Oxidation and the Effects of High Temperature Exposures on Notched Fatigue Life of an Advanced Powder Metallurgy Disk Superalloy
Oxidation and the effects of high temperature exposures on notched fatigue life were considered for a powder metallurgy processed supersolvus heat-treated ME3 disk superalloy. The isothermal static oxidation response at 704 C, 760 C, and 815 C was consistent with other chromia forming nickel-based superalloys: a TiO2-Cr2O3 external oxide formed with a branched Al2O3 internal subscale that extended into a recrystallized - dissolution layer. These surface changes can potentially impact disk durability, making layer growth rates important. Growth of the external scales and dissolution layers followed a cubic rate law, while Al2O3 subscales followed a parabolic rate law. Cr- rich M23C6 carbides at the grain boundaries dissolved to help sustain Cr2O3 growth to depths about 12 times thicker than the scale. The effect of prior exposures was examined through notched low cycle fatigue tests performed to failure in air at 704 C. Prior exposures led to pronounced debits of up to 99 % in fatigue life, where fatigue life decreased inversely with exposure time. Exposures that produced roughly equivalent 1 m thick external scales at the various isotherms showed statistically equivalent fatigue lives, establishing that surface damage drives fatigue debit, not exposure temperature. Fractographic evaluation indicated the failure mode for the pre-exposed specimens involved surface crack initiations that shifted with exposure from predominately single intergranular initiations with transgranular propagation to multi-initiations from the cracked external oxide with intergranular propagation. Weakened grain boundaries at the surface resulting from the M23C6 carbide dissolution are partially responsible for the intergranular cracking. Removing the scale and subscale while leaving a layer where M23C6 carbides were dissolved did not lead to a significant fatigue life improvement, however, also removing the M23C6 carbide dissolution layer led to nearly full recovery of life, with a transgranular initiation typical to that observed in unexposed specimens.
Interfacial reactions of a MAX phase/superalloy hybrid
Oxidation resistant, strain tolerant MAX phase coatings are of general interest for high temperature applications. Accordingly, Cr2AlC MAX phase coupons were vacuum diffusion bonded to an advanced turbine disk alloy at 1100 °C for compatibility studies. The interface revealed an inner diffusion zone consisting of ~10 µm of β‐Ni(Co)Al, decorated with various γ′ (Ni,Co)3Al, Ta(Ti,Nb)C, and W(Cr,Mo)3B2 precipitates. On the Cr2AlC side, an additional ~40‐µm Al‐depletion zone of Cr7C3 formed an interconnected network with the β‐Ni(Co)Al. On the superalloy side, enhanced carbide precipitation developed over a depth of ~80 µm. Subsequent annealing for 100 h and 1000 h at 800 °C coarsened some features, enhanced TCP precipitation in the superalloy, but only enlarged the diffusion layers by ~5 µm at most. Because of Al depletion from the MAX phase and corresponding Al enrichment of the alloy, the reaction zone displayed similarities to an oxidized Cr2AlC surface and an aluminized superalloy, respectively. Published 2015. This article is a U.S. Government work and is in the public domain in the USA.
Assessment of fractures in endodontically treated teeth restored with and without root canal posts using high-resolution cone beam computed tomography
Background Root fractures are a diagnostic challenge for dentists in endodontic treatment. This study aimed to determine the relationship between the characteristics of tooth fractures and the presence of root canal posts in endodontically treated teeth using high-resolution cone beam computed tomography (CBCT). Material and Methods Fifty high-resolution CBCT scans of endodontically treated teeth with a diagnosis of fracture were obtained, of which 30 were from women and 20 were from men. These scans were acquired with three Veraviewepocs 3D units and one 3D Accuitomo 170 unit, with a 40 × 40-mm field of view and 125 μm voxel size. The variables assessed included the type of fracture, extent of fracture, type of retention, post length, cause of endodontic failure, location of the lesion, and time required to detect the fracture (difficulty score). For data analysis, the chi-squared test, Student’s t-test, and multiple linear regression (α <0.05) were used. Results No association was found between the type of fracture and type of retention or between the type of fracture and its extent (P>0.05). On the other hand, the type of fracture significantly influenced the time required for its detection. Additionally, the most difficult plane for detecting the fracture and the difficulty score were associated, with statistically significant results. Conclusions The type of fracture in endodontically treated teeth was not associated with the type of post used for restoration. All of the CBCT systems used to detect tooth fracture showed the same efficiency. Key words:Cone-Beam CT, Tooth Fracture, Root Canal Post.