Recent trends in preparation and application of carbon nanotube graphene hybrid thin films
The combination of one dimensional (1D) carbon nanotubes (CNTs) and two dimensional (2D) graphene materials to generate three dimensional (3D) carbon nanotube graphene hybrid thin films (CNGHTFs) has attracted great attention owing to their intriguing properties via the synergistic effects of these two materials on their electrical, optical, and electrochemical properties in comparison with their individual components. This review aims to provide a brief introduction of recent trends in preparation methodologies and some outstanding applications of CNGHTFs. It contains two main scientific subjects. The first of these is the research on preparation techniques of CNGHTFs, including reduction agent assisted mechanical blending of reduced graphene oxide (rGO) and CNTs, hybridization methods for layer by layer (LBL) assembly of CNTs and rGO sheets, multi step methods using combinations of a solution and chemical vapor deposition (CVD) processing, one step growth of CNGHTFs by the CVD method, and modified CVD methods via thermal deposition of carbon source on catalyst surfaces. The advantages and disadvantages of the preparation methods of CNGHTFs are presented and discussed in detail. The second scientific subject of the review is the research on some outstanding applications of CNGHTFs in various research fields, including transparent conductors, electron field emitters, field effect transistors, biosensors and supercapacitors. In most cases, the CNGHTFs showed superior performances than those of the pristine GO/graphene or CNT materials. Therefore, the CNGHTFs exhibit as high potential materials for various practical applications. Opportunites and challenges in the fields are also presented.