Measuring Thermal Crystallinity in PET
The mechanical properties of poly (ethylene terephthalate) (PET) depend on the degree of crystallinity. PET crystallizes from both thermal and strain-induced process paths. Strain-induced crystallization occurs under uniaxial or biaxial stretching, the latter is common in stretch blow molding. Thermal crystallization takes place when cooling from the melt or under sustained elevated temperature which are both common during injection and blow molding. The current work focuses on comparing methods used to quantify the percent thermal crystallinity in injection molded water bottle preforms. An injection molded preform with a gradient of induced thermal crystallinity was examined using Differential Scanning Calorimetry (DSC), Micro X-ray Diffraction (μXRD), and Raman Spectroscopy. Correlating these three techniques for percent thermal crystallinity, helps with the development of nondestructive crystallinity measurement methods to aid with process optimization and part quality.
Crystallization of Polyethyleneterephthalate
Abstract Polyethyleneterephthalate (PET) is a versatile engineering plastic with excellent thermal and chemical resistance and mechanical performance. It is extensively used as fibers for apparel, films for packaging, in bottles for beverages, and also in engineering components. Because of the high melting point (ca. 255°C) and glass transition temperature (ca. 7O°C), PET retains its good mechanical properties at temperatures up to 175°C. It is a semi-crystalline polymer composed of crystalline and amorphous regions. A great variety of microstructures can be developed in PET by changing the crystallization conditions. The crystallite size and shape, volume fraction, orientation, and perfection can be varied through control of crystallization process. Study of the crystallization process and the microstructure devel-opment is intriguing and provides deeper insight into the effect of process parameters on the structure development and ultimately the properties of the end product.
Global Islamic Politics
1. Introduction to Islam and Islamic Revivals. 2. Islam: A Vehicle for Political Action. 3. The Muslim Fundamentalists. 4. The Muslim Traditionalists. 5. The Muslim Modernists. 6. The Muslim Pragmatists. 7. Failure of Secular Ideologies and Developmental Crises. 8. Islamic Revivalism in the Arab-Israeli Context. 9. OPEC, OIC, and Islamic Politics. 10. The Islamic Revolution in Iran. 11. Islamic Revival in Central Asia. 12. Conclusion. Glossary of Islamic Terms.