Chemical reduction of hematite by sodium borohydride
Well-crystallized hematite was suspended in water and treated at room-temperature (RT) with sodium borohydride. The product of the reaction is a highly magnetic black powder, which is stable at RT. The NaBH4 treatment converts about half of the hematite to an amorphous Fe–B alloy and to a small fraction of sub-micron sized, amorphous metallic-Fe nodules. Heating at 400°C of this composite has resulted in the crystallization and/or oxidation of more than half of the amorphous Fe–B phase to α-Fe and Fe3O4 and B2O3, respectively. After treatment at 800°C, the metallic Fe and the amorphous Fe–B have completely vanished, and the resulting product consists of hematite and FeBO3 embedded in the matrix of α-Fe2O3.
ILEEMS: Methodology and Applications to Iron Oxides
ILEEMS is the acronym for Integral Low-energy Electron Mössbauer Spectroscopy. In this variant of Mössbauer spectroscopy the low-energy electrons, E < ∼15 eV, emitted by the probe nuclei in the absorber are counted as a function of source velocity. As a consequence of their low energy, the detected electrons' origin lies within a very thin surface layer with thickness of a few nanometers and consequently, ILEEMS is a useful technique to examine surfaces of Fe-containing substances. In a first part of this paper the authors briefly describe the design of a home-made ILEEMS equipment allowing the temperature of the investigated sample to be varied between 77 K and room temperature. The second part of this contribution deals with a selection of results obtained from ILEEMS spectra for various Fe oxides. In particular, the following items are covered: (1) surface versus bulk Morin transition in small-particle and near-bulk hematite, α-Fe2O3; (2) bulk and thin-film magnetite, Fe3O4; (3) ferrihydrite, 5Fe2O3·9H20, goethite, α-FeOOH, and lepidocrocite, γ-FeOOH, all to some extent in relation to their morphology. Interesting and intriguing findings concerning the surface properties of these oxides were obtained and it is argued that the results encourage more systematic research in this and related fields using the surface-sensitive ILEEMS technique.
The Russian language maintenance and language contacts
In our introductory article, we outline the main sociolinguistic features of Russian as a heritage language of post-Soviet immigrants in European settings and beyond. We offer a general overview of the evolution of Russian as a global language, with a particular focus on its geodemographics and economic and social value as a lingua franca . Based on this, we analyse the main principles defining the maintenance of Russian as a language of migration and as a heritage language in different countries, and emphasise the most important questions that still need to be addressed in this field of research. The main objective of this special issue is to combine the most recent research on the vitality of different languages of post-Soviet republics in new political milieu, with a particular focus on European and Asian countries, but there are other objectives as well. We propose to explore the factors that have either favoured or hindered the maintenance and transmission of languages of post-Soviet immigrants and repatriates, and how these sociolinguistic processes become evident in language vitality on both private and public levels. Our special issue primarily addresses the questions of family language policy, new language contacts and their management, and linguistic landscape in heritage speakers, diasporas and their new settings in Europe, Asia and the US.