Study on atomic sodium release from pulverised coal particles in a pre-mixed natural gas flame
Atomic sodium release during coal combustion has been shown to be a significant factor in fouling and corrosion of heat transfer surfaces within industrial coal-fired boilers. Although there has been significant research into the final forms of sodium from combustion, information about the release of sodium is limited. An initial study of the release of atomic sodium from pulverised coal particles in a pre-mixed natural gas flame was conducted using planar laser induced fluorescence, PLIF. Measurements were made of the intensity of sodium fluorescence, coal particle velocities and gas phase temperature within the flame in a purpose-designed laminar flame facility that provides similar time-temperatures history to coal particles in their early stages of combustion in an industrial coal-fired boiler. The velocity of the coal particles was measured to be about 6.1 m/s using particle streak velocimetry obtained from the natural luminescence of the hot particles and a 2.25 ms gate of the CCD camera. Temperatures were measured using thermocouples, and the maximum measured temperature was ~1500 °C. Calibration of the sodium fluorescence was not undertaken, but useful information was obtained of the release rate of sodium atoms from combusting pulverised coal particles.
A kinetic description of vapor phase alkali transformations in combustion systems
Abstract A kinetic model was developed to predict concentrations of atomic and molecular sodium species existing in both flame and post-flame zones of pulverized coal combustors with and without chlorine. To date, the model has successfully predicted measured literature values of sodium species in the Na/H 2 /O 2 /N 2 system. At temperatures above 1900 K, sodium hydroxide is predicted to be the dominant species at times longer than a few milliseconds. Atomic sodium levels decay rapidly, representing less than 1% of the total sodium species present at time greater than 5 msec for lean hydrogen flames. At lower temperatures, NaO 2 forms in significant quantities as well, leading to decreases in the levels of atomic sodium. Addition of 1 ppm levels of chlorine generated approximately 10% sodium chloride in addition to sodium hydroxide at 1500 K, while addition of 1000 ppm levels yielded sodium chloride as the dominant species. Current understanding regarding the addition of sulfur chemistry to the matrix, and specifically the formation of vapor phase sodium sulfate, is also discussed.
Pedagogy of the “Not”: Negation, Exodus, and Postdigital Temporal Regimes
Postdigital capitalist time is an incessant acceleration that acts to homogenize time and wed us to the present, to which we have to constantly catch up. While the impulse of this is no doubt economic (the realization of value), it is crucially undergirded by a pedagogical logic wherein we have to perpetually learn and re-learn the latest apps, social media configurations, operating systems, and so on. Political strategies of resistance thus need to be bolstered by an alternative mode of educational life, and I propose a pedagogy of the “not” as one possibility. Such a pedagogy is an act of suspension that sustains a detachment from the present, clearing out oppositions and thereby exposing us to a radical indeterminacy and potentiality that is always untimely. Suspension is the praxis of negation, which means that negation operates by keeping sense indeterminate to meaning and signification. Rather than suppressing, disavowing, or annihilating the stated content, negation retains even that which is negated. While this would appear as a form of exopedagogy, which withdraws from the dialectic of the private/public, I instead argue that it redefines the terms of any dialectic, redefining the very categories exopedagogy withdraws from. Before concluding, I spend some time with Sandy Grande’s important critiques of Eurocentrism and progress in Western critical education, demonstrating how negation as suspension circumvents these errors through its accommodation of—or, better, insistence on—variegated temporalities and forms of life.