Sm Addition to GdCo and TbFe Films for Magneto-Optical Memory
Introduction In order to improve the magnetic properties of rare earthtransition metal alloys being studied for magneto-optical memory media, we added Sm to GdTbFeCo (a quaternary alloy), to make a quinternary alloy. We already reported that both the Kerr rotation angle and the magnetic anisotropy increase with the addition of Sm [1]. In order to study the origin of these improvements, we added Sm to GdCo and TbFe (each a binary alloy) to make ternary alloys. We then investigated their magnetic and magneto-optical properties.
The thermo-magnetic writing and erasing properties and Kerr rotation angle of amorphous TbFe thin film
The compositional dependences of writing, erasing and reading properties of amorphous TbFe thin film were examined in detail. As a result, there was marked differences between Fe-rich and Tb-rich film. That is, the external magnetic field necessary for writing was generally weaker and less dependent on composition in Tb-rich film and the composition range where erasing could be performed by the field of the same intensity as in writing was wider in Tb-rich side. Kerr rotation angle was measured in two different methods and the scattering values between them were observed in Fe-rich film, while there was no significant difference in Tb-rich film. The origins of these compositional dependence were explained by the differences of temperature dependences of M s and H c besides the compositional dependences of rectangular ratio and M s itself. The effects of the adding third elements to TbFe in Kerr rotation angle and minimum writing laser power were also measured. As a result, it was found, among some elements examined in this study, that Sm had effects of not only decreasing writing power but also increasing Kerr rotation angle in some degree.
Rational Design, Synthesis and Evaluation of γ-CD-Containing Cross-Linked Polyvinyl Alcohol Hydrogel as a Prednisone Delivery Platform
This study describes the in-silico rational design, synthesis and evaluation of cross-linked polyvinyl alcohol hydrogels containing γ-cyclodextrin (γ-CDHSAs) as platforms for the sustained release of prednisone (PDN). Through in-silico studies using semi-empirical quantum mechanical calculations, the effectiveness of 20 dicarboxylic acids to generate a specific cross-linked hydrogel capable of supporting different amounts of γ-cyclodextrin (γ-CD) was evaluated. According to the interaction energies calculated with the in-silico studies, the hydrogel made from PVA cross-linked with succinic acids (SA) was shown to be the best candidate for containing γ-CD. Later, molecular dynamics simulation studies were performed in order to evaluate the intermolecular interactions between PDN and three cross-linked hydrogel formulations with different proportions of γ-CD (2.44%, 4.76% and 9.1%). These three cross-linked hydrogels were synthesized and characterized. The loading and the subsequent release of PDN from the hydrogels were investigated. The in-silico and experimental results showed that the interaction between PDN and γ-CDHSA was mainly produced with the γ-CDs linked to the hydrogels. Thus, the unique structures and properties of γ-CDHSA demonstrated an interesting multiphasic profile that could be utilized as a promising drug carrier for controlled, sustained and localized release of PDN.