Investigation of Nd:Yb - codoped silica fibers as a laser material
The increasing interest in high power fiber lasers is connected with the task of providing the necessary pump energy at acceptable costs. High power laser experiments with commercially available multi-wavelengths diode laser systems and silica fibers codoped with Neodymium (Nd) and Ytterbium (Yb) demonstrated the potential of this laser concept. Fluorescence investigations of Nd:Yb-codoped silica fibers proved an effective energy transfer from stimulated Nd ions to Yb ions. To get a better understanding of this laser medium we investigated the fluorescence spectra, the fluorescence decay and the laser characteristics both experimentally and theoretically. In conclusion, we present experimental results and a model for the understanding of fluorescence and laser properties of Nd:Yb-codoped silica fibers
Spectroscopy of Nd3+ and Yb3+ codoped fluoroindogallate glasses
The Nd–Nd and Nd–Yb energy transfer processes are studied in lead fluoroindogallate glasses with the following molar composition: 30PbF2–20GaF3–15InF3–15ZnF2–(20–X)CaF2–XNdF3 (with X=0.1, 0.5, 1, 2, 4, and 5), 30PbF2–20GaF3–15InF3–15ZnF2–(20–X)CaF2–XYbF3 (with X=0.1, 0.5, 1, 2, 3, and 5), and 30PbF2–20GaF3–15InF3–15ZnF2–(19–X)CaF2–XYbF3–1NdF3 (with X=0.1, 0.5, 1, 2, 3, and 5.5). The Dexter, Yokota–Tanimoto, and Holstein formalisms were used to treat the experimental data. The following microparameters of energy transfer were obtained: CDD(Nd–Nd)≈7×10−40, CDA(Nd–Nd)=2.5×10−40, and CDA(Nd–Yb)≈3×10−40 cm6/s. It was also shown that the energy migration between Nd ions depends on the third power of temperature (T3) up to a saturation value of about 80 K. This behavior was attributed to the site to site energy migration. The Yb doped samples presented no nonradiative losses for the Yb3+ emission at 969 nm.
Influence of temperature and acceptor concentration on energy transfer from Nd3+ to Yb3+ and from Yb3+ to Er3+ in tellurite glass
Abstract Multicomponent tellurite glass doped with neodymium, erbium and ytterbium were studied experimentally using the methods of conventional spectroscopy. Results of measurements were interpreted on the basis of a kinetic model which describes the interactions between rare earth ions in terms of parameters characterizing the probabilities of energy migration and luminescence quenching. The probability of Nd3+ − Yb3+ energy transfer is found to be high and independent on temperature in the range 13–300 K. This is due partly to the lack of back transfer from ytterbium to neodymium. Observed excitation energy transfer from Yb3+ to Er3+ is considerably less efficient because the small rate of multiphonon relaxations from the 4 I 11 2 level of Er3+ favours an efficient back transfer from erbium to ytterbium.