Trends in the Development of Machinery and Associated Technology ” TMT 2010 , Mediterranean Cruise , 11-18 September 2010 ANNEAL HARDENING EFFECT IN SINTERED COPPER ALLOYS DEPENDENCE ON ALLOYING ELEMENTS AND DEFORMATION
This paper reports results of investigation carried out on sintered copper alloys: Cu-8at%Ni, Cu8at %Zn, Cu-8at%Al, Cu-8at%Ag, Cu-4at%Ni-4at%Sn, Cu-4at%Ni-4at%Zn and Cu-4at%Au. For comparison, investigation carried out on the sintered copper. The sintered alloys, as well as pure copper, were subjected to the same thermomechanical treatment. Thermomechanical treatment included cold rolling of 30,50 and 70% in reduction. Isochronal and isothermal annealing up to the recrystallization temperature were performed, followed with hardness and electrical conductivity measuring. This investigation shows that hardness and electrical conductivity of cold deformed copper-alloys increase after annealing in the temperature range of 160 400°C, due to anneal hardening effect. Electrical conductivity decreases with increasing the amount of alloying elements. During the annealing the electrical conductivity slowly increases for both set of the samples copper and alloys due to recovery and recrystallization
A calorimetric investigation on the kinetics of solute segregation to partial dislocations in Cu–3.34at%Sn
The kinetics of solute segregation to partial dislocations in a Cu–3.34at%Sn alloy was studied using a phenomenological approach with differential scanning calorimetry and isothermal calorimetry. The material, severely deformed by repeated bending, presented an excess of dissociated edge dislocations with a dislocation density amounting to about 9.8×1014 m−2, calculated using an authors' prior model together with calorimetric recrystallization trace analysis. The kinetics was found to be ruled by two overlapping mechanisms: diffusion of solute atoms mostly through dislocations pipes at the beginning and medium stages of reaction process, acting together bulk solute diffusion at that stages and later on. Bulk solute diffusion increases as the reaction proceeds, as shown then by increasing values of apparent activation energy in the reaction. The exponent of the Mehl-Johnson-Avrami equation used in the phenomenological description was successfully fitted to a time-temperature dependent function increasing in agreement with the apparent activation energy behaviour, as may be expected.
Single step formation of biocompatible bimetallic alloy nanoparticles of gold and silver using isonicotinylhydrazide.
Manufacturing nanoparticles with controlled physicochemical properties using environment-friendly routes have potential to open new prospects for a variety of applications. Accordingly, several approaches have been established for manufacturing metal nanoparticles. Many of these approaches entail the use of hazardous chemicals and could be toxic to the environment, and cannot be used readily for biomedical applications. In the present work, we report a single step bio-friendly approach to formulate gold (Au), silver (Ag), and Au-Ag alloy nanoparticles with desired surface corona and composition using isonicotinylhydrazide (INH) as a reducing agent. INH also functioned as a stabilizing agent by enabling a surface corona around the nanoparticles. Remarkably, within a single step INH could also provide a handle in regulating the composition of Au and Ag in bimetallic systems without any additional chemical modification. The physicochemical and surface properties of the different nanoparticles thus obtained have been examined by analytical, spectroscopic and microscopic techniques. Cell cytotoxicity (release of lactate dehydrogenase), cell viability and intracellular reactive oxygen species (ROS) assays confirmed that the Au, Ag, and Au-Ag bimetallic nanoparticles prepared with INH are biocompatible. Finally, the presence of organic surface corona of INH on the nanoparticles was found to impart nanozyme activity and antimycobacterial sensitivity to the nanoparticles.