EPR and Optical Absorption Studies of VO2+ Doped Trisodium Citrate Dihydrate Single Crystals
The electron paramagnetic resonance of VO2+ doped trisodium citrate dihydrate (Na3C6H5O7·2H2O) single crystals and powder has been examined at room temperature. The angular variation of the EPR spectra has shown that two different VO2+ complexes are located in different chemical environments, each environment containing two magnetically inequivalent VO2+ sites in distinct orientations occupying substitutional positions in the lattice and showing a very large angular dependence. The crystalline field around the VO2+ ion is nearly axial. The optical absorption spectrum shows three bands, centered at 24631, 16892, and 12195 cm−1. The spin Hamiltonian parameters and the molecular orbital coefficients are calculated from the EPR and optical data, and result are discussed. Keywords EPR; Trisodium Citrate; Absorption the Spectrum; Vanadyl Ion
Mixed alkali effect on borosilicate glass structure with vanadyl ion as spin probe
Mixed alkali borosilicate glasses doped with 2% vanadium oxide were synthesized by conventional melt-quench method. The Micro structure of the materials was analysed using XRD, SEM and EDX spectrum. Optical nature of glasses was studied by computing optical bandgaps with absorption spectral data. Covalent nature of glasses was estimated correlating optical bandgap energy with EPR spectral data. The metallization criterion of glasses was evaluated from the physical parameters. FTIR and Raman spectral techniques were used to identify the structural groups of the borates and silicates that are formed with addition of modifiers. Emission spectra were recorded at excitation wavelength of 350 nm and their thermal nature was also studied using TGA/DTA techniques.
Human reproduction: irrational but in most cases morally defensible
While I am inclined to agree that in most cases a choice to become pregnant and bring to birth a child is an irrational choice, unlike Professor Hayry,1 I believe that choosing to do so is far from being necessarily immoral. In fact I will argue that it is often these irrational (but morally defensible) choices which make human life the valuable commodity many of us believe it is.

Hayry argues that not only is the choice to have children always an irrational choice, but also it is necessarily an immoral choice. Thus, for Hayry “human reproduction is fundamentally immoral”.1 He claims it is important to point out to prospective parents that their urge to have children is irrational. From this, he argues, it follows that once this is accepted the use of advance technologies to assist conception should be reassessed, and furthermore, the irrationality and immorality of having children should become a legitimate part of guidance given to those expressing a wish to have children.

According to Hayry the reason it is irrational and immoral to choose to bring to birth a child is that “having a child can always realistically lead to the worse possible outcome, when the alternative is not having a child”.1 He argues that when people consider having children they are faced with the choice between deciding not to have children and thus harming or benefiting no-one (this, it is argued has a value of zero), or having children where this life may be good or bad, and thus the value of this choice can be …