Regeneration Of Diesel Particulate Filters With Hydrogen Rich Gas
The options for the regeneration of a Diesel Particulate Filter (DPF) using hydrogen rich gas are investigated. The advantages of using hydrogen rich gas for this purpose are described. The system requirements for such a system are also evaluated. The use of a plasmatron fuel converter for the onboard generation of hydrogen rich gas from diesel fuel is discussed. The advantages of homogeneous, non-catalytic reforming by the plasmatron fuel converter are described. Finally, the effect of homogeneous combustion of the hydrogen rich gas in the exhaust (upstream from the DPF) is investigated.
Visualization of Combustion Phenomena in Regeneration of Diesel Particulate Filter
Combustion phenomena in the regeneration of a diesel particulate filter (DPF) were clarified through a visualization experiment, using a half-cylindrical wall-flow DPF covered by a quartz glass plate. At a constant oxygen concentration (8.5% and 10% in the current study) of a working gas used for regeneration, in the cases of large particulate masses and high working gas temperatures, the particulate matter trapped on the filter surface is burned in a narrow reaction zone which can be observed as a high brightness zone moving slowly toward the downstream side. Just after the reaction zone passes, a sharp temperature peak is detected and there remains no particulate matter on the filter surface. Furthermore, the particulate matter is ignited first around the middle of the DPF, and then, the reaction zone propagates toward both the upstream and the downstream sides. On the other hand, in cases of small particulate masses and/or low working gas temperatures (but higher than 600°C), no such bright reaction zone is seen; however, it was observed that with time the particulate matter disappeared uniformly on the entire filter surface. These regeneration patterns can be summarized as separate and distinct reaction patterns in a reaction diagram consisting of the particulate mass and the inlet temperature of the working gas.
Lupin alkaloids from teratogenic and nonteratogenic lupins. II. Identification of the major alkaloids by tandem gas chromatography-mass spectrometry in plants producing crooked calf disease.
The major alkaloids of lupin plants producing crooked calf disease were identified by tandem gas chromatography-mass spectrometry and infrared analysis. The gas chromatography peak invariably present in teratogenic plants proved to be anagyrine. A minor but irregular contaminant of the peak was α-isolupanine. Other alkaloids present but apparently not associated with crooked calf disease were lupanine and two others that were probably epimethoxylupanine and 5,6-dehydrolupanine.