Impression materials: effect of hydrophilicity and viscosity on ability to displace water from dentin surfaces.
The water-displacing ability of hydrophilic and hydrophobic impression materials was determined and related to the hydrophilicity and viscosity of the materials. The water-displacing ability of the materials was determined on a network of grooves in a dentin surface covered by a drop of water. After setting of the material, the number of crossings reproduced in the impression was calculated in percent of the total number of crossings. The hydrophilicity was assessed by measuring the contact angle between water and impression material. To determine viscosity, a rotoviscosimeter was used. Impression materials with contact angles less than 70 degrees showed a significant negative correlation between water-displacing ability and contact angle, i.e. the reproducing ability decreased with decreasing hydrophilicity of the materials. Impression materials with contact angles above 70 degrees showed a significant positive correlation between water-displacing ability and viscosity, i.e. the water-displacing ability improved with increasing viscosity.
Penetration of restorative resins into acid etched enamel. I. Viscosity, surface tension and contact angle of restorative resin monomers.
It has been a controversial question whether an intermediate layer of low-viscous, non-composite resin between composite restorative and etched enamel is beneficial. It was the purpose of the present work to investigate some of the factors that govern the penetration of resins into the capillary pores of etched enamel surfaces. Viscosity, surface tension and contact angle on human enamel were measured using monomer mixtures similar to those found in commercial restorative resins. Employing a cylindrical model of relevant dimensions of the capillary pores, and on the basis of Poiseuille's equation the time of penetration was calculated for a relatively high-viscous and a relatively low-viscous monomer mixture. It was concluded that viscosity as such is not a limiting factor for the penetration of restorative resin monomers into the pores of etched enamel surfaces.
Titanium incorporation and VITi3+ -IVTi4+ charge transfer in synthetic diopside
Abstract A series of Ti-doped diopside samples synthesized by fluxgrowth methods under reducing conditions were investigated by microanalytical methods and optical absorption spectroscopy, to assess Ti incorporation mechanisms, valence states, and related electronic transitions. Chemical characterization show that Ti occurs both in the tri-and tetravalent states, with Ti4+ preferentially ordered to the tetrahedral position whereas Ti3+ is restricted to the M1 position. Charge-balance is maintained by incorporation of Na and minor B, stemming from the flux compound. Polarized optical absorption spectra reveal three major absorption features. Two relatively narrow bands centered at 18 500 and 15 700 cm-1, mainly polarized in the crystallographic c-direction, display absorbance values that correlate with the calculated Ti3+ (M1) concentration, and are assigned to spin-allowed d-d transitions in Ti3+. A broader band centered around 24 500 cm-1 displays absorbance values that are well correlated with the product of VITi3+ and IVTi4+. Based on the spectral characteristics of this band, including a strong polarization in the crystallographic b-direction, we assign this band to an M1Ti3+-TTi4+ intervalence charge transfer process.