A fast real time measurement system to track in and out of plane optical retardation/ birefringence, true stress, and true strain during biaxial stretching of polymer films.
An instrumented and highly integrated biaxial stretching system was designed and constructed to obtain true stress, true strain, and optical behavior of polymeric films during biaxial stretching. With programmable drive motors, any form of temporally varying biaxial deformation profiles, including linear, exponential, logarithmic as well as cyclic, can be applied to a square-shaped films. This machine allows the investigation of mechano-optical behavior of films under profiles captured in industrial processes. To overcome the edge effects, the samples are painted with a dot pattern that is imaged using a high speed video capture system. This system accurately determines the locations of the each dot matrix in subsequent images acquired and calculates the true strains in both directions. The in-plane optical retardation is determined using spectral birefringence method that uses polarized white light and optical spectrometer in the optical train. This is carried out automatically at less than 10 nm in retardation resolution with the light beam passing through the symmetry center of the sample. Out of plane retardation is measured with an identical optical train tilted 45° to the plane of the film with its light beam going through the same spot on the sample as 0° beam. The true stress and birefringences are calculated with the determined instantaneous thickness of the film. With this system, the stress optical behavior of PET's is determined up to very large deformation levels at moderate to high deformation rates. Beyond the initial linear stress optical behavior, these films exhibit sudden positive deviation from linearity and this start of nonlinearity was directly associated with the stress induced crystallization.
Strain-Induced Crystallization during Relaxation Following Biaxial Stretching of PET Films: A Real-Time Mechano-Optical Study
The relaxation behavior of simultaneously and sequentially biaxially stretched PET films was studied at the rubbery state stretching temperatures. The primary objective was to investigate the influence of process conditions and the mode of deformation on the structural changes that take place in the stretched films. Using an instrumented biaxial stretcher, the films were stretched and held at the stretching temperature at fixed dimensions while true stress, true strain, in- and out-of-plane birefringences were monitored. The relaxation behavior was found to be dependent on the process prehistory including extent and rate of deformation. The behavior was divided into three regimes: Regime I, where the birefringence and strain always decrease and the material remains in the amorphous state. Regime II, where both the birefringence and strain first decrease while the film remains amorphous; then they start to increase when the first evidence of strain crystallization appears. Regime III, where strain-induced ...
5.63 and 5.80 MeV levels of Ne20; de-excitation branching
Abstract The ratio Г γ /Г for the 5.63 and 5.80 MeV levels of Ne 20 has been determined to be 0.077 (±0.008) and −4 , respectively, by using the C 12 (C 12 , α)Ne 20 reaction and determining the fraction of the events in which the alpha-particle and the Ne 20 recoil are present in coincidence at the kinematically correct angles. In both cases these results in themselves are shown to imply radiative E1 transition (5.63→1.63 and 5.80→0, respectively) probabilities ⪡5 × 10 −5 Weisskopf units. When taken together with the life-time for the 5.63 MeV level measured by Evans et al . values of Г( E1 ) ≲ 5 × 10 −6 and Г α ≈ 6% of the particle estimate are obtained for this state.