Determination of the location of coke in catalysts by a novel NMR-based, liquid-porosimetry approach.
In this work, a new technique, suitable for chemically-heterogeneous materials, has been used to characterise the structural properties of porous heterogeneous catalysts. A liquid-liquid exchange (LLE) process within nanoporous catalysts has been followed using NMR relaxometry and NMR diffusometry. In order to validate the new technique, two model materials were used. First, a chemically-pure, sol-gel silica, with a simple, mono-disperse pore-space, was studied. The second model material was a bidisperse, eggshell Pt-alumina catalyst. The Pt-alumina catalyst was studied both fresh, and coked following chemical reaction. The degree of structural and chemical complexity added by coking was restricted by the localisation of the coke deposition to the Pt-eggshell layer. Under so-called 'metered' supply conditions, when a high affinity liquid (water) displaced a low affinity liquid (cyclohexane) from the sol-gel silica, entrapment of the low affinity liquid was observed which was similar to that observed in mercury porosimetry. In a similar experiment, comparing LLE in fresh and coked samples of the Pt-alumina catalyst pellets, it was found, for the fresh sample, that water initially displaced cyclohexane from a sub-set of the most accessible, smallest pores, as might expected under metered conditions, but this did not occur for coked catalysts. This finding suggested coking had removed some smaller pores located close to the surface of the pellet, in agreement with where the Pt-metal was preferentially located and coking was known to have occurred.
Structural characterisation of porous materials in relation to entrapment of non-wetting fluids
An understanding of the physical mechanisms by which non-wetting fluids become entrapped is important to oil recovery techniques from reservoir rocks, and the structural characterization of porous media. The mechanisms of entrapment and the spatial distribution of non-wetting fluid (mercury) within model materials with similar chemical and geometrical properties to oil reservoir rocks have been investigated using mercury porosimetry and computed X-ray tomography. The combination of both techniques has allowed the direct observation of entrapped mercury within the model materials. 
 
In this thesis, a novel experimental technique involving combined mercury porosimetry and mercury thermoporosimetry techniques has been used to determine pore size distributions for disordered porous solids. Mercury porosimetry was conducted, and the mercury entrapped following porosimetry was used as the probe fluid for thermoporosimetry. The fully integrated combination of techniques described here permits the validation of assumptions used in one technique by another. Mercury porosimetry scanning curves were used to establish the correct correspondence between the appropriate Gibbs-Thomson parameter, and the nature of the meniscus geometry in melting, for thermoporosimetry measurements on entrapped mercury. Mercury thermoporosimetry has been used to validate the pore sizes, for a series of sol-gel silica materials, obtained from mercury porosimetry data using the independently-calibrated Kloubek correlations. 
 
A Liquid-liquid exchange (LLE) process within mesoporous materials has also been investigated using NMR relaxometry and NMR diffusimetry experiments. In this method, a high affinity liquid (water) displaced a low affinity liquid (cyclohexane) from the sol-gel silica samples. Entrapment of low affinity liquid was observed which was similar to the entrapment of non- wetting fluid observed in mercury porosimetry. In addition, the molecular diffusion of n-pentane has been measured in mesoporous sample using PFG NMR method in a broad temperature range.
Research on Control and Planning of Soft-Wing UAV for Haze Removal
The existence of fog and haze has caused great pollution to the environment. The research of removing haze is a hot topic in recent years. In this paper, a special haze removal algorithm based on Soft- Wing UAVis proposed. In this algorithm, two track control strategies are designed based on the Soft-Wing UAV model transfer function. A SIMULINK platform based mathematical model of Soft-Wing UAV is built to testified effectiveness of the two track control strategies. An autonomous ergodic-planning algorithm with greedy strategy and foldback algorithm for Soft-Wing UAV is designed. Within the algorithm, the haze regional has been modelled, the cost matrix is constructed, and the planning and ergodic strategy is proposed. Finally, the experimental results validates the reliability of the algorithm in the application of haze removal with the proposed evaluation Index.