Some recent research results and their implications for RPV irradiation surveillance under long term operation
During the last decade the irradiation behaviour of characteristic RPV steels used in Pressurized Water Reactors has been extensively investigated in the international research programs CARISMA, CARINA and LONGLIFE. Whereas the CARISMA and CARINA programs were mainly focused on material testing of German RPV steels and data base applications by the RTNDT and Master Curve concepts, the main emphasis of the LONGLIFE project was placed on microstructural examinations of a wide range of RPV steels used in European NPP. Atom Probe Tomography, Small Angle Neutron Scattering, Transmission Electron Microscopy and others belonged to the techniques applied. Four of those RPV steels which are particularly interesting under the point of view of long term irradiation behavior have been studied at different irradiation levels up to 8×10 n/cm (E > 1 MeV) in all three research programs. In this way it was possible to get a comprehensive understanding of the material behavior induced by neutron irradiation and the responsible mechanisms behind. By means of the material properties and microstructural data obtained, in particular the impact of chemical composition (copper and nickel), and neutron flux on the material’s fracture toughness was quantified. Moreover, the most important mechanisms such as formation of element specific precipitations, segregations, and matrix defects could be demonstrated in relation to the change of material properties. For one material the occurrence of late irradiation effects has been observed in both material properties and microstructural appearance. All the available data are discussed thoroughly by consulting the relevant literature in the light of the practical implications they have for RPV irradiation surveillance under long term operation of 60 years and beyond. Specific issues like material specific application of reference temperature concepts, data scattering, prediction of high fluence behavior and use of material test reactor data are addressed. Finally, based on the results obtained by the research programs concerned, best practices for RPV irradiation surveillance programs are suggested and exemplified by industrial experience and adopted measures already in use.
Dislocation spreading and ductile–to-brittle transition in post-irradiated ferritic grains: Investigation of grain size and grain orientation effect by means of 3D dislocation dynamics simulations
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Submicron polymer structures with X-ray lithography and hot embossing
This article describes the process chain for replication of submicron structures with varying aspect ratios (AR) up to 6 in polymethylmethacrylate (PMMA) by hot embossing to show the capability of the entire LIGA process to fabricate structures with these dimensions. Therefore a 4.7 μm thick layer of MicroChem 950k PMMA A11 resist was spin-coated on a 2.3 μm Ti/TiOx membrane. It was patterned with X-ray lithography at the electron storage ring ANKA (2.5 GeV and λc ≈ 0.4 nm) at a dose of 4 kJ/cm3 using a Si3N4 membrane mask with 2 μm thick gold-absorbers. The samples were developed in GG/BDG and resulted in AR of 6–14. Subsequent nickel plating at 52°C resulted in a 200 μm thick nickel tool of 100 mm diameter, which was used to replicate slit-nozzles and columns in PMMA. Closely packed submicron cavities with AR 6 in the nickel shim were filled to 60% during hot embossing.