Application of ‘molecular’ theories to the structure of the crystalline state
Recent years have seen the development of simple molecular orbital based ideas to view the structures of molecular ring, cage and cluster compounds. The principles of these methods are used here to demonstrate in a new way how the structures of solids depend on electronic configuration.
Electrons-Skeletal electron counting in cluster and ring compounds
MINGOS has discussed the structural significance of the number of skeletal bonding electrons in cluster and ring compounds1. My recent studies of this topic2–8 lead me to suggest that the following points are worth noting concerning the scope of the closo, nido and arachno relationships that hold for the boron hydrides4,9.
Ceramic microwave antennas for mobile applications
Due to their medium to high permittivity values, ceramic microwave materials are attractive as building blocks for miniaturised antenna solutions. Further advantages are low dielectric losses and an excellent temperature stability of standard ceramic materials. Yet, the permittivity of the ceramic material also has a strong influence on the radiation efficiency and bandwidth of the antenna. This implies that in the design process a suitable compromise has to be found between the degree of miniaturisation on the one hand and the antenna efficiency and bandwidth on the other. We describe two approaches towards efficient miniaturised ceramic microwave antennas: the dielectric resonator antenna (DRA) with partial metallisation and the shorting post patch antenna. We focus on design steps taken to ensure both a high degree of miniaturisation and high values of the radiation efficiency, the choice of the ceramic material and the experimental performance of the antennas.