Continuous Sorbent Reactions in a High-Temperature Fabric Filter Following Convective Pass Ca(OH)2 Injection for SO2 Removal.
A specially designed two-stage reactor was used to study solid sorbent reactions in the filtration stage of a high-temperature fabric which follow convective pass Ca(OH)2 injection. Solid conversions during the progress of the sorbent reactions were thoroughly analyzed. It was found that, unlike the sorbent reactions in the injection stage, which proceed extremely fast with strong carbonation under high temperatures, the subsequent sorbent reactions in the filtration stage are much slower and residual sorbent is mainly utilized in removing sulfur dioxide (SO2). Two major reaction pathways are discovered in the filtration stage. The first route is through the decomposition of residual calcium hydroxide (Ca(OH)2), which is critical in inducing further sorbent reactions when there is sufficient residual sorbent. The second route is the sulfation of the carbonation product, calcium carbonate (CaCO3), which may become the principal reaction to remove SO2 after the residual sorbent is consumed. The con-vective pass and the fabric filter are found to be equally important reaction sites in the combined process of convec-tive pass sorbent injection with high-temperature filtration. The overall SO2 removal efficiency of the system is affected by both the sorbent injection and filtration conditions.
CO 2 reaction with Ca(OH) 2 during SO 2 removal with convective pass sorbent injection and high temperature filtration
The Kyoto Protocol calls for greenhouse gas emission reductions which could affect the use of coal for producing electricity. Carbon credits are being explored as a method for countries to meet their reduction commitments. Carbon dioxide removal in flue gas desulfurization (FGD) systems should be considered if and when the concept of carbon credits are implemented. This paper addresses the factors affecting sulfur dioxide removal, including the reaction of carbon dioxide, occurring during convective pass sorbent injection with high temperature filtration for a typical coal-fired power plant. Significant carbonation is found to occur, and the levels are found to depend on injection/filtration temperatures and the residence time on the filter. Ca/S stoichiometry during sorbent injection is found to affect not only the sorbent conversions in the convective pass sorbent injection stage but also the final sorbent conversions in the filtration stage. Even though high sorbent carbonation hinders the sorbent utilization for SO2 removal, slight alterations in CO2 concentration are found to have no significant effects on the SO2 removal of the process.
A bifunctional Cr/Yb/Tm:Ca3Ga2Ge3O12 phosphor with near-infrared long-lasting phosphorescence and upconversion luminescence.
Currently, upconversion nanocrystals and long-lasting phosphorescent particles have attracted extensive research interest for their possible applications as bioimaging probes. However, there are few reports concerning the achievement of both upconversion luminescence of lanthanide ions and long-lasting phosphorescence of transition metal ions in a sole host so far. Herein, we demonstrate a novel calcium gallium germanium garnet (Ca3Ga2Ge3O12) host where lanthanide ions such as Tm(3+)/Yb(3+) and transition metal ions such as Cr(3+) can be easily incorporated through substituting the Ca(2+) and Ga(3+) respectively. This Cr/Yb/Tm:Ca3Ga2Ge3O12 phosphor exhibits both broadband near-infrared long-lasting phosphorescence of Cr(3+) with an afterglow time of more than 7000 s and near-infrared to near-infrared upconversion luminescence of Tm(3+). Impressively, it is evidenced that the addition of Yb(3+)/Tm(3+) into Cr:Ca3Ga2Ge3O12 not only results in Tm(3+) upconversion luminescence but also greatly increases Cr(3+) afterglow time. Based on excitation/emission, three-dimensional thermoluminescence, and time-resolved luminescence spectra, the related long-lasting phosphorescence and upconversion luminescent mechanisms are systematically discussed as well.