Mussel Inspired Materials: Self Healing through Coordination Chemistry.
Improved understanding of the underwater attachment strategy of the blue mussels and other marine organisms has inspired researchers to find new routes to advanced materials. Mussels use polyphenols, such as the catechol containing amino acid 3,4 dihydroxyphenylalanine (DOPA) to attach to surfaces. Catechols and their analogues can undergo both oxidative covalent cross linking under alkaline conditions and take part in coordination chemistry. The former has resulted in the widespread use of polydopamine and related materials. The latter is emerging as a tool to make self healing materials due to the reversible nature of coordination bonds. We review how mussel inspired materials have been made with a focus on the less developed use of metal coordination and illustrate how this chemistry can be widely to make self healing materials.
Chemistry