The Moisture Dependence of the Electrical Sheet Resistance of Aluminum Oxide Thin Films with Application to Integrated Moisture Sensors
The measurement of moisture inside integrated circuit packages for reliability purposes involves either destructive mass spectroscopic tests, measurement of the impedance between interdigitated electrode pairs, or measurement of the capacitance of a parallel plate capacitor with a porous upper electrode and a dielectric of anodized aluminum oxide. This paper reports the use of an integrated circuit that combines interdigitated electrodes with a pair of matched field-effect transistors to permit sensitive, quantitative measurement of the moisture dependence of the sheet resistance of very thin filmis of oxidized aluminum. Data analysis is based on an equivalent circuit model for the device. It is found that the room temlperature sheet resistance of a 1500 Å film varies from 2 × 1015 Ohms/sq. at an ambient dew point of ¿43°C to 2 × 1010 Ohms/sq. at a dew point of +22°C. The device retains useful sensitivity below dew points of ¿60°C, and because of the absence of a porous upper electrode, exh ibits rapid response to changes in ambient moisture. Fabrication details, reproducibility, hysteresis, and aging of these devices is discussed.
Estimation of thickness, complex bulk permittivity and surface conductivity using interdigital dielectrometry
Theoretical techniques for deducing continuum parameters from the gain-phase response of interdigital electrodes provide a basis for experiments that demonstrate the use of 50- mu m or 1-mm-wavelength interdigitated electrodes for the absolute measurement of: (1) the thickness and voltage of a layer formed by the sedimentation of 41- mu m particles in transformer oil; (2) the thickness and high-frequency bulk permittivity of plasma-deposited bromobenzene and vacuum-deposited parylene, the former in situ; (3) the complex permittivity of transformer oil without and with a parylene layer for passification against adsorption of water; (4) the dispersion of oil-impregnated paper having a finite thickness; and (5) the surface conductivity due to adsorption of water on a silicon dioxide substrate. The frequency range for (3)-(5) is 0.005 Hz to 10 kHz. Difficulties apparently due to charging effects on the integrated circuitry are discussed.<<ETX>>
Experimental investigation of the geotechnical properties and microstructure of lime-stabilized saline soils under freeze-thaw cycling
Abstract The Song-Nen Plain in northeastern China holds one of the three largest expanses of soda saline-alkali soil in the world. Due to its disadvantageous geotechnical properties, the saline soil in this area is unable to meet the needs of construction projects. This study evaluates the stabilizing effect of adding lime to such soils. Specifically, it investigates how the physicochemical and mechanical properties and microstructure of soda saline-alkali soil are altered by lime and how these changes are affected by both freeze-thaw cycling and the duration of curing. The results reveal that adding lime to saline soil transforms clay particles into sand and silt particles and causes the pore size distribution (PSD) to become bimodal, with small-pore and macropore populations. An increase in lime content leads to an increase in the unconfined compressive strength (UCS) but a gradual decrease in both the cation exchange capacity (CEC) and plastic index. Freeze-thaw cycles break up coarse particles and aggregate finer particles, increasing the diameter of macropores and decreasing the USC; however, the effect on specimens with >9% lime is negligible. It is further shown that the geotechnical properties of the soil change immediately after the addition of lime, indicating that the cation exchange reaction takes place very quickly. Furthermore, the pozzolanic reaction leads to an increase in the percentage of sand-sized particles and a decrease in porosity after 28 days of curing. Overall, these results indicate that it is feasible to use lime to improve the engineering properties of soda saline-alkali soil in this area.