Gas Source MBE Growth and Characterization of TlInGaAs/InP DH Structures for Temperature-independent Wavelength LD Application
Abstract : TlInGaAs/InP double-hetero (DH) structures were grown on (100) InP substrates by gas source MBE. The photoluminescence (PL) peak energy variation with temperature decreased with increasing Tl composition. For the DH with a Tl composition of 13%, the PL peak energy varied only slightly with temperature (-0.03 meV/K). This value corresponds to a wavelength variation of 0.04 nm/K and is much smaller than that of the lasing wavelength of InGaAsP/InP distributed feedback laser diodes (0.1 nm/K). TlInGaAs/InP light emitting diodes with 6% Tl composition were fabricated and the small temperature variation of the electroluminescence peak energy (-0.09 meV/K) was observed at the wavelength around 1.58 micrometers. The results are promising to realize the temperature-independent wavelength laser diodes, which are important in the wavelength division multiplexing (WDM) optical fiber communication systems.
Very small temperature-dependent band-gap energy in TlInGaAs/InP double heterostructures grown by gas-source molecular-beam epitaxy
TlInGaAs/InP double heterostructures (DHs) were grown on (100) InP substrates by gas-source molecular-beam epitaxy. Almost no occurrence of Tl interdiffusion at the InP/TlInGaAs heterointerface was confirmed. The photoluminescence (PL) intensity for the DH was approximately ten times stronger than that of the single heterostructure. The PL peak energy and its variation with temperature for the TlInGaAs/InP DH decreased with increasing Tl composition. For the DH with a Tl composition of 13%, the PL peak energy varied only slightly with temperature (0.03 meV/K). This value corresponds to a wavelength variation of 0.04 nm/K and is much smaller than that of the lasing wavelength of InGaAsP/InP distributed feedback laser diodes (0.1 nm/K).
Numerical and experimental investigation on air distributor design of fluidized bed reactor of sawdust pyrolysis
Abstract An improved biomass conversion in a lab-scale fluidized bed reactor (FBR) is achieved by optimizing the air distributor orifice size and number. Two approaches for introducing air were numerically and experimentally examined. These included perforated plate and downward orifice sparger. 3 mm and 5 mm orifice diameters, and 7, 9 and 13 holes were simulated at flow velocities of 2, 4, 6, and 8 times the minimum fluidization velocity, Umf. The simulation results revealed that increasing the orifice number has a positive effect on gas holdup, particularly for the perforated plate, which showed a uniform distribution of bubbles. The sparger configuration produced larger bubbles sizes, which could lead to better recirculation of solid flux, while stagnant particle zones were observed at the lower section of both distributors. A pyrolysis unit is also inserted at the top of freeboard of the FBR. For perforated plate with 6Umf, the pyrolysis process achieved thermal and cold gas efficiencies of 82.91% and 52.03%, respectively, while combustible gases with 41.6%mol CO, 8.7%mol CH 4 and 2.17%mol HC, were obtained. For sparger pipe and 6U mf _sp, 35.33 ppm NOx and 111 ppm SO 2 were measured in flue gas from combustion process at bed region.