Lubrication of Mo, W, and their Alloys with H2S gas admixtures to room temperature air
Abstract The in situ lubrication of molybdenum and tungsten using admixtures of hydrogen sulfide to room temperature and pressure air was achieved. Raman spectroscopy confirmed the presence of molybdenum disulfide and tungsten disulfide solid lubricants on elemental molybdenum and tungsten specimens, respectively. Pin-on-disk experiments were conducted with elemental molybdenum, elemental tungsten, and alloys of molybdenum and tungsten in atmospheres containing hydrogen sulfide. Friction coefficients were continuously recorded and comparisons between the sliding friction coefficient in air and in the hydrogen sulfide atmospheres were evaluated. In general, hydrogen sulfide admixtures reduced the friction coefficient for all materials containing molybdenum or tungsten. Friction coefficients for self-mated elemental molybdenum and self-mated elemental tungsten were reduced to μ =0.15 with hydrogen sulfide admixtures to air of 5% and 15%, respectively. In some cases friction coefficients as low as μ =0.08 were recorded.
Vapor-phase lubrication in combined rolling and sliding contacts: Modeling and experimentation
The in situ vapor-phase lubrication of M50 steel, in combined rolling and sliding contacts at 540°C using nitrogen atmospheres containing acetylene, is achieved. Acetylene partial pressures of 0.05 atmospheres are capable of providing continuous lubrication to combined rolling and sliding contacts through pyrolytic carbon deposition. In these tests, friction coefficients as low as μ = 0.01 are found for contacts at 2.0 m/s rolling speed, 10 cm/s sliding speed, 100 N load (1.3 GPa Hertzian contact pressure), and ambient temperature of 540°C, with even lower values observed at more modest sliding speeds. One example of a model for vapor phase lubrication of combined rolling and sliding contacts is developed which predicts the lubricant steady-state fractional coverage of the contact surfaces, and from this makes friction coefficient predictions using a linear rule-of-mixture. Friction coefficient responses to step changes in acetylene partial pressure, sliding speed, and disk wear-track diameter are measured. Increased partial pressure of acetylene and increased area available for deposition are observed to be beneficial, while increased sliding speed is detrimental to lubrication performance. Shapes and trends of steady-state friction coefficient versus acetylene partial pressure, sliding speed, and disk wear-track diameter are described and curve-fit by the model. In combined rolling and sliding this example model predicts large regions of operating conditions over which friction coefficient is independent of rolling speed, as well as regions of independence of vapor partial pressure. In the special case of pure sliding, a region of friction coefficient independence of a ratio of partial pressure to sliding speed and another region of independence of a ratio of partial pressure to the product of sliding speed and normal load are predicted.
Structure of s adsorbed on Mo(001) by LEED analysis; Effects on CO adsorption
Abstract The exposure of a clean Mo(001) surface to H 2 S results in a series of different overlayer patterns of S. It is found that ordering into c(2 × 2)S islands occurs for small fractions of a monolayer coverage. The binding site of S in the c(2 × 2) structure is determined using a dynamical LEED analysis. A relaxation of the Mo(001) surface layer towards bulk layer spacing is also observed. A model for adsorption is proposed which includes both bridge and four-fold bonded sites. CO adsorption is inhibited even by the c(2 × 2)S overlayer.