Effects of stoichiometry on the magnetic and structural properties of perpendicular barium ferrite thin film media
The effects of stoichiometry factor n on the magnetic and structural properties of perpendicular barium ferrite thin films with composition of BaO.n(Fe/sub 2/O/sub 3/) were systematically investigated. Within the range 2.2<n<6, the c-axis for barium ferrite thin films can be oriented perpendicularly by the use of a Pt underlayer and with optimized processing conditions. Perpendicular c-axis orientation becomes worse as n decreases from 6 to 2.2. The average grain size was greatly reduced from about 2000 /spl Aring/ to 300 /spl Aring/ with the decrease of n. The decrease of the grain size can be related to the existence of nonmagnetic phase BaFe/sub 2/O/sub 4/, which was observed by X-ray diffraction.
Influence of technological factors and chemical composition on the thermal stability and electromagnetic properties of M-type hexaferrites
The possibility of increasing the coercive force of barium hexaferrite by the isomorphous substitution of iron oxide with alumina, gallium and scandium oxides, and by impurity doping is shown. The results of the synthesis and study of new a (Me+2Me+4)xMey + 3Fe12–x–yO19 hexagonal ferrites with thermally stable anisotropy field and coercive force are presented. It is shown that doping with metal vapors of Me+2Me+4 = Ni+2Ti+4, Ni+2Ge+4, Ni+2Cu+2Ge+4, Me+3 = Al+3, Cr+3 allows improvement in the reproducibility of the properties and the thermal stability of barium hexaferrite.
Effects of the mineral phase and valence of vanadium on vanadium extraction from stone coal
The influence of roasting on the leaching rate and valence of vanadium was evaluated during vanadium extraction from stone coal. Vanadium in stone coal is hard to be leached and the leaching rate is less than 10% when the raw ore is leached by 4 mol/L H2SO4 at 90°C for 2 h. After the sample is roasted at 900°C for 2 h, the leaching rate of vanadium reaches the maximum, and more than 70% of vanadium can be leached. The crystal of vanadium-bearing mica minerals decomposes and the content of V(V) increases with the rise of roasting temperature from 600 to 900°C, therefore the leaching rate of vanadium increases significantly with the decomposition of the mica minerals. Some new phases, anorthite for example, form when the roasting temperature reaches 1000°C. A part of vanadium may be enwrapped in the sintered materials and newly formed phases, which may impede the oxidation of low valent vanadium and make the leaching rate of vanadium drop dramatically. The leaching rate of vanadium is not only determined by the valence state of vanadium but also controlled by the decomposition of vanadium-bearing minerals and the existence state of vanadium to a large extent.