Growth Rate and Morphology of Nb3Sn Layers in ITER-Type Bronze-Processed Wires Under Different Diffusion Annealing Regimes
The Nb3Sn-based bronze-processed multifilamentary composites have been fabricated at the Bochvar Institute of Inorganic Materials, Moscow, Russia, and studied by electron microscopy to determine the relationships between their structural parameters and annealing duration at different temperatures (575 °C, 650 °C, 750 °C). The structure of superconducting layers during their formation is characterized by thickness, average size of equiaxed grains, and by the fraction ratio of columnar and equiaxed grains. It was found that at high diffusion annealing temperatures (above 650 °C), the superconducting layers grow much faster, but the average size of equiaxed Nb3Sn grains even under a short exposure (10 h) is much larger than after a long low-temperature annealing. It is shown that to ensure the best current-carrying capacity of Nb3Sn-based wires in high magnetic fields, it is necessary to take into account different trends: on the one hand, the possibility of approaching the Nb3Sn phase stoichiometry and providing its maximum amount and on the other hand to avoid the undesirable growth of grains resulting in a lower pinning force.
Effect of Intermediate Heat Treatment on the Formation and Structure of Superconducting Layers in Multifilamentary Nb3Sn- Based Wires
In the present study, the Nb3Sn-based multifilamentary wires with coupled Nb filaments have been investigated by SEM and TEM after various regimes of intermediate annealing including short high-temperature heat treatments and after two-staged diffusion annealing. The formation of some amount of pre-reacted Nb3Sn layers has been revealed in all the wires studied, and their amount depends on the wire diameter, temperature and duration of the intermediate heat treatment. The structure of final diffusion layers is also affected by the regimes of these preliminary treatments. This research enables the revealing of the optimal heat treatment schedules for the formation of most perfect nanocrystalline structure of superconducting layers ensuring the highest critical current densities.
Recalculation of Mass Defects
THE well-known mass defect curve of the old nuclear scheme calculated with regard to α-particles and protons presented a difficulty with its minimum of binding energy for tin and an increasing portion between tin and lead. On the other hand, the mass defect values against protons give a rather smoothly decreasing curve.1 As has already been pointed out,2 the number of α-particles must be considerably reduced from the point of view of the new scheme, which does not admit any electrons in nuclei, but only neutrons and protons (presumably joined as α-particles). The curve of mass defect against protons and neutrons (perhaps with a single ‘central’ α-particle) is very similar to the old curve against protons, but decreases less rapidly. Clearly the new mass defect values relatively to α-particles, neutrons and protons must lie somewhere between the old values computed relative to protons and α-particles respectively (because the number of α-particles is decreased). We may emphasise that this new mass defect curve shows no increasing portion between tin and lead. For illustration we give two typical values: Old: 50Sn124 = 31α + 12&#38;epsiv;; mass defect = 0.158 (in mass units); 82Pb208 = 52α + 22&#38;epsiv;; mass defect = 0.035. New: 50Sn124= 25α + 24ω (ω = neutron); mass defect = 0.304; 82Pb208 = 41α + 44ω; mass defect = 0.366.