Effects of silicon fume and latex on properties and hydration of modified mortars
Polybutadiene-graft-polystyrene (PB-g-PS) latex with a weight ratio of 50/50 was used to modify cement mortar. This study examines the effects of silicon fume content and the polymer-cement ratios (P/C) on the flow, compressive and flexural strength and water absorption rate of PB-g-PS latex modified cement mortar. The experimental results show that the flow of modified mortar is increased with increasing polymer-cement ratios, and it is decreased with increasing silicon fume content, PB-g-PS latex and suitable silicon fume content can markedly reduce capillary water absorption rate. PB-g-PS latex can marked influences much on the mechanical properties of modified mortars. The compressive of the polymer modified mortar decreased, and the flexural strength of a portion of polymer modified mortar increased. The suitble silicon fume can improve mechanical properties of modified mortats. The effect of PB-g-PS latex and silicon fume content on cement hydration was explored by XRD, the analysis results showed that the cement hydration was influenced by silicon fume content and P/C.
Study of cement mortars modified by emulsifier-free latexes
Abstract Cationic copolymer latex of vinyl acetate (VA) with methacryloxyethyl trimethylammonium chloride (MTC) and anionic copolymer latex of VA with sodium acrylate (SA) were prepared via emulsifier-free emulsion copolymerization. Modifications of cement mortars by these copolymer latexes were studied, and the results were compared with mortars modified by homopolymer of VA (PVA) as well as with blank mortars. The experimental results showed that flow of the mortars modified by PVA homopolymer and P(VA–MTC) copolymer latexes were increased compared with the blank, whereas a decrease was observed for that modified by P(VA–SA) anionic copolymer latex; a volume expansion was detected in polymer modified mortars by PVA and P(VA–MTC), while no volume expansion was observed in the anionic P(VA–SA) modified mortars; the flexural strength of mortars modified by P(VA–MTC) increased by 79.5% compared to unmodified mortars after 5 day water curing plus 21 day air curing. This value reached 95% when the curing process was followed by a supplementary 24 h vacuum curing. These polymer modified mortars were then subjected to hydration analysis through X-Ray diffraction (XRD). Mechanisms of the mortar modification are discussed based on the characterization results.
A New Vacuum Pressure Infiltration CFRP Method and Preparation Experimental Study of Composite
In order to prepare a carbon-fiber-reinforced polymer composite (CFRP) with ideal microstructure and properties, a new vacuum pressure infiltration CFRP method is proposed based on an analysis of existing CFRP preparation process methods. Research on composite material preparation systems was carried out by using this new method principle. The system mainly includes a fiber pre-forming module, a vacuum heating infiltration module, a hot-press curing molding module, and a data acquisition control module. Under the conditions of natural curing at 0 MPa + 6 h + 25 °C, vacuum heating curing at –0.05 MPa + 30 min + 80 °C, and hot-press curing at 0.7 MPa + 5 min + 50 °C, a two-dimensional (2D) CFRP with excellent microstructure and properties was successfully prepared. Observing the microstructure of the prepared composite material, it can be found that the inside of the composite material was sufficiently and uniformly infiltrated, and common preparation defects such as holes and delamination were effectively controlled. Through the performance test, the bending strength of the material reached 790 MPa.