Adaptive photo-EMF detectors based on CdTe and their solid solutions
The complex measurements of V(Ti)-doped CdTe (crystals and films) and their solid solutions were carried out. This allowed to establish the nature and energy structure of the intrinsic defects and impurity centers and to propose the micromechsnism of photo-EMF effect. The adaptive photodetectors based on these crystals and CdTe polycrystalline films were developed.
Optical and Photoelectric Properties
Investigations of the optical and photoelectric properties of semiconductors are among the most important sources of information on the band structure, the frequencies of the optical modes of the phonon spectrum, the permittivity, the recombination parameters, and other properties of semiconductors. It is also essential to know the optical and photoelectric properties of lead chalcogenides for the applications of these materials in semiconductor electronics.
Effects of the mineral phase and valence of vanadium on vanadium extraction from stone coal
The influence of roasting on the leaching rate and valence of vanadium was evaluated during vanadium extraction from stone coal. Vanadium in stone coal is hard to be leached and the leaching rate is less than 10% when the raw ore is leached by 4 mol/L H2SO4 at 90°C for 2 h. After the sample is roasted at 900°C for 2 h, the leaching rate of vanadium reaches the maximum, and more than 70% of vanadium can be leached. The crystal of vanadium-bearing mica minerals decomposes and the content of V(V) increases with the rise of roasting temperature from 600 to 900°C, therefore the leaching rate of vanadium increases significantly with the decomposition of the mica minerals. Some new phases, anorthite for example, form when the roasting temperature reaches 1000°C. A part of vanadium may be enwrapped in the sintered materials and newly formed phases, which may impede the oxidation of low valent vanadium and make the leaching rate of vanadium drop dramatically. The leaching rate of vanadium is not only determined by the valence state of vanadium but also controlled by the decomposition of vanadium-bearing minerals and the existence state of vanadium to a large extent.