Preparation and Characterization of Porous Composite Filter Medium by Polytetrafluoroethylene Foam Coating
Abstract The high costs of ceramic and Teflon filter media for hot gas cleaning has limited their industrial applications. This paper presents a foam coating technology that can be used to produce an inexpensive and highly efficient filter for industrial applications. A new apparatus was designed and built that coats porous glass mats with liquid-phase polytetrafluoroethylene (PTFE). The machine generates bubbles, enables the formation of uniform micropores less than 45 μm in diameter, and produces a product with air permeability greater than 5.5 cm3/cm2/sec. The resulting filter was found to be thermally stable up to 270 °C without any visible distortion and was comparable in dust collection efficiency to other commercial filter media. In addition, its de-dusting efficiency was greater than 85%, which is similar to that of other test filter media.
Characterization of ceramic composite membrane filters for hot gas cleaning
Abstract Novel composite ceramic membrane filters suitable for hot gas cleaning operations have been prepared from fly ash and titania particles on stainless steel woven mesh substrates. Both membranes had a structure like a solid packed bed with a thickness of less than 100 μm. In the domain of laminar flow, significant differences in the pressure drop between experimental results and those predicted from the Kozeny-Carman relationship were found, particularly for flow through the titania membrane. Membrane filters with extremely small pores such as the titania membrane are greatly affected by slip up to 80% in permeability at elevated temperatures. Efficiencies of filtration of typical coal fired power station exhaust fly ashes were found to be greater than 909% for both titania and ash membranes, whilst there was greater variation in the pressure drops in the ash membrane than in the titania at typical gas flows.
Rational Design, Synthesis and Evaluation of γ-CD-Containing Cross-Linked Polyvinyl Alcohol Hydrogel as a Prednisone Delivery Platform
This study describes the in-silico rational design, synthesis and evaluation of cross-linked polyvinyl alcohol hydrogels containing γ-cyclodextrin (γ-CDHSAs) as platforms for the sustained release of prednisone (PDN). Through in-silico studies using semi-empirical quantum mechanical calculations, the effectiveness of 20 dicarboxylic acids to generate a specific cross-linked hydrogel capable of supporting different amounts of γ-cyclodextrin (γ-CD) was evaluated. According to the interaction energies calculated with the in-silico studies, the hydrogel made from PVA cross-linked with succinic acids (SA) was shown to be the best candidate for containing γ-CD. Later, molecular dynamics simulation studies were performed in order to evaluate the intermolecular interactions between PDN and three cross-linked hydrogel formulations with different proportions of γ-CD (2.44%, 4.76% and 9.1%). These three cross-linked hydrogels were synthesized and characterized. The loading and the subsequent release of PDN from the hydrogels were investigated. The in-silico and experimental results showed that the interaction between PDN and γ-CDHSA was mainly produced with the γ-CDs linked to the hydrogels. Thus, the unique structures and properties of γ-CDHSA demonstrated an interesting multiphasic profile that could be utilized as a promising drug carrier for controlled, sustained and localized release of PDN.