DETERMINATION OF BASIC CHARACTERISTICS OF PROTECTIVE LAYERS BASED ON POLYMERIC NANOFIBERS
This work focuses on a basic research in developing new class of protective layers for building materials based on polymeric nanofibers. Nonwoven nanotextiles are fibers with diameter spanned from tens to hundreds of nanometers. Thin films consisting of suitable polymer-based nanofibers were prepared using NANOSPIDER equipment. Applied technology is unable to fully guarantee quality (homogeneity, thickness, etc.) of the protective coating. Traditionally used technologies –such as painting or spraying – are not too effective and the separation of protective coating or loosing of protective properties is frequently observed.
Nucleation on Polymer Nanofibers and their Controllable Conversion to Protective Layers: Preliminary Theoretical Study
Nanofibers are very promising new type of material with a broad range of possible applications. The new NANOSPIDER technology opens a possibility to produce nanofabrics in an amount large enough for them to start being interesting as a construction material. There are many so-called passive applications of nanotextiles (including different types of filters and protective layers), and active applications, when the active chemical agent is incorporated in their structure. In the present paper, however, the new possible application of nanofabrics is proposed: as a base material on which technically interesting nanoclusters are heterogeneously nucleated. The basic thermodynamics of heterogeneous nucleation on nanofibers is considered. The extreme curvature of nanofibers manifests itself in an energetic barrier of nucleation, which is quite different from a case of nucleation on a flat surface. The expression for Gibbs energy of cluster formation is derived, taking into account the elastic strain resulting from a volume (or shape) changes during nucleation.
Influence of Pozzolana Admixture on Long-Term Chemical Characteristic of Cement Mortars
nfluence of non-flowing model sulphate solution determined for cement mortar with pozzzolana admixture are presented in this paper. In the predetermined time intervals the influence of the aggressive liquid on chemical properties and mineralogical composition was tested. The changes caused by corrosive sulphate environment on the testing specimens were determined in dependence on the different type of cement and used ground clay brick as pozzolana admixture. From the results obtained follows that the additive of ground clay bricks has positively impact on the sulphate resistance.