Detection of Ni–Sn phases in temper embrittled Ni–Cr steels
A GENERIC problem in ferritic steels is the reduction in the grain boundary cohesive strength produced by the segregation of trace impurities of Groups IVB and VB of the Periodic Table. Such segregation results in a deterioration in mechanical properties produced, for example, by reversible temper embittlement1 and it also promotes enhanced susceptibility to a range of environmental enhanced cracking processes2–4. It has long been recognised that the embrittlement of steels is enhanced by the presence of certain alloy elements, that is Ni, Cr or Mn, and measurements using Auger electron spectroscopy (AES)5–7 have demonstrated that specific combinations of alloy and impurity elements cosegregate to the boundaries, for example, Ni+Sn, Ni+Sb, Cr+P. These observations can be rationalised using Guttmann's phenomenological theory8 which attributes the increased driving force for segregation to a positive interaction between alloy and impurity solute atoms. Previous investigations1,9–11 have failed to detect the presence of any three dimensional phase using conventional transmission electron microscopy and it is generally considered that the alloy element–trace impurity atoms form two dimensional phases at the boundaries. The only direct evidence for such alloy–impurity interactions and phase formation has been obtained using Mössbauer spectroscopy12,13 but it is not possible using this technique to draw any positive conclusions regarding the location of such compounds. Measurements on a pure Fe-3.5 wt% Ni alloy doped with 119Sn12 showed that Ni atoms associate preferentially with Sn atoms during tempering at 650°C and the marked change in the spectrum observed on ageing at 500°C, within the embrittling temperature range, is consistent with the formation of a Ni–Sn compound (Ni3Sn2 or Ni3Sn4). We report here some initial results from a detailed electron microscopic analysis of the microstructures of a commercial (En30A) Ni–Cr steel and a special laboratory made steel (BE 10) having similar Ni and Cr contents, but doped specifically with tin. The composition of the two steels is presented in Table 1. Both steels were oil quenched from 950°C, tempered for 1 h at 650°C and aged at 500°C for times up to 5,000 h. Carbon extraction replicas, taken from polished surfaces were examined in a Philips EM400 microscope fitted with an energy dispersive X-ray system. Selected individual precipitate particles were analysed using convergent beam microdiffraction and X-ray analysis. Attention was focused on the particles which delineated the lath packet and previous austenite boundaries, that is, high-angle boundaries.
Interfacial Fracture in Alloy Steels
It is well-established that the segregation of trace impurities and alloy elements to high angle boundaries in alloy steels may promote intergranular failure. In this paper, the effects of solute segregation on a range of mechanical properties are reviewed with particular reference to the phenomena of temper embrittlement and stress relief cracking which represent conditions of intergranular cracking at constant segregation level and constant chemical potential respectively.
Athenian Democracy at War
Classical Athens perfected direct democracy. The plays of this ancient Greek state are still staged today. These achievements are rightly revered. Less well known is the other side of this success story. Democratic Athens completely transformed warfare and became a superpower. The Athenian armed forces were unmatched in size and professionalism. This book explores the major reasons behind this military success. It shows how democracy helped the Athenians to be better soldiers. For the first time David M. Pritchard studies, together, all four branches of the armed forces. He focuses on the background of those who fought Athens' wars and on what they thought about doing so. His book reveals the common practices that Athens used right across the armed forces and shows how Athens' pro-war culture had a big impact on civilian life. The book puts the study of Athenian democracy at war on an entirely new footing.