Effects of Co/Sm Composition on the Ordered Phase Formation in Sm-Co Thin Films Grown on Cu(111) Single-Crystal Underlayers
Sm-Co thin films were prepared on Cu(111) single-crystal underlayers by changing the Sm composition from 12 to 35 at.% and the effects of Co/Sm composition on the ordered phase formation were investigated. The epitaxial SmCo5 thin films were obtained for all samples. The SmCo5 epitaxial layer grown on Cu underlayer has two different types of domains whose orientations are rotated around film normal by 30 degrees to each other. Cu atoms substitute a part of the Co sites in the SmCo5 structure, and an alloy compound of Sm(Co,Cu) 5 phase was formed for all samples. The Sm(Co,Cu)5 phase was more Cu enriched with increasing the Sm composition. The Cu atom diffusion into Sm-Co layer plays an important role in assisting the formation of Sm(Co,Cu)5 ordered phase.
The effects of underlayers for SmCo5 thin films with perpendicular magnetic anisotropy
In this paper, the magnetic properties of thin SmCo5 film has been studied. A thin sandwich structure, Ru/Cu/Ru, is proposed as a new structure of the underlayer for SmCo5 films with perpendicular magnetic anisotropy. The first Ru layer is deposited to improve the Cu(111) orientation, and the second Ru layer is to restrict the interlayer diffusion between Cu and SmCo5. The Sm-Co films as thin as 10 nm with excellent perpendicular anisotropy have been obtained with the total sandwich underlayer as thin as 15 nm.
Heavy metal adsorption from industrial wastewater by PAMAM/TiO2 nanohybrid: Preparation, characterization and adsorption studies
Abstract This study investigates the removal of heavy metals from industrial wastewater using TiO 2 nanoparticles modified with poly-amidoamine dendrimer (PAMAM, G 4 ). The metal ions Cu 2 + , Pb 2 + , and Cd 2 + were selected as model pollutants. FTIR, SEM, BET surface area and Zeta potential measurements, and Dispersion Observing methods have been employed for characterizing the synthetic nanohybrid and these techniques indicated that the PAMAM loaded on to TiO 2 have been favorably synthesized. The effects of several parameters including initial metal ion concentration, temperature, pH solution, the nanohybrid dosage and contact time were studied. The experimental data were analyzed using equilibrium isotherm and kinetics models. The adsorption process was studied using isotherm, kinetics, and thermodynamics models. The analysis shows that the Langmuir isotherm and pseudo-second-order kinetics are appropriate models for the adsorption process. The thermodynamic parameters illustrate that the absorption is endothermic and spontaneous. The findings suggest that the nanohybrid is a good super absorbent for the removal of heavy metals from industrial effluents.