Coordination of a Water Molecule to a Square-pyramidal N2S3-type Co(III) Complex Directed to an Active Site of Nitrile Hydratase
A novel distorted square-pyramidal N2S3-type Co(III) complex with a vacant site was synthesized as an active center model of nitrile hydratases (NHases) and characterized by UV–vis and 1H NMR spect...