Stability of Structure, Phase and Elemental Composition of ChemicallyDeposited and Electrodeposited Gold Layers in Multilayer SystemsAuchemically reduced; electrodeposited /Co-W/Cusputtered / Glass-Ceramics
The changes in the structure and elemental composition of Au and Co-W thin layers after thermal treatment of 200 h at 200-300 oC and 50 h at 450 oC were systematically studied using the X-ray microanalysis of scanning electron microscope XL-30 ESEN Philips. The phase stability was evaluated by X-ray diffraction (XRD). The electrodeposited Co-W layer (W 46.0-53.0 wt. % depending on the electrodeposition regime) is amorphous and maintains its amorphous state after heating at 200 oC for 200 h and subsequent heating (+) at 300 oC for 150 h. Co-W amorphous layers prevent interdiffusion of Au and Cu atoms and formation of intermetallics AuCu in the systems of layers Au chemically reduced; Au electrodeposited /Co-W/Cu sputtered / glass-ceramics. The chemically reduced 0.4 � m Au layers maintain their structure and phase in the systems of layers upon heating at 200 oC for 200 h and subsequent heating (+) at 300 oC for 50 h. The Au layer maintains its Au content 85-86 wt. % upon heating at 450 oC for 50 h, the cobalt content of the layer up to 8.6 wt. % and content of oxygen bonded to Au of 8.6 wt. %. The electrodeposited Au layers (0.8 - 1.0 � m) maintain their structure at heating at 200 oC and 300 oC for 200 h. After additional heating at 450 oC for 30-50 h gold content in the layer decreases from 98.4 wt. % to 85.0 wt. %, cobalt content increases to 7.6 wt. % and oxygen to 7.2 wt. %. Functional properties of the above multilayer systems deteriorate by mutual diffusion of metal atoms and formation of brittle intermetallics. The latter may give rise to the formation of monolithic films, cause the deterioration of mutual adhesion of the layers and complete reactions of the upper conducting Sn, Au layers with the base metal Ni, Cu, Ti, Sn (15, 16). This diffusion can worsen the properties of very thin (0.5-1.0 � m) metal layers electrodeposited on a Cu layer (1-2 � m) sputtered on glass-ceramics (15).
Electrodeposition & Characterization of Co-W Alloys
Cobalt-tungsten alloys have been electroplated from alkaline bath solutions under different plating and bath conditions. Diammonium hydrogen citrate and dimethyl sulfoxide in the bath solution have produced good quality deposits. The hardness and magnetic properties of the alloys are found to depend on composition and heat treatment. Cyclic voltammetric and spectral studies revealed the complexation of cobalt ions with diammnonium hydrogen citrate in the plating bath solution. Dimethyl sulfoxide has activated the codeposition of tungsten. The alloys are amorphous under plating conditions and become partially crystalline upon heat treatment. AES analysis revealed the absence of oxygen, chlorine and carbon on the surface of the coated alloys. Working conditions were optimized to get good quality deposits with appreciable coercivity and hardness values.
Women's health in prison: urgent need for improvement in gender equity and social justice.
The needs of women held in detention have received little attention and con-tinue to be neglected by health systems and prison authorities. One reason for this, too readily accepted until now, is that women prisoners are a clear minor-ity group within prisons all over the world. It is only recently that attention has been drawn to the fact that a minor-ity status does not justify the widespread ignorance of women’s basic rights and the considerable gender insensitivity still dominating criminal justice systems.In Europe alone, there are about 100 000 women and girls in prison.