Video-taped sample evaporation in hot chambers simulating gas chromatography split/splitless injectors. I. Thermospray injection.
The processes in devices imitating vaporising injectors were visualised and video-taped using perylene as a fluorescent marker for non-evaporated samples. The observations in the context of thermospray injection are summarised. Partial evaporation inside the needle turns the solvent into a propellant which nebulises the sample liquid at the needle exit. Evaporation in the vaporising chamber occurs from fine droplets suspended in the gas phase. Empty injector liners are best suited; packings with glass wool or obstacles in the liner, like the cup, have no significant effect on the process observed. Non-evaporated (matrix) material forms aerosol particles which may enter the column together with the vapours, but most of them are transferred to the liner wall. Since solute material may be carried along, this is a possible source of matrix effects.
The influence of evaporative dynamics on precision in split capillary GC
La vitesse d'evaporation d'un solvant est mesuree pour quatre solvants a des temperatures d'injection differentes. Les solvants utilises sont l'hexane, l'heptane, le pentane et l'acetone
ANALYSIS OF BOLT′S ANCHORING QUALITY BASED ON WAVELET NEURAL NETWORK
The dynamic response of bolt achieved by impact-echo method can be effected easily by some factors.It′s difficult to classify bolt′s anchoring quality according to the dynamic response of bolt.In this paper,a new analytical method of bolt′s dynamic response is put forward.The new analytical method combing with advantages of wavelet analysis and artificial neural network is presented.Firstly,the dynamic response of bolt by numerical simulation software FLAC3D is obtained.Secondlyt,he features are extracted from the dynamic response of bolt by wavelet analysis.Thirdlyt,hese features are fed into the artificial neural network for training.Finallyt,his artificial neural network to classify the bolt′s anchoring quality intelligent according to the dynamic response of bolt is employed.In order to validate this new analytical method,some practical signals of bolt′s dynamic response are used for the test.The results indicate that the new analytical method is practicable.