Near band-edge optical properties of cubic GaN with and without carbon doping
We report the results of studying the optical properties of cubic GaN thin films with photoluminescence and photoluminescence excitation spectroscopies. The films are deposited by plasma-assisted molecular beam epitaxy on GaAs (001) substrates, with and without intentional doping with carbon atoms (p-type doping). The evolution of the optical spectra of the C-doped samples is consistent with a picture in which carbon enters into N-vacancies at low concentrations, producing a marked improvement in the crystalline properties of the material. At higher concentrations it begins to form complexes, possibly due to interstitial occupation. The temperature dependence on the absorption edge of the doped material is also measured and is analyzed with standard theoretical models.
Ionization energy levels in C-doped InxGa1−xN alloys
The InxGa1−xN alloys present levels as a result of the intentional (doped) or unintentional (contamination) introduction of C atoms into the host semiconductor. The III-V nitride semiconductors and their alloys usually crystallize in the wurtzite structure although the zinc blende structure has also been grown. We obtained the InxGa1−xN:C ionization energies from first-principles calculations of the two ordered wurtzite and zinc blende structures using different exchange and correlation terms. In accordance with the experimental results, the ionization levels could give rise, on some occasions, to a metallic impurity band.
Determination of Optimal Ball-Burnishing Parameters for Plastic Injection Moulding Steel
The objective of this study is to determine the optimal plane ball-burnishing parameters for plastic injection moulding steel PDS5 on a machining centre by utilising the Taguchi’s orthogonal array method. The design and manufacture of a burnishing tool are described. Four burnishing parameters, namely the ball material, burnishing speed, burnishing force and feed, were selected as the experimental factors in Taguchi’s design of experiments to determine the optimal burnishing parameters which have the dominant influence on surface roughness. The optimal burnishing parameters were found after carrying out the experiments specified by Taguchi’s L18 orthogonal table, by the analysis of variation, and by a full factorial experiment. The optimal plane burnishing parameters for the plastic injection moulding steel PDS5 were a combination of a tungsten carbide ball, a burnishing speed of 200 mm/min, a burnishing force of 300 N and a feed of 40 μm. The surface roughness Ra of the specimen can be improved from about 1 μm to 0.07 μm by using the optimal burnishing parameters for plane burnishing.