Influence of Thermal Stability of Quartz and the Particle Size Distribution of Burden Materials on the Process of Electrothermal Smelting of Metallurgical Silicon
The article describes the thermal stability of quartz deposits in Kazakhstan-Aktas and Sarykul. It is established that the quartz of the Aktas deposit is a raw material with low thermal stability, and quartz is of medium-durability at Sarykul deposit. The complex influence of the thermal stability of this raw material on the technological parameters of smelting of technical silicon under experimental industrial conditions of electrothermal melting in a furnace with a capacity of 30 MVA was studied at LLP “Tau-Ken-Temir” (Kazakhstan). A new method for optimizing the smelting of commercial silicon has been developed, even when using raw materials with low thermal stability. The main idea of the method is that the less thermally stable quartz is used, the more the initial size of its pieces should be. Optimum values of the average size of pieces of quartz-Aktas(85-95 mm) and Sarykul-(30-40 mm) are obtained.
Changes in Quartz During Heating and the Possible Effects on Si Production
In Si and FeSi production, the main Si source is SiO2, in the form of quartz. Reactions with SiO2 generate SiO gas that further reacts with SiC to Si. During heating, quartz will transform to other SiO2 modifications with cristobalite as the stable high-temperature phase. Transformation to cristobalite is a slow process. Its rate has been investigated for several industrial quartz sources and has been shown to vary considerably among the different quartz types. Other differences in behavior during heating between these quartz sources, such as softening temperature and volume expansion, have also been studied. The quartz-cristobalite ratio will affect the rate of reactions involving SiO2. The industrial consequences and other implications of the observed difference between quartz types are discussed. Initial studies of industrial quartz were published by Ringdalen et al. In the current work, a new experimental method has been developed, and an investigation of several new quartz sources has confirmed the earlier observed large variation between different sources. The repeatability of the data has been studied and the effect of gas atmosphere investigated. The results from the earlier work are included as a basis for the discussion.
Effects of Equipment Dimensions on Liquid Mixing Time of Bubble Column with Draft Tube
The liquid mixing time of a bubble column with a draft tube is experimentally studied. The diameter and height of the column, the diameter and length of the draft tube, and the mode of sparging gas were changed and the liquid mixing time was measured.The lengths of bottom and top clearances have significant effects on the liquid mixing time. The liquid mixing time increases with increasing column aspect ratio of height to diameter. The liquid mixing time of the bubble column with a draft tube is longer than that of a standard bubble column when the column aspect ratio is relatively high. The liquid mixing time has a minimum when the diameter ratio of draft tube to column is 0.5 to 0.6. These effects of equipment dimensions are expressed by an equation. In the experiment using different solutions, the liquid mixing time becomes shorter with increasing liquid surface tension, or with increasing liquid viscosity.