Three-dimensional Insight on the Evolution of a Supramolecular Preorganization Complex to Hollow-Structure Carbon Nitride
The supramolecular preorganization approach can be applied to effectively fabricate various morphologies of graphitic carbon nitride(g-CN)with improved photocatalytic activity, while a comprehensive understanding for the morphology evolution from supramolecular aggregates to g-CNs is lacking. Herein, 3D characterizations from electron tomography provide a fundamental insight on the evolution from rod-like melamine-cyanuric acid(MC)complex to hollow-structure g-CN in the thermal polycondensation process. The internal region and a group of surfaces of the rod-like complex initially underwent polycondensation, while the other two groups of surfaces with ~100 nm thickness almost unchanged. With the temperature reached to 550 degree C, the hollow-structure g-CN eventually formed due to most of the internal matter vanishing, and voids arose in the previously unaffected surfaces(edges),resulting in a porous shell structure. Quantitative electron tomography indicates that the key of structure evolution is the differentiated condensation polymerization between edges and inner region of the rod-like MC complex, which is ascribed to a higher dense of surfaces and a lower dense of inner matter with loose, defective orignization.