Wavelength tunability in photoinitiated cationic polymerization
Onium salts, widely used cationic photoinitiators, have absorption in the short wavelength of the UV spectrum. However, their spectral sensitivity can be tuned up to the visible region by using several methods. Photosensitization of onium salts, their charge transfer complex formation and their free radical promotion are some techniques that are used to provide wavelength flexibility. This chapter summarizes these methods. Upon irradiation photosensitizers such as anthracene, perylene and phenothiazine form exciplexes with onium salts generating reactive species via electron transfer. Furthermore, ground state charge transfer formation Correspondence/Reprint request: Dr. Y. Yagci, Istanbul Technical University, Department of Chemistry, Maslak, Istanbul 34469, Turkey. E-mail: yusuf@itu.edu.tr
New aspects on the photoinitiated free radical promoted cationic polymerization
General aspects of the photoinitiated free radical promoted cationic polymerization are discussed. The applicability of pyridinium salts, a new class of photoinitiators, of appropriate redox potential Ered1/2 in oxidizing carbon-centered free radicals to carbocations capable of initiating the polymerization of various compounds is demonstrated. Moreover, the use of polysilanes as source for readily oxidizable free radicals is described. Furthermore, possibilities for preparing block copolymers by free radical promoted cationic polymerization are pointed out.
LABORATORY AND FIELD TESTING OF SEED SPACING UNIFORMITY FOR SUGARBEET PLANTERS
Five planter configurations were evaluated for seed spacing uniformity at three field speeds using a seed 
location method in the field and a laboratory method involving an opto-electronic sensor system. Planter seed spacing 
uniformity was described using the Coefficient of Precision (CP3) measure. Results showed that CP3 measures 
determined using the laboratory test method were significantly different from those determined using the field test method. 
This indicated the laboratory test method cannot be used to predict planter seed spacing uniformity in the field. Seed 
spacing uniformity determined in laboratory tests was higher than, or equal to, seed spacing uniformity determined in 
field tests. This indicated the laboratory test method may be useful to screen out planters or planter units with poor 
uniformity of seed metering. Field testing of the planters that perform well in laboratory tests must be conducted to 
adequately determine the seed spacing uniformity of those planters in the field. Results from laboratory and field tests 
could be useful in determining areas for improvement of planters or planter units.