Erosion-corrosion of RAFM JLF-1 steel in Lithium flow induced by impeller
The purpose of the present study is to investigate erosion-corrosion characteristics of reduced activation ferritic martensitic steel, JLF-1 (Fe-9Cr-2W) in flowing Li. The erosion-corrosion characteristics were investigated by means of corrosion tests with rectangular plate type specimen of JLF-1 in Li stirring pot, where the Li flow was induced by impeller in the pot. The test temperature was 500 C and 600 C, and there was no temperature difference in the Li stirring pot. The erosion-corrosion characteristics were evaluated by the weight loss measurement of the specimens and metallurgical analysis for the corroded surface. The results were compared with those obtained from the tests at static condition to feature the effect of Li flow on the corrosion. The weight loss of the specimens tested in Li flow was larger than that tested in the static tests. The corroded surface showed the local corrosion along lath boundary and grain boundary of JLF-1 as the same as that after the test at static condition. There were defects which were not observed in the specimen tested at the static condition. The defects were the trace of the erosion-corrosion. The corrosion attack to the boundaries made weak bonding between the subgrains, and the subgrains were peeled from the surface by the Li flow.
Effect of nitrogen on the corrosion behavior of RAFM JLF-1 steel in lithium
Abstract The corrosion behavior of RAFM JLF-1 (Fe–9Cr–2W) steel in static N-added Li (0.5 wt.%N) at 600 °C for times up to 750 h was investigated. The kinetics of weight change and peculiarities of corrosion interaction were determined. Samples showed intensive weight losses during first 120 h while with an exposure time the weight losses became slower. Corrosion attack proceeded most intensively along the boundaries of prior austenitic grains, martensite packets and laths, causing formation of the extremely relief surface. The porous and softened ferrite zone depleted markedly in Cr was formed beneath the relief surface. The martensite to ferrite transformation occurred in this zone. The weight losses of steel in N-added Li were about 25 times higher than those in “pure” Li (0.004 wt.%N) under the same time–temperature conditions of tests. The scheme of corrosion interaction in “JLF-1 steel–Li[N]” system was proposed.
Numerical and experimental investigation on air distributor design of fluidized bed reactor of sawdust pyrolysis
Abstract An improved biomass conversion in a lab-scale fluidized bed reactor (FBR) is achieved by optimizing the air distributor orifice size and number. Two approaches for introducing air were numerically and experimentally examined. These included perforated plate and downward orifice sparger. 3 mm and 5 mm orifice diameters, and 7, 9 and 13 holes were simulated at flow velocities of 2, 4, 6, and 8 times the minimum fluidization velocity, Umf. The simulation results revealed that increasing the orifice number has a positive effect on gas holdup, particularly for the perforated plate, which showed a uniform distribution of bubbles. The sparger configuration produced larger bubbles sizes, which could lead to better recirculation of solid flux, while stagnant particle zones were observed at the lower section of both distributors. A pyrolysis unit is also inserted at the top of freeboard of the FBR. For perforated plate with 6Umf, the pyrolysis process achieved thermal and cold gas efficiencies of 82.91% and 52.03%, respectively, while combustible gases with 41.6%mol CO, 8.7%mol CH 4 and 2.17%mol HC, were obtained. For sparger pipe and 6U mf _sp, 35.33 ppm NOx and 111 ppm SO 2 were measured in flue gas from combustion process at bed region.