Influence of an acceptor on multiphoton dissociation of CF3Br molecules in strong infrared field of a pulsed CO2 laser
A significant increase in the dissociation yield, compared with pure CF3Br, was achieved when a buffer N2 and an acceptor NO were added. The frequency dependences of the dissociation yield, absorbed energy, and quantum efficiency of the dissociation of CF3Br were determined. The isotopic shift was found for the 12CF3Br and 13CF3Br molecules.