Metal hydride air conditioning of the waste heat of automobile engine coolant driving
Aiming at developing metal hydride air-conditioning system driven by the waste heat of automobile engine coolant, the principle of metal hydride air-conditioning system was introduced and a hydride pair LaNi4.7Al0.3/LaNi5 was developed working at 363 K/303 K/283 K. the working cycle was described in detail. the values of characteristic parameters of the metal hydrides used in the system were also given.
Prediction of transient heat and mass transfer in a closed metal–hydrogen reactor
Abstract The metal–hydrogen reactor is usually composed of a porous medium (hydride bed) and an expansion volume (gaseous phase). During the sorption process, the hydrogen flow and the heat transfer in the expansion part are badly known and can have some effects on the sorption phenomena in the hydride medium. At our knowledge, the hypothesis that neglects those effects is typically used. In this paper, a 2D study of heat and mass transfer has been carried out to investigate the transient transport processes of hydrogen in the two domains of a closed cylindrical reactor. A theoretical model is conducted and solved numerically by the control-volume-based finite element method (CVFEM). The result on temperature and hydride density distribution are presented and discussed. Moreover, this paper discusses in detail the effects of some governing operating conditions, such as dimensions of the expansion volume, height to the radius reactor ratio, and the initial hydrogen to metal atomic ratio, on the evolution of the pressure, fluid flow, temperature and the hydrogen mass desorbed.
Effects of the mineral phase and valence of vanadium on vanadium extraction from stone coal
The influence of roasting on the leaching rate and valence of vanadium was evaluated during vanadium extraction from stone coal. Vanadium in stone coal is hard to be leached and the leaching rate is less than 10% when the raw ore is leached by 4 mol/L H2SO4 at 90°C for 2 h. After the sample is roasted at 900°C for 2 h, the leaching rate of vanadium reaches the maximum, and more than 70% of vanadium can be leached. The crystal of vanadium-bearing mica minerals decomposes and the content of V(V) increases with the rise of roasting temperature from 600 to 900°C, therefore the leaching rate of vanadium increases significantly with the decomposition of the mica minerals. Some new phases, anorthite for example, form when the roasting temperature reaches 1000°C. A part of vanadium may be enwrapped in the sintered materials and newly formed phases, which may impede the oxidation of low valent vanadium and make the leaching rate of vanadium drop dramatically. The leaching rate of vanadium is not only determined by the valence state of vanadium but also controlled by the decomposition of vanadium-bearing minerals and the existence state of vanadium to a large extent.