Effects of Formulated Glyphosate and Adjuvant Tank Mixes on Atomization from Aerial Application Flat Fan Nozzles
Abstract : This study was designed to determine if the present USDAARS spray-nozzle models, which were based on spray solutions of water plus non-ionic surfactant, could be used to estimate spray droplet-size data for different spray formulations through use of experimentally determined correction factors. Twelve spray-solution treatments were evaluated, ten of which contained a formulated glyphosate product and nine of these contained an additional tank-mix adjuvant. Droplet-size testing was conducted across multiple operational points (nozzle-orifice size, nozzle orientation spray pressure, and airspeed), in a high-speed wind tunnel, which corresponds to the response surface experimental model used to develop the present spray-nozzle models. The hypothesis that the different treatment solutions would respond linearly across a range of operational parameters and that a correction factor from relative to water plus non-ionic surfactant solution was proven false. When compared to water or the water plus non-ionic surfactant, the changes in atomization across the operation spectrum of the nozzle were not consistent and varied by formulation. Attempts to apply regression fits for a correction factor based on solution physical properties were not successful. With the formulated glyphosate tank mix used, none of the adjuvants tested, except the polymer, showed significant changes in droplet size under the high air shear regime. Whereas there is likely a need to develop formulated product-specific atomization models, the further addition of adjuvants do not significantly change the atomization characteristics and, as such, should not require a unique spray-nozzle model.
Influence of Airspeed and Adjuvants on Droplet Size Distribution in Aerial Applications of Glyphosate
Drift is one of the most hazardous consequences of an improper aerial application of glyphosate. Wind, droplet size, application height, and distance to sensitive areas are the most important factors for drift. Droplet size is affected by nozzle, operating pressure, flight speed, deflection angle, and physicochemical properties of the spray solution. The objective of this study was to evaluate the effect of flight speed and the use of adjuvants on droplet size spectra in aerial applications of glyphosate. The study was conducted in a high-speed wind tunnel at the Pesticide Application Technology Laboratory (University of Nebraska-Lincoln, West Central Research and Extension Center, North Platte, Neb.). Aerial applications were simulated with four different airspeeds (44.4, 52.8, 61.1, and 69.4 m/s) and glyphosate combined with adjuvants (high surfactant oil concentrate, microemulsion drift reduction agent, nonionic and acidifier surfactant, polyvinyl polymer, and glyphosate alone). Droplet size spectra were evaluated using a Sympatec Helos laser diffraction instrument measuring 90 cm from the nozzle tip (CP11-4015). The volumetric droplet size distribution parameters (VMD, DV0.1, and DV0.9) and the percentage of droplets smaller than 100 µm were reported. The relative span was calculated to indicate the droplet size homogeneity [(DV0.9 - DV0.1) / DV0.5]. Glyphosate solutions with adjuvants had a larger VMD than the glyphosate alone solution at 44.4 m/s wind speed. At 69.4 m/s only the glyphosate solution with polymer had a larger VMD. Conversely, the glyphosate with polymer had the smallest DV0.1, and the greatest relative span and percentage of droplets smaller than 100 µm. Generally, adjuvants influence on droplet size was diminished or muted as the airspeed was increased. The polymer tested in this study failed as a drift agent reduction agent, especially at higher airspeeds. While not all polymers were tested, cautions should be taken if using these types of adjuvants in aerial applications. The interaction of airspeed and adjuvants influencing droplet size distribution in aerial applications of glyphosate should be considered by applicators in order to mitigate glyphosate drift to the surrounding environment. Further studies are necessary to better understand the interaction between solution viscosity and air shear effect on the atomization process and droplet size distribution, as well as confirm that trends hold true for other adjuvants in the polymer class. Although applicators tend to operate aircrafts with increased flight speeds in order to optimize the application time efficiency, this practice can reduce or mute adjuvants effects, decrease the droplet size distribution, and increase drift potential in aerial applications of glyphosate.
High‐precision U‐Pb zircon age calibration of the global Carboniferous time scale and Milankovitch band cyclicity in the Donets Basin, eastern Ukraine
High‐precision ID‐TIMS U‐Pb zircon ages for 12 interstratified tuffs and tonsteins are used to radiometrically calibrate the detailed lithostratigraphic, cyclostratigraphic, and biostratigraphic framework of the Carboniferous Donets Basin of eastern Europe. Chemical abrasion of zircons, use of the internationally calibrated EARTHTIME mixed U‐Pb isotope dilution tracer, and improved mass spectrometry guided by detailed error analysis have resulted in an age resolution of <0.05%, or ∼100 ka, for these Carboniferous volcanics. This precision allows the resolution of time in the Milankovitch band and confirms the long‐standing hypothesis that individual high‐frequency Pennsylvanian cyclothems and bundles of cyclothems into fourth‐order sequences are the eustatic response to orbital eccentricity (∼100 and 400 ka) forcing. Tuning of the fourth‐order sequences in the Donets Basin to the long‐period eccentricity cycle results in a continuous age model for the Middle to Late Pennsylvanian (Moscovian‐Kasimovian‐Ghzelian) strata of the basin and their record of biological and climatic changes through the latter portion of the late Paleozoic Ice Age. Detailed fusulinid and conodont zonations allow the export of this age model to sections throughout Euramerica. Additional ages for Mississippian strata provide among the first robust radiometric calibration points within this subperiod and result in variable lowering of the base ages of its constituent stages compared to recent global time scale compilations.