Mass spectrometry of some N-acyldaunosamine derivatives.
Abstract The principal modes of fragmentation subsequent to electron impact of some N -acyl derivatives of daunosamine, the glycoside moiety of the antitumour antibiotics daunomycin and adriamycin, have been studied by using specifically deuterated derivatives and high-resolution measurements. In particular, the elimination of MeOH from methyl β-daunosaminides is shown to occur extensively and stereo-specifically, and involves HO-4. The splitting of the moieties C-1-C-2 and C-5-O-5 affords the fragments D 2 , D ′ 2 , and D ′′ 2 , which are among the most abundant.
Mass spectrometric investigations : Part XVII. Mass spectrometric analysis of the linkages in polysaccharides containing amino sugars. Mass spectra of derivatives of 2-amino-2-deoxy-D-galactose
Zusammenfassung Massenspektren geeigneter Derivate ermoglichen die Bestimmung der Verknupfungsstellen von aminozuckerhaltigen Polysacchariden. Untersucht wurden die partiell methylierten Methyl-2-acetamido-2-desoxy-D-galaktopyranoside,die entsprechenden acetylierten Verbindungen und die Acetate der partiell methylierten 2-Acetamido-2-desoxy-D-galaktose.
Research on health and oral health status of elderly living alone compared to elderly living with their families - based on the data (2014) from the 6th two-year Korea national health and nutrition examination survey -
Objectives: I examined the health and oral health status of elderly people living alone compared to elderly people living with their families by using data (2014) from the 6th Two-Year Korea National Health and Nutrition Examination Survey. Methods: Among 1,454 health survey respondents aged 65 years and over who participated in the 6th Two-Year Korea National Health and Nutrition Examination Survey conducted in 2014, 311 were elderly people living alone and 1,143 were elderly people living with their families. Results: In terms of socio-demographic characteristics, the percentage of elderly people living alone was high especially in women and when the subjects’ age, education level, and income level were low. In terms of oral health status, the percentage of elderly people living alone was high when elderly people thought that their subjectively viewed health was poor and the frequency of drinking and exercise was low. In terms of oral health status, the percentage of elderly people living alone was high among elderly people who did not have good oral health in their subjective view and did not get oral examinations for a year and had a lot of difficulty chewing. Conclusions: Family support or additional social support for elderly people who live alone should be considered to promote the healthy lives of elderly people.