Increased solubility of quartz following ferrous–ferric iron reactions
A knowledge of the solubility of quartz and silicates in natural waters is important to the understanding of many gelogical processes. Here we provide experimental data to support an earlier hypothesis1, that during the supergene enrichment of banded iron-formations, redox reactions involving iron result in a much more rapid dissolution of quartz than would be predicted from its known solubility in water. The process is relevant not only to iron ore genesis but also to the much wider field of chemical weathering— for example, to the genesis of laterites and soils from quartz-bearing rocks. In addition, the reactions may offer a mechanism by which quartz is pseudomorphed by iron oxides.
Review Article Silicon pools and fluxes in soils and landscapes—a review
Silicon (Si) is the second-most abundant element in the earth's crust. In the pedosphere, however, huge spans of Si contents occur mainly caused by Si redistribution in soil profiles and landscapes. Here, we summarize the current knowledge on the different pools and fluxes of Si in soils and terrestrial biogeosystems. Weathering and subsequent release of soluble Si may lead to (1) secondarily bound Si in newly formed Al silicates, (2) amorphous silica precipitation on surfaces of other minerals, (3) plant uptake, formation of phytogenic Si, and subsequent retranslocation to soils, (4) translocation within soil profiles and formation of new horizons, or (5) translocation out of soils (desilication). The research carried out hitherto focused on the participation of Si in weathering processes, especially in clay neoformation, buffering mechanisms for acids in soils or chemical denudation of landscapes. There are, however, only few investigations on the characteristics and controls of the low-crystalline, almost pure silica compounds formed during pedogenesis. Further, there is strong demand to improve the knowledge of (micro)biological and rhizosphere processes contributing to Si mobilization, plant uptake, and formation of phytogenic Si in plants, and release due to microbial decomposition. The contribution of the biogenic Si sources to Si redistribution within soil profiles and desilication remains unknown concerning the pools, rates, processes, and driving forces. Comprehensive studies considering soil hydrological, chemical, and biological processes as well as their interactions at the scale of pedons and landscapes are necessary to make up and model the Si balance and to couple terrestrial processes with Si cycle of limnic, fluvial, or marine biogeosystems.
Predicting the gas resource potential in reservoir C-sand interval of Lower Goru Formation, Middle Indus Basin, Pakistan
Abstract The integrated study of seismic attributes and inversion analysis can provide a better understanding for predicting the hydrocarbon-bearing zones even in extreme heterogeneous reservoirs. This study aims to delineate and characterize the gas saturated zone within the reservoir (Cretaceous C-sand) interval of Sawan gas field, Middle Indus Basin, Pakistan. The hydrocarbon bearing zone is well identified through the seismic attribute analysis along a sand channel. The sparse-spike inversion analysis has efficiently captured the variations in reservoir parameter (P-impedance) for gas prospect. Inversion results indicated that the relatively lower P-impedance values are encountered along the predicted sand channel. To further characterize the reservoir, geostatistical techniques comprising multiattribute regression and probabilistic neural network (PNN) analysis are applied to predict the effective porosity of reservoir. Comparatively, the PNN analysis predicted the targeted property more efficiently and applied its estimations on entire seismic volume. Furthermore, the geostatistical estimations of PNN analysis significantly predicted the gas-bearing zones and confirmed the sand channel as a major contributor of gas accumulation in the area. These estimates are in appropriate agreement with each other, and the workflow adopted here can be applied to various South Asian regions and in other parts of the world for improved characterization of gas reservoirs.