Analysis of grain structure evolution via image processing based on optical measurements of mc Si wafers
A fast and thorough characterization of grain structure in multicrystalline silicon (mc-Si) is crucial to improve crystal growth and thus bulk lifetime in solar cells. The presented characterization techniques are based on simple optical measurements on as-cut mc-Si wafers. An insight into the entire brick is gained by connecting 2D-information, computed via advanced pattern recognition techniques, over brick height. We identify robust statistical key parameters. Their development within typical bricks of different cast-Si techniques is compared and it is found that the distinct behavior of different materials in the lower part of the brick subsides towards the brick top where grain size distribution is similar.
Formation mechanism of parallel twins related to Si-facetted dendrite growth
We propose a simple model to explain formation mechanism of parallel twins that are related to Si-facetted dendrite growth, and attempt to confirm its validity by in situ observations. The model involves the formation of a twin boundary at the {1 1 1} facet plane on the growth interface followed by formation of another twin parallel to the first one. Subsequently, a facetted dendrite grows parallel to the facet plane in this model. This growth behavior was successfully observed by growth experiments.
Recent progress in engineering near-infrared persistent luminescence nanoprobes for time-resolved biosensing/bioimaging
Persistent luminescence nanoprobes (PLNPs) can remain luminescent after ceasing excitation. Due to the ultra-long decay time of persistent luminescence (PersL), autofluorescence interference can be efficiently eliminated by collecting PersL signal after autofluorescence decays completely, thus the imaging contrast and sensing sensitivity can be significantly improved. Since near-infrared (NIR) light shows reduced scattering and absorption coefficient in penetrating biological organs or tissues, near-infrared persistent luminescence nanoprobes (NIR PLNPs) possess deep tissue penetration and offer a bright prospect in the areas of in vivo biosensing/bioimaging. In this review, we firstly summarize the design of different types of NIR PLNPs for biosensing/bioimaging, such as transition metal ions-doped NIR PLNPs, lanthanide ions-doped NIR PLNPs, organic molecules-based NIR PLNPs, and semiconducting polymer self-assembled NIR PLNPs. Notably, organic molecules-based NIR PLNPs and semiconductor self-assembled NIR PLNPs, for the first time, were introduced to the review of PLNPs. Secondly, the effects of different types of charge carriers on NIR PersL and luminescence decay of NIR PLNPs are significantly emphasized so as to build up an in-depth understanding of their luminescence mechanism. It includes the regulation of valence band and conduction band of different host materials, alteration of defect types, depth and concentration changes caused by ion doping, effective radiation transitions and energy transfer generated by different luminescence centers. Given the design and potential of NIR PLNPs as long-lived luminescent materials, the current challenges and future perspective in this rapidly growing field are also discussed.