Effect of exchangeable sodium percent on surface sealing
Abstract Laboratory studies were conducted to evaluate the effect of exchangeable sodium percent (ESP) on soil surface sealing and of surface sealing on infiltration and evaporation processes. Surface seals with hydraulic conductances 52.20 × 10 −3 , 49.20 × 10 −3 , 39.00 × 10 −3 , 33.00 × 10 −3 , and 17.91 × 10 −3 h −1 were attained on top of a sandy loam soil with ESP of 4 by placing a 5-mm layer of the same soil with ESP's 6, 10, 20, 30, and 60 respectively. Surface sealing increased with increasing ESP and appeared complete at ESP 30. Evaporation remained unaffected by the seals. Infiltration, however, was considerably reduced. Soil water profiles, which largely depended on the amount of infiltrated water, tended to become uniform. Equal moisture contents were also observed under evaporation.
Modeling the dynamics of soil seal formation: Analysis of the effect of soil and rainfall properties
The dynamic model of soil sealing developed by Assouline and Mualem [1997] is applied to study the effect of the main variables affecting seal formation, namely, the rainfall characteristics, the flow conditions, and the soil properties. The model is further extended to provide for the first time a quantitative estimation of the effect of the soil and water chemical properties on infiltration during soil surface sealing. The predicted effects of the chemical conditions on infiltration seem to be in agreement with experimental observations. Also, the model is used to explain the wide variability in seal thickness, found in the literature, in terms of the resolution of the method applied to measure the soil bulk density.
Instrumentation and Automated Photometric Titration Procedure for Total Acidity Determination in Red Wine Employing a Multicommuted Flow System
An automated procedure for photometric titration of red wine and associated instrumentation is described. The procedure was based on the flow-batch approach implemented employing multicommutation. The photometric detection was carried out using a homemade LED-based photometer. The mixing device, LED, and photodetector were attached to the titration chamber in order to form a compact and small-sized unit. The flow system comprised an automatic injector and three-way solenoid valves, which were controlled by a microcomputer through an electronic interface card. The software, written in Quick BASIC 4.5, was designed with abilities to accomplish all steps of the titration procedure including data acquisition and real-time processing to decide about the course of titration in the following step and so forth, until the titration endpoint was reached. The usefulness of the proposed titration system was demonstrated by analyzing red wine samples. When results were compared with those obtained using the AOAC reference method, no significant difference was observed at the 95% confidence level. A relative standard deviation of ca  2% (n=9 ) was obtained when processing a typical red wine sample containing 7.3 gl -1 total acidity expressed as tartaric acid.