NiII1,4,8,11-tetraazacyclotetradecane electrocatalytic films prepared on top of surface anchored PAMAM dendrimer layers. A new type of electrocatalytic material for the electrochemical oxidation of methanol.
Gold electrodes, previously prepared with surface anchored PAMAM dendrimers, were further modified with a Ni-containing tetraazamacrocycle resulting in a novel electrocatalytic material which proved to be particularly efficient for the electrochemical oxidation of methanol in basic aqueous medium.
Electrocatalytic oxidation of methanol on Ni modified polyaniline electrode in alkaline medium
Electrolytically deposited Ni on polyaniline film covered carbon paste electrode (Ni/PANI/CPE) was used as anode for the electrooxidation of methanol in alkaline medium. The electrochemical behavior and electrocatalytic activity of the electrode were studied using cyclic voltammetry, impedance spectroscopy, chronomethods, and polarization studies. The morphology and composition of the modified film were obtained using scanning electron microscope and energy dispersive X-ray analysis techniques. The electrooxidation of methanol in NaOH was found to be more efficient on Ni/PANI/CPE than on bare Ni, electrodeposited Ni on Pt, Ni on glassy carbon, and Ni on CPE substrates. Partial chemical displacement of dispersed Ni on PANI with Pt or Pd further improved its performance towards methanol oxidation.
Experimental Study for a Double-Glazed Forced-Flow Solar Collector/Regenerator
Experimental study of a double-glazed forced-convection solar collector/regenerator for absorption solar cooling is presented. The south facing experimental solar collector/regenerator with 10 deg slope is located at Kaohsiung, Taiwan at 120{degree}19minutesE longitude and 22{degree}34minutesN latitude. The size of the collector is 1 m wide and 7 m long with an effective regeneration area of 0.9 m by 6 m. Previous study for single-glazed forced-convection solar collector/regenerator operated at the same location has shown to have a best day-average efficiency of 17%. In order to raise the system performance, a double-glazed collector/regenerator is constructed such that air can be preheated in the upper channel flow. The preheated air is then conducted into the lower channel where it contacts with the film flow of solar heated lithium-chloride solution and regenerates the solution by carrying out the evaporated water vapor. The preheated air has lower relative humidity but the same humidity ratio since it is sensibly heated. Therefore, the regeneration driving potential is increased. The present study shows that the best day-average efficiency can reach 20% which increases the feasibility of the open-cycle absorption solar cooling system. Effects of controlling parameters on the collector/regenerator performance are studied, and heat and mass transfer correlationsmore » are also presented for design purposes.« less