COMPATIBILISERS IN WOOD-POLYETHYLENE COMPOSITES AND THERE INFLUENCE ON THE MECHANICAL PROPERTIES AND WATER ABSORPTION
In this paper the improvement of the compatibilisation between wood particles and HDPE-matrix composites was investigated. A series of methods of compatibilisation and modification of the composite were performed and compared. The objective was to find the most suitable method for industrial up scaling, based on mechanical properties obtained. The tensile test of samples was performed, before and after water absorption investigation. Water absorption of composites was studied at two different temperatures: 25°C and 50°C. The water absorption kinetics was studied and it was found that water is absorbed in composites following the kinetics described by the Fick`s diffusion theory. After absorption, an important loss of properties was observed, due to the destruction of the wood structure due to the water absorbed.
Effects of processing method and fiber size on the structure and properties of wood-plastic composites
Abstract The aim of this study was to understand the roles of processing method and fiber size on the properties of wood–plastic composites (WPC). Composites were manufactured using extrusion or injection molding (IM) and fibers of different fiber length-to-diameter (L/D) ratio. IM resulted in better mechanical properties and lower water absorption and swelling than extrusion. These differences can be explained by the structure and surface quality of the composites. Fiber L/D ratio had a beneficial effect on mechanical properties but resulted in decreased water absorption characteristics. These results allow identifying a suitable forming process and/or fiber size according to application needs. This study provides a better understanding of the relationships between processing method, fiber characteristics, and composite behavior.
An Ultrasensitive Analytical Method Based on Chemiluminescence Sensing Electrochemical Parallel Catalytic Reaction Event
An ultrasensitive electrochemiluminescence (ECL) method on the combination of electrochemical parallel catalytic reaction and chemiluminesence signal sensing was proposed for improving ECL analytical characteristics using vanadate(V) as a representative. Vanadate(V) could be electrochemically reduced to generate vanadate(II) which could be chemically oxidized by potassium periodate to regenerate vanadate(V) and give parallel catalytic wave effect. Then, the reduced product of potassium periodate could react with butyl-rhodamine B to emit a sensitive chemiluminescence signal. The chemiluminescence intensity was correlative with vanadate(V) concentration. The investigation on the electrochemical reaction rate constant (k0) confirmed that the speed of electrochemical reaction was faster than that of the subsequent chemiluminescence reaction. The possibility of the combination of electrochemical parallel catalytic reaction with chemiluminescence signal sensing was proved. The similar ECL behaviors could be observed at zirconia nanowires-Nafion modified electrode. Because of the separation and enrichment effect of the modified electrode on vanadate(V), the selectivity and sensitivity was further improved greatly. Based on these findings, a new concept on the combination of electrochemical parallel catalytic reaction and chemiluminesence signal sensing was proposed and an ultrasensitive ECL method for the determination of vanadate(V) was developed at zirconia nanowires-Nafion modified electrode. Under the optimum experimental conditions, the ECL intensity was linear with the concentration of vanadate(V) in the range of 2.0×10−12 mol/L–2.0×10−10 mol/L. The detection limit was 8.0×10−13 mol/L, which was more than 6 orders of magnitude lower than that observed by electrochemical current transduction for electrochemical parallel catalytic reaction at zirconia nanowires-Nafion modified electrode.