Properties of PAN Fibers Solution Spun into a Chilled Coagulation Bath at High Solvent Compositions
In this work, multifilament, continuous polyacrylonitrile (PAN) fiber tow was solution spun mimicking industrial processing at the small pilot scale (0.5 k tow), while carefully altering the composition of the coagulation bath, in order to determine the effect on the resulting fiber shape, density, orientation, and tensile properties at varying points in the spinning process. Novel here are the abnormally high coagulation bath solvent compositions investigated, which surpass those often reported in the literature. In addition, the coagulation bath was maintained at a slightly chilled temperature, contrary to reported methods to produce round fibers. Further, by altering the composition of the bath in a step-wise fashion during a single spinning run, variations in all other process parameters were minimized. We found that with increasing solvent composition in the coagulation bath, the fibers not only became round in cross section, but also became smaller in diameter, which persisted down the spin line. With this decrease in diameter, all else equal, came an accompanying increase in apparent fiber density via a reduction in microvoid content. In addition, molecular orientation and tensile properties also increased. Therefore, it was found that inadequate understanding of the coagulation bath effects, and spinning at low coagulation bath solvent compositions, can hinder the ability of the fiber to reach optimum properties.
THE LIMITS & EFFECTS OF DRAW ON PROPERTIES AND MORPHOLOGY OF PAN-BASED PRECURSOR AND THE RESULTANT CARBON FIBERS
OF THESIS THE LIMITS & EFFECTS OF DRAW ON PROPERTIES AND MORPHOLOGY OF PAN-BASED PRECURSOR AND THE RESULTANT CARBON FIBERS The process, structure, and property relationship of PAN fiber as a precursor to carbon fiber was studied. The limitations of stable spinning and property improvement associated with hot draw in solution spinning were found and quantified. Conditions were varied to generated precursor fiber up to the limit of draw, from which actual samples were collected for thermal conversion to carbon fiber. Samples of PAN and subsequent carbon fiber were characterized using tensile testing and x-ray analysis. The effects of draw on modulus and break stress, as well as the orientation of the crystalline structure of both parent precursor and resultant carbon fiber were found and related back to the quantified draw limit.
Experimental Study on Acoustic Agglomeration of Fine Particles from Coal Combustion
The removal of fine particles in coal-fired fumes was experimentally studied based on acoustic agglomeration. An experiment facility was designed and set up. In this facility, a fluidized bed coal combustor was used as fume generator, and an Electrical Low Pressure Impact or (ELPI) was used to measure the fine particle concentration and size distribution in the fumes. The results show that under the effect of high intensity sound waves, there is good performance to remove fine particles in coal-fired fumes, which with a number mean diameter of 0.07μm. Especially, under the conditions of the frequency of 1 000Hz and the sound intensity of 161.5dB, the number concentration of 0.0233~9.314μm particles decreased by 85.2%, and their mass concentration decreased by 92.5%.