The Role of Isopropyl Alcohol in the Properties of Sudanese Reformat Gasoline
The role of isopropyl alcohol in the properties of Sudanese reformat gasoline (produced by the refinery located at Algily, Khartoum North city, in Sudan) was studied. The properties of the reformat gasoline which were investigated include , distillation, sulfur content, density, vapor pressure, oxidation stability, copper strip corrosion, gum existence, lead content, and the octane number . The addition of isopropyl alcohol (5 and 10% (v/v)) improved the properties of the Sudanese reformat gasoline to the limits assigned by American Society For Testing And Materials (ASTM) and Khartoum refinery. The motor octane number (MON) of the reformat gasoline was determined initially by the Cooperative Fuels Research engine (CFR engine), MON was found to be 88.5. Results revealed that the addition of isopropyl alcohol 5 and 10 % (v/v) to the Sudanese reformat gasoline shift the value of the (MON) to 94.1 and 96 respectively. keywords: Isopropyl alcohol, Sudanese gasoline properties, Motor octane number, Cooperative fuels research engine.
Study of the influence of alcohols addition to gasoline on the distillation curve, and vapor pressure
Abstract The properties of gasoline change as a result of blending with an alcohol. The aim of this paper is to report new experimental data on distillation curve and Reid vapor pressure of pseudo-binary blends of a catalytic reforming gasoline with ethanol, i-propanol and n-butanol, respectively. Gasoline blend with ethanol was used as reference for discussing properties of isopropanol and respectively, n-butanol blends with gasoline. The main conclusion is that alcohol addition to gasoline affects the relevant characteristics of the blend that influence engine operation. Gasoline+i-propanol blends have intermediate behavior between gasoline+ethanol and gasoline+n-butanol blends.
HPLC determination of chlorhexidine gluconate and p-chloroaniline in topical ointment.
A novel fast isocratic reversed-phase HPLC method for simultaneous determination of chlorhexidine and its degradation product p-chloroaniline was developed. Zorbax SB Phenyl column (75 mm x 4.6 mm, 3.5 microm) was used for the separation. Mobile phase composed of acetonitrile and buffer solution of 0.08 M sodium phosphate monobasic containing 5 ml of triethylamine (0.5%) and adjust with 85% phosphoric acid to pH 3.0 in ratio 35:65 (v/v) pumped isocratically at flow rate 0.6 ml min(-1) was used. UV detection was performed at 239 nm, the total analysis time was about 10 min. The method is suitable for practical routine analysis of topical ointment in the quality control laboratory.