Comparative analysis of complex liquids based on a multi-experimental approach.
A parallel analysis is here presented between the results gathered by the author by means of three different experimental approaches--Dielectric analysis, Thermally Stimulated Depolarization (TSD) and Differential Scanning Calorimetry (DSC)--on some multi-component complex liquids consisting of association structures of self-assembling amphiphiles as, water-in-oil microemulsions. The highly dispersed nature of these systems was evidenced with the dielectric study: a Maxwell-Wagner relaxation was found to characterize this type of systems. The structural evolution of the system, against water addition, was well described by the orientational processes induced in the liquid samples by a nearly static electric field as in the TSD method. The investigation by DSC, besides offering a basic picture of the system's thermodynamics, allowed the measure of the specific heat, at constant pressure, at the higher order percolative phase transition. The comparison between the results obtained on samples processed with identical thermal cycles, once under the action of an impressed electric field as in TSD, and, once in the absence of any impressed electric field as in DSC, did help distinguish three main concentration intervals within which structurally different systems form namely, isotropic microemulsions and two liquid crystalline structures of lyotropic type.
A cell for measuring the complex permittivity of lossy liquids at very high radio frequencies
A dielectric cell for investigating high permittivity liquids has been designed for use with a radio frequency admittance bridge. The cell has negligible self-inductance below 100 MHz and thus requires no corrections in its use. Details are given for modifying the bridge terminals when temperature control of the system is required.
Quantitative and qualitative relationship between swirl burner operatingconditions and pulverized coal flame length
Abstract Currently, there are used in power plants two types of burners to combustion the pulverized coal: jet burners and swirl burners. Most of the published works in the field of analysis of burners operating conditions are related to jet burners and are limited to initial region of the flame at the outlet of the burner. For jet burners an offset between the burner outlet and the flame beginning point could be analyzed. In the case of swirl burners with the pre-mixing diffuser chamber an offset between flame ignition point and burner outlet is usually not visible. Because already in the pre-mixing diffuser chamber of swirl burner occurs the ignition of coal-dust together with oxidant-gas cloud and thereby the formation of the flame. Therefore, the analysis of operating conditions for this types of burners requires a different approach. There is a lack of researches, in which will be analyzed changes of the flame length, that are caused by changes of design and operating parameters of swirl burner with the pre-mixing diffuser chamber. Therefore the aim of this study was to implement and verify the methodology for estimating the flame length, which will allow monitoring changes of operating conditions, that are caused by changes of design and operating parameters of swirl burner with the pre-mixing diffuser chamber. To carry out the analysis of the image of the coal flame, the two algorithms have been presented. This two algorithms, being based on the video images of the coal flame allows to specify and detect the end point of the flame and on that basis the length of the flame, as well as the fluctuation changes of flame length can be later determined. Both, the change thermal loads of coal burner, streams of secondary air, as well as the constructional change of the angle of swirler assemblies, resulted in distinct changes in the length of the pulverized coal flame.