Investigating the optical properties of polycrystalline AgCl(1-x)Br(x) (0≤x≤1) and Ag(0.95)Tl(0.05)Br(0.95)I(0.05) for IR engineering.
Using the Michelson technique we measured the refractive indices for the plane-parallel thin plates made of AgCl1-xBrx(0≤x≤1) and, to the best of our knowledge, for the first time for the Ag0.95Tl0.05Br0.95I0.05 plate, manufactured by hot embossing, at 632.8 nm. We recorded their absorption spectra within the range of 0.19-41.67 μm using UV-Vis spectrophotometry and Fourier transform infrared spectroscopy, which demonstrated that the increase of substituent silver bromide or thallium monoiodide mole fraction in the corresponding solid solution causes the optical density to grow. As the result it moves the transmission edges toward longer wavelengths, while slightly reducing the transmission peak.
Creating an antireflection coating on the surface of silver and a monadic thallium halide crystalline materials
On the global market the demands for the quality and, more important, for the level of the special properties of polycrystalline IR optical fibers is rapidly rising. The transition at progressively longer wavelengths requires the use of materials with high refractive index, which, in its turn, implies increasing of the Fresnel reflection at the interface when injecting the radiation into the fiber. In this regard, the issue arises to create the antireflective coatings, which could neutralize this effect.
The elastic constants and their temperature and pressure derivatives of AgBr-AgCl mixed crystals
Abstract The three independent second-order elastic constants and their temperature and pressure derivatives have been measured for four AgBr-AgCl mixed crystals, with 19.5, 39.1, 56.6 and 78.7 mole % AgCl, using the ultrasonic pulse-echo technique at room temperature. The explicit temperature dependence of the elastic constants is calculated and is found to be much larger than that of other NaCl structure crystals. The violation of the Cauchy relation C 12 = C 44 is found to be significant and increases between AgBr and AgCl. The high temperature limit of the Gruneisen parameter is calculated from the elastic data. A comparison is made between the elastic properties of the silver halides and the alkali halides.