Phase Transitions in the Brominated Ferroelectric Tris‐Sarcosine Calcium Chloride
paraelectrics SrTiO 3 and KTaO 3 . [ 9 ] However, the ultra-weak nature of the dipole moment in TSCC referred to below may reduce the effects of such long-range dipole interactions to a narrow temperature region around the critical point. This would mean that more conventional classical or quantum critical behaviour would be expected over a wider range of temperatures and tuning parameters. TSCC is hydrogen bonded and was characterized in the past as order-disorder albeit with no direct supporting evidence. [ 16,17 ] Since the time of these studies TSCC has come to be a prototypical displacive ferroelectrics, [ 18 ] as demonstrated by the existence of an under-damped soft mode. This mode can be followed into the GHz frequency regime [ 19 ] from highT values of ca 630 GHz = 21 cm −1 . Deuteration [ 20 ] produces little change in T C , implying that the transition is not controlled by the N-Cl-hydrogen bonds, a result compatible with the soft-mode mechanism operating in TSCC. [ 2 ]
Quantum criticality in a uniaxial organic ferroelectric
Tris-sarcosine calcium chloride (TSCC) is a highly uniaxial ferroelectric with a Curie temperature of approximately 130 K. By suppressing ferroelectricity with bromine substitution on the chlorine sites, pure single crystals were tuned through a ferroelectric quantum phase transition. The resulting quantum critical regime was investigated in detail and was found to persist up to temperatures of at least 30–40 K. The nature of long-range dipole interactions in uniaxial materials, which lead to non-analytical terms in the free-energy expansion in the polarization, predict a dielectric susceptibility varying as 1/T3close to the quantum critical point. Rather than this, we find that the dielectric susceptibility varies as 1/T2 as expected and observed in better known multi-axial systems. We explain this result by identifying the ultra-weak nature of the dipole moments in the TSCC family of crystals. Interestingly, we observe a shallow minimum in the inverse dielectric function at low temperatures close to the quantum critical point in paraelectric samples that may be attributed to the coupling of quantum polarization and strain fields. Finally, we present results of the heat capacity and electro-caloric effect and explain how the time dependence of the polarization in ferroelectrics and paraelectrics should be considered when making quantitative estimates of temperature changes induced by applied electric fields.
Simulation study of high power microwave generation by virtual cathode oscillation in coaxial vircator
Summary form only given, as follows. We have numerically simulated the high power microwave generation by virtual cathode oscillation in a coaxial vircator with 3 dimensional PIC code Magic. It is noted that the coaxial vircator has the advantage of an enhancement of power efficiency and gaining of narrow bandwidth frequency. The study is focused on the design of a diode structure for a coaxial vircator suitable for Chundoong IREB pulser (Max. 600 kV, 85 kA, 60 ns). It consists of a center annular cathode, a cylindrical meshed-anode and a reflector. The simulation results showed that the coaxial vircator can indeed be operated at the selected frequency with the narrow bandwidth and the microwave output power strongly depends on the position and geometry of the reflector. From this simulation results we expect that the maximum microwave output power will be obtained by the reflector of 4 cm in width and also 4 cm in distance away from the IREB, where the resonant frequency of microwave from coaxial vircator is simulated to be 6.577 GHz.