A Polymer Visualization System with Accurate Heating and Cooling Control and High-Speed Imaging
A visualization system to observe crystal and bubble formation in polymers under high temperature and pressure has been developed. Using this system, polymer can be subjected to a programmable thermal treatment to simulate the process in high pressure differential scanning calorimetry (HPDSC). With a high-temperature/high-pressure view-cell unit, this system enables in situ observation of crystal formation in semi-crystalline polymers to complement thermal analyses with HPDSC. The high-speed recording capability of the camera not only allows detailed recording of crystal formation, it also enables in situ capture of plastic foaming processes with a high temporal resolution. To demonstrate the system’s capability, crystal formation and foaming processes of polypropylene/carbon dioxide systems were examined. It was observed that crystals nucleated and grew into spherulites, and they grew at faster rates as temperature decreased. This observation agrees with the crystallinity measurement obtained with the HPDSC. Cell nucleation first occurred at crystals’ boundaries due to CO2 exclusion from crystal growth fronts. Subsequently, cells were nucleated around the existing ones due to tensile stresses generated in the constrained amorphous regions between networks of crystals.
Mechanism of extensional stress-induced cell formation in polymeric foaming processes with the presence of nucleating agents
Abstract Addition of nucleating agents (e.g., talc) is a common way to promote the cell density in polymeric foaming process. It is widely believed that such enhancement is caused by the decrease in free energy barrier for the nucleation to initiate heterogeneously as well as the reduction in gas loss with the existence of the inorganic fillers. In this paper, in situ visualization of the cell formation phenomena during polymeric foaming processes of polystyrene–talc composites blown with carbon dioxide revealed that the expansion of nucleated cells triggered the formation of secondary cells around them. Subsequently, the expansion of the secondary cells also promoted the formation of tertiary cells around them similar to a chain reaction. These observations provided evidences to support the theoretical simulation of stress-induced cell formation around expanding bubbles. A series of parametric studies were conducted to correlate the stress-induced cell formation and various processing and material parameters. The elucidation of the aforementioned cell formation mechanism with the presence of nucleating agents would provide additional guidelines for polymeric foam manufacturers to control the cell morphologies of their products in order to optimize and tailor the desired physical properties.
Livestock Aspects of Feed Grain Policy
It is a signal event that our topic should be included on this program. In recent years, the livestock and poultry economy has scarcely been considered in the making of price and income policy for feed grains. It has been disregarded by pragmatic policy makers. It has been almost equally bypassed by theoretical economists, who usually kibitz freely. Policy for support and target prices for corn, grain sorghums, and other feed grains has been made with an eye almost exclusively fixed on the producers of those crops. The target price has been set relatively high in order to protect crop farmers' income. The latest (and current) loan rate policy has been to hold the rate low. Although a low rate facilitates moving grain into livestock and poultry consumption when crops are abundant, it does nothing to provide buffer stocks for years when crops are short. In addition, a couple of years ago it became administrative policy to dispose of the stocks inherited from an earlier period, even subsidizing their sale abroad. But the foremost example of one-sidedness is the attitude toward release prices. In all the rhetoric heard recently about the peril of holding corn or sorghums in reserve, the scold has been that release prices would not be set high enough. What group can the spokesmen have had in mind? Feed producers, of course! Not feed consumers, that is, livestock and poultry men. It has been a one-sided consideration of a two-sided issue. If all groups are to have equal voice in policy making, how can livestock and poultry interests be so ostracized? The one-sidedness has more impact now that so much livestock and poultry production has become detached from feed supply on individual farms. The livestock-poultry economy is therefore more sensitive to the availability and price of feed. It is in fact a contradiction that historically, livestock and poultry got more attention when they were still closely connected with feed production on the farm. In the early years of farm programs, the "ever-normal granary" was consciously designed to level out the supply and price of feed for livestock and poultry. Now that livestock and poultry have become more commercial and more vulnerable to a volatile feed situation, feed price stabilization has been progressively removed from the councils of farm policy. And the ultimate contradiction is that the alleged price-depressing perils of a feed reserve have been proclaimed in disregard of the fact that the main defense of feed grain producers' incomes is the target price-direct payment mechanism, not support prices. If grains on reserve should cause market prices to be reduced below target level, producers would get bigger direct payments, that is, producers with a base on their farm are protected in that way. Admittedly, production outside such a base would not be eligible for payment.