Equivalence of Measurements on Soft Magnetic Materials in the U.K. and Measurements for Operational Conditions
Measurements on soft magnetic materials were made to determine the measurement capabilities available to the partners of a government-funded collaborative research project, with 16 partners from industry and academia. One of the objectives of this project was the development of advanced magnetic materials for novel electrical machines for use in harsh environments such as gas turbines. To establish the measurement confidence necessary to deliver this project objective, an equivalence study was undertaken. A reference core of soft magnetic material that has been measured over a period of many years at the National Physical Laboratory (NPL) was distributed and the dc and ac properties were measured. The measurement systems of the three laboratories are independent and this ensured that no correlations that could skew the results existed. In the analyses, the measurements at NPL were used as the baseline. With the core capabilities established, it was possible to develop the new measurements required to deliver the overall project objectives. At NPL, a standard permeameter method was modified for the measurement of strips. This was incorporated into a stress machine to measure the dc properties of the soft magnetic materials used by the partners, at stress levels of up to 700 MPa. The results for seven materials are presented and the changes in the properties with applied stress compared to establish which materials exhibit favorable properties.
Equivalence of measurements on soft magnetic materials in the UK and measurements for operational conditions
Measurements on soft magnetic materials were made to determine the measurement capability available to the partners of a government funded collaborative research project with 16 partners. One of the aims of this project was the development of advanced magnetic materials for novel electrical machines for use in harsh environments such as gas turbines. To establish the measurement confidence necessary to deliver the project goals, an equivalence study between the three institutes that are authors of this paper and who provided the required measurement knowledge was undertaken. The results of this are presented in this paper and more results along with the measurement capabilities of the institutes involved will be presented in the full paper. The development of these capabilities to determine properties for operational conditions such as mechanical stress will be introduced and results presented in the full paper.
Inhibition of Mild Steel Corrosion Using L-tryptophan and Synergistic Surfactant Additives
The corrosion inhibition characteristics of nitrogen containing amino acid L-tryptophan on mild steel in 0.1 M HCl solution, in the temperature range of 30-50 o C, was studied by weight loss and potentiodynamic polarization measurements. L-tryptophan significantly reduces the corrosion rates of mild steel; the maximum inhibition efficiency being 83% at 50 o C in presence of inhibitor concentration of 500 ppm. The effect of the addition of very small concentrations of anionic surfactant, sodium dodecyl sulfate (SDS), and of cationic surfactant, cetyl trimethyl ammonium bromide (CTAB), on the corrosion inhibition behavior of L-tryptophan was also studied. The inhibition efficiency (IE) of L-tryptophan significantly improved in presence of both surfactants. The effect of SDS and CTAB on the corrosion inhibition behavior of L-tryptophan appears to be synergistic in nature, the values of synergism parameter being greater than unity. The adsorption of inhibitors on mild steel surface obeyed Langmuir’s adsorption isotherm. The calculated thermodynamic parameters for adsorption reveal a strong interaction between the inhibitors and the mild steel surface. The results obtained by electrochemical studies are consistent with the results of the weight loss measurements. L-tryptophan acts more anodic than cathodic inhibitor.