Application of Fly Ash in ASHphalt Concrete : from Challenges to Opportunities
Fly ash has been effectively used for many years in producing high performance concrete, with limited use in asphalt pavements. This is possibly because the performance benefits that fly ash provides to asphalt mixtures are under-investigated. The reported research investigated the interaction of fly ash with different types of asphalt binders and documented important improvements found in the critical properties of asphalt. Microstructural investigation demonstrated in previous work, that crack-arresting behavior was successfully induced by evenly distributed fly ash particles within the bitumen matrix. Investigation of the rheological performance of blends of asphalt binders with different types of ash using dynamic shear rheometer confirmed the feasibility of using fly ash to improve the performance of asphalt
New Alumosilicate Fillers Based on Sedimentary Rocks for Asphalt Concrete
Asphalt concrete is the most common material for highway and motorway construction. The quality of asphalt is determined, to a large extent, by properties of asphalt binder. Fillers, which are mineral powders from carbonate rocks and aggregates fines, such as limestone and dolomite, are often used in the composition of bitumen mastics affecting the performance of asphalt. This article explores the feasibility of using the fines of aluminosilicate sedimentary rocks as fillers. These materials are composed of clay minerals, which change their properties upon the contact with water. Normally, the use of such fillers is restricted because of poor water resistance and swelling of asphalt concrete. In order to improve the performance of these fillers, the thermal modification at moderate temperatures of 500–600 C has been proposed. Such treatment provides sufficient structural stability of obtained materials and results in the reduction of water absorption of asphalt, improved water resistance (up to 2.5 times) and also, in reduced swelling (up to 9 times). It has been demonstrated that improvement in the filler performance can be achieved by a heat treatment. Such treatment induces changes in the mineral composition and converts the structure of clay minerals into the frame structure of zeolite, as confirmed by X-ray diffraction and infrared spectroscopy. Due to thermal treatment, there is a change in the acid-base properties of the surface of the filler, which is reflected in the profiles of the main adsorption centers. As a result, due to chemisorption, the modified aluminosilicate fillers are able to interact with bitumen. The application of new filler materials in asphalt concrete enables to enhance the performance.
A preliminary account of a new tyrannosauroid theropod from the Wessex Formation (Early Cretaceous) of southern England
Abstract A new genus and species of coelurosaurian theropod dinosaur from the Wessex Formation (Early Cretaceous, Barremian) of the Isle of Wight, England, is described and named. Distinctive characters of the premaxilla, its dentition, maxilla and nasals allow it to be diagnosed. The teeth in the premaxilla are D-shaped in cross-section and the nasals are fused. The hands are elongate and slender and the hindlimbs are gracile. Lack of element fusion elsewhere in the skeleton suggests that it is a subadult. Numerous character states are shared with tyrannosaurids but the new taxon appears to be excluded from the group that comprises aublysodontine and tyrannosaurine tyrannosaurids. We conclude that the taxon is a basal tyrannosauroid and as such it is one of the earliest and (with the exception of some teeth and an isolated ilium from Portugal) the first from Europe. Implications for tyrannosauroid biogeography and evolution are discussed. The animal was part of an unusual taphonomic assemblage in which some elements were partially articulated while others were scattered or broken.