Water and Oil Repellent Finishing of Textiles by UV Curing: Evaluation of the Influence of Scaled-Up Process Parameters
In this work, various textile fabrics were coated with silicone and fluorocarbon-based resins by photo-curing using ultraviolet irradiation. A great number of large fabric samples were impregnated by padding with commercial finishing agents and then irradiated in air with a high power, semi-industrial UV source. The add-on of various finishing agents was kept low to reduce the treatment cost. White and dyed samples of different textile composition were treated and evaluated in terms of conferred repellency, yellowing, or color changes. Most relevant process parameters were investigated, utilizing the thermal process normally adopted at industrial level as reference. The results were statistically evaluated by ANOVA using Minitab 16 software, in order to identify the most influential parameters and to evaluate the real possibility of replacing the thermal treatment with UV curing.
An Experimental Investigation on Optimizing Liquid Repellency of Fluorochemical Urethane Finish and Its Effect on the Physical Properties of Polyester/Cotton Blended Fabric
This paper aims to optimize the liquid repellency performance of fluorochemical urethane (FU)—a patented technology with a shorter fluorocarbon chain (C4). FU is free from persistent bioaccumulative toxins such as perfluorooctanoic acid (PFOA) and perfluorooctanesulfonate (PFOS), unlike the long-chain fluorinated chemicals (>C6). Different sets of varied finish concentrations with an extender and a wetting agent were prepared to treat the 65/35% polyester/cotton blended fabric. The finish concentration was optimized based on the liquid repellency (water and oil-repellency) of the treated fabric and its laundering durability. In addition, the effect of the finish concentration on selected physical properties of the treated fabric was studied as well. The liquid repellency, laundering durability, and selected physical properties of the treated and untreated fabrics were analyzed using ASTM and AATCC standard test methods. The results of textile substrates treated with 60 g/L of FU show an optimum balance of desired liquid repellency without affecting the physical properties of the fabric significantly.
Ultraviolet curing for surface modification of textile fabrics.
In this study, cotton, polyester and polyamide fabrics were treated by radical or cationic ultraviolet curing of different commercial products conferring water and oil repellency. Moreover, radical ultraviolet curing of chitosan was applied to confer antimicrobial properties. The advantages of this technology are well known making it very interesting for industrial applications: energy savings, low environmental impact, simple, cheap and small equipment, high treatment speed. The polymerization was controlled through weight gain and gel content measurements, while the properties of hydro and oil repellency were determined in terms of contact angle, moisture adsorption and water vapor permeability. The polymer distribution on fabric surfaces was investigated by scanning electron microscopy and atomic force microscopy. However the fabrics treated with chitosan were subjected to the standard test for determining the antimicrobial activity. Finally the finished cotton samples were subjected to washing fastness tests.