Monoterpenoids from Acanthopanax sessiliflorus Fruits
Three new acyclic monoterpenoids named (2E)-3,7-dimethylocta-2,6-dienoate-6-O-α-l-arabinopyranosyl-(1→6)-β-d-glucopyranoside (1), (3Z,6E)-3,7-dimethyl-3,6-octadiene-1,2,8-triol (2) and (6E)-7-methyl-3-methylene-6-octene-1,2,8-triol (3) were isolated from Acanthopanax sessiliflorus fruits, along with three known monoterpenoid compounds. The structures of the new compounds were determined by means of extensive spectroscopic analysis (1D, 2D NMR and HRESIMS) and chemical methods.
Bioactive constituents from Chinese natural medicines. XXVIII. Chemical structures of acyclic alcohol glycosides from the roots of Rhodiola crenulata.
Five new glycosides, creosides I, II, III, IV, and V, were isolated from the methanolic extract of the roots of Rhodiola crenulata, together with 21 known compounds. The chemical structures of new constituents were elucidated on the basis of chemical and physicochemical evidence.
Design of reinforced concrete lining in pressure tunnels, considering thermal effects and jointed rockmass
Abstract Jaeger's theory (Jaeger, Rock Mechanics and Rock Engineering , Cambridge University Press, 1972) of the design of the lining for a pressure tunnel applies to a tunnel located in an isotropic, homogeneous and elastic medium. The theory is derived from the elasticity equations for the plane stress condition. In this paper, Jaeger's theory is extended to a plane strain situation. Also included is a discussion of the effects of a uniform increase (or decrease) in the lining temperature, jointed rockmass, cracking of the tunnel lining, and cracking of the rockmass around the opening. Tables are presented for the modulus of subgrade reaction for various rockmass conditions and for rock sharing pressures for various lining conditions. The reduction factor to include the effect of joints in rockmass is derived by the analysis of a numerical model of the lined tunnel by the finite-infinite-interface element method.