Devdopment of the Monolith Froth Reactor for Catalytic Wet Oxidation of CELSS Mo_
The aqueous phase oxidation of acetic acid, used as a model compound for the treatment of CELSS (Controlled Ecological Life Support System) waste, was carried out in the monolith froth reactor which utilizes two-phase flow in the monolith channels. The catalytic oxidation of acetic acid was carried out over a Pt/AI.,O_ catalyst, prepared at The University of Tulsa, at temperatures and pressures below the critical point of water. The effect of ex'temally controllable parameters (temperature, liquid flow rate, distributor plate orifice size, pitch, and catalyst distance from the distributor plate) on the rate of acetic acid oxidation was investigated. Results indicate reaction rate increased with increasing temperature and exhibited a maximum with respect to liquid flow rate. The apparent activation energy calculated from reaction rate data ,,,,,as 99.7 kJ/mol. This value is similar to values reported for the oxidation of acetic acid in other systems and is comparable to intrinsic values calculated for oxidation reactions. The "kinetic data were modeled using simple power law kinetics.
Wet oxidation for industrial waste treatment
For those wastes that are not biotreatable, wet oxidation is an economically attractive method of treatment in reducing oxygen demand and altering the biotreatability. Further, when biological treatment changes are based on COD, the cost of wet oxidation is not much greater than typical municpal industrial changes.
Research on velocity distribution in semi-dry flue gas desulfurization tower
As an accurate high-quality instantaneous measurement technology, particle image velocimetry (PIV in acronym) has applied widely in single-phase flow and multiphase flow. The velocity distribution in semi-dry FGD tower directly influences gas-solid mix and contact situation. In base of the tower, gas-solid two-phase flow field is more complex, and has the quite tremendous influence to the overall system desulphurization efficiency. This paper utilized PIV to study velocity distribution in Semi-dry flue gas desulfurization tower and obtained velocity distribution.