Pyrolysis of polystyrene waste in the presence of activated carbon in conventional and microwave heating using modified thermocouple.
Pyrolysis process was experimented using two types of heating source, namely conventional and microwave. Polystyrene (PS) plastic waste was used as feedstock in a batch reactor for both the conventional (slow pyrolysis) and microwave pyrolysis. The effect of activated carbon to polystyrene ratio on (i) yield of oil, gas and residues (ii) reaction temperature (iii) reaction time were studied. Quality of oil from pyrolysis of polystyrene were assessed for the possible applicability in fuel production. Microwave power of 450 W and polymer to activated carbon ratio of 10:1, resulted in the highest oil yield of 93.04 wt.% with a higher heating value of 45 MJ kg-1 and a kinematic viscosity of 2.7 cSt. Microwave heating when compared to conventional heating method, exhibits a reaction temperature and time of 330 °C in 5.5 min, whereas in conventional heating system it was 418 °C in 60 min. The gas chromatography-mass spectrometry analysis of liquid oil from microwave pyrolysis predominantly yields alkenes of 8.44 wt.%, α-methyl styrene 0.96 wt.%, condensed ring aromatics 23.21 wt.% and benzene derivatives 26.77 wt.% when the polystyrene to activated carbon ratio was 10:1. Significant factor of using microwave heating is the amount of energy converted (kWh) is lesser than conventional heating.
Progress and perspective for conversion of plastic wastes into valuable chemicals.
Today, discarded plastics in nature have caused serious "white pollution", however these plastic wastes contain abundant carbon resources that could serve as the feedstock to produce commodities. Because of this, it is requisite to convert these plastic wastes into valuable chemicals. Herein, the state-of-the-art techniques for plastic conversion are divided into two categories, those performed under violent conditions and mild conditions, in which the conversion mechanisms are discussed. The strategies under violent conditions are closer to practical application thanks to their excellent conversion efficiencies, while the strategies under mild conditions are more environmentally friendly, showing enormous development potential in the future. We summarize in detail the pyrolysis, hydropyrolysis, solvolysis and microwave-initiated catalysis for bond cleavage in plastic wastes at temperatures ranging from 448 to 973 K. Also, we overview the photocatalysis, electrocatalysis and biocatalysis for bond cleavage in plastic wastes at near and even normal temperature and pressure. Finally, we present some suggestions and outlooks concerning the improvement of current techniques and in-depth mechanisms of investigation for conversion of plastics into valuable chemicals.
Mathematical Simulation of Combustion of Boron Powder Gas Suspension
Based on a two-phase two-velocity model of a reacting gas-dispersed medium, a mathematical model of combustion of a boron powder gas suspension has been formulated. The results of numerical solution of the problem are presented. The influence of the composition of the gas suspension, its size, size distribution of particles, mass concentration of particles, as well as of the presence of aluminum powder in the suspension on the visible and normal velocities of flame propagation in the gas suspension, is shown. A comparison of the results of calculation with the well-known experimental and theoretical data is carried out. Satisfactory agreement of the predicted results with experimental data is shown.