analytical calculation of creep in hot section components. Accurate prediction of creep is critical to assuring the mechanical integrity of heavy-duty, industrial gas turbine (IGT) hardware. The accuracy of such predictions depend upon both the creep models assumed and how those models are implemented in a finite element solution. A modified theta projection creep model for a nickel-based super alloy was presented in a previous paper as an accurate simulation of creep behavior [1]. Application of such a user defined creep law depends upon definition of a hardening rule in the form of either an explicit or an implicit integration scheme in order to calculate incremental strains during any time increment. Time hardening is the simplest and least computationally intensive of the two most common hardening rules, but does not correctly show the effect of changing stresses or temperatures. Strain hardening may provide the most accurate solution, but the creep models are too complex to invert, which results in highly iterative and computationally intensive solutions. A life fraction hardening rule has been presented in other works [2] as a compromise between time hardening and strain hardening. Life fraction hardening is presented here as a highly efficient and accurate means of calculating incremental creep strain when applied to a modified theta projection creep model. A user creep subroutine was defined using a state variable to represent the strain life fraction at any time. By using the time to tertiary creep as the denominator for the life fraction, no new material constants are needed to relate to creep failure. The start of tertiary creep is effectively considered to be a failure. Additional design insight can be provided through the inclusion of other state variables to calculate temperature margins at current conditions. Material testing with changing stress levels will be used to help validate the technique. A simplified example of the technique is presented in the paper. More accurate creep predictions allow our company to improve the structural integrity of its turbine blades and vanes.Copyright © 2014 by Alstom Technologie AG
A new statistical framework for the determination of safe creep life using the theta projection technique
In this article a new estimation framework is put forward for the well-known theta projection technique which enables, for the first time, levels of confidence to be associated with the creep property predictions made using this technique. The predictions made from the resulting model are in the form of distributions, which is a substantial advance on existing life assessment methodologies used in high-temperature applications such as the disks and blades used in aero engines. This additional information should prove invaluable for questions related to the issues of possible life extension. When applied to data on Ti.6.2.4.6, accurate interpolations and extrapolations could be made of the actual distribution of the minimum creep rate, which in combination with the Monkman–Grant relation, also enabled accurate predictions to be made for the time to failure. For example, when extrapolating to a stress of 480 MPa, the time to failure was predicted to follow a non-normal distribution with a median time of 3450 h and a 95% confidence interval of 3250–3800 h. The single experimental data point available at this stress was consistent with such an extrapolation.
Mucoadhesive Nanoparticles for Drug Delivery to the Anterior Eye
While the use of topical drops for the delivery of drugs to the anterior of the eye is well accepted, it is far from efficient with as little as 5% of the drug instilled on the eye actually reaching the target tissue. The ability to prolong the residence time on the eye is desirable. Based on the acceptability of 2-hydroxyethyl methacrylate based polymers in contact lens applications, the current work focuses on the development of a poly(2-hydroxyethyl methacrylate (HEMA)) nanoparticle system. The particles were modified to allow for degradation and to permit mucoadhesion. Size and morphological analysis of the final polymer products showed that nano-sized, spherical particles were produced. FTIR spectra demonstrated that the nanoparticles comprised poly(HEMA) and that 3-(acrylamido)phenylboronic acid (3AAPBA), as a mucoadhesive, was successfully incorporated. Degradation of nanoparticles containing N,N′-bis(acryloyl)cystamine (BAC) after incubation with DL-dithiothreitol (DTT) was confirmed by a decrease in turbidity and through transmission electron microscopy (TEM). Nanoparticle mucoadhesion was shown through an in-vitro zeta potential analysis.