Preparation and characterization of electroless nickel-coated cellulose fibres
The aim of this project was to fabricate electroless nickel-coated cellulose fibres. Ultimately, these nickel-coated cellulose fibres will be used to develop a cost-effective polymer composite for electromagnetic interference (EMI) shielding and/or electrostatic discharge (ESD) applications. An attempt has been made to impart electrical conductivity onto cellulose fibres via an electroless nickel plating process. The aim was to achieve a homogeneous, continuous layer of Ni on the cellulose fibres, and the plating conditions were optimized to achieve this. The relationship between the coating morphology and the performance of the coated fibre was also of interest. Testing was carried out using cellulose filter paper and then loose cellulose fibres. Scanning electron microscopic (SEM) images of nickel-coated filter paper showed that nickel particles are bonded to the cellulose fibres. The coating appeared more compacted and continuous as plating time increased, corresponding to lower surface resistivity. This observation suggested a correlation between morphology and electrical conductivity of the coating. For nickel-coated cellulose fibres, after optimization of plating conditions, a uniform deposition of nickel particles around the cellulose surfaces was confirmed by SEM images. EDS and XRD results confirmed similar coating could be produced on filter paper and cellulose fibres. SEM images of cross-sectioned nickel-coated cellulose fibres illustrated nickel particles had penetrated into the inner walls of the cellulose fibres. This impregnation of the fibres should act to increase the bonding between nickel coating and cellulose fibres. These nickel-impregnated cellulose fibres could now be incorporated into a polymer matrix to create an electrically conducting composite with the right processing parameters.
Adhesion enhancement between electroless nickel and polyester fabric by a palladium-free process
Abstract A new, efficient, palladium- and etchant-free process for the electroless nickel plating of poly(ethylene terephthalate) (PET) fabric has been developed. PET electroless plating can be prepared in three steps, namely: (i) the grafting of thiol group onto PET, (ii) the silver Ag0 seeding of the PET surface, and (iii) the nickel metallization using electroless plating bath. Scanning electron microscopy (SEM), energy dispersive X-ray (EDX) analysis, X-ray photoelectron spectroscopy (XPS), Raman spectrometer, X-ray diffraction (XRD), and thermogravimetric analysis (TG) were used to characterize the samples in the process, and the nickel loading was quantified by weighing. This process successfully compares with the traditional one based on KMnO4/H2SO4 etching and palladium-based seed layer. The nickel coating obtained in this palladium-free process can pass through ultrasonic washing challenge, and shows excellent adhesion with the PET substrate. However, the sample with Pd catalyst via traditional process was damaged during the testing experiment.
THE ATLANTIC SLAVE TRADE AND COLONIALISM: REASONS FOR AFRICA’S UNDERDEVELOPMENT?
It is probably an understatement to assert that Africa, the world’s second largest continent, is underdeveloped compared with other continents. Two major exogenous factors often cited for Africa’s development crisis are the so called ‘dual historical injustices’ – the Atlantic slave trade and colonialism. It is often pointed out that while the former almost completely arrested and retarded Africa’s demographical growth for more than three centuries, evoked a perennial state of acrimony and warfare and created a tense and unprecedented atmosphere of insecurity which hindered economic activities and stifled local entrepreneurship and technological drive and dislocated Africa’s socio-economic and political structures and institutions; the latter tied African countries to the apron strings of western imperial powers thereby rendering the pre-conditions necessary for socio-economic and political transformation unachievable. This paper contends that while the history of Africa’s underdevelopment may be traceable to the Atlantic slave trade and colonialism, African leaders had made enormous contributions to the continent’s underdevelopment and backwardness. The paper concludes that irresponsible and irresponsive leadership, vampirism and prodigality, corruption, lack of respect for democratic ideals, insecurity, endemic civil wars, nepotism, etc are the fundamental causes of Africa’s underdevelopment.