Dielectric relaxations in amorphous polymers with complex chain architectures
By combining thermostimulated current and dynamic dielectric spectroscopies, the dielectric properties characteristic of the molecular mobility can be described over a very broad frequency range. The study of dielectric relaxations of phosphorus-containing dendrimers in the sub-glass transition region, and of poly(n-alkyl methacrylates) at and above the glass transition region allows us to gain insight into the molecular dynamics of complex architecture systems. From these sets of data we make an attempt to propose a structural interpretation of molecular mobility through the glass transition.
Study of dielectric relaxations in cellulose by combined DDS and TSC
In this work, thermally stimulated currents (TSC) analyses combined with dynamic dielectric spectroscopy (DDS) have been applied to the investigation of molecular mobility of cellulose. The correlation between results obtained by both methods allows us to attribute the low temperature DDS relaxation mode to the c-mode resolved in TSC. The values of its activation parameters point out that the chain mobility remains localized. At high temperature, the various dielectric relaxation phenomena are separated by applying a recent analytical protocol. The comparison between the activation enthalpy values obtained by DDS and TSC leads to the assignment of the socalled a-mode to cooperative movements of polymeric sequences. The Arrhenius behavior of a-relaxation time is explained using the strong/fragile pattern. The influence of water content on secondary and primary relaxation modes was examined as well.
Judicial Review, Socio-Economic Rights and the Human Rights Act
INTRODUCTION 1 THE ROLE OF COURTS IN THE PROTECTION OF SOCIO-ECONOMIC RIGHTS: INTERNATIONAL AND DOMESTIC PERSPECTIVES I. The Indivisibility of Human Rights II. The Protection of Socio-economic Rights in Domestic Courts III. Conclusion 2 THE REGIONAL PROTECTION OF SOCIO-ECONOMIC RIGHTS: EUROPE I. Introduction II. The European Convention on Human Rights (ECHR) 1950 III. The Protection of Socio-economic Rights in the ECHR IV. The Protection of Socio-economic Rights in EC/EU Law V. Conclusion 3 COURTS, THE UK CONSTITUTION AND THE HUMAN RIGHTS ACT 1998 I. Introduction II. Reading and Giving Effect to ECHR Rights in UK Courts III. Conclusion 4 JUDICIAL REVIEW: DEFERENCE, RESOURCES AND THE HUMAN RIGHTS ACT I. Introduction II. The Constitutional Foundations of Judicial Review III. Public Law, Deference and the Human Rights Act IV. Conclusion 5 FROM NEED TO 'CHOICE' IN PUBLIC SERVICES: THE BOUNDARIES OF JUDICIAL INTERVENTION IN PRIORITISATION DISPUTES I. Introduction II. NHS Rationing: The Role of Courts in Disputes over Access to Medical Services III. Local Authority Resource Allocation Disputes IV. Interpreting Local Authority Statutory Duties Post-HRA V. Conclusion 6 ARTICLES 3 AND 8 ECHR: FAILURE TO PROVIDE AND POSITIVE OBLIGATIONS IN THE SOCIO-ECONOMIC SPHERE I. Introduction II. Anufrijeva, Article 8 ECHR and Maladministration in the Provision of Welfare III. Article 3 ECHR: Respect for Dignity IV. Conclusion 7 ARTICLE 14 ECHR AND THE UNEQUAL DISTRIBUTION OF PUBLIC GOODS AND SERVICES IN THE UNITED KINGDOM I. Introduction II. Socio-economic Entitlements and the Limits of Substantive Fairness in Article 14 ECHR III. Carson's Case: Refusal of Up-rated Payments to Pensioners Abroad 283 IV. Reynolds' Case: The Intensity of Scrutiny in Other 'Status Disputes' V. Equality and Human Rights VI. Conclusion 8 ARTICLE 6 ECHR: JUDICIAL REVIEW, DUE PROCESS AND THE PROTECTION OF SOCIO-ECONOMIC RIGHTS I. Introduction II. What is a Civil Right for the Purposes of Article 6 ECHR? III. The Quality of Administrative Justice: The Scope of Article IV. Conclusion