Role of Asphaltenes in Inhibiting Corrosion and Altering the Wettability of the Steel Surface
Abstract Asphaltenes (heptane insolubles) from a variety of crude oils have been identified previously as contributors to inhibition of internal corrosion of mild steel pipelines. However, the mech...
Effects of Asphaltene Solvency on Stability of Water-in-Crude-Oil Emulsions
Abstract The formation of stable and persistent emulsions and foams in the production and refining of crude petroleum is a challenge which has defied broad and generic resolution for several decades. Rational and systematic approaches to demulsification have been slow to develop due to a lack of fundamental understanding of the molecular origins of emulsion stabilization and the full range of factors which govern emulsion stability. Several studies have shown the importance of resins and asphaltenes, which have the ability to organize and form rigid films at the oil/water interface. We have developed a molecular model in which we propose that the integrity of these films and thus their ability to stabilize water-in-crude-oil emulsions are sensitive to a variety of crude solvency parameters, such as aromaticity, resin-to-asphaltene ratio, and polar functional group concentration. This model was tested by correlating the stability of emulsions formed from a variety of crude oils—Arab Berri (Extra Light), Arab Heavy, Alaska North Slope, and San Joaquin Valley—in which the resin and asphaltene contents vary, as well as their specific characteristics. The results of the elemental and functional group characterization of these crudes and their fractions and the techniques utilized to obtain them were presented previously. Detailed quantitative protocols for gauging relative emulsion stability have been developed to further evaluate the proposed model by blending solvents of varying aromaticity and by doping isolated resins from different crudes into solvent-modified crudes. Dramatic destabilization of emulsions was accomplished by modifying the crude solvency in either fashion. Simple physical and chemical techniques for minimizing emulsion formation such as basic crude blending and solvent-recycle schemes will also be discussed.
Role of the coronoid process in varus osteoarticular stability of the elbow.
The role of the coronoid process in varus osteoarticular stability of the elbow was investigated in 10 cadaveric elbows. Testing was performed at multiple flexion angles after incremental removal of the coronoid. At each flexion angle, removal of more than 50% of the coronoid produced a statistically significant decrease in the load resisting varus displacement compared with all lesser resection levels (P < .003). There was a trend for decreasing load after removal of 50% of the coronoid. The mean decrease in load across all flexion angles was 10.1%, 50.4%, and 75.4% after removal of 50%, 75%, and 100% of the coronoid, respectively. Resistance to varus displacement tended to decrease more as a percent of control at lower flexion angles than at higher flexion angles after removal of more than 50% of the coronoid. The coronoid process was found to be a key varus stabilizer in the elbow and may contribute more to elbow stability in extension than in flexion.