Source of the detrital components of uraniferous conglomerates, Quirke ore zone, Elliot Lake, Ontario, Canada
Large volumes of pyritic quartz-pebble conglomerate in the Elliot Lake district of Ontario contain at least 300,000 tonnes U3O8 recoverable at a grade of 0.1% (ref. 1), with much greater tonnages available at lower recovery grades. The Quirke zone alone contains in excess of 224,000 tonnes U3O8 at ∼0.1% (refs 2–4) and is, accordingly, one of the world's largest known uranium deposits. Situated 40 km north of the North Channel of Lake Huron, 400 km north-west of Toronto, ore conglomerates occur in the Matinenda Formation, locally the basal unit of the Huronian Supergroup, and, although their age is not well constrained, they are probably close to 2,350 Myr old.5 Uraninite, the most important primary ore mineral, occurs as poorly rounded to euhedral grains 0.05–0.2 mm across within the matrix between quartz pebbles. While its chemical and morphological characteristics have led most workers to consider that the uraninite is detrital5–7, there has hitherto been no attempt to characterize its source lithology, a matter of considerable significance as regards mineral exploration. This was the aim of the present study. We have examined the mineral and fluid inclusions observed in the quartz pebbles in the conglomerate and conclude that they were derived from a pegmatitic, potassic (alaskitic) granite. We have also demonstrated that in this source lithology, pebble-sized quartz was spatially associated with radioactive minerals, by inference, uraninite. The postulated characteristics of such a source are remarkably similar in several respects to the uraniferous alaskites of the Rössing deposit in Namibia.
Radioactive quartz-pebble conglomerates from western margin of Bonai granite pluton, Sundargarh district, Orissa — A new find
Several radioactive quartz-pebble conglomerate (QPC) occurrences at the western margin of Archaean Bonai granite and overlying Iron Ore Group (IOG) rocks have recently been located over a total strike length of 8–10 km intermittently in a NE-SW to E-W trend with steep dips due north-west to north in parts of Sundargarh district of Orissa. The QPC samples have analysed up to 0.039% U3O8 and 0.035% ThO2 with high concentration of Y (74 to 518 ppm), La(<100 to 880 ppm), Cr ( 126 to 633 ppm), Zr (137 to 1250 ppm) and Pb (31 to 581 ppm). Cellulose Nitrate (CN) film studies of few QPC samples indicated adsorbed uranium over goethite and infiltrated ferruginous material (limonite), secondary uranium as encrustation and fracture filling and discrete sub-rounded grains of monazite, zircon, allanite and rare xenotime in the matrix of QPC as radioactive phases. Higher content of Th over U, elevated concentration of Y and La in QPC eliminates the possibility of its low temperature product by epigenetic processes. Poor correlation of U with elements like Pb, Y, Zr, La and Cr can be explained due to surficial leaching of uranium from QPC after its deposition as reflected by adsorbed U over iron-oxides and low U/Th ratio in QPC in the area.
Igneous Rock Associations 23. The Bushveld Complex, South Africa: New Insights and Paradigms
SUMMARYThe Bushveld Complex has continued to serve as the basis for study into the fundamental nature of petrological processes for layered intrusion formation and for oxide and sulphide hosted Platinum Group Element (PGE)–Cu–Ni ore deposits. These studies have included discoveries in terms of the physical extent of Bushveld magmatism, both laterally and internally. Lateral variations in the mafic to ultramafic Rustenburg Layered Suite of the Northern Lobe of the complex have also revealed petrologically distinctive Upper Critical Zone equivalent rocks (the so-called Flatreef) with enhanced contamination and mineralization traits that reflect a transition between Eastern and Western Lobe equivalent stratigraphy and Platreef-style complexity. Traditional magma mixing models have been re-examined in light of radiogenic isotopic evidence for crustal involvement early in the chromite precipitation or formation process, combined with evidence for associated heterogeneous fluid contents, cryptic layering profiles, and textural evidence. A wide variety of alternative ore-genesis models have been proposed as a consequence. The fundamental mechanics of magma chamber processes and the existence of the magma chamber as an entity have been called into question through various lines of evidence which have promoted the concept of progressive emplacement of the complex as a stack of not-necessarily-quite-sequentially intruded sills (with or without significant quantities of transported phenocrysts), emplaced into variably crystallized and compacted crystal-liquid mush mixtures, modified by compaction-driven late magmatic fluid (silicate and aqueous) activity. Alternatively, petrological and geochemical observations have been used to discount these interpretations in favour of more conventional cooling and gravity-driven accumulation of silicate and ore minerals in a large, liquid-dominated system.RÉSUMÉLe complexe de Bushveld a demeuré à la base d’études sur la nature fondamentale des processus pétrologiques de formation d’intrusions litées et des gîtes des éléments du groupe platine (ÉGP)-Cu-Ni hébergés dans les oxydes et les sulfures. Ces études ont comporté des découvertes sur l’étendue physique, à la fois latérale et interne, du magmatisme de Bushveld. Les variations latérales de la suite stratifiée et mafique à ultramafique Rustenburg du lobe nord du complexe ont également révélé des roches équivalentes pétrologiquement distinctes de la zone critique supérieure (le communément désigné Flatreef) avec des traits de contamination et de minéralisation accrus qui reflètent une transition entre la stratigraphie équivalente des lobes est et ouest et la complexité de type Platreef. Les modèles traditionnels de mélanges magmatiques ont été réexaminés à la lumière de preuves isotopiques radiogéniques indiquant une implication de la croûte au début du processus de précipitation ou de formation de la chromite, combinées à des preuves de contenu fluide hétérogène associé, de profils de litage cryptique et de preuves texturales. Ainsi, une grande variété de modèles alternatifs de genèse de minerai a été proposée. La mécanique fondamentale des processus de la chambre magmatique et l'existence de la chambre magmatique en tant qu'entité ont été remises en question au moyen de divers éléments de preuve qui ont mis en avant le concept de mise en place progressive du complexe sous forme d'un empilement non-nécessairement séquentiel de sills injectés (avec ou sans quantités significatives de phénocristaux transportés) mis en place dans des mélanges de bouillie cristaux/liquide à cristallisation et compaction variable, modifiés par une activité tardive de fluide magmatique (silicaté et aqueux) induite par la compaction. Alternativement, des observations pétrologiques et géochimiques ont été utilisées pour écarter ces interprétations en faveur d'un processus plus conventionnel de refroidissement et d’accumulation de minérais silicatés et minéralisés induite par la gravité dans un vaste système à dominance liquide.