Highly Chemoselective Mono‐Suzuki Arylation Reactions on All Three Dichlorobenzene Isomers and Applications Development
A Pd catalyst system is described that allows very high chemoselective monoarylation on all three isomers of dichlorobenzene. Direct application of these commodity chemicals to high-value ligands, anilines, azides, and carbazoles was achieved through this process discovery.