REGIOSELECTIVE C–C BOND FORMATION OF O-LINALYL-N,N-DIMETHYLHYDROXYLAMINE VIA CARBOPALLADATION
Stable carbopalladation complexes were prepared by regioselective addition of active methylene compounds to O-linalyl-N,N-dimethylhydroxylamine (1) in the presence of Pd(II) complexes, and degradated selectively to the corresponding alkene derivatives by treatment with trimethylsilyl chloride.