Comparison of reverse flow and counter-current reactors in the case of selective catalytic reduction of NOx
Abstract The paper is focused on the comparison between a reverse flow reactor (RFR) and a counter-current reactor (CCR) in terms of the performances that may be achieved in these kinds of reactors when selective catalytic reduction (SCR) of NO x with ammonia is carried out. In order to investigate the performances of both reactor configurations, a mathematical model based on heat and mass balances for gas and solid phase was used. The possibility of achieving auto-thermal operation, even when a gas with a low temperature is going to be fed to the reactor was investigated. The temperature profiles, the reactants conversion, as well as the response to disturbances in the feeding flow have been used as criteria for comparison. Numerical simulations have shown that the CCR model is able to provide the same results as the RFR model in terms of temperature profiles when certain values of heat transfer coefficient, switching time, flow conditions and reactor geometry are taken into consideration. As a consequence of such similar thermal behaviour, the CCR model could be applied as a limiting case of RFR operation when the fast switching of the flow direction conditions is taken into account. Nevertheless, this analogy provides a simple basis for short-cut calculations since the steady-state profile of a CCR can be computed much easier than the periodic steady-state of a RFR.
NOx removal in forced unsteady-state chromatographic reactors
Abstract The feasibility of the selective catalytic reduction (SCR) of NO x with ammonia in unsteady-state reactors is investigated by means of numerical simulations. A reactors network (RN) with periodical change of the feeding position is shown to be an alternative to the well investigated reverse-flow reactor (RFR) in order to fulfil the requirements on NO x conversion and ammonia emissions. Non-isothermal operation was studied, with low temperature feed, and the influence of the switching time on the mean outlet concentration of NH 3 and NO x was investigated, as well as the response of these devices to perturbations in the pollutant feed concentration.
Using Fuzzy-Delphi technique to determine the concession period in BOT projects
BOT projects are affected by several risks and uncertainties. One of the most important issues in this type of contract is to determine the length of concession period considering these uncertainties. The previous studies have developed several models to determine the concession period. However, the uncertainties are not taking into account in most of the previous works. Moreover, none of the previous researches has the capability to aggregate the opinions of different experts being involved in a project regarding the values of the uncertain input parameters. In this research, a Fuzzy-Delphi technique is implemented to determine the length of concession period considering uncertainties. Using the proposed Fuzzy-Delphi technique, the values of different uncertain factors affecting a BOT project is determined considering opinions of a group of experts. The NPV value is calculated considering the resulted aggregated values of uncertain input parameters. Finally, the concession period is determined using fuzzy approach. A case study is conducted to evaluate the performance of the proposed methodology. It is shown that the concession period is determined more effectively using the proposed approach.