A Coupled Thermal–Hydrological–Mechanical Damage Model and Its Numerical Simulations of Damage Evolution in APSE
This paper proposes a coupled thermal–hydrological–mechanical damage (THMD) model for the failure process of rock, in which coupling effects such as thermally induced rock deformation, water flow-induced thermal convection, and rock deformation-induced water flow are considered. The damage is considered to be the key factor that controls the THM coupling process and the heterogeneity of rock is characterized by the Weibull distribution. Next, numerical simulations on excavation-induced damage zones in Äspö pillar stability experiments (APSE) are carried out and the impact of in situ stress conditions on damage zone distribution is analysed. Then, further numerical simulations of damage evolution at the heating stage in APSE are carried out. The impacts of in situ stress state, swelling pressure and water pressure on damage evolution at the heating stage are simulated and analysed, respectively. The simulation results indicate that (1) the v-shaped notch at the sidewall of the pillar is predominantly controlled by the in situ stress trends and magnitude; (2) at the heating stage, the existence of confining pressure can suppress the occurrence of damage, including shear damage and tensile damage; and (3) the presence of water flow and water pressure can promote the occurrence of damage, especially shear damage.
Feasibility of Using Modified Silty Clay and Extruded Polystyrene (XPS) Board as the Subgrade Thermal Insulation Layer in a Seasonally Frozen Region, Northeast China
To achieve the purposes of storing industry solid wastes and enhancing subgrade stability in seasonally frozen regions, Structure III, which utilized the modified silty clay (SC) and extruded polystyrene (XPS) board as a novel subgrade thermal insulation layer (NSTIL), was presented. The above modified SC consisted of oil shale industry solid waste, fly ash and SC. In terms of environmental impact, the average single pollution index, the Nemerow integrated pollution index and national standards were carried out to estimate whether the modified SC could be used as a subgrade filler. These results show that, although the modified SC will produce pollution to the environmental background, the concentration of each hydrochemical constituent from the modified SC meets the corresponding national standards in China. In terms of the thermal insulation capability, the numerical simulation of coupling moisture and temperature was applied to analyze that of Structures I, II and III. The research results show that the numerical results of the Structure I are approximated to the official website information of Jilin province, indicating that the above numerical simulation is effective for coupling moisture and temperature of frozen soil. Both modified SC and NSTIL have the advantage of good thermal insulation property, but the thermal insulation property of the NSTIL is greater. Furthermore, the NSTIL at the top of the Structure III can protect the SC of the experimental road from the damage of frost heave. The research results are of great significance for reducing environmental pollution caused by oil shale industry solid waste and fly ash, increasing the utilization rate of industrial waste and enhancing the subgrade stability in seasonally frozen regions.
Synthesis of 2,4-dideoxy-.beta.-D-erythro-hexopyranosyl nucleosides
The synthesis of 1-(2,4-dideoxy-β-D-erythro-hexopyranosyl)thymine (12) 1 was accomplished using two different synthetic routes. It was obtained starting either from 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose or from tri-O-acetyl-D-glucal. The other modified nucleosides, with either a cytosine, guanine, or adenine moiety, were synthesized using the second reaction scheme. Deoxygenation reactions were accomplished with the (2,4-dichlorophenoxy)thiocarbonyl derivatives generated in situ