The nuclear magnetic moment of "Ir and the directional distribution of gamma rays in "Os
Angular distributions of gamma transitions between levels in I9OOs fed in the decay of I9'Ir aligned in a rhenium single crystal have been measured at temperatures down to 2 mK. Multipole mixing ratios in both gamma and electron-capture transitions are deduced and compared with various nuclear models. The angular distribution coefficients are applied to interpret very small anisotropies observed when I9'Ir is polarised in an iron host matrix, cooled to 2.5 mK. The deduced magnetic dipole moment of the 4 + ground state of I9'Ir is Ip(I9'Ir; GS)~ = 0.04( l)pN. Possible single-particle descriptions compatible with this result are suggested. NUCLEAR MOMENTS: I9'Ir (from Re(a, n)): measured I,(@ from oriented nuclei in single crystal Re and polycrystalline Fe: deduced I9OOs S(E2/M1), Jp in electron capture, lpl(1901r ground state).
Nuclear orientation of 188-189Ir and 189-191Pt
188-189Ir and 189-191Pt have been oriented at low temperature in the hyperfine magnetic field in iron. Precise energy measurements of some high-energy gamma rays in the disintegration of 188Ir have also been performed, resulting in the modification of the high-energy level scheme of 188Os. In the daughter nuclei spins and parities of excited states and multipole mixing ratios of transitions are established. For some non-unique electron-capture transitions jbeta =0/jbeta =1 intensity ratios are also deduced. Results are analysed in terms of mixed p3/2 and f5/2 configurations in the neutron shell.
Identification of Dihydroxy Aromatic Compounds in a Low-Temperature Pyrolysis Coal Tar by Gas Chromatography−Mass Spectrometry (GC−MS) and Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS)
Dihydroxy aromatics in coal tar undergo rapid coupling reactions with each other and with some coal-derived species during coal pyrolysis and liquefaction. However, only limited information on the structure of dihydroxy aromatics is known. In this study, Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) and gas chromatography−mass spectrometry (GC−MS) were used to characterize the dihydroxy aromatics in a low-temperature pyrolyzed coal tar and its distillate and residue fractions. Negative-ion electrospray ionization (ESI) FT-ICR MS spectra of coal-tar-derived samples had low molecular masses and narrow mass ranges. Negative-ion ESI is extremely selective for the dihydroxy aromatics present in coal tar. The O2 class species had the highest ion intensity among the species in the negative-ion FT-ICR mass spectrum for each sample. Dihydroxy compounds with an aromatic core structure of benzene, indan, biphenyl (and/or acenaphthene), and naphthalene were identified in the distillate fract...