Effect of Post Heat Treatment on the Microstructure and Microhardness of Friction Stir Processed NiAl Bronze (NAB) Alloy
NiAl bronze (NAB) alloy is prepared by using friction stir processing (FSP) technique at a tool rotation rate of 1200 rpm and a traverse speed of 150 mm/min. A post heat treatment is performed at the temperature of 675 °C. The effect of heat treatment on the microstructure and microhardness is studied. The results show that the microstructure of the FSP NAB alloy consists of high density dislocations, retained β phase (β′ phase) and recrystallized grains. When annealed at 675 °C, discontinuous static recrystallization (DSRX) takes place. The content of β′ phase gradually decreases and fine κ phase is precipitated. After annealing for 2 h, both the microhardness of the FSP sample in the stir zone (SZ) and the difference in hardness between the SZ and base metal decrease due to the reduction of the dislocation density and β′ phase, accompanying recrystallized grain coarsening. With further increasing of the annealing time to 4 h, the aforementioned difference in hardness nearly disappears.
Studies of the nobility of phases using scanning Kelvin probe microscopy and its relationship to corrosion behaviour of Ni-Al bronze in chloride media
Abstract An as-cast Ni–Al bronze (NAB) was subjected to friction-stir processing. The microstructure, nobility of the phases and corrosion behaviour of the as-cast and friction-stir processed NAB were studied using EPMA, scanning Kelvin probe force microscopy (SKPFM) and SEM, respectively. SKPFM results revealed that the κ phase in the as-cast NAB and the small-sized phases inside β′ in the friction-stir processed NAB exhibited relatively lower nobility. These phases were preferentially corroded in acidic chloride solution but protected in neutral chloride solution. The correlation between the nobility of the phases and the practical corrosion behaviour was also discussed.
InTlP — a proposed infrared detector material
In1−xTlxP is proposed as a promising material for infrared detectors. A number of key optical and structural properties are studied within local density‐functional theory. In1−xTlxP at x=0.67 and In1−xTlxAs at x=0.15 are estimated to have a gap of 0.1 eV. Their binding energies are larger than that of InSb, and they are found to form stable zinc‐blende alloys for all x. In1−xTlxP nearly lattice matches to InP, and offers the potential to integrate detector array and read‐out circuit.