Hydrogen-bonded Charge-Transfer Complex of Ethylenediaminoglyoxime Transition Metal Complex with Tetracyanoquinodimethane
We prepared the hydrogen-bonded charge-transfer complex containing a transition metal, (ethylenediaminoglyoximato)(ethylenediaminoglyoxime)palladium(II), with TCNQ, which showed a segregated stacking mode of crystal structure and contained H-bonds between the anionic and cationic columns and between the cationic columns. The high electrical conductivity (90 Scm−1) was observed.