Assessing the quality of pipe borne water using Magnetic Susceptibility Measurements
Magnetic susceptibility measurements and chemical analysis were performed on samples of water taken from the academic and residential areas of the Kwame Nkrumah University of Science and Technology (KNUST) campus, Kumasi. The aim of these measurements was to see if water delivered through metallic pipes was clean. Magnetic susceptibility measurements were performed using the Bartington MS2 magnetic susceptibility meter, with MS2G single frequency sensor and the chemical analysis was performed with the Varian SpectrAA 220FS Atomic Absorption Spectrometer. Results of the measurements showed that the water samples had negative magnetic susceptibility (χ) values of the order of 10 –5 and were thus diamagnetic. The χ values obtained for the samples were between –1.3  10 -6 SI and –1.23  10 -5 SI for the Academic Area (sampled colleges) and –3.0  10 -7 SI and –8.7 10 -6 SI for the Residential Area (sampled Halls of residence). Chemical analysis of the samples showed variation in the concentrations of iron and zinc. Regression analysis of their concentrations with their χ values revealed zinc to have a strong inverse relationship with a correlation coefficient of 73%. Although the study showed some level of metallic contamination in the water samples of average concentration of 0.03mg/l, these were well below the concentration of 3mg/l which is of detrimental concern as outlined by the World Health Organization (WHO). This makes drinking water from the study area safe for drinking.
Practical guide to measurement and interpretation of magnetic properties (IUPAC Technical Report)
Abstract Rules are pointed out to protect the magnetochemist from pitfalls in both measurement and interpretation of magnetic data. Carefully chosen magnetic field strengths during magnetic susceptibility measurements guarantee the recording of genuine data. With the help of examples, the effect of too strong applied fields is demonstrated producing magnetic saturation and, for example, quenching of weak ferro- or antiferromagnetic spin–spin couplings. In consequence, the data run the risk of being misinterpreted unless model susceptibility equations are applied that take the field dependence of χm into consideration. Recommendations are given for the presentation of experimental and theoretical data. The limited applicability of the most overworked formula in paramagnetism, the Curie–Weiss law χm = C/(T–θ), is clearly presented (magnetically condensed systems, pure spin magnetism). While rough and ready susceptibility formulae are applicable to specific 3d and 4f systems, the complex situation for the remaining d and f centers, including actinides, demands computer programs which consider simultaneously interelectronic repulsion, ligand field potential, spin-orbit coupling, interatomic exchange interactions, and applied magnetic field.
Hygroscopic Expansion of some Casting Investments
CREDIT is generally given to Taggart1 for introducing the cast gold inlay to the dental profession. Although he realized that gold shrinks when cooled from molten state to solid state of room temperature, the investment available to him did not supply sufficient compensation. In 1910, Van Horn2 published a paper dealing with a method by which he obtained the compensation by means of wax expansion. The next major research in connection with this problem was the work of Coleman3 at the National Bureau of Standards. He determined the gold shrinkage to be 1.25 per cent and presented a casting technic with compensation values of quantitative nature. The total compensation for the gold shrinkage was obtained by the combination of the setting and thermal expansion of the mold. This procedure is the general practice followed at the present time for compensation. There are some disadvantages to this method. Skinner has indicated the difficulty of obtaining smooth castings and the improper compensation for the casting shrinkage.4 It has been found by Hollenback5 and Scheu6a that castings made at a high temperature are rougher than those made at a low temperature (450° C.), depending upon the great difference in thermal expansion between plaster of Paris and silica, which causes a poor union of the fine particles. This may also result in friability and there may be some warpage due to the differential expansion. A method which provides sufficient compensation at a low mold temperature is the hygroscopic casting technic.b Wilson7 showed that certain plasters expand as much as 0.0044 inch to the inch by taking up moisture from the air. With this information at hand, Scheula, b tested some commercial investment to determine what results the addition of moisture would have. He found6b: (1) All of the casting investments that were tested expanded. (2) The thicker the mix, the greater the expansion. (3) A mix with hot water expanded more than one with cold water. (4) The time at which the mix is placed in the water is of great importance. It was found that if the mix is placed in the water early, it would not expand so much as when placed in a little later. It was also found that if the mix was placed in the water after a certain time, it could not expand to the maximal amount. (5) The temperature of the water in which the mix is placed is important, for two reasons; (a) the temperature of the water controls slightly the expansion of the investment, and (b) water at a temperature of 1000 F. slightly softens the wax pattern so that the fine margins are not marred while expansion is taking place. The mix should remain in the water at least 20 minutes to obtain the full expansion, after which time no further expansion is obtained.