Humidity effects on the fatigue of fiber reinforced polymers in micro/nano functional systems
Micro and nano functional systems like MEMS and smart systems are exposed to complex and very challenging service conditions (e.g., within airframe structures or in automotive applications under the hood or within battery cells). Therefore, long-term reliability and structural integrity of the chassis and the printed wiring boards is of rising concern. These parts are often made of fiber reinforced polymers (FRP). Recently, a new methodology for accelerated fatigue testing of FRP has been presented. It allows predictions of the structural fatigue lifetime of FRP for arbitrary temperatures and loading ratios based on three simple tests: visco-elastic DMA, constant strain rate tests, and high cycle fatigue tests at a limited number of temperatures and strain rates. However, this methodology considers dry samples only, which does not suffice for describing the behavior of micro/nano systems as mentioned before. The paper reports the approach to the expansion of this testing methodology to the effects of humidity. Choosing PCB material as typical example for FRP in micro/nano systems, the time / temperature shift functions have been determined for wet and dry samples. Subsequently, constant strain rate and high cycle fatigue tests have been performed. They show a substantial loss in strength and fatigue lifetime for FRP structures that were exposed humid environment. Determining the quantities measuring this reduction in structural reliability paves the way to the expansion of the fatigue testing methodology towards accounting for the humidity effect as well.
Long-term life prediction of woven CFRP laminates under three point flexural fatigue
Abstract This technical contribution reports details of an investigation of the long-term flexural fatigue life behavior of plain weave carbon 3K-70P/epoxy (CFRP) laminates using accelerated testing methodology (ATM) coupled with time temperature superposition principle (TTSP). Initially, dynamic mechanical analysis (DMA) tests were performed on the CFRP laminates to determine the time-temperature shift factors followed by constant strain rate (CSR) tests at different temperatures to construct the creep strength master curve. The time-temperature shift factors were computed using an automated curve shifting programme. Horizontal shift factors were found to follow Arrhenius linear relationship for both above and below glass transition temperatures with different gradients. The scatter in the strength data was considered using Weibull analysis. Flexural fatigue tests were then conducted at different temperatures and loads. Finally, the master curves of flexural fatigue strength were constructed to predict the life of the CFRP laminates at arbitrary frequencies and load cycle ratios. Predicted fatigue behavior at non-default test parameters was found to be in good agreement with experimental data.
Full-scale measurements of SO2 gas phase concentrations and slurry compositions in a wet flue gas desulphurisation spray absorber
Abstract Two measurement campaigns were carried out at ENERGI E2's Asnaes Power plant, unit 5. The unit has a capacity of 620 MW e and is equipped with a wet flue gas desulphurisation (FGD) plant employing a counter-current spray absorber with five spray levels. In the first campaign, the power plant was firing Orimulsion ® with 2.85 wt% S resulting in a flue gas concentration of SO 2 exceeding 2000 ppmv. In the second campaign, the fuel applied was a low-S blended coal and the SO 2 concentration in the raw gas was around 400 ppmv. A novel probe for in situ sampling of gas phase concentrations in wet FGD spray absorbers was developed and applied for measuring axial profiles of the SO 2 gas phase concentrations in the absorber. The expected decrease in SO 2 concentrations along the height of the absorber was found in the spray section (from height 26.5 to 36.2 m) whereas the SO 2 concentration above the holding tank and below the gas inlet was quite low probably due to long local residence times in the region. Horizontal variations, due to somewhat different flow conditions near the column wall were investigated and the SO 2 concentrations were found to be higher near the wall. Measurements at different gross loads showed that the SO 2 gas phase concentration at a given position inside the absorber was roughly linearly related to the L/G ratio in the measuring interval. Turning off one of the lower spray levels, while burning coal with low S content, did not lower the overall removal efficiency of the absorber. However, the SO 2 gas phase concentration inside the lower part of the absorber was increased by a factor of 2–3. Measurements of slurry pH at different positions showed a decrease of approximately 0.5 units from the upper to the lower part of the absorber. The full-scale measurements provide a detailed set of experimental data for validation of mathematical models of a wet FGD spray absorber.