Is neutron radiation exposure always detrimental to metals (steels)?
It is well established that irradiated metals and alloys exhibit increased mechanical strength accompanied by reduced ductility, commonly referred to as irradiation strengthening and embrittlement. We talk about radiation damage and environmental degradation of metals following radiation exposure. Indeed, there have been numerous conferences and symposia held and planned on this subject, which include research work and discussions with the central theme being the damage created in materials by neutron radiation exposure. Radiation embrittlement in metals is believed to be due mainly to (1) changes in flow properties because of the interaction of dislocations with irradiation-produced defects1, and (2) precipitation of transmutation-produced gases and irradiation-induced segregation at grain boundaries which are potential fracture sites2. Contrary to the previously observed radiation embrittlement in metals, I report here that neutron irradiation of mild steel improved both the mechanical strength and ductility at 373 K even at relatively high (∼1018 neutrons cm−2), fast (>1 MeV) neutron doses. To my knowledge, such improvement has never been observed before.
Revealing of the Wave-Like Process in Kinetics of the Reactor Pressure Vessel Steel Radiation Degradation
Influence of neutron irradiation on reactor pressure vessel (RPV) steel degradation are examined with reference to the possible reasons of the substantial experimental data scatter and furthermore – nonstandard (non-monotonous) and oscillatory embrittlement behavior. In our glance this phenomenon may be explained by presence of the wavelike recovering component in the embrittlement kinetics. We suppose that the main factor affecting steel anomalous embrittlement is fast neutron intensity (dose rate or flux), flux effect manifestation depends on state-of-the-art fluence level. At low fluencies radiation degradation has to exceed normative value, then approaches to normative meaning and finally became sub normative. Data on radiation damage change including through the ex-service RPVs taking into account chemical factor, fast neutron fluence and neutron flux were obtained and analyzed. In our opinion controversy in the estimation on neutron flux on radiation degradation impact may be explained by presence of the wavelike component in the embrittlement kinetics. Therefore flux effect manifestation depends on fluence level. At low fluencies radiation degradation has to exceed normative value, then approaches to normative meaning and finally became sub normative. As a result of dose rate effect manifestation peripheral RPV’s zones in some range of fluencies have to be damaged to a large extent than situated closely to core. we at some stages of irradiation damaged metal be partially restored by irradiation i.e. neutron bombardment. Nascent during irradiation structure undergo occurring once or periodically transformation in a direction both degradation and recovery of the initial properties. our hypothesis at some stage(s) of metal structure degradation neutron recovering Self-recovering section of RPV steel radiation embrittlement kinetics indication
Measuring Sheet Resistances of Dielectrics Using Co‐Planar Hydrogel Electrochemical Cells with Practical Applications to Characterize the Protective Quality of Paints on Sculptures
Electrical properties of thin dielectric films at the solid-liquid phase boundary are an important performance characteristic of many devices, coatings and sensors. In this paper, co-polymeric hydrogels of polyacrylic acid co-sulfonic acid, swollen with a salt solution to act as the solid electrolyte, were used to assess interfaces using electrochemical impedance spectroscopy (EIS) in a co-planar geometry. Silane-modified glasses were characterized by the co-planar hydrogel EIS cell and found to be distinguishable based on their surface monolayer chemistry. EIS measurements were also made on primed and painted metal substrates, using both test panels and an outdoor sculpture, Tony Smith's Stinger. The panels were then exposed to accelerated and outdoor weathering and showed degradation on the surface paint layers, which was observable electrochemically using EIS and confirmed visually by SEM. Electrochemical spectral features were compared between data from a standard paint-test cell versus this co-planar hydrogel cell; both cell types were able to measure coating capacitance, providing useful information about the condition of the bulk coating. Yet, sheet resistance (Rs) was a spectral feature seen only by the co-planar hydrogel cell. Thus, it can be concluded that the use of such co-planar hydrogel cells can provide an earlier warning sign to coating degradation and such cells provide a new type of spectral information that is not assessable by the standard geometry.