Dielectric response and breakdown strength improvement of LDPE/TiO2 nanocomposites by using POSS as compatibilizing agent
In this paper, two types of nanocomposites were prepared by ball milling techniquee The first type consists of 5% untreated titanium dioxide (TiO2) incorporated into LDPE. For the second one, 5% commercial TiO2 chemically treated with trisilanol phenyl polyhedral oligomeric silsesquioxane (TSP-POSS) as dispersant was ball-milled with LDPE. The microscopic observation by Atomic Force Microscopy (AFM) showed a better dispersion into polymer matrix of the TiO2 treated with POSS as compared to untreated TiO2. It was found that LDPE/treated TiO2 nanocomposite exhibited lower relative permittivity and dielectric losses compared to LDPE/untreated TiO2. The surface treatment of LDPE/TiO2 by TSP-POSS also affects the dielectric strength. The LDPE/treated TiO2 revealed highest breakdown strength of 82 kV/mm, compared to 78 kV/mm and 71 kV/mm of LDPE neat and LDPE/untreated TiO2, respectively.
Dielectric properties of epoxy/alumina nanocomposite influenced by control of micrometric agglomerates
Introduction of metal oxide nanoparticles to polymer material is known to have unique dielectric behavior and significant advantages in electrical insulation performance in power apparatus. This paper presents an attempt to clarify the influence of dispersibility of nanoparticles, especially focusing on agglomerates, on dielectric properties of a nanocomposite system by changing particle dispersion processes. Experiments were carried out in epoxy/alumina nanocomposites with the particle dispersion techniques by applying ultrasonic wave and centrifugal force. For the dispersibility control of nanoparticles, we changed the duration of ultrasonic wave and centrifugal force. The experimental results clarified the effect of centrifugal force on the separation of agglomerates and the effect of ultrasonic wave on the disruption of agglomerates. Next, we examined the dielectric properties such as relative permittivity and tan δ of the nanocomposites. As the result, we verified that the permittivity of epoxy/alumina nanocomposites became low due to separation and disruption effects of the agglomerates.
Finite Difference Modeling on the Temperature Field of Substrate in Friction Surfacing
Friction surfacing is an advanced process of great potential, especially in the field of repair and reclamation of worn and damaged components. As a kind of thermal processing technology, the temperature profile and changes of the substrate in friction surfacing are important factors to get coatings of high quality. In this paper, the temperature field of the substrate during the process is simulated by finite difference method. The results are consistent with experiments, reappearing the temperature change of the substrate during friction surfacing, allowing further study on figuration and quality of coatings.