Molecular Dynamics Simulations of Li Insertion in a Nanocrystalline V 2 O 5 Thin Film Cathode
The behavior of lithium ion diffusion from an electrolyte into a polycrystalline layered cathode has been studied using molecular dynamics computer simulations. Lithium silicate glass was the model solid electrolyte whilethe cathode was a nanocrystalline vanadia with amorphous V 2 O 5 intergranular films (IGF) between the crystals. Nanosized V 2 O 5 crystals were aligned with their (001) planes parallel to electrolyte/cathode interface, rotated 90° from each other around this interface's normal in order to present two different orientations between the crystal planes for lithium intercalation via the amorphous vanadia IGF. A series of nanocrystalline vanadia cathodes with different IGF thicknesses was simulated to examine the effects of the IGF thickness on lithium transport into the cathodes. Results showed preferential diffusion of Li from the electrolyte into the amorphous vanadia IGF, with some of those Li diffusing into the crystalline V 2 O 5 from the IGF. Results also showed easier lithium diffusion from the IGF into the V 2 O 5 crystal along the (010) direction than along the (100) direction. Additionally, an optimum IGF thickness of 2.5-3.0 nm is suggested as being neither too thick to decrease the capacity of the cathode nor too thin to impede the transport of lithium from glassy electrolyte into the cathode.
Molecular dynamics simulations of Li transport between cathode crystals
The molecular dynamics (MD) computer simulation technique has been used to study the effect of an amorphous intergranular film (IGF) present in a polycrystalline cathode on Li transport. The solid electrolyte is a model lithium silicate glass while the cathode is a nanocrystalline vanadia with an amorphous V2O5 IGF separating the crystals. Thin (� 1 to a few nanometer thick) IGFs are known to be present in most polycrystalline oxide materials. However, the role of such a film on Li transport in oxide cathodes has not been addressed. Current scanning probe microscopy (SPM) studies have shown that the orientation of the layered nanocrystalline vanadia crystals near the cathode/solid electrolyte interface is not optimized for Li ion transport. While the precise structure of the material between the crystals has not been identified, initially it can be initially considered as likely to be a thin non-crystalline (amorphous) film. This is based on the ubiquitous presence of such a structure in other polycrystalline oxides. Also, and with more relevance to the materials used in thin film batteries, an amorphous film can be expected to form between nanocrystals that crystallized from an amorphous matrix, as would be the case in a deposited thin film cathode. Consistent with simulations of Li transport in amorphous vanadia, the current simulations show that Li ions diffuse more rapidly into the amorphous intergranular thin film than into the layered vanadia with the (0 0 1) planes parallel to the cathode/electrolyte interface. # 2002 Elsevier Science B.V. All rights reserved.
Introduction and experience with the primary mail services based on their names for students
Kyushu University provided mail service based on student IDs such as "1AB10123X" to the university students for many years. Using this model, we had problems communicating with the students who graduated from the University and enrolled in the graduate school. The students received new mail addresses based on their new student IDs such as "2AB12789Y". Faculty members were forced to change the student mail addresses in the mailing lists and in their mail client address book. Furthermore, students were forced to notify the e-mail address change to all of their existing contacts. We introduced a new mail system to provide addresses based on the student name, as well as student ID in April 2011. The new naming convention uses the following format: lastname.firstname.999 where 999 is a random number of 3 digits. Students can select some combination patterns of their first and last names for Japanese. We also consider the middle names for foreign students. In the system implementation, we did not have the formal information of alphabetical names for students. We generated alphabetical names from Japanese Katakana names. It is not easy for us to get the appropriate name in this manner. We implemented a confirmation stage of the alphabetical name at first use, and then students can select their mail addresses for their convenience. We paid much attention to the user interface in the system. Since April 2011, the number of users who use the mail address based on their own name has been increasing gradually. This paper will detail the usage status of the new system.