Using a pulsed deflector for extraction of pulsed beams from the TRIUMF cyclotron
In the normal mode of operation, the TRIUMF cyclotron accelerates H/sup -/ ions to produce 500 MeV proton beams of 160 /spl mu/A with 4 nsec pulses separated by 43 nsec. A proposed experiment (/spl mu//spl rarr/e conversion) requires a 500 MeV beam with 100-200 nsec pulses separated by 1-2 /spl mu/ sec with an average intensity of 200 /spl mu/A. Two methods have been investigated to achieve this time structure. Both incorporate a pulsed electric deflector and take advantage of extraction by stripping. In the first case, a deflector with a thin septum deflects radially up to six accumulated turns onto a stripping foil in one turn. In the second, a pair of vertically deflecting plates are pulsed at a frequency to excite a coherent vertical growth, and the particles are eventually intercepted by a stripping foil. Under certain conditions extraction occurs in almost perfect synchronism with the driving pulse. Both methods will be described in detail and results of computer simulations will be presented.
Reducing phase-dependent emittance growth with local flattopping
The efficiency of the proposed H/sup -/ extraction in the TRIUMF cyclotron is improved by inducing a precessional component to the radius gain per turn by exciting a coherent radial betatron oscillation at /spl nusub r/=3/2. Beam test and computer simulation results show that accompanying this improvement is a growth in the transverse emittance of the extracted beam. The growth is, in part, due to phase-dependent mixing of the perturbed beam. This phase-dependence can be greatly reduced by flattopping the local energy gain per turn with the addition of a higher harmonic accelerating field in phase opposition to the fundamental. A 92 MHz, 4/sup th/ harmonic, /spl lambda4 cavity installed in the TRIUMF cyclotron has been used for such a purpose. Results of both computer simulations and beam tests will be presented.<<ETX>>
Experimental energy barriers to anions transporting through nanofiltration membranes.
Environmentally relevant contaminants fluoride, chloride, nitrate, and nitrite face Arrhenius energy barriers during transport through nanofiltration (NF) membranes. The energy barriers were quantified using crossflow filtration experiments and were in the range of 7-17 kcal·mol(-1), according to ion type and membrane type (Filmtec NF90 and NF270). Fluoride faced a comparatively high energy barrier for both membranes. This can be explained by the strong hydration energy of fluoride rather than other ion properties such as bare ion radius, fully hydrated radius, Stokes radius, diffusion coefficient, or ion charge. The energy barrier for fluoride decreased with pressure, indicating an impact of directional force on energy barriers. The influence of temperature-induced pore radius variability and viscosity on energy barriers was considered. The novel link between energy barriers and ion properties emphasizes the importance of ion hydration and/or partial dehydration mechanisms in determining transport in NF.