Synthesis and Structure Determination of the Quaternary Zinc Nitride Halides Zn2NX1−yX′y (X, X′ = Cl, Br, I; 0 < y < 1)
The quaternary series Zn2NCl1−yBry and Zn2NBr1−yIy were synthesized from solid-liquid reactions between zinc nitride and the respective zinc halides in closed ampoules, and the evolution of their crystal structures was investigated by single-crystal and powder X-ray diffraction. Zn2NX1−yX′y (X, X′ = Cl, Br, I) adopts the anti-β-NaFeO2 motif in which each nitride ion is tetrahedrally coordinated by four zinc cations, and the halide anions are located in the voids of the skeleton formed by corner-sharing [NZn4] tetrahedra. While Zn2NCl1−yBry crystallizes in the acentric orthorhombic space group Pna21 (No. 33), isotypic to Zn2NX (X = Cl, Br), the structure of Zn2NBr1−yIy is a function of the iodide concentration, namely, Zn2NBr (Pna21) for low iodine content and Zn2NI (Pnma) for higher (y ≥ 0.38).
Preparation and Crystal Structure of Ordered and Disordered Lithium Nitride Dichloride, Li5NCl2
Abstract A previosly unknown ordered low-temperature phase Li5NCl2-II has been obtained from the disordered high-temperature phase Li5NCl2-I by slow cooling (100°/h), while prolonged annealing at 400°C resulted in a decomposition to Li4NCl and LiCl. Neutron powder diffraction data were collected for both compounds and analyzed by the Rietveld method of profile refinement. Li5NCl2-II crystallizes in the hexagonal rhombohedral space groupR 3 m,a=366.10 (3),c=2851.6 (3) pm with three formula units per unit cell. Its structure may be regarded as composed of lithium nitride-like [Li4N]+layers and rock-salt-like [LiCl2]−double-layers, stacked along the hexagonalcaxis. A redetermination of the Li2O-type structure of Li5NCl2-I indicates the presence of N–Cl short-range order.
Determination of Optimal Ball-Burnishing Parameters for Plastic Injection Moulding Steel
The objective of this study is to determine the optimal plane ball-burnishing parameters for plastic injection moulding steel PDS5 on a machining centre by utilising the Taguchi’s orthogonal array method. The design and manufacture of a burnishing tool are described. Four burnishing parameters, namely the ball material, burnishing speed, burnishing force and feed, were selected as the experimental factors in Taguchi’s design of experiments to determine the optimal burnishing parameters which have the dominant influence on surface roughness. The optimal burnishing parameters were found after carrying out the experiments specified by Taguchi’s L18 orthogonal table, by the analysis of variation, and by a full factorial experiment. The optimal plane burnishing parameters for the plastic injection moulding steel PDS5 were a combination of a tungsten carbide ball, a burnishing speed of 200 mm/min, a burnishing force of 300 N and a feed of 40 μm. The surface roughness Ra of the specimen can be improved from about 1 μm to 0.07 μm by using the optimal burnishing parameters for plane burnishing.