Vapor-Phase Thermal Conductivity of Binary Mixtures of Cyclopentane and R134a with R365mfc
The thermal conductivity of mixtures of R365mfc (1,1,1,3,3-pentafluorobutane), with R134a (1,1,1,2-tetrafluoroethane) and cyclopentane were measured using a transient hot-wire method, in the pressure range between 0.1013 and 0.7 MPa and temperatures between 311 and 413 K. The composition of the measured mixtures was 93.0% R365mfc + 7.0% R134a (kg/kg), 27.0% R365mfc + 73.0% R134a (kg/kg) and 62.8% R365mfc + 37.2% Cyclopentane (kg/kg). The Wassiljewa mixing rules modified by Mason and Saxena and the Extended Corresponding States Theory were used to correlate and to predict the experimental results obtained, with an average absolute deviation of 1.8 and 10%, respectively.
Experimental Determination of the Vapor Phase Thermal Conductivity of Blowing Agents for Polyurethane Rigid Foam
Blowing agents are mainly responsible for the insulation properties of polyurethane rigid foams. Detailed knowledge about the vapor conductivity of blowing agents and their mixtures is essential for their basic understanding. In addition to their insulation properties, blowing agents to a large extent determine the mechanical properties of the foam. Today, blowing agent mixtures are often used in an attempt to combine both worlds, low thermal conductivity and high vapor pressure at low temperatures. Our investigations aim at a better understanding of the relevant practical properties of blowing agents and their mixtures and to focus on their meaning for actual and potential foam systems of interest to the rigid foam insulation market. A newly developed transient hot wire method was used to determine the vapor phase thermal conductivity of various blowing agents used in rigid polyurethane foam. Data for CFC-11, HCFC-141b, HFC-365mfc, HFC-356mffm, HFC-245fa, HFC-245ca, cyclopentane, isopentane, n-pentane, isobutane, n-butane, and carbon dioxide have been generated. In addition to measurements of the pure compounds, current market mixtures of cyclopentane with low boiling hydrocarbons have been investigated. Experiments have been performed at pressures between 0.2 MPa and 1.5 MPa and temperatures between 298 K and 421 K.
Effects of the mineral phase and valence of vanadium on vanadium extraction from stone coal
The influence of roasting on the leaching rate and valence of vanadium was evaluated during vanadium extraction from stone coal. Vanadium in stone coal is hard to be leached and the leaching rate is less than 10% when the raw ore is leached by 4 mol/L H2SO4 at 90°C for 2 h. After the sample is roasted at 900°C for 2 h, the leaching rate of vanadium reaches the maximum, and more than 70% of vanadium can be leached. The crystal of vanadium-bearing mica minerals decomposes and the content of V(V) increases with the rise of roasting temperature from 600 to 900°C, therefore the leaching rate of vanadium increases significantly with the decomposition of the mica minerals. Some new phases, anorthite for example, form when the roasting temperature reaches 1000°C. A part of vanadium may be enwrapped in the sintered materials and newly formed phases, which may impede the oxidation of low valent vanadium and make the leaching rate of vanadium drop dramatically. The leaching rate of vanadium is not only determined by the valence state of vanadium but also controlled by the decomposition of vanadium-bearing minerals and the existence state of vanadium to a large extent.