Time-Resolved Profiles in Modulated Polarization Spectroscopy
The absorption of a modulated light beam in which the state of the polarization is continuously variable is discussed. It is now possible to measure the average time-dependent profile for the polarization cycle of such a beam, and corresponding theoretical descriptions are needed in order to extract the information contained in it. This work generates such a description. Based on a semiclassical treatment of light/matter interactions, a three-parameter fit function is derived that permits the simultaneous extraction of absorbance, linear dichroism, and circular dischroism from the profile for various types of uniformly oriented, partially oriented, and isotropic materials and combinations of them. The theoretical expressions are used to analyze data for (+)-3-methylcyclopentanone, the results being (1) an increase of the S/N ratio, (2) the simultaneous generation of absorption and dichroism spectra of identical quality, and (3) a description of window adsorbates of the cyclopentanone material. The Jones p...
Natural and Magnetic Vacuum Ultraviolet Circular Dichroism Measurements at the Synchrotron Radiation Center University of Wisconsin-Madison
Substances which rotate the plane of polarization of linearly polarized light are called optically active. The optical rotation occurs due to unequal responses to left and right circularly polarized radiation. Circular dichroism spectroscopy measures the difference in absorption between left and right circularly polarized light (usually expressed as the difference in molar extinction coefficient, eL-eR, or absorbance, AL-AR) as a function of wavelength.
Time behavior of gas pressure and PD activity in insulation cavities under AC voltage
In the framework of developing defect-based life models (i.e. the life model of partial discharge-induced damage growth from a micro-void in polymer matrix), ageing tests were performed on PE layered specimens with artificial cavities under constant gas pressure and constant gas volume conditions, respectively. Time behavior of the discharge repetition rate and amplitude were recorded and compared under these two conditions. Results show that pressure variation has little influence on PD activities at constant gas volume. Under constant gas pressure, the evolution of gas volume has similar characteristic to the product of discharge amplitude and repetition rate.