Singlet-oxygen generation in the catalytic reaction of dioxiranes with nucleophilic anions.
Nucleophilic anions such as Cl(-), I(-), Br(-), t-BuO(-), O(2)(-) and OH(-) efficiently catalyze the decomposition of dimethyldioxirane (DMD) and methyl(trifluoromethyl)dioxirane (TFD). Singlet oxygen ((1)O(2)) is formed in these catalytic reactions, as demonstrated by the characteristic infrared chemiluminescence (IR-CL) at 1268 nm. The yield of (1)O(2) generation, measured by the IR-CL method, lies in the range between 2 and 98%, which depends on the particular anion employed. For the bromide ion, the catalytic decomposition of the dioxirane is in competition with the oxidation of Br(-) to elemental bromine.
A new bright chemiluminescent reaction: interaction of acetone with solid potassium peroxymonosulfate in the complex of europium nitrate
The interaction of acetone with a mixture of potassium peroxymonosulfate and europium nitrate hexahydrate powders at 90 °C is accompanied by chemiluminescence due to the formation of excited Eu3+; dioxirane is proposed to be a key intermediate responsible for the chemiluminescence observed.
Rapid determination of the effectiveness of insect resistant packaging
A technique was developed to evaluate the usefulness of odour barriers and to determine the effect of package content in consumer size packages on resistance to infestation by insects. Female Plodia interpunctella (Hubner) could distinguish sealed packets containing food from non-food items as a suitable site for oviposition. Utilization ofthis technique will reduce the time needed to evaluate new materials for use in insect resistant packaging.