Sensing Characteristics to Acid Vapors of a TPPS Coated Fiber Optic: A Preliminary Analysis
In this work we report on preliminary analysis of a novel optoelectronic gas sensor based on an optical fiber integrated with a tetrakis(4-sulfonatophenyl)porphyrin (TPPS) thin film. The sensitive materials are selectively deposited on the core region of a fiber tip by UV light induced deposition technique. A simple and cheap process which can be easily extended to different porphyrin derivatives. When the TPPS film on the fiber tip is exposed to acid and/or base vapors, dramatic changes occur in the aggregation structure of the dye molecules in the film, from Jto H-type, resulting in a profound modification of their corresponding reflectance spectra. From the achieved experimental results it is evident that the presence of intense and narrow band peaks in the reflected spectra could be monitored to detect hazardous vapors. Keywords—Optical fiber sensor, Porphyrins, Thin films UVinduced deposition, TPPS.
Syndiotactic polystyrene thin film as sensitive layer for an optoelectronic chemical sensing device
Abstract In this work the performance of an optoelectronic sensor system able to measure the concentration of organic analytes, in aqueous environment was analyzed. Syndiotactic polystyrene (sPS) in the nanoporous crystalline δ form was here used as sensitive polymeric layer due to its high sorption properties towards chlorinated and aromatic compounds. In particular, a thin semi-crystalline sPS film with crystalline nanoporous δ form was cast on the cleaved end of a standard fiber optic and measurements of reflectivity as the analyte was sorbed by the polymer were carried out allowing on-line detection of even very low concentrations (in the range of few ppm) of chloroform and toluene in water. The refractometer performance was compared with that of a classical resonant quartz-crystal microbalance sensor (QCM), using the same polymer as sensing element.
Monte carlo simulation of events with Drell-Yan lepton pairs from antiproton-proton collisions
The complete knowledge of the nucleon spin structure at leading twist requires also addressing the transverse spin distribution of quarks, or transversity, which is yet unexplored because of its chiral-odd nature. Transversity can be best extracted from single-spin asymmetries in fully polarized Drell-Yan processes with antiprotons, where valence contributions are involved anyway. Alternatively, in single-polarized Drell-Yan the transversity happens convoluted with another chiral-odd function, which is likely to be responsible for the well known (and yet unexplained) violation of the Lam-Tung sum rule in the corresponding unpolarized cross section. We present Monte Carlo simulations for the unpolarized and single-polarized Drell-Yan pp{sup ({up_arrow}}{sup )}{yields}{mu}{sup +}{mu}{sup -}X at different center-of-mass energies in both configurations where the antiproton beam hits a fixed proton target or it collides on another proton beam. The goal is to estimate the minimum number of events needed to extract the above chiral-odd distributions from future measurements at the high energy storage ring (HESR) at GSI. It is important to study the feasibility of such experiments at HESR in order to demonstrate that interesting spin physics can be explored already using unpolarized antiprotons.