Kinetic model for quartz and spinel dissolution during melting of high-level-waste glass batch
The dissolution of quartz particles and the growth and dissolution of crystalline phases during the conversion of batch to glass potentially affects both the glass melting process and product quality. Crystals of spinel exiting the cold cap to molten glass below can be troublesome during the vitrification of iron-containing high-level wastes. To estimate the distribution of quartz and spinel fractions within the cold cap, we used kinetic models that relate fractions of these phases to temperature and heating rate. Fitting the model equations to data showed that the heating rate, apart from affecting quartz and spinel behavior directly, also affects them indirectly via concurrent processes, such as the formation and motion of bubbles. Because of these indirect effects, it was necessary to allow one kinetic parameter (the pre-exponential factor) to vary with the heating rate. The resulting kinetic equations are sufficiently simple for the detailed modeling of batch-to-glass conversion as it occurs in glass melters. The estimated fractions and sizes of quartz and spinel particles as they leave the cold cap, determined in this study, will provide the source terms needed for modeling the behavior of these solid particles within the flow of molten glass in the melter.
Experimental Investigation and Mathematical Modeling of Cold Cap Behavior in High‐Level‐Waste Glass Melter
The cold cap is a layer of reacting melter feed floating on the surface of molten glass in a glass-melting furnace. The cold cap consists of two distinct portions, of which the upper allows the reaction gases to escape through open pores, whereas the lower portion traps the gases within the continuous glass-forming melt, creating foam. The temperature span over the cold cap is ~1000 K. Data needed to simulate the cold cap mathematically include the kinetics of multiple reactions, reaction enthalpies, heat capacity, density, porosity, and heat conductivity as functions of both the temperature and the rate of heating. These data were produced via crucible experiments. The mathematical model has been completed. It relates the cold cap thickness, the rate of melting, the temperature field, and cold cap structure (foaming, dissolution of quartz particles, and formation and subsequent dissolution of crystalline phases, such as spinel) to the cold cap bottom temperature, the fraction of heat flow to the upper cold cap surface, the melt foaminess, and the chemical and physical nature of melter feed materials. To verify the model, cold caps were produced in a laboratory-scale melter and their structure is currently investigated.
Preparation and performance evaluation of swine manure bio-oil modified rubber asphalt binder
Abstract In order to study the effect of the preparation process of swine manure bio-oil modified rubber asphalt binder on the rheological properties of the binder, the matrix asphalt and asphalt rubber were used as the control group, and swine manure bio-oil modified rubber asphalt binders were obtained by three preparation processes. Then the rheological properties of five binders were evaluated by rotational viscosity, DSR, MSCR and BBR tests. The results show that the addition of swine manure bio-oil to asphalt rubber is beneficial to the workability, but cause negative effect on its high temperature performance, fatigue performance and low temperature crack resistance. The preparation method of premixing bio-oil and rubber powder can reduce the degradation of high-temperature performance of asphalt rubber caused by addition of swine manure bio-oil to a certain extent. The fatigue properties of the three bio-binders are close, and the critical temperature is less than 25 °C. The process of premixing bio-oil and rubber powder will increase the creep stiffness and reduce the low-temperature performance. However, the low-temperature performance of the binder obtained by this process is still better than that of the matrix asphalt and can meet the requirements of use. Therefore, it is recommended to use the preparation process of premixing bio-oil and rubber powder to prepare swine manure bio-oil modified asphalt rubber.