Redox reactions in non-aqueous media: determination of organic isothiocyanates alone, in formulations and in important mixtures.
A simple potentiometric method for the determination of organoisothiocyanates is described. The isothiocyanate is treated in acetonitrile medium with an excess of primary amine to convert it into a substituted thiourea and the surplus amine is converted into a dithiocarbamate by addition of carbon disulphide. The solution is then titrated with a copper(II) solution in acetonitrile. The three-step titration curve enables the results to be calculated on the bash of the dithiocarbamate and/or thiourea formed. The method has been successfully applied to the analysis of a commercial insecticide formulation based on isothiocyanate and important mixtures containing isothiocyanates.
Analytical applications of copper(II) and copper(I) in acetonitrile: potentiometric and spectrophotometric determination of dithiocarbamates.
The use of copper(II) perchlorate and tetra-acetonitrilocopper(I) perchlorate (in acetonitrile) for the potentiometric and spectrophotometric determination of dithiocarbamates in acetonitrile medium is described. The proposed methods are simple, accurate and reliable and show promise of wide applicability. They are recommended for routine determination of dithiocarbamates. Their advantages over the carbon disulphide evolution method, commonly employed for the determination of these compounds, are discussed.
Phytochemical and FT-IR Spectral Analysis of Certain Bamboo Species of SouthIndia
Bamboo with its varied uses has historically been an integral part of livelihoods and lifestyles in India. The present study was carried out to characterize the bioactive constituents present in the leaf extracts of certain bamboo species using Fourier transform infrared spectroscopic analysis (FT-IR). The various solvent extracts of various bamboo leaves subjected to qualitative analysis showed the availability of phytoconstituents including alkaloids, phenolic compounds, flavonoids, saponins, glycosides, terpenoids, steroids, coumarins and phytosterols. Quinones were completely absent in all the five bamboo species. The FT-IR spectrum confirmed the presence of sulphides (SS), phenols (C-O), aromatic compounds, thiols (S-H), aliphatic compounds (C-Cl) and amines (NH) in different bamboo species. The present investigation has also opened avenues for further research into the development of potent phytomedicines from different bamboo species.