A comparison of flexural strengths of polymer (SBR and PVA) modified, roller compacted concrete
This brief article aims to reveal the flexural performance, including the equivalent flexural strength of PVA (Polyvinyl Alcohol) modified concrete by comparing it primarily with that of SBR (Styrene Butadiene Rubber) concrete. This data article is directly related to Karadelis and Lin [6].
Cement-based material modified by in-situ polymerization: From experiments to molecular dynamics investigation
Abstract A critical obstacle to the design of more sustainable and durable cement-based material is its relatively low flexural strength and susceptibility to brittle fracture. In this paper, a novel cement-polymer composite was developed by in-situ crosslinking polymerization of sodium acrylate monomers and the synchronous hydration of ordinary Portland cement. In-situ polymerization in cement paste can significantly shorten the initial setting time to less than 10 min and the cement hydration process is inhibited during ions dissolution and dynamic balance stage. In-situ polymerization produces the intertwined inorganic-organic network, bridging the defections of cement paste at micro-level. Due to the formation of double-network structure, as compared with OPC, the optimized design can obtain 15% improvement in compressive strength and 200% improvement in flexural strength. The monomer to cement ratio and initiator to monomer ratio are essential factors for improving mechanical properties of composites. Furthermore, molecular dynamics is utilized to investigate the structure, dynamics and mechanical properties of interfacial bonds between sodium polyacrylate molecule and cement hydrate. The carboxyl groups in the polyacrylate provides oxygen sites to accept H-bond from protonated silicate tetrahedron and neighboring water molecules. The calcium and sodium ions play bridging role in connecting oxygen atoms in functional group and oxygen in silicate chain of calcium silicate hydrate. The H-bond, O–Ca–O and O–Na–O salt bridges strengthen the interfacial bonding, which inhibits the cracking development and enhance the ductility of cement-polymer composite. Hopefully, this in-situ polymerization strategy can provide valuable insights on high-performance cement-based composite design.
Development of Laboratory Device to Simulate Roller-Compacted Concrete Placement
Laboratory study results are presented in this paper in regard to a device that simulates roller-compacted concrete placement. A novel device is used in the laboratory setup that realistically simulates site conditions, including several curing conditions, as it consolidates concrete layers. Field results obtained at Brazil's Dona Francisca Hydro Power Plant were compared to laboratory test results. The correlation between field and laboratory results was analyzed by using statistical methods.