The influence of different tempers on the composition of pottery
The modification of the raw clay by the potter to produce a paste suitable for the intended purposes adds a layer of obfuscation to the problem of provenancing the original clay source by chemical fingerprinting. By preparing different pastes from the same commercially available raw clay and their chemical analysis by Instrumental Neutron Activation Analysis, an experiment under controlled conditions (tempers, mixing ratios, firing temperatures and sampling methods) sheds light on the influence of different tempers. The results show that two different sampling procedures (drilling and grinding) have almost no influence on the chemical fingerprint with the exception of the elemental concentrations of As, Zr, and Hf. This may be due to the volatility of the compounds (As) or the presence of zircon crystals (containing Zr and Hf) which are partly lost during drilling. Three different firing temperatures show no significant influence as well. The application of the modified Mahalanobis distance introduced by Beier and Mommsen in 1995 as a statistical filter and the introduction of a ‘dilution factor’ to the raw data show that the influence of quartz-dominated tempers can be filtered out of the data, resolving the underlying chemical fingerprint of the original clay source. At the same time, by mathematically removing the additional spread introduced by dilution, even subtle differences between similar pastes can be resolved by standard multivariate statistical means.
A workflow for neutron activation analysis of archaeological ceramics at the Atominstitut in Vienna, Austria
The main focus for neutron activation analysis (NAA) at the Atominstitut in Vienna has moved to the analysis of archaeological ceramics. The workflow for NAA has been adapted for this material and the elemental spectrum quantified has been expanded for compatibility with international databases. Statistical methods for the grouping of the archaeometric data have been implemented, following the methods applied by Mommsen et al. in Bonn (Archaeometry 30(1):47–57, 1988). Limits of detection specific for ceramics have been calculated and are at the ng/g level. High reproducibility as necessary for archaeometric analysis can be shown by comparative measurements of an internal quality control sample.
"Flying Triangulation" - a new optical 3D sensor enabling the acquisition of surfaces by freehand motion
In order to obtain complete 3D surface information of an object it is often necessary to acquire many partial 3D views. For this purpose, the sensor has to be moved (e.g. for the acquisition of sculptures or rooms). Further, in many cases a motion of the object relative to the sensor is unintended but inevitable (e.g. for medical applications such as intraoral measurements of teeth). Nearly all existing optical 3D sensors either lack an easy handling or require a standstill during the acquisition of a single partial 3D view, since usually multiple camera shots have to be taken for this purpose. This makes such measurements elaborate or even impossible.