Strengths of Sapphire Crystals
THE strength of single crystals of entirely brittle materials should depend on the presence of stress raising flaws. Internally these could be formed by static dislocation arrays, voids or inclusions of foreign material. On the surface the flaws could be formed by mechanical damage or by surface steps as suggested by Marsh1.
Strengthening Sapphire by Compressive Surface Layers
Compressive surface layers were formed on sapphire rods. The methods included glazing and quenching, formation of Al2O3–Cr2O3 solid solution surface layers, and formation of mullite and calcium aluminate surface layers. The presence of the compressive stresses was demonstrated by slotted rod tests. Substantial improvements in flexural strength and thermal shock resistance were observed. The highest average flexural strength was obtained by glazing and quenching and was 340 000 psi. The strengths were measured in the ``as‐treated'' and ``as‐treated and abraded'' conditions. The abraded samples retain a substantial portion of the improved strength.
Evolution of carbide precipitates in Hastelloy N joints during welding and post weld heat treatment
Abstract The effects of welding and post weld heat treatment (PWHT) on the morphology, composition and lattice parameter of the precipitates in the welding joints of Hastelloy N alloy have been investigated. Joint samples were prepared using a gas tungsten arc welding process with ERNiMo-2 fillers, and then solid-solution treated at 1100 °C for 20 min. After welding, eutectic M6C carbides can be observed in the heat affected zones (HAZ) and weld zones (WZ). These eutectic M6C carbides become spheroidized during the following PWHT. The concentration of Si decreases during the transformation from the primary ones to eutectic ones, and then increases during the spheroidizing process. The total concentration of Si + Cr in M6C carbides remains stable during welding and PWHT. At the same time, the heat leads to the outward diffusion of Mo from the M6C carbides, which results in a decrease of the lattice parameter.