Simulation of flows in shock-tube facilities by means of a detailed chemical mechanism for nitrogen excitation and dissociation
A database was recently developed at NASA Ames Research Center for the dissociation and excitation rates of the rovibrational energy levels of nitrogen. This work is a first step toward the development of a simplified mechanism for 3-D simulations of atmospheric entry flows. First, we have derived a Boltzmann average dissociation rate based on rotational and vibrational temperatures. At thermal equilibrium, a very good agreement is obtained with the rate proposed by Park (1990). Significant discrepancies are observed in thermal non-equilibrium conditions. Then, we have developed a 0-D vibrational state-to-state collisional model to simulate a typical shock in a nitrogen flow based on vibrational-specific excitation and dissociation reaction rates derived by assuming a Boltzmann distribution of the rotational energy levels at the translational temperature. We have shown that the vibrational energy relaxation for the monoquantum excitation processes deviates significantly from the conventional Landau-Teller law. The dissociation process, coupled with the energy level relaxation dynamics, strongly depends on multi-quantum jump processes. Finally, we have implemented the multi-temperature dissociation rate in a 1-D code for shock-tube flows and have compared our results with experimental results.
Modeling and Experimental Validation of CN Radiation Behind a Strong Shock Wave
Assessment of nonequilibrium thermochemical models for shock layer radiation in N2/CH4 mixtures is presented via comparisons with spectrally and temporally resolved intensity measurements from a set of shock tube experiments. The experiments were carried out at the Electric Arc Shock Tube (EAST) facility at NASA Ames Research Center in a rarified environment [13.3-133.3 Pa (0.1 and 1 Torr)] representative of the peak heating conditions of a Titan aerocapture trajectory (5-9 km/s). The baseline model that assumes a Boltzmann population of the CN excited states consistently overpredicts the shock layer radiation intensity. A non-local collisional radiative model that solves a simplified master equation and includes radiative transport and non-local absorption in the shock tube is presented. The proposed model improves the prediction of the nonequilibrium radiation overshoot peak, but still underpredicts the intensity decay rate in the low pressure case. Further analysis suggests possible reasons for the remaining disagreement, the most likely being a slow CN consumption in the current chemical kinetics model in the intensity fall-off region.
The REX-ISOLDE project
The Radioactive Beam Experiment REX-ISOLDE [1–3] is a pilot experiment at ISOLDE (CERN) testing the new concept of post acceleration of radioactive ion beams by using charge breeding of the ions in a high charge state ion source and the efficient acceleration of the highly charged ions in a short LINAC using modern ion accelerator structures. In order to prepare the ions for the experiments singly charged radioactive ions from the on-line mass separator ISOLDE will be cooled and bunched in a Penning trap, charge bred in an electron beam ion source (EBIS) and finally accelerated in the LINAC. The LINAC consists of a radiofrequency quadrupole (RFQ) accelerator, which accelerates the ions up to 0.3 MeV/u, an interdigital H-type (IH) structure with a final energy between 1.1 and 1.2 MeV/u and three seven gap resonators, which allow the variation of the final energy. With an energy of the radioactive beams between 0.8 MeV/u and 2.2 MeV/u a wide range of experiments in the field of nuclear spectroscopy, astrophysics and solid state physics will be addressed by REX-ISOLDE.