Preformed Particle Gel for Conformance Control: Factors Affecting Its Properties and Applications
Preformed particle gel (PPG) is a particled superabsorbent crossklinking polymer that can swell up to 200 times its orginal size in brine. The use of PPG as a fluid-diverting agent to control conformance is a novel process designed to overcome some distinct drawbacks inherent in in-situ gelation systems. This paper introduces the effect of gelant compositions and reservoir environments on the two properties of PPG: swollen gel strength and swelling capacity. Results have shown that PPG properties are influenced by gelant compositions, temperature, brine salinity, and pH below 6. Temperature increases PPG swelling capacity but decreases its swollen gel strength. Salinity decreases PPG swelling capacity but increases its swollen gel strength. PPG is thermostable at an elevated temperature of 120°C if a special additive agent is added into its gelant as a composition. PPG is strengthand sizecontrolled, environmentally friendly, and not sensitive to reservoir minerals and formation water salinity. Two field applications are introduced to illustrate the criteria of well candidate selection and the design and operation process of PPG treatments. Field applications show that PPG treatment is a cost-effective method to correct permeability heterogeneity for the reservoirs with fractures or channels, both of which are widely found in mature waterflooded oil fields.
Placement of Gels To Modify Injection Profiles
This study investigates how flow profiles in injection wells are modified when zones are not isolated during placement of gelling agents. Mathematical models are used to examine the degree of gel penetration and injectivity loss in zones of different permeability. Several conclusions are drawn that apply to reservoirs in which crossflow between layers does not occur. First, zone isolation is far more likely to be needed during placement of gels in unfractured wells than in fractured wells. Productive zones in unfractured wells may be seriously damaged if zones are not isolated during gel placement. Second, gel placement without zone isolation should cause the least damage to productive zones in unfractured wells when (a) the gelling formulation exhibits a low resistance factor during placement, (b) the water-oil mobility ratio is relatively high, (c) the most-permeable layer(s) are watered-out, and (d) the waterfronts are not close to the production well in the productive zones. Third, parallel linear corefloods overestimate the degree of profile modification that can be attained in radial systems. Fourth, chemical retention, dispersion and diffusion will probably not significantly mitigate injectivity losses caused by gel penetration into lowpermeability zones. Finally, a need exists to determine the permeability and velocity dependencies of gelling-agent resistance factors and of gel residual resistance factors.
Results of an inter-laboratory comparison of methods for quantitative clay analysis
Abstract In a comparison of analytical methods in clay mineralogy, two clay samples (from Hennersdorf and Freydegg) of different clay composition were analyzed by 19 laboratories mainly by XRD. Participants used different methods of pre-treatment, preparation, analysis and evaluation. In spite of the diversity of analytical methods applied, reasonable conformity in quantitative results was obtained for the associated minerals (quartz, calcite and dolomite). On the other hand, qualitative identification of the clay minerals showed considerably stronger divergencies, causing a stronger deviation of quantitative data; analysis of the Freydegg sample proved to have been particularly difficult. The evaluation methods of the different participants were examined to determine whether similar methods provided results that could be more easily compared. In addition, the authors calculated the clay mineral composition according to three different recognized methods, using the same diffractograms and same preparation and measuring conditions. In spite of this, different results were obtained. In the next phase of the programme, an inter-laboratory comparison of methods will be achieved under exactly defined conditions of preparation and analysis.