Understanding polymer degradation under voltage stress in PV applications
AC Partial Discharge (PD) specification has been a key design parameter for PV backsheets, as called for in IEC 61730-1. In previous work, we have studied how the structure of polymeric materials can impact their behavior in this test. In this paper, we shift the focus to consideration of potential root causes which can lead to electrical degradation in actual usage (e.g. a PV module producing DC power), and the efficacy of the AC partial discharge test in air and oil to identify these. The suitability of utilizing AC voltage stresses in PV is also challenged in this paper. New experimental evidence is presented as to why testing partial discharge with AC with specimens immersed in the medium is not suitable for testing of solar backsheet materials. PD measurements can be very different for tests performed in air versus oil, and can lead to different pass/fail conclusions for the same material. When tested in oil, materials with voids had a much lower Ve than materials with no voids; in air, there was no difference in Ve for a material prepared with and without voids. With regard to AC versus DC testing the time to breakdown versus voltage was measured for both; these are not linearly related: the AC and DC breakdown voltages for one material study were 25 kV(AC) and 85 kV (DC), more than 3× difference; the voltages which led to breakdown after 10000 seconds were 5 kV(AC) and 50 kV (DC), a 10× difference. The issues raised in this study are active areas of discussion for the TC 82 WG2 Standards Committee.
Study of Partial Discharge effects of PV backsheet component films. Structure property relationships, and measurement consistency
Partial Discharge is one of a number of tests defined in IEC61730–2, which specifies properties of photovoltaic modules and components for safe electrical and mechanical operation during their expected lifetime. The test is of practical importance in the development and manufacturing of backsheet barrier films because of the limitations it places on film thickness. The objective of this study was to understand the relationship of this test to film properties. Although simple to describe, in practice, the test is difficult to perform with consistency. We have found that this test performed in air usually provides consistent relative behavior, but that absolute values can vary on different days, or in different laboratories. We have tested several materials with varied thickness, and found a linear relationship between Ve and square root of film thickness when measured in air, in line with a surface discharge phenomenon. This paper will describe efforts to define and understand sources of variability in both inter and intra laboratory measurements, and on the measurements of some typical component materials of PV backsheets.
Shape and surface texture of molten droplets deposited on cold surfaces
When a molten droplet impacts on a cold surface, the interaction between solidification and fluid dynamics can lead to different shapes and surface textures of deposited droplets. This article presents an experimental study on deposition of small droplets (39 μm diameter) of molten wax ink on solid surfaces. Our results show that both the final shape and the surface texture of deposited droplets are extremely sensitive to deposition conditions, which include initial temperature of droplets, type of substrate surface and distance between substrate and printhead. Different surface textures are observed and shown to depend on the thermal and flow histories of ink droplets during the process of impact. A test using crystalline wax reveals crystallization as one of the major factors in determining the final texture.