The anisotropic glass-like properties of disordered crystals
The low temperature acoustic and thermal properties of amorphous, glassy materials are remarkably similar. All these properties are described theoretically with reasonable quantitative accuracy by assuming that the amorphous solid contains dynamical defects that can be described at low temperatures as an ensemble of two-level systems (TLS), but the deep nature of these TLSs is not clarified yet. Moreover, glassy properties were found also in disordered crystals, quasicrystals, and even perfect crystals with a large number of atoms in the unit cell. In crystals, the glassy properties are not universal, like in amorphous materials, and also exhibit anisotropy. Recently it was proposed a model for the interaction of two-level systems with arbitrary strain fields (Phys. Rev. B 75, 64202, 2007), which was used to calculate the thermal properties of nanoscopic membranes at low temperatures. The model is also suitable for the description of anisotropic crystals. We describe here the results of the calculation of anisotropic glass-like properties in crystals of various lattice symmetries.
Scattering of phonons on two-level systems in disordered crystals
We calculate the scattering rates of phonons on two-level systems in disordered trigonal and hexagonal crystals. We apply a model in which the two-level system, characterized by a direction in space, is coupled to the strain field of the phonon via a tensor of coupling constants. The structure of the tensor of coupling constants is similar to the structure of the tensor of elastic stiffness constants, in the sense that they are determined by the same symmetry transformations. In this way, we emphasize the anisotropy of the interaction of elastic waves with the ensemble of two-level systems in disordered crystals. We also point to the fact that the ratio γl/γt has a much broader range of allowed values in disordered crystals than in isotropic solids.
Scaffolds Containing Spirulina sp. LEB 18 Biomass: Development, Characterization and Evaluation of In Vitro Biodegradation.
Polymer nanofibers are nanomaterials that can be used as scaffolds in tissue engineering. The objective of this study was to develop, characterize and evaluate the in vitro degradation of a biomaterial consisting of nanofibers produced from biodegradable and biocompatible polymers with potential applications as a scaffold for tissue regeneration and containing Spirulina sp. LEB 18 biomass as the bioactive compound. The polymers used were poly(hydroxybutyrate-co-hydroxyvalerate) and polycaprolactone. The polymeric solutions exhibited sufficiently high viscosity to produce uniform nanofibers with diameters between 335 and 617 nm. The applied conditions were as follows: a voltage of 25 kV, a distance from the capillary to the collector of 120 mm, a capillary diameter of 0.80 mm, and 12% polycaprolactone and a blend of 5% polycaprolactone and 10% poly(hydroxybutyrate-co-hydroxyvalerate). The biomass was incorporated into the nanofibers at a concentration of 3%, and the incorporation was confirmed using confocal microscopy. The nanofibers were characterized using differential scanning calorimetry and thermogravimetric analysis, which showed that the addition of biomass did not alter the thermal properties of the biomaterial. The addition of biomass improved the tensile strength and elongation of the scaffolds compared with those produced with polymers alone. A biodegradation assay showed enzymatic action toward the biomaterial, simulating the behavior of natural tissue. Based on the analysis, it was concluded that the scaffolds that were produced have the potential to be applied in the field of tissue regeneration as biomaterials with pharmacological properties.