Spectroscopy of gadolinium gallium garnet crystals doped with Y b3 + revisited
The optical spectroscopy measurements of gadolinium gallium garnet (GGG) crystals doped with Yb show evidence of the presence of non-equivalent optical centers with very similar radiative decay rates. The energy level schemes of those centers have been determined on the basis of optical absorption, luminescence and Raman experiments. Crystal field fitting resulted in two sets of slightly different crystal field parameters for two non-equivalent Yb centers. Both sets of parameters describe perfectly the experimentally detected Y b3 + energy levels. Correlation between systematic trends in the experimental energy level schemes and crystal field parameters is discussed.
Spectroscopic peculiarities of excitation and emission processes as well as relaxation dynamic of excited states in doubly and triply doped Gd3Ga3Al2O12:Ln3+ (Ln3+=Eu3+, Tb3+, Ce3+) crystals
Abstract Spectroscopic properties of Gd3Ga3Al2O12 (GGAG) single crystals co-doped with various configurations of (Eu + Tb); (Eu + Ce); (Tb + Ce) and (Eu+ Tb + Ce) ions have been investigated. The effect of distinct Ln3+ co-doping variations on luminescence of garnet crystals was studied using the different excitation wavelengths. The Ln3+-Ln3+ and host-Ln3+ interplays have been considered in doubly and triply doped GGAG:Ln3+. The crystals containing cerium ions are characterized by mainly broadband emission in the 450–750 nm spectral region that is adequately modified in green and red spectral range in the samples co-doped with terbium and europium, respectively. The Eu3+ luminescence in materials under study is selectively excited employing solely f-f europium transitions. Contrary to that, emission of terbium and cerium occur as result of interaction with Gd3+ and adjacent co-dopants.
Measurement and Demonstration of Thermal Expansion Coefficient
There are many classroom demonstrations, such as the ball-and-ring experiment, for showing the existence of thermal expansion of solids. The coefficient of linear expansion α (= increase in length divided by the original length times the change in temperature) may be measured in high school laboratories using a number of methods.1–4 In this paper we describe an especially simple experiment for determining α for a metal rod. It is based on the well-known optical lever method and is suitable for either a laboratory experiment or a classroom exercise.