Combustion, Fuels and Emissions for Industrial Gas Turbines
It is important that gas turbines used in Oil & Gas applications can burn a wide variety of fuels with the minimum impact on the environment or economics. Many types of gaseous and liquid fuels that can be used in Gas Turbines are discussed, as will be the two basic types of combustion system employed – ‘conventional’ and ‘Dry Low Emissions’ – along with the flexibility of these systems to accept different types of fuel. Some of the common contaminants found in fuels are discussed along with the impact these have on the operability and maintenance of industrial and aero-derivative gas turbines. Topics include: Types of gas turbines Types of exhaust emissions regulated Conventional combustion systems Dry Low (Pre-mixed) emissions combustion systems Fuel quality requirements ‘Pipeline’ quality Natural Gas fuels Premium liquid fuels (diesel, kerosene) Wellhead Gases as a Gas Turbine Fuel Liquified Natural Gas (LNG) Biogas fuels Refinery and process off gases Syngas Natural Gas Liquids and LPG fuels Crude Oil Operational impact of contaminants Water in fuel Storing fuels correctly
Preferential Vaporization Potential of Crude Oils and its Impact on Flame Flashback Behaviors
............................................................................................................................ iv List of Tables ................................................................................................................... viii List of Figures .................................................................................................................... ix List of symbols .................................................................................................................. xii List of Abbreviations ....................................................................................................... xiii Chapter 1: Introduction ........................................................................................................1 1.1 Global Energy Sources ...........................................................................................1 1.2 Crude Oil Characterizations by API and Sulfur Content ........................................5 1.3 Crude Oil Combustion Characteristics in Literature Review .................................8 1.4 Hydrocarbon Fuels Studies Relevant to Gas Turbine Combustors ........................9 Chapter 2: Experimental Methodology ..............................................................................16 2.1 Distillation Apparatus ...........................................................................................16 2.2 Ignition Quality Tester (IQT)................................................................................18 2.3 Nuclear Magnetic Resonance (NMR) ...................................................................20 2.4 Phase Doppler Particle Analyzer (PDPA) ............................................................21 2.5 Spray Burner .........................................................................................................23
Mesozoic rifting and basin inversion along the northern African Tethyan margin: an overview
Abstract The northern African Tethyan margin registered three major rifting episodes from the latest Palaeozoic-earliest Mesozoic to the earliest Cenozoic. Break-up of Gondwana was initiated in the late Carboniferous. Along the northern African-Arabian plate margin rifting propagated westward from the northeastern Arabian margin to Morocco during the Permian and Triassic, and was accompanied by Mid-Late Triassic-earliest Liassic extensive alkaline flow basalts. Rifting continued during the Liassic, e.g. in the Moghrebian Atlas troughs. A second stage of rifting occurred in the Late Jurassic and continued into, or was rejuvenated during, the Early Cretaceous. Along the east Mediterranean margin, some large E-W trending rifts formed, often with associated volcanism, e.g. southern Sirt and Abu Gharadig. Most researchers believe the oceanization of the eastern Mediterranean basin occurred at this time. Flexural subsidence affected the Moghrebian Atlas, including the Riffian-Tellian domain, where a thick flysch series was deposited. Two short-lived, but widespread and tectonically important, compressional or wrench-dominated events occurred during the Santonian and the latest Maastrichtian. From Morocco to Oman, most sedimentary basins were folded and inverted at these times. The Santonian event resulted from onset of the collision between the African-Arabian and Eurasian plates. New stress-fields favoured NE-SW extension along the African plate margin, generating or rejuvenating some rifts, e.g. in the Euphrates trough and in the Libya-Tunisia region (northwestern Sirt, Pelagian Sea). Rifting and magmatism continued in these regions into the Paleocene. During the Mesozoic, therefore, the northern margin of the African-Arabian plate registered both rifting resulting in the oceanization of the Tethys and rifting resulting from the initiation of the closure of the Tethys. The intraplate domain exhibited echoes of the tectonic events affecting the margin.