Nanopatterning in Langmuir-Blodgett monolayers of a thermoresponsive double hydrophilic block copolymer studied by atomic force microscopy.
The microphase-separation of Langmuir-Blodgett (LB) monolayers of a rhodamine B (RhB) end-labeled double hydrophilic block copolymer (DHBC), RhB-Poly(N,N-dimethylacrylamide)-b-poly(N,N-diethylacryl-amide) (RhB-PDMA(207)b-PDEA177) and the 1:1 segmental mixture of PDEA and RhB-PDMA homopolymers was followed by AFM. The DHBC LB films revealed a loose distribution of nano-aggregates with variable geometries below the lower critical solution temperature (LCST) of PDEA (32 degrees C) and low surface pressure (3 mN m(-1)). By increasing either the temperature above the LCST of PDEA or the surface pressure beyond the immersion regime of PDMA in the subphase (7 mN m(-1)) a dense nanopatterning was obtained. The absence of a corresponding regular nanopatterning in LB films of mixed homopolymers with the same composition highlights the role of the covalent bonding between PDEA and PDMA on the self-segregation of the two blocks at the air-water interface.
Surface Micelle Structures and Monolayer Compression Moduli of Double Hydrophilic Block Copolymer
At the air/water interface, amphiphilic block copolymers are well-known to form typical surface micelles composed of hydrophobic block cores and hydrophilic block coronas. However, the micelle/aggr...
To Devolve or Not To Devolve? Welfare Reform in the States
This article analyzes variation in the degree to which states have responded to the devolution of welfare at the federal level by devolving authority over welfare policy to local government. I find that to the extent that states have devolved authority to lower levels of government, they tend to be states that already had a high degree of involvement of local government in welfare provision. In states without this record of local government involvement, the devolution that has occurred has not generated greater involvement of local government, but rather responsibility has been devolved to regional entities with ties to workforce development and with a substantial degree of business involvement. As states gain increasing authority over a redistributive policy, they may begin to treat it as a subset of a larger developmental policy—workforce development.