Determination of gallium by anodic stripping square-wave voltammetry Detection of a GaZn intermetallic compound and its destruction by Sb in an NaSCNNaClO(4) supporting electrolyte.
Reproducibility for successive determinations with a hanging mercury drop electrode is assessed in relation to solution stirring, drop size and back-diffusion to the mercury thread. The effect of experimental parameters such as drop size, deposition time and gallium concentration on the observed stripping current is investigated. The interference of zinc present in a 0.5M NaSCN + 4.2M NaClO(4) supporting electrolyte on the gallium detection limit and calibration plots is described. Formation of an intermetallic compound with a Zn:Ga ratio of 2:3 and its destruction by co-deposition of zinc with Sb are reported. A detection limit of 10(-8)M gallium was obtained in the presence of 10(-5)M Sb(III).
Space-age analysis.
A survey is given of present-day analysis, from an editorial point of view, and suggests that though techniques have changed in order to meet the challenges of modern technological advances and materials, the fundamental character of analytical research and its publication has not.
Solitary Orbital Paget Disease: A Case Report
Purpose: To describe the clinical findings in a patient who had developed painless supraorbital prominence. Methods: Clinical and histopathological findings of the case are reviewed and presented. Results: The patient had an isolated histologically confirmed Paget disease of the orbit. Local excision of the lesion was performed. Conclusion: Paget disease can present not only as a diffuse process but also as a painless, solitary lesion of the orbit.