Cadmium telluride nanofilms application in carbon monoxide detection
The research is centered on CdTe nanofilms. The article is aimed at developing innovative primary transducer nanoscale material for semi-conductor sensors, investigating their surface physicochemical properties and evaluation their applicability in carbon monoxide diagnostics. Cadmium telluride nanofilms were obtained by discrete thermal evaporation in vacuum. CdTe nanofilms applicability in gas analysis was investigated. Adsorption properties of the given material for carbon oxide (II) and oxygen were studied by the piezoquartz microweighing. The principles of adsorption, depending on the process conditions and the test sample habitus, were established. Based on the obtained experimental data, CO micro-impurities sensors were developed, the laboratory tests passed successfully.
MoS2 hybrid heterostructure thin film decorated with CdTe quantum dots for room temperature NO2 gas sensor
Abstract Molybdenum disulfide (MoS2) is a very promising candidate for room temperature (RT) gas sensing applications. However, the limitation of synthesis techniques, incomplete recovery, and selectivity at RT are prime drawbacks. In this report, MoS2 nanoworms (NWs) thin film and CdTe quantum dots (QDs) decorated MoS2 NWs hybrid heterostructure thin film (CdTe QDs/MoS2 NWs) have been fabricated by scalable sputtering technique on the p-Si substrate and tested for RT NO2 gas sensing applications. The proposed CdTe QDs/MoS2 NWs hybrid heterostructure thin film sensor manifests an excellent sensor response (∼40 %), fast response time = 16 s, complete recovery (recovery time = 114 s) and highly selective towards 10 ppm NO2 at room temperature in comparison to pristine MoS2 NWs thin film sensor (response ∼26 %, response/recovery time ∼23 s/incomplete recovery). This superior gas sensing performance may be attributed to the combined effect of factors such as hybrid heteronanostructure with unique morphology, catalytic activity, synergistic effects, and p-n heterojunctions. The approach employed here may lead to the development of RT operable MoS2-based heterojunction gas sensors.
Scaffolds Containing Spirulina sp. LEB 18 Biomass: Development, Characterization and Evaluation of In Vitro Biodegradation.
Polymer nanofibers are nanomaterials that can be used as scaffolds in tissue engineering. The objective of this study was to develop, characterize and evaluate the in vitro degradation of a biomaterial consisting of nanofibers produced from biodegradable and biocompatible polymers with potential applications as a scaffold for tissue regeneration and containing Spirulina sp. LEB 18 biomass as the bioactive compound. The polymers used were poly(hydroxybutyrate-co-hydroxyvalerate) and polycaprolactone. The polymeric solutions exhibited sufficiently high viscosity to produce uniform nanofibers with diameters between 335 and 617 nm. The applied conditions were as follows: a voltage of 25 kV, a distance from the capillary to the collector of 120 mm, a capillary diameter of 0.80 mm, and 12% polycaprolactone and a blend of 5% polycaprolactone and 10% poly(hydroxybutyrate-co-hydroxyvalerate). The biomass was incorporated into the nanofibers at a concentration of 3%, and the incorporation was confirmed using confocal microscopy. The nanofibers were characterized using differential scanning calorimetry and thermogravimetric analysis, which showed that the addition of biomass did not alter the thermal properties of the biomaterial. The addition of biomass improved the tensile strength and elongation of the scaffolds compared with those produced with polymers alone. A biodegradation assay showed enzymatic action toward the biomaterial, simulating the behavior of natural tissue. Based on the analysis, it was concluded that the scaffolds that were produced have the potential to be applied in the field of tissue regeneration as biomaterials with pharmacological properties.