Pyrolysis of polystyrene waste in the presence of activated carbon in conventional and microwave heating using modified thermocouple.
Pyrolysis process was experimented using two types of heating source, namely conventional and microwave. Polystyrene (PS) plastic waste was used as feedstock in a batch reactor for both the conventional (slow pyrolysis) and microwave pyrolysis. The effect of activated carbon to polystyrene ratio on (i) yield of oil, gas and residues (ii) reaction temperature (iii) reaction time were studied. Quality of oil from pyrolysis of polystyrene were assessed for the possible applicability in fuel production. Microwave power of 450 W and polymer to activated carbon ratio of 10:1, resulted in the highest oil yield of 93.04 wt.% with a higher heating value of 45 MJ kg-1 and a kinematic viscosity of 2.7 cSt. Microwave heating when compared to conventional heating method, exhibits a reaction temperature and time of 330 °C in 5.5 min, whereas in conventional heating system it was 418 °C in 60 min. The gas chromatography-mass spectrometry analysis of liquid oil from microwave pyrolysis predominantly yields alkenes of 8.44 wt.%, α-methyl styrene 0.96 wt.%, condensed ring aromatics 23.21 wt.% and benzene derivatives 26.77 wt.% when the polystyrene to activated carbon ratio was 10:1. Significant factor of using microwave heating is the amount of energy converted (kWh) is lesser than conventional heating.
Chemical and microscopic investigation of co-pyrolysis of crumb tire rubber with waste cooking oil at mild temperature.
Approximate rubber/bitumen homogeneous system formed by desulfurization and degradation of crumb tire rubber in bitumen under high temperature is beneficial to enhance the storage stability of rubberized bitumen. However, the main problems during the processing of desulfurized and degraded rubberized bitumen are aging caused by volatilization of light components, and burning or explosion due to the direct utilization of low flash point bitumen. Therefore, waste cooking oil was proposed as a safer medium to desulfurize and degrade crumb rubber prior to production of rubberized bitumen. This study focused on the feasibility and effectiveness of the application of waste cooking oil in desulfurizing and degrading rubber particles through co-pyrolysis of them at mild temperature (240-280 °C). Chemical and microscopic analyses were performed to investigate the structural changes of vulcanized rubber. Results showed that solubility of rubber powder reached above 60 wt% after pyrolysis in waste cooking oil, which increased with higher temperatures and more of oil, while increased to a maximum at 2 h and then decreased with the extension of time. The rubber hydrocarbon content decreased greatly, and dramatic reduction of carbon, hydrogen and sulfur elements happened according to component and elemental analyses. The surface of pyrolysis product was even and smooth without obvious rubber particles. The grooves and cavities of rubber residues in scanning electron microscopy micrographs proved that shedding of degraded polymer molecules occurred. Fourier transform infrared spectra revealed that breakage of carbon-sulfur, carbon=carbon and sulfur=oxygen bonds took place during pyrolysis, with appearance of natural rubber characteristic peak.
Effects of signaling topic structure on text recall
Two experiments studied effects of signaling devices (headings, overviews, and summaries) on text memory. In Experiment 1, subjects read a text with or without signals, then recalled the topics of the text. Signaling produced better memory for the topics and their organization. In Experiment 2, subjects recalled the content of the text they read, and recalls were scored for the number of accurately recalled ideas. Signals produced recalls that were better organized by text topics. Signals also influenced the distribution of recall of ideas: Subjects remembered more topics but recalled less about each accessed topic if the text they read contained signals than if it did not