Evaluation of missing pellet surface geometry on cladding stress distribution and magnitude
Abstract Missing pellet surface (MPS) defects are local geometric defects in nuclear fuel pellets that result from pellet mishandling or manufacturing. The presence of MPS defects can cause significant clad stress concentrations that can lead to through-wall cladding failure for certain combinations of fuel burnup, and reactor power level or power change. Consequently, the impact of MPS defects has limited the rate of power increase, or ramp rate, in both pressurized and boiling water reactors (PWRs and BWRs, respectively). Improved three-dimensional (3-D) fuel performance models of MPS defect geometry can provide better understanding of the probability for pellet clad mechanical interaction (PCMI), and correspondingly the available margin against cladding failure by stress corrosion cracking (SCC). The Consortium of Advanced Simulations of Light Water Reactors (CASL) has been developing the Bison-CASL fuel performance code to consider the inherently multi-physics and multi-dimensional mechanisms that control fuel behavior, including cladding stress concentrations resulting from MPS defects. This paper evaluates the cladding hoop stress distributions as a function of MPS defect geometry with discrete pellet radial cracks for a set of typical operating conditions in a PWR fuel rod. The results provide a first step toward a probabilistic approach to assess cladding failure during power maneuvers. This analysis provides insight into how varying pellet defect geometries affect the distribution of the cladding stress, as well as the temperature distributions within the fuel and clad; and are used to develop stress concentration factors for comparing 2-D and 3-D models.
Multi-Dimensional Simulation of LWR Fuel Behavior in the BISON Fuel Performance Code
Nuclear fuel operates in an extreme environment that induces complex multiphysics phenomena occurring over distances ranging from inter-atomic spacing to meters, and times scales ranging from microseconds to years. To simulate this behavior requires a wide variety of material models that are often complex and nonlinear. The recently developed BISON code represents a powerful fuel performance simulation tool based on its material and physical behavior capabilities, finite-element versatility of spatial representation, and use of parallel computing. The code can operate in full three dimensional (3D) mode, as well as in reduced two dimensional (2D) modes, e.g., axisymmetric radial-axial (R-Z) or plane radial-circumferential (R-θ), to suit the application and to allow treatment of global and local effects. A BISON case study was used to illustrate analysis of Pellet Clad Mechanical Interaction failures from manufacturing defects using combined 2D and 3D analyses. The analysis involved commercial fuel rods and demonstrated successful computation of metrics of interest to fuel failures, including cladding peak hoop stress and strain energy density. In comparison with a failure threshold derived from power ramp tests, results corroborate industry analyses of the root cause of the pellet-clad interaction failures and illustrate the importance of modeling 3D local effects around fuel pellet defects, which can produce complex effects including cold spots in the cladding, stress concentrations, and hot spots in the fuel that can lead to enhanced cladding degradation such as hydriding, oxidation, CRUD formation, and stress corrosion cracking.
A bifunctional Cr/Yb/Tm:Ca3Ga2Ge3O12 phosphor with near-infrared long-lasting phosphorescence and upconversion luminescence.
Currently, upconversion nanocrystals and long-lasting phosphorescent particles have attracted extensive research interest for their possible applications as bioimaging probes. However, there are few reports concerning the achievement of both upconversion luminescence of lanthanide ions and long-lasting phosphorescence of transition metal ions in a sole host so far. Herein, we demonstrate a novel calcium gallium germanium garnet (Ca3Ga2Ge3O12) host where lanthanide ions such as Tm(3+)/Yb(3+) and transition metal ions such as Cr(3+) can be easily incorporated through substituting the Ca(2+) and Ga(3+) respectively. This Cr/Yb/Tm:Ca3Ga2Ge3O12 phosphor exhibits both broadband near-infrared long-lasting phosphorescence of Cr(3+) with an afterglow time of more than 7000 s and near-infrared to near-infrared upconversion luminescence of Tm(3+). Impressively, it is evidenced that the addition of Yb(3+)/Tm(3+) into Cr:Ca3Ga2Ge3O12 not only results in Tm(3+) upconversion luminescence but also greatly increases Cr(3+) afterglow time. Based on excitation/emission, three-dimensional thermoluminescence, and time-resolved luminescence spectra, the related long-lasting phosphorescence and upconversion luminescent mechanisms are systematically discussed as well.