Interpretation of electron diffraction data from organic microcrystals: a theoretical perspective.
The current framework for the quantitative analysis of transmission electron diffraction data from organic microcrystals is discussed. The appropriate formulation depends upon the crystal perfection: solution-grown material tends to be nearly perfect with regular elastic bends whilst the epitaxial samples are usually considerably less perfect with highly irregular bends. It is possible to obtain Bragg intensity data which are near-kinematical and thus amenable to ab initio structure analysis. Thereafter, the further refinement of the model proceeds with a consideration of dynamical and crystal bending effects. If both of these are small it is a good approximation to analyse them independently rather than use the correct description of dynamical scattering from a deformed foil. The analysis of three-dimensional data sets from tilt series is considered. Although the technique has been successfully demonstrated in several instances there are still details of the analysis that need further clarification.
Kink defects in linear chain molecules-structure analysis based on spot and continuous diffuse electron diffraction intensities
Abstract Calculated defect diffuse scattering patterns, using the kink defect model employed earlier to explain changes in Bragg electron diffraction intensities for heated n-paraffins, are shown to account best for observed diffuse data from solution-grown and epitaxially grown micro-crystals. The presence of significant diffuse scattering below 15°K, moreover, indicates that such chain kinks are stable in the crystal lattice.
DEM generation from new VIR sensors: IKONOS, ASTER and Landsat-7
DEM generation is a living R&D topic since new-launched satellite images can be used to generate stereoscopic images. Using a coplanarity equation model developed at CCRS and an automatic matching method developed at PCI, DEMs are generated with new VIR stereo data. Accuracy of 4.9 m with high-resolution IKONOS images, and 33 m and 101 m with medium-resolution ASTER and Landsat-7 ETM/sup +/ images respectively are obtained. The same matching accuracy of one-pixel is translated into worse results with Landsat due to a small B/H ratio of 0.15.