Modelling of viscous effects in natural clays
A new approach to allow the modelling of the viscous behaviour of natural clay soils, including creep, stress relaxation and the effects of applied strain rate on soil stiffness, has been developed based on the BRICK constitutive model (published by Simpson in 1992). The new model, "strain rate-dependent" (SRD) BRICK, was used in a series of simulations to demonstrate its capabilities in predicting realistic behaviour during one-dimensional compression and undrained triaxial tests in which applied strain rates were varied. Triaxial stress path tests conducted by Gasparre et al. in 2007 to assess the influence of creep, resulting from recent stress history, on soil stiffness were also simulated. The observed trends concerning the stiffness at small strains were successfully modelled.
Modelling Viscous Effects during and after Construction in London Clay
A new approach to allow the modelling of the viscous behaviour of clay soils has recently been developed (Clarke & Hird, 2012) based on the BRICK constitutive model (Simpson, 1992). In this approach viscous effects, such as creep and stress relaxation, and the effects of strain history on soil stiffness are modelled within a single conceptual framework. The developed model, SRD (strain-rate dependent) BRICK, has been incorporated in a finite element program, allowing boundary value problems to be analysed. In this paper two case histories involving London Clay, where viscous effects possibly had an influence on the observed displacements, are back-analysed. These cases are the Jubilee Line extension at St James's Park (Standing et al., 1996, Nyren et al., 2001) and a deep basement at Horseferry Road (May, 1975, Chapman, 1999). The results of the numerical modelling show that, in each case, the SRD BRICK model is able to achieve closer agreement with the recorded displacements when compared with the un-modified BRICK model.
Evaluation of CuAl2O4 as an Oxygen Carrier in Chemical-Looping Combustion
The chemical-looping combustion (CLC) process is a novel solution for efficient combustion with intrinsic separation of carbon dioxide. The process uses a metal oxide as an oxygen carrier to transfer oxygen from an air to a fuel reactor where the fuel, or gasification products of the fuel, reacts with the solid oxygen carrier. In this work, copper(II) aluminate (CuAl2O4) was assessed as a potential oxygen carrier using methane as fuel. The carrier particles were produced by freeze–granulation and calcined at 1050 °C for a duration of 6 h. The chemical-looping characteristics were evaluated in a laboratory-scale fluidized-bed reactor in the temperature range of 900–950 °C during 45 alternating redox cycles. The oxygen carrier exhibited reproducible and stable reactivity behavior in this temperature range. Neither agglomeration nor defluidization was noticed in any of the cycles carried out at 900–925 °C. However, after reactivity tests at 950 °C, soft agglomeration and particle fragmentation were observed. Systematic phase analysis of the Cu–Al–O system during the redox cycle was carried out as a function of duration of reduction and oxygen concentration during the oxidation period. It was found that the CuAl2O4 is reduced to copper(I) aluminate (CuAlO2; delafossite), Cu2O, and elemental Cu. The CuAlO2 phase is characterized by slow kinetics for oxidation into CuO and CuAl2O4. Despite this kinetic limitation, complete conversion of methane with reproducible reactivity of the oxygen carrier is achieved. Thus, CuAl2O4 could be a potential oxygen carrier for chemical-looping combustion.