Synchrotron X-ray study of orthorhombic Rb(3)Ta(5)O(14) with a modified pyrochlore structure.
The structure of a new orthorhombic trirubidium pentatantalum oxide (Rb(3)Ta(5)O(14)) phase with Pnma symmetry was identified from a half sphere of synchrotron X-ray data measured at a wavelength of 0.85 A. This notionally linked TaO(6) octahedral structure broadly consists of three different modifications of the pyrochlore ring motif with layer stacking normal to (205) planes. Successive pyrochlore layers do not simply stack normal to these planes but are offset along the [100] axis. An unusual aspect of this structure is the occurrence of TaO(5) trigonal bipyramids in structurally complex regions where the modified pyrochlore rings connect.
Synthesis and powder diffraction analysis of tri-rubidium penta-tantalum oxide, Rb3Ta5O14, with novel three-dimensionally nanostructured Rb-bearing channels
The powder pattern of Rb3Ta5O14 is reported here for the first time. Single crystals of Rb3Ta5O14 of 0.1–0.2 mm in size were grown using a RbCl flux at 1100 °C. The Rb3Ta5O14 powders were synthesized at 1200 °C by firing the Rb2CO3 and Ta2O5 raw materials with starting Rb/Ta ratios ranging from 0.450 to 0.800. The products with Rb/Ta ratios between 0.550 and 0.633 contained almost pure Rb3Ta5O14 with Rb/Ta ratio of 0.600, while those with Rb/Ta ratio larger than 0.677 also contained the α form of Rb4Ta6O17 with the Rb/Ta ratio of 0.677. Past studies of the synthesis and characterization of Rb4Ta6O17 should be carefully examined in the light of possible coexistence with Rb3Ta5O14, because the former structure has not been completely solved, and thus the powder pattern is inaccurate, while the presence of the latter had not been known until the present study.
Hill country sheep production. I. The influence of age, flock, and year on some components of reproduction rate in Romney and Border Leicester × Romney ewes.
Data from 7,091 straightbred Romney and Border Leicester × Romney ewes grazed at the Whatawhata Hill Country Research Station over the period 1959 to 1967 have been used to obtain estimates of flock and age-of-ewe effects on reproduction rate and its components and of year-to-year variation. The ewes were from six groups: a Romney control (RCR) flock, a Romney flock in which ewes were mated either to Romney (RER) or to Border Leicester rams (REB), and flocks of first-cross (F1), second-cross (F2), and third-cross (F3) Border Leicester × Romney ewes mated to first-cross Border Leicester × Romney rams. The ewes' ages at lambing varied from 2 to 5 years and no selection was practised. The ratio of number of lambs weaned per ewe present at lambing increased from the RCR (0.84) to the F1 (1.07), then declined with interbreeding to the F2 (0.92) and further to the F3 (0.87) ewes. Similar changes were evident for the percentage of ewes lambing, of multiple births, and of lambs surviving to weaning. Over...