Synthesis and Structure Determination of the Quaternary Zinc Nitride Halides Zn2NX1−yX′y (X, X′ = Cl, Br, I; 0 < y < 1)
The quaternary series Zn2NCl1−yBry and Zn2NBr1−yIy were synthesized from solid-liquid reactions between zinc nitride and the respective zinc halides in closed ampoules, and the evolution of their crystal structures was investigated by single-crystal and powder X-ray diffraction. Zn2NX1−yX′y (X, X′ = Cl, Br, I) adopts the anti-β-NaFeO2 motif in which each nitride ion is tetrahedrally coordinated by four zinc cations, and the halide anions are located in the voids of the skeleton formed by corner-sharing [NZn4] tetrahedra. While Zn2NCl1−yBry crystallizes in the acentric orthorhombic space group Pna21 (No. 33), isotypic to Zn2NX (X = Cl, Br), the structure of Zn2NBr1−yIy is a function of the iodide concentration, namely, Zn2NBr (Pna21) for low iodine content and Zn2NI (Pnma) for higher (y ≥ 0.38).
A neutron powder diffraction study of the β to γ phase transformation in NaFeO2
Etude de la transformation de phase β, (basse temperature, Pn2 1 a) en γ (haute temperature, PH 1 2 1 2) dans NaFeO 2 par analyse de Rietneld des donnees de diffraction de neutrons, dans le domaine de temperatures compris entre 298 et 1373 K. La transformation comporte des rotations cooperatives des tetraedres FeO 4 , des relocalisations des atomes d'oxygene autour des atomes de sodium, l'augmentation de l'angle Fe-O-Fe et des effets de memoire
Economics of General-Purpose Assembly Robots
Summary A study of the comparative economics of various automatic assembly systems using general-purpose assembly robots is described. In the study, use is made of a “typical” candidate assembly whose profile is obtained from statistical analysis of actual products submitted by interested companies. It is shown that the choice of assembly system and the various parts presentation methods depends on three main factors, namely: the annual production volume per shift, the number of parts in the product and the equipment payback period.