Giant magneto-impedance in heterogeneous microwires
Recent results concerning the giant magneto-impedance effect, GMI, in magnetic microwires having diameter in the range of a few micrometers and heterogeneous character are introduced in this work. Two types of microwires have been studied, namely, (i) magnetic microwires covered by insulating Pyrex glass coating and (ii) copper wires covered by electrodeposited magnetic microtubes. The magnetic anisotropy distribution in each type of microwire is correlated with giant magneto-impedance. While the main source of anisotropy in glass coated microwires is of magnetoelastic origin created by the stresses induced during quenching and by the coating, in the case of the microtubes the origin is the columnar growth during the electrodeposition. The influence on GMI of various treatments that modify the anisotropy is analyzed. Heterogeneous microwires with different thicknesses of insulating coating and of magnetic tube are analyzed.
Magnetic anisotropy of electrodeposited Co--P amorphous alloys
The development of magnetic anisotropy with regard to thickness in amorphous electrolytic Co-P alloys (15 at % P) has been observed in the range of thicknesses between 0.06-7.00μm. The study has been undertaken starting from the ratio M r /M s of the hysteresis loops. The results obtained indicate that for thicknesses below 4000 A the samples show an axis of easy magnetization in the plane. In the case of greater thicknesses, the axis of easy magnetization develops gradually out of the plane, reaching a perpendicular position near 10 μm. Our results suggest that what we are dealing with here is a shape anisotropy such as that proposed by Cargill, III et al.
Measuring Sheet Resistances of Dielectrics Using Co‐Planar Hydrogel Electrochemical Cells with Practical Applications to Characterize the Protective Quality of Paints on Sculptures
Electrical properties of thin dielectric films at the solid-liquid phase boundary are an important performance characteristic of many devices, coatings and sensors. In this paper, co-polymeric hydrogels of polyacrylic acid co-sulfonic acid, swollen with a salt solution to act as the solid electrolyte, were used to assess interfaces using electrochemical impedance spectroscopy (EIS) in a co-planar geometry. Silane-modified glasses were characterized by the co-planar hydrogel EIS cell and found to be distinguishable based on their surface monolayer chemistry. EIS measurements were also made on primed and painted metal substrates, using both test panels and an outdoor sculpture, Tony Smith's Stinger. The panels were then exposed to accelerated and outdoor weathering and showed degradation on the surface paint layers, which was observable electrochemically using EIS and confirmed visually by SEM. Electrochemical spectral features were compared between data from a standard paint-test cell versus this co-planar hydrogel cell; both cell types were able to measure coating capacitance, providing useful information about the condition of the bulk coating. Yet, sheet resistance (Rs) was a spectral feature seen only by the co-planar hydrogel cell. Thus, it can be concluded that the use of such co-planar hydrogel cells can provide an earlier warning sign to coating degradation and such cells provide a new type of spectral information that is not assessable by the standard geometry.