Isolation and Structural Elucidation of New Xanthone from Rot Bark of Cratoxylum sumatranum
Sumatranaxanthone A (1), a new xanthone, was isolated from the rot bark of Cratoxylum sumatranum. The structures were established based on spectroscopic studies, notably of the 1D and 2D NMR spectra. Preliminary results showed that 1 has antioxidative activity with inhibition 81% to fit with ascorbat acid standard.
Naturally-occurring xanthones: recent developments.
A literature survey covering the report of naturally occurring xanthones from January 2000 to December 2004, with 219 references, is presented in this review. Among 515 xanthones reported in this period, 278 were new natural xanthones. These xanthones have been identified from 20 families of higher plants (122 species in 44 genera), fungi (19 species) and lichens (3 species). The structural formulas of 368 identified xanthones, their distribution and a brief mention of their biological properties are also included.
Centrifuge modelling of effects of shield tunnels on existing tunnels in soft clay
With the rapid development of the subway network,the phenomena of shield tunnels going across the adjacent tunnels are becoming more and more common.The interaction between shield tunneling and nearby tunnels is more complicated than the ordinary shield tunneling in intact soil strata.Based on the project of Shanghai Bund Passage crossing Metro Line 2,the method of centrifuge modeling together with the field measurement is employed to study the effects shield tunneling on nearby strata and existing tunnels.In centrifugal model tests,the effects simulation techniques considering the unloading of excavation,ground loss and grouting are developed to analyze the longitudinal settlement of the shield tunnel and the existing tunnel induced by the shield tunneling.Besides,the deformation distribution and settlement curves of the existing tunnels during shield construction are studied by using the monitoring data.