Prospects of Mixtures as Working Fluids in Real-Gas Brayton Cycles
This paper discusses the thermodynamic characteristics of the closed Brayton cycles in which the compression is placed near the critical point of the working fluid. Under these conditions, the specific volumes of the fluid during the compression are a fraction of the corresponding values under ideal gas conditions, and the cycle performances improve significantly, mainly at moderate top temperatures. As the heat is discharged at about the critical temperature, the choice of the correct working fluid is strictly correlated with the environmental temperature or with the temperature of potential heat users. To resort to mixtures greatly extend the choice of the right working fluid, allowing a continuous variation of the critical temperature. These cycles have a high power density, and the use of ordinary turbomachinery is accompanied by high capacities (tens of megawatts). In the low power range, microturbines or reciprocating engines are required. One important constraint on the choice of the right working fluid is its thermochemical stability that restricts the operative temperatures. Among the organic compounds, the maximum safe temperatures are limited to about 400 °C and, forecasting high temperature applications, it could be interesting to explore the potentiality of the inorganic compounds as secondary fluids in binary mixtures.
Dinitrogen tetroxide and carbon dioxide mixtures as working fluids in solar tower plants
Abstract The competitiveness of concentrated solar power technology in the near-future electricity generation scenario, requires a substantial reduction of the Levelized Cost of Energy which can be achieved with an increase of the energy conversion efficiencies while maintaining or reducing the investment costs. This paper discusses the use of pure Dinitrogen tetroxide N2O4, and N2O4/CO2 mixture, as working fluids in supercritical Brayton cycles applied to solar tower power plants. When N2O4 is combined with CO2, the resulting mixture has a comparatively higher critical temperature than pure CO2, allowing a condensing cycle even at the fairly high ambient temperatures of desert areas, where solar power plants are typically installed. This allows the adoption of simpler cycle configurations than the one used in sCO2 cycles (cost reduction) while achieving very high thermodynamic efficiency (47% at 700 °C). The N2O4/CO2 mixture with optimized composition, integrated in a solar tower unit, increases the solar-electric efficiency by 1% with respect to commercial plants based on steam cycle with 550 °C maximum temperature (22.3% vs. 21.3%). At 700 °C, the overall solar-electric efficiency can reach 24.5% which is slightly higher than supercritical CO2 cycles, yet with a foreseeable reduction of the investment costs as consequence of the simpler plant lay-out.
Suitability and water quality criteria of an open drainage municipal sewage water at Coimbatore, used for irrigation.
Sanganur canal is the major open drainage system which has intricate linkage with storm water supply, domestic sewage and industrial effluent disposal. Water samples from various stations were collected and analysed for physicochemical parameters to assess the water quality of the Sanganur canal system. The study revealed that physicochemical parameters like pH, EC, TDS, DO, BOD, COD exceeded the permissible limit, clearly indicating the need of proper treatment of waste water before discharge into the Noyyal river.