Electrical and thermal transport properties of icosahedral Al70Pd22.5(Re1−xMnx)7.5 quasicrystals
This work presents measurements of the electrical resistivity (ρ), Seebeck coefficient, and thermal conductivity (κ) of icosahedral Al70Pd22.5(Re1−xMnx)7.5 quasicrystals from 10to300K. A series of quasicrystals was prepared with x=0, 0.1, 0.2, 0.3, 0.5, 0.6, 0.8, and 1.0 to systematically study the effect of substitution. The electrical resistivity increases as the temperature decreases, suggesting a semiconductinglike behavior in these alloys. The room-temperature values of the Seebeck coefficient vary from −5μV∕K to +65μV∕K, showing a significant dependence on the value of x. However, κ exhibits a rather weak composition dependence in the temperature range investigated. The room-temperature dimensionless thermoelectric figure of merit (ZT) of this system is optimized at x=0.1. With further appropriate heat treatments, high ZT is presumably available at elevated temperatures in the Al70Pd22.5(Re0.9Mn0.1)7.5 sample.
Advances in thermoelectric microcooling
As the rapidly increasing integration density of electronics, thermal management is becoming more rigorous for the reliability of microelectronic devices. Advanced thermoelectric microcooling technology is receiving more attention due to advantages, such as long lifetime, no moving parts, and etc. In the past 50 years, researchers have been searching for materials with high ZT. Quasicrystals, such as Al-based icosahedral quasicrystals, which possess peculiar electronic and thermal transport properties are considered to be the candidate for thermoelectric materials. While this work on new compounds is in progress, there have also been a number of attempts to produce thermoelectric materials in which at least one of the dimensions is not much greater than the lattice constant, such as superlattice, nanowire and quantum dot. In 1997, Shakouri and Bowers proposed thermionic emission cooling in heterostructures, in which a potential barrier was used for selective emission of hot electrons, and the evaporative cooling of the electron gas. It is expected that non-planar potential barrier could overcome the conservation of momentum that limits the efficiency of thermionic emission cooling for planar barrier.
Physical Ageing of the Research Reactor Core Structural Materials Due to Neutron Irradiation Exposure: a Review
A research reactor (RR) is a  nuclear reactor that has function to generate and utilize neutron flux and radiation ionization for  research purposes and industrial applications. More than 60% of current operating RRs have  been operated for 30 years or more. As the time passes, the functional capabilities of structures,  systems and components (SSCs) of those RRs deteriorate by physical ageing, which can be  caused by neutron irradiation exposure such as irradiation induced dislocation and  microstructural changes. To extend the lifetime and/or to avoid unplanned outages, ageing on  the safety related SSCs of RRs need to be properly managed. An ageing management is a  strategy to engineer, operate, maintenance, and control SSC degradation within acceptable limits. The purpose of this study is to review physical ageing of the core structural materials of  the RRs caused by neutron irradiation exposure. In order to achieve this objective, a wide range  of literatures are reviewed. Comprehensive discussions on irradiation behaviors are limited only  on reactor vessel and core support structure materials made from zirconium and beryllium as  well as their alloys, which are widely used in RRs. It is found that the stability of the mechanical  properties of zirconium and beryllium as well as their alloys was mostly affected by the neutron  fluences and temperatures.