High Temperature Corrosive Environment in a Sintering Plant for Pig Iron Production and Its Effect on Different Steel Grades
The harsh environment in a sintering plant for pig iron production leads to high temperature corrosion of the sinter grates. In the present study, a detailed analysis of the corrosives in such applications is given to understand materials failure. Various steels are tested, revealing effects of various alloying concepts, the resulting phases and their corrosive behavior in this complex corrosive environment at ≈900 °C. In order to understand the underlying corrosion mechanisms, detailed analyses are performed. Results indicate mainly chlorine, sulfur, and oxidation based corrosive decay at elevated temperature and a high relevance of protecting alloying elements within the steels.
High temperature corrosion studies of cermet particle reinforced NiCrBSi hardfacings
Abstract Metal matrix composite hardfacings provide various types of heat and wear resistant products. They are widely used in high temperature aggressive environments due to their excellent high temperature corrosion and wear resistance. In this study, Cr3C2–Ni and TiC–NiMo particles were used to reinforce a NiCrBSi matrix in plasma transferred arc welding process. These cermet particle reinforced hardfacings were examined on their oxidation behaviour and high temperature corrosion in different solid salts to optimise the field of application under high temperature conditions. Corrosion behaviour in solid salts is strongly dependent on the corroding anion. Cr3C2–Ni reinforced hardfacings behave better in oxidative and sulphate/phosphate environment, while TiC–NiMo hardfacings show better resistance against chlorine and carbonate ions up to 700 °C. Additionally, oxidation is no critical exposure for these types of hardfacings.
Submicron polymer structures with X-ray lithography and hot embossing
This article describes the process chain for replication of submicron structures with varying aspect ratios (AR) up to 6 in polymethylmethacrylate (PMMA) by hot embossing to show the capability of the entire LIGA process to fabricate structures with these dimensions. Therefore a 4.7 μm thick layer of MicroChem 950k PMMA A11 resist was spin-coated on a 2.3 μm Ti/TiOx membrane. It was patterned with X-ray lithography at the electron storage ring ANKA (2.5 GeV and λc ≈ 0.4 nm) at a dose of 4 kJ/cm3 using a Si3N4 membrane mask with 2 μm thick gold-absorbers. The samples were developed in GG/BDG and resulted in AR of 6–14. Subsequent nickel plating at 52°C resulted in a 200 μm thick nickel tool of 100 mm diameter, which was used to replicate slit-nozzles and columns in PMMA. Closely packed submicron cavities with AR 6 in the nickel shim were filled to 60% during hot embossing.