Cadmium telluride nanofilms application in carbon monoxide detection
The research is centered on CdTe nanofilms. The article is aimed at developing innovative primary transducer nanoscale material for semi-conductor sensors, investigating their surface physicochemical properties and evaluation their applicability in carbon monoxide diagnostics. Cadmium telluride nanofilms were obtained by discrete thermal evaporation in vacuum. CdTe nanofilms applicability in gas analysis was investigated. Adsorption properties of the given material for carbon oxide (II) and oxygen were studied by the piezoquartz microweighing. The principles of adsorption, depending on the process conditions and the test sample habitus, were established. Based on the obtained experimental data, CO micro-impurities sensors were developed, the laboratory tests passed successfully.
Adsorption of gases on binary and multicomponent semiconductors of the ZnSe-CdTe system
Adsorption of carbon monoxide(II) and oxygen on powders and nanofilms of solid solutions and binary compounds of the ZnSe-CdTe system was studied volumetrically, and by piezoquartz microweighing and IR spectroscopy of multiple disturbed complete internal reflections. The mechanisms and principles of adsorption were established in dependence on the conditions of the habitus of an experimental sample and the composition of the system’s semiconductors, based on an analysis of IR spectra; the thermodynamic and kinetic characteristics of adsorption; experimental dependences αp = f(T), αT = f(P), and αT = f(t); and the acid-base and other physicochemical characteristics of adsorbents and the electron nature of adsorbate molecules. Conclusions drawn earlier as to the retention of local active centers on the surface of a diamond-like semiconductor (which are responsible for adsorption and catalytic processes) upon a change in the habitus of a sample were confirmed. Certain features in the behavior of solid solutions (ZnSe)x(CdTe)1 − x were revealed alongside commonalities with binary compounds (ZnSe, CdTe), testifying to the presence of critical points on “adsorption characteristics-composition” diagrams. The most active adsorbents (with respect to CO and O2) were discovered on the basis of these diagrams, which were used in creating highly sensitive and selective sensors.
SR topography of plastically deformed Fe-Si bicrystals - observation in situ and post mortem
SR reflection topography was applied to study the interaction of slip dislocations with the grain boundaries in Fe-4at%Si bicrystals deformed by compression. Three experimental settings with either a white or monochromatic beam were used and the corresponding orientation contrast analysed. Dislocation transmission through the grain boundary was observed in bicrystals with favourable geometry of the slip systems.