Sensing Characteristics to Acid Vapors of a TPPS Coated Fiber Optic: A Preliminary Analysis
In this work we report on preliminary analysis of a novel optoelectronic gas sensor based on an optical fiber integrated with a tetrakis(4-sulfonatophenyl)porphyrin (TPPS) thin film. The sensitive materials are selectively deposited on the core region of a fiber tip by UV light induced deposition technique. A simple and cheap process which can be easily extended to different porphyrin derivatives. When the TPPS film on the fiber tip is exposed to acid and/or base vapors, dramatic changes occur in the aggregation structure of the dye molecules in the film, from Jto H-type, resulting in a profound modification of their corresponding reflectance spectra. From the achieved experimental results it is evident that the presence of intense and narrow band peaks in the reflected spectra could be monitored to detect hazardous vapors. Keywords—Optical fiber sensor, Porphyrins, Thin films UVinduced deposition, TPPS.
Evaluation of optical fiber microcell reactor for use in remote acid sensing.
An optical fiber acid-sensor based on protonation of a porphyrin solution within a single-hole structured optical fiber is proposed and demonstrated. The liquid-core fiber acts as a microcell reactor, and changes in the spectral signature with acidification are detected. Challenges and limitations in the practical deployment of such sensors are evaluated. An effective chemical sensor is demonstrated, but issues such as diffusion limit its full utilization. Some solutions are discussed.
The Invariance of the Vacuum is the Invariance of the World
The following theorem is demonstrated: If the vacuum is invariant under the group generated by the space integral of the time component of a local vector current, then the Hamiltonian is invariant also. A similar theorem holds for the group generated by the space integral of a space component of a local axial-vector current.