Video-taped sample evaporation in hot chambers simulating gas chromatography split/splitless injectors. I. Thermospray injection.
The processes in devices imitating vaporising injectors were visualised and video-taped using perylene as a fluorescent marker for non-evaporated samples. The observations in the context of thermospray injection are summarised. Partial evaporation inside the needle turns the solvent into a propellant which nebulises the sample liquid at the needle exit. Evaporation in the vaporising chamber occurs from fine droplets suspended in the gas phase. Empty injector liners are best suited; packings with glass wool or obstacles in the liner, like the cup, have no significant effect on the process observed. Non-evaporated (matrix) material forms aerosol particles which may enter the column together with the vapours, but most of them are transferred to the liner wall. Since solute material may be carried along, this is a possible source of matrix effects.
Inserts providing complete sample evaporation above the column entrance in vaporizing GC injectors
Completeness of sample evaporation in conventional vaporizing injection is a problem for many samples and calls for measures to arrest the sample liquid in the space between the needle exit and the column entrance. A visual testing procedure reveals that a small plug of loose glass or quartz wool ensures complete evaporation in all instances. Obstacles built into the liner also stop liquid, provided they force the sample to pass through narrow channels. Other important design characteristics concern access to the narrow channel. Evaporation in a packed insert usually occurs from a surface, whereas the sample hardly touches surfaces in the instance of an insert with obstacles. Evaporation from a packing is, in fact, more reliable, but creates more problems concerning inertness.
Impacts of climate and land use changes on flood risk management for the Schijn River, Belgium
Abstract Flooding is the most common natural disaster in Europe. Modern flood risk management relies not only infrastructure development but also on governmental and non-governmental actors applying legal, economic and communicative water management instruments. Within the European Union (EU), flood management closely relies on policy set at the EU and national levels. It is now recognized that a sound understanding of climate change is required in addition to current management by taking into account land use change and socio-political context, as climate and land use changes have major impacts on hydrological responses. This paper investigates the hydrological behavior due to urbanization under current and future climate scenarios of high summer and high winter rainfall for 20 sub-catchments of the Schijn River, located in the Flanders region near Antwerp, Belgium. As urbanization increases and existing rainfall-runoff models neglecting the specific behavior of urban runoff, a hydrological model was developed based on a basic reservoir concept and applied to the existing rainfall-runoff model (PDM) flow to examine the specific urban contribution. Results revealed that peak flow for urban runoff and the total peak flow (i.e. rural and urban runoff) were significantly higher (i.e. ranges from 200% to 500%) than the existing rainfall-runoff model (PDM) flows, because of faster and more peaked urban runoff response. The impact of climate change on current and future conditions was also assessed by estimating peak flows with respect to return periods from the flood frequency curve. The predicted peak flow of high summer future climate scenario was significantly higher (i.e. ranges from 200% to 250%) than that of the current climatic condition for this region. Furthermore, hourly peak flow and daily volume ratios of 100-year return period for the highest, lowest and average impervious area were projected for the time horizon of the year 2100. It is concluded that climate change impacts contribute the most in producing peak flow in coming years, while increased urbanization takes the second place for both hourly and daily values. Results on urbanization effect and climate change impact assessment are useful to the water managers for spatial planning, emergency planning and insurance industry.