Phase Formation Modeling of an Alloy 706 Casting Using Computational Thermodynamics
Computational thermodynamics to perform alloy and process modeling for Ni-based superalloys is a new technology which has become available to industry. This paper presents an application of the technology to a superalloy of current interest. The objective of this paper is to show how results obtained from the computational program Thermo-Calc ‘1 using a recently developed thermodynamic database for Ni-based superalloy9 can be applied to help understand solidification in INCONEL’ alloy 706. The ability of the computational method to predict both stable and metastable phase formation is explored. INCONEL@ alloy 706 was chosen because of its importance in the manufacture of large land-based gas turbine disks. In addition, the alloy’s complex structure tested the viability of the computational method. The phases examined were: Laves, MC carbide, and the y matrix. Quantitative microstructure evaluation and X-ray dispersive analysis were performed on an as-cast, vacuum induction melted (VIM) ingot. Differential Thermal Analysis (DTA) was performed on selected samples of the alloy. The experimental data was compared to the data generated via the computational approach. TM Thermo-Calc, trade name of the Division of Computational Thermodynamics, Royal Institute of Technology, Stockholm, Sweden. 8 INCONEL is a trademark of the INCO group of companies.
Thermo-Calc of the Phase Diagram of Calcium Silicon (Ca–Si) System
Thermo-Calc software was used to investigate the phase diagram of the calcium silicon (Ca–Si) system for the range of Si mass percent 0–100, and temperature range T = 200–1800 K. The melting points of Ca and Si deduced from the phase diagram are very close to the values obtained experimentally. Three stable intermediate solid phases were found, which are Ca2Si, CaSi, and CaSi2, where the first one appeared in the Ca rich side of the phase diagram, and the third one in the Si rich side. In addition, three eutectic points were found at Si mass percents of 3.95, 33.00, 62, and temperatures T = 1048.7, 1519.14, 1308.5 K respectively. Atomic Si (Diamond structure) is found mixed with CaSi2 intermediate phase for temperatures less than 1305 K, and mixed with a liquid CaSi for higher temperatures. These results are important for thermodynamic and metallurgic studies of these intermediate phases.
The Contemporary British History Play
Introduction Biographical History Plays Social History Plays Oppositional History Plays Marxist and Socialist History Plays Feminist History Plays Deconstructionist and Postmodern History Plays and Satire The Search for a Theatrical Form Appendix A: Performance Dates of Contemporary British History Plays Appendix B: Performance Locales of Contemporary British History Plays Bibliography Index