Increased Fracture Toughness of Graphite-Epoxy Composites through Intermittent Interlaminar Bonding
The objective of this study has been to increase the fracture toughness of multi-layer continuous-filament graphite-epoxy composites. The method used is intermittent interlaminar bonding, which can lead to a large in crease in the fracture surface area. In this study we achieved intermittent bonding through introduction of thin perforated Mylar between the layers of the composite. For the best optimum condition included in this study, fracture toughness was increased from about 100 kJ/m2 for untreated specimens to an average of about 500 kJ/m2, while tensile strength dropped from 500 MPa to 400 MPa, and elastic modulus remained the same at about 75 GPa. An approximate analysis is presented to explain the observed improvement in toughness.
The effect of aspect ratio on toughness in composites
Much information now exists on factors affecting toughness in composites. Theoretical expressions for fracture energy also abound, in response to the many factors that have been identified as contributing to toughness in fibre reinforced materials.This material is reviewed from the point of view of the effect of aspect ratio on toughness. Expressions relating fracture energy to aspect ratio are derived and compared with experimental data. It is shown that in many cases aspect ratio should be as large as possible. There are a few cases, however, where the aspect ratio should be as close to the critical value as possible.
Measuring Sheet Resistances of Dielectrics Using Co‐Planar Hydrogel Electrochemical Cells with Practical Applications to Characterize the Protective Quality of Paints on Sculptures
Electrical properties of thin dielectric films at the solid-liquid phase boundary are an important performance characteristic of many devices, coatings and sensors. In this paper, co-polymeric hydrogels of polyacrylic acid co-sulfonic acid, swollen with a salt solution to act as the solid electrolyte, were used to assess interfaces using electrochemical impedance spectroscopy (EIS) in a co-planar geometry. Silane-modified glasses were characterized by the co-planar hydrogel EIS cell and found to be distinguishable based on their surface monolayer chemistry. EIS measurements were also made on primed and painted metal substrates, using both test panels and an outdoor sculpture, Tony Smith's Stinger. The panels were then exposed to accelerated and outdoor weathering and showed degradation on the surface paint layers, which was observable electrochemically using EIS and confirmed visually by SEM. Electrochemical spectral features were compared between data from a standard paint-test cell versus this co-planar hydrogel cell; both cell types were able to measure coating capacitance, providing useful information about the condition of the bulk coating. Yet, sheet resistance (Rs) was a spectral feature seen only by the co-planar hydrogel cell. Thus, it can be concluded that the use of such co-planar hydrogel cells can provide an earlier warning sign to coating degradation and such cells provide a new type of spectral information that is not assessable by the standard geometry.