Magnetic phase transition and Mossbauer spectroscopy of ErNi2Mnx compounds
Investigation of ErNi2Mnx with 0.90 ≤ x ≤ 1.10 indicates that the MgCu2-type structure (with space group Fd-3m) is formed within x = 0.97−1.10. Curie temperature TC = 50 K of ErNi2Mn is significantly higher than those of the corresponding ErNi2 (TC = 7 K) and ErMn2 (TC = 15 K) compounds. Detailed analyses of DC magnetization data demonstrate that the magnetic phase transition at the Curie temperature is second order. The magnetic entropy change around TC has been found to be 4.8 J/kg K for a magnetic field change of 0 to 5 T with its relative cooling power ∼283 J/kg. 57Fe Mossbauer spectra below TC have been fitted with three sub-spectra representing three inequivalent local magnetic environments while the paramagnetic spectra are fitted using two sub-spectra for two inequivalent crystal sites (8a and 16d), which supports the conclusion based on Rietveld refinement that Mn atoms occupy at both 8a and 16d sites.
Magnetic anomalies of thermal expansion in (rare-earth) Ni2 intermetallic compounds
Abstract The thermal expansion of eight RENi 2 intermetallic compounds (RE = La, Nd, Sm, Tb, Dy, Ho, Er, Tm) and YNi 2 have been measured between 3.8 and approx. 300 K. The anomalies found at the paramagnetic-magnetically ordered phase transition have allowed an accurate determination of the Curie temperatures. From the low temperature comparison of the thermal expansion of the light RE compounds with that of LaNi 2 , and of the heavy RE compounds with that of YNi 2 , the Debye temperatures have been obtained. In the case of the compounds DyNi 2 , TbNi 2 and HoNi 2 the contributions from crystal field and exchange interactions to the spontaneous volume strain at the magnetically ordered phase have been calculated, the agreement between experiment and calculation being good.
A new method of near field analysis
The problem of the accurate determination of the total electromagnetic field produced by a current distribution on a circular disc type aperture is examined. For comparison of the near and Fresnel region solutions, an exact Maxwellian integral is used as the starting point. Aperture and space coordinates are separated by the use of Bessel function addition theorems, allowing the field to be expressed as a sum of terms containing radial and angular integrals. The radial integrals involve only the disc (aperture) distribution and coordinates while the angular integrals involve only the elevation angle. The distance from origin appears implicitly in the series coefficients. These integrals are suitable for high speed computations and have been evaluated for a number of cases. The results are compared with the small angle and general Fresnel formula values for various observation angles, distances from the aperture, and aperture distributions.