Trivalent zirconium and hafnium ions in yttria-based transparent ceramics
Electron paramagnetic resonance spectra of transparent yttria-based ceramics with zirconium and hafnium additives contain signals with close parameters due to paramagnetic Zr3+ and Hf3+ ions, which have similar ground-state electron configurations of [Kr]4d1 and [Xe]5d1, respectively.
Zirconia-doped yttria transparent ceramics via slip casting and sintering
Abstract In this work, slurries containing 70 wt % yttria (Y2O3) nanopowder (~90 nm), and 1 wt % zirconium (IV) chloride (ZrCl4) were prepared to fabricate yttria transparent ceramics via slip casting and sintering. To do this, several processing parameters including the pH value of slurries, amounts of Dolapix CE 64 as a dispersant, citric acid, solid load, and de-agglomeration time were optimized. Then, slip-casted samples with the highest relative green density (~65%) were sintered at 1715 °C under vacuum and the microstructure and transmission properties of the obtained samples were investigated. The results showed that with the addition of 1 wt % ZrCl4 to the slurry, the transparency of the fabricated Zr-doped yttria ceramics increased significantly and the highest transmittance (~78%) at a wavelength of 800 nm was obtained for 3 mm-thick sintered samples with a total relative density of 99.4 ± 0.2%.
Asymptotic Properties of Solutions to Second-Order Difference Equations of Volterra Type
<jats:p>We consider the discrete Volterra type equation of the form <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="M1"><mml:mi mathvariant="normal">Δ</mml:mi><mml:mo stretchy="false">(</mml:mo><mml:msub><mml:mrow><mml:mi>r</mml:mi></mml:mrow><mml:mrow><mml:mi>n</mml:mi></mml:mrow></mml:msub><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mrow><mml:mi>x</mml:mi></mml:mrow><mml:mrow><mml:mi>n</mml:mi></mml:mrow></mml:msub><mml:mo stretchy="false">)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mrow><mml:mi>b</mml:mi></mml:mrow><mml:mrow><mml:mi>n</mml:mi></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:mrow><mml:msubsup><mml:mo stretchy="false">∑</mml:mo><mml:mrow><mml:mi>k</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow><mml:mrow><mml:mi>n</mml:mi></mml:mrow></mml:msubsup><mml:mrow><mml:mi>K</mml:mi><mml:mo stretchy="false">(</mml:mo><mml:mi>n</mml:mi><mml:mo>,</mml:mo><mml:mi>k</mml:mi><mml:mo stretchy="false">)</mml:mo><mml:mi>f</mml:mi><mml:mo stretchy="false">(</mml:mo><mml:msub><mml:mrow><mml:mi>x</mml:mi></mml:mrow><mml:mrow><mml:mi>k</mml:mi></mml:mrow></mml:msub><mml:mo stretchy="false">)</mml:mo></mml:mrow></mml:mrow></mml:math>. We present sufficient conditions for the existence of solutions with prescribed asymptotic behavior. Moreover, we study the asymptotic behavior of solutions. We use <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="M2"><mml:mi mathvariant="normal">o</mml:mi><mml:mo stretchy="false">(</mml:mo><mml:msup><mml:mrow><mml:mi>n</mml:mi></mml:mrow><mml:mrow><mml:mi>s</mml:mi></mml:mrow></mml:msup><mml:mo stretchy="false">)</mml:mo></mml:math>, for given nonpositive real <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="M3"><mml:mrow><mml:mi>s</mml:mi></mml:mrow></mml:math>, as a measure of approximation.</jats:p>