Headspace solid phase microextraction – GC/C-IRMS for δ13CVPDB measurements of mono-aromatic hydrocarbons using EA-IRMS calibration
This work aims at comparing the δ13CVPDB of mono-aromatic hydrocarbons benzene, toluene, ethylbenzene and xylene isomers (BTEX) measured by elemental analyser (EA)-isotope ratio mass spectrometer (IRMS) with the δ13CVPDB measured on the same compounds by headspace solid phase microextraction – GC/C-IRMS (hSPME – GC/C-IRMS) with the final goal of using these compounds as internal standards on the latter system. The EA-IRMS measurements were done using calcium and lithium carbonate isotopic reference materials: NBS19 and L-SVEC for establishing the δ13CVPDB scale. The EA-IRMS measurements with helium dilution of a set of five reference materials (USGS40, USGS41, IAEA-CH-6, IAEA-CH-3 and IAEA-601) show systematic bias of 1‰ relative to their assigned values. This bias due to the dilution mechanism in the used ConfloII interface device could not be avoided. As the selected hydrocarbons: BTEX could not be analysed by EA-IRMS without helium dilution, their δ13CVPDB must be corrected from this observed bias using an external calibration. The CO2 gas calibrated using EA-IRMS without helium dilution, was used as an in-house reference for the δ13CVPDB measurements of the BTEX by the hSPME – GC/C-IRMS system. The comparison made between the δ13CVPDB measured on the same BTEX compounds by EA-IRMS (with external calibration) and by hSPME – GC/C-IRMS techniques showed good agreement.
Inter-laboratory comparison of elemental analysis and gas chromatography combustion isotope ratio mass spectrometry (GC-C-IRMS). Part I: delta13C measurements of selected compounds for the development of an isotopic Grob-test.
This study was directed towards investigating suitable compounds to be used as stable isotope reference materials for gas chromatography combustion isotope ratio mass spectrometry (GC-C-IRMS) calibration. Several compounds were selected from those used in the 'Grob-test' mixture. Oxygen- and nitrogen-containing substances were added to these compounds to allow the mixture to be used as a possible multi-isotopic calibration tool for 2H/1H, 13C/12C, 15N/14N and 18O/16O ratio determinations. In this paper we present the results of delta13C measurements performed by the consortium of the five laboratories taking part in this inter-calibration exercise. All the compounds were individually assessed for homogeneity, short-term stability and long-term stability by means of EA-IRMS, as required by the bureau communitaire de reference (BCR) Guide for Production of Certified Reference Materials. The results were compared then with the GC-C-IRMS measurements using both polar and non-polar columns, and the final mixture of selected compounds underwent a further certification exercise assessing limits of accuracy and reproducibility under specified GC-C-IRMS conditions.
Indian Fig Cactus (Opuntia Ficus-Indica (L.) Miller) in the Americas: an Uncertain History
Abstract: 
 Opuntia ficus-indica (L.) Miller is a globally important cactus species with a long history of human use. In addition to the importance of O. ficus-indica as a food for humans and livestock, it also has long served a role in the production of cochineal, a once important textile dye. This cactus also is intimately interwoven into the story of Cactoblastis cactorum (Berg) (South American cactus moth), one of the best-known examples of biological weed control. In this regard, O. ficus-indica has been a target weed as well as an unintended host in C. cactorum invasion. Although the distribution and human-assisted movement of this cactus throughout much of the world is well documented, surprisingly little has been written about its history and movement within the Americas. Literature associated with Opuntia and their phytophagous pests in North and South America was examined in an attempt to determine the history of O. ficus-indica in the Americas. Available information suggests with some certainty that O. ficus-indica originated in present-day Mexico, but the timing of its introduction to South America is much less clear. Taxonomic difficulties associated with distinguishing among Opuntia species and the long pre-Columbian history of exchange between South American and Mesoamerican cultures are two primary complicating factors associated with dating the dispersal of this species to South America. Additionally, previous evidence in support of a pre-Columbian introduction to South America relied on questionable identification of insect-based textile dyes. These uncertainties are significant because clearer knowledge of the history of O. ficus-indica introduction to South America could provide a more complete biological and ecological context to efforts at managing this species in its native and introduced ranges, particularly with respect to the threat posed by C. cactorum in North American and Argentinean plantations.