Early Diagenetic Silica Deposition in Algal Cysts and Spores: A Source of Sand in Black Shales?
ABSTRACT Devonian black shales deposited on the North American craton contain abundant Tasmanites cysts. Although these are typically flattened because of compaction, a small proportion are filled with diagenetic silica. The latter are spherical to ellipsoidal (0.1-0.5 mm), and filled with chalcedony, microquartz and megaquartz, and single quartz crystals. Chalcedonic cyst fillings are preserved best in cheat and phosphate nodules, whereas megaquartz and single quartz crystals are most common in shale matrix. Together with colloform textures, this suggests that the various silica types originated from recrystallization of early diagenetic silica deposits. Thin sandstone beds in the Chattanooga Shale (e.g., Bransford Sandstone) contain abundant quartz sand that is much coarser than the detrital quartz component of the underlying black shales. Because of this, their quartz component is thought to have been transported over considerable distances from the basin margin. However, because certain shale horizons contain as much as 10% silicified cysts that upon reworking could have yielded quartz grains of fine to coarse sand size, the quartz component of these sandstone beds may actually have formed in situ. Indeed, petrographic examination of the sandstone beds shows them to contain quartz grains with morphological and textural features of "cyst" quartz (e.g., rounding, sphericity, chalcedony, pyrite inclusions, lobate grain margins). Thus, silica deposition in algal cysts may provide a significant component of intrabasinal quartz sand in shale sequences. Distinction of this type of quartz from extrabasinal detrital quartz is important to the reconstruction of the depositional history of shale sequences.
Eocene Diatom Chert From Adak Island, Alaska
ABSTRACT Bedded quartz cherts that contain recognizable diatoms are rare in the geologic record and are described here for the first time. The Eocene Andrew Lake Formation on Adak Island, Alaska consists of about 800 m of sedimentary and volcanogenic rocks. Quartz cherts containing diatoms occur in the upper part of the Andrew Lake Formation and crop out on the northern part of the island. The quartz chert formed at about 70°C as determined by its oxygen isotopic composition. The diatoms were preserved in the chert because early and rapid alteration of ubiquitous volcanic glass in the section released silica and saturated the pore waters with respect to opal-A. Then, temperature rapidly increased with burial and the pore waters became undersaturated with respect to opal-A (biogenic silica) which occurred at a temperature greater than that needed to convert opal-CT to quartz. At this stage, delicate species of diatoms dissolved and quartz precipitated around the remaining more robust diatoms, forming diatom theft. Subsequently, grain-growth occurred and quartz replaced the frustules on a very fine scale.
A First-Order Inquisitive Semantics
Chapter 4 defines an inquisitive semantics for the language of firstorder logic, which includes the logical connectives (conjunction, disjunction, negation, and implication) as well as universal and existential quantifiers.The semantics of these connectives and quantifiers is given in terms of the algebraic operations on propositions identified in the previous chapter. The main features of the system are highlighted, and illustrated with a range of examples. In Chapters 5–10, a number of linguistic applications of this logical framework are discussed.