Regeneration of diesel particulate filter using sliding discharge
Diesel particulate filter (DPF) is widely used to trap fine soot particles emitted from diesel engines. It can collect particles as small as submicron but it is necessary to oxidize accumulated particles by heating the filter. Temperatures of 600 degree C or higher is required to oxidize the soot but it is difficult to maintain stable reaction because this is exoergic reaction. The filter is sometimes damaged due to thermal runaway of the reaction. To address this trade-off problem, we have studied low temperature regeneration of DPF using sliding discharge, which can be generated on the surface of DPF and produces oxidative species at room temperature. Diesel soot collected by DPF was used. Simulated air consisting of N2 and O2 and not including CO2 or CO was used and CO and CO2 concentration was monitored by real time FTIR to estimate the soot oxidation. All the experiment was carried out at temperatures between 100 and 190 degree C to simulate exhaust temperature under low load. Experimental results show that soot was oxidized by generating sliding discharge on the DPF. No thermal damage of the DPF was found. Energy efficiency, denoted by the amount of oxidized soot per electric energy dissipated in the sliding discharge, increased with increasing the temperature as well as oxygen concentration in the test gas. Small amount of Ag2O supported by the DPF significantly increase the energy efficiency of soot oxidation. On the contrary, excessive amount of Ag2O resulted in energy efficiency lower than that of DPF without Ag2O probably because the sliding discharge was not generated favorably due to high conductivity resulted from metal Ag. These results suggest that sliding discharge can induce soot oxidation and that Ag2O possibly catalyzes soot oxidation.
Silver discharge electrode for suppression of ozone generation in positive dc corona
The aim of this paper is to suppress the ozone production in dc corona discharges, and is to report the effect of material of the discharge electrode on the ozone production. In this study, corona discharges were generated in a coaxial wire-cylinder reactor stressed by positive or negative dc voltage. A set of high purity wires made of different metals, and has constant radii, was tested as discharge electrodes. The reactor was fed by either dry air or oxygen flowing with a constant rate at atmospheric conditions. In the positive dc corona discharge, the ozone production was affected by material of the discharge electrode, and silver was effective to suppress the ozone production in dry air up to about 1/10 compare with that using tungsten electrode.
Denitrification of PVA-immobilized denitrifying photosynthetic bacterium, Rhodobacter sphaeroides
Abstract A newly isolated denitrifying strain, Rhodobacter sphaeroides NII2 was immobilized in polyvinyl alcohol (PVA) gel, and the properties of the cells in the gel were examined. The immobilized cells had low or almost no denitrification activity, but the cells were activated by incubation in light with culture medium for denitrification containing 0.5% nitrate and no other nitrogen source. Cells grown in the dark were activated by incubation at an earlier stage and to a higher rate than the light-grown cells. The activation was markedly enhanced in the PVA gel with a low cell concentration. The immobilized cells consumed nitrate with a temporary accumulation of NO 2 and evolved nitrogen gas. The immobilized cells could use various organic compounds as electron donors for denitrification. Thus, the immobilized cells were applied to a continuous treatment of synthetic wastewater using an aparatus devised by this laboratory. The results showed an efficient removal of NO 3 -N from the test water.