Simultaneous online determination of S, Cl, K, Na Zn and Pb release from a single particle during biomass combustion Part 2: Results from test runs with spruce and straw pellets
To gain better insight into inorganic element release processes, test runs with a specially designed single particle reactor connected with an inductively coupled plasma mass spectrometer (ICP MS) have been performed. Relevant combustion related parameters such as mass loss during thermal degradation, temperature development of the particle (surface and center) and composition of released gases were recorded. By coupling the reactor to an ICP MS, time resolved release profiles of relevant aerosol forming elements (S, Cl, K, Na, Zn, and Pb) were determined. Targeted and controlled interruptions of the experiments (quenching) after a certain time were performed to validate reactor performance and reliability of the measurements. Test runs with softwood and straw pellets (8 mm in diameter and about 20 mm in length) were performed at reactor temperatures of 700, 850, and 1000 degC under oxidizing conditions (5.6 or 4.2 vol O2) These test runs have revealed that the release ratios of volatile and semivolatil.