Actinic defect counting statistics over 1-cm2 area of EUVL mask blank
As a continuation of comparison experiments between EUV inspection and visible inspection of defects on EUVL mask blanks, we report on the result of an experiment where the EUV defect inspection tool is used to perform at-wavelength defect counting over 1 cm2 of EUVL mask blank. Initial EUV inspection found five defects over the scanned area and the subsequent optical scattering inspection was able to detect all of the five defects. Therefore, if there are any defects that are only detectable by EUV inspection, the density is lower than the order of unity per cm2. An upgrade path to substantially increase the overall throughput of the EUV inspection system is also identified in the manuscript.
Adaptive optics for extreme ultraviolet lithography : actuator design and validation for deformable mirror concepts
In the production of integrated circuits (e.g. computer chips), optical lithography is used to transfer a pattern onto a semiconductor substrate (wafer). For lithographic systems using light in the ultraviolet band (EUV) with a 13.5nm nm wavelength, only reflective optics with multi-layers can reflect that light by means of interlayer interference, but these mirrors absorb around 30% of the incident light. Depending on pattern and beam shape, there is a nonuniform light distribution over the surface of the mirrors. This causes temperature gradients and therefore local deformations, due to different thermal expansions. To improve the throughput (wafers per hour), there is a demand to increase the source power, that will increase these deformations even further. Active mirrors are a solution to correct these deformations by reshaping the surface. This thesis addresses the challenges to accurate deform a mirror with high repeatability, meeting the requirements for implementation in a lithographic illumination machine. The main design criteria are vacuum compatibility, actuator stroke and the distance between actuators. Four different experimental mirrors, with increasing complexity, are successfully designed, realized and validated. All mirrors are equipped with thermomechanical actuators to either bend, or axially deform them. These actuators are free from mechanical hysteresis and therefore have a high position resolution with high reproducibility. Extensive finite element analysis is done, to maximize actuator stroke and minimize input power. All mirrors are tested and validated with interferometer surface measurements and thermocouple temperature measurements. The first experimental mirror with one thermo-mechanical bending actuator is successfully built and tested (chapter 2). To obtain a high mirror deflection at a given inserted actuator power, aluminum is chosen as the actuator material. The mirror is made from Zerodur® like the mirrors in the first EUV lithographic demonstration machines. A mirror deformation of 4:7 nm/C is achieved, where the inserted actuator power is 0.044 C/mW, meaning 0:21 nm/mW. The measured characteristic time constant is 10 s, meaning that for a given input, 63% of the steady state stroke is reached within that time scale. All values are close to the predicted ones from the models and also meet the requirements for implementation. To further investigate the concept and to measure the mechanical and thermal actuator coupling, an experimental mirror with four actuators is designed, developed and validated (chapter 3). It is an extension of the mirror with one actuator. In a single actuator step-response, a mirror deflection of 3.4 nm/C is achieved. A design optimization is proposed and successfully tested which reduces the actuator coupling from 30% to 10%, while the mirror deflection at the same input is reduced to 55%. Actuator speed is demonstrated while simultaneously heating all actuators with 3mW, which correspond with a mirror deformation of 33 pm/s. When using an adaptive mirror in an EUV lithography system, actuator strokes of 1 nm/min are required. The demonstrated actuator speed of 33 pm/s = 2 nm/min meets that requirement. The third and fourth mirror have actuators placed perpendicular to the surface (chapter 4). By placing the actuators on a thin back plate, the force loop is localized and therefore a lower actuator coupling is achieved. The results obtained from the third mirror with 7 actuators are close to the predicted values from the static and thermal models. Based on these good results, this actuation principle is implemented in a smaller deformable mirror with 19 actuators inside a 25mm beam diameter. A linear relation between actuator power and temperature of 0.190 C/mW and between power and averaged interactuator stroke of 0.13 nm/mW is achieved. So, the successfully realized mirror deflection is 0:68 nm/ C and no hysteresis is observed. For both mirrors a support frame is developed, that minimizes introduced surface deformations by temperature variations. Thermal step responses are fitted and both heating and cooling characteristic time constants are 2:5 s. The thermal actuator coupling from an energized actuator to its direct neighbor is 6:0, to their neighbors it is 1:3%. The total actuator coupling is approximated around 10%, based on the good agreement between simulated and measured inter-actuator stroke. Finally, chapter 5 summarizes the main findings from the different deformable mirrors and compares them. Also, suggestions for future research are given for implementation into a lithographic machine.
Rational Design, Synthesis and Evaluation of γ-CD-Containing Cross-Linked Polyvinyl Alcohol Hydrogel as a Prednisone Delivery Platform
This study describes the in-silico rational design, synthesis and evaluation of cross-linked polyvinyl alcohol hydrogels containing γ-cyclodextrin (γ-CDHSAs) as platforms for the sustained release of prednisone (PDN). Through in-silico studies using semi-empirical quantum mechanical calculations, the effectiveness of 20 dicarboxylic acids to generate a specific cross-linked hydrogel capable of supporting different amounts of γ-cyclodextrin (γ-CD) was evaluated. According to the interaction energies calculated with the in-silico studies, the hydrogel made from PVA cross-linked with succinic acids (SA) was shown to be the best candidate for containing γ-CD. Later, molecular dynamics simulation studies were performed in order to evaluate the intermolecular interactions between PDN and three cross-linked hydrogel formulations with different proportions of γ-CD (2.44%, 4.76% and 9.1%). These three cross-linked hydrogels were synthesized and characterized. The loading and the subsequent release of PDN from the hydrogels were investigated. The in-silico and experimental results showed that the interaction between PDN and γ-CDHSA was mainly produced with the γ-CDs linked to the hydrogels. Thus, the unique structures and properties of γ-CDHSA demonstrated an interesting multiphasic profile that could be utilized as a promising drug carrier for controlled, sustained and localized release of PDN.