Fabrication and characterization of highly transparent and conductive indium tin oxide films made with different solution based methods
Solution based fabrication methods can greatly reduce the cost and broaden the applications of transparent conducting oxides films, such as indium tin oxide (ITO) films. In this paper, we report on ITO films fabricated by spin coating methods on glass substrates with two different ITO sources: (1) a commercial ITO nanopowder water dispersion and (2) a sol gel ITO solution. A simple and fast air annealing process was used to treat as coated ITO films on a controlled temperature hot plate. Thermogravimetric analysis and x ray diffraction showed that highly crystalline ITO films were formed after the annealing steps. The final ITO films had a good combination of optical properties and electrical properties, especially for films made from five layers of sol gel ITO (92.66% transmittance and 8.7 x 10 3 O cm resistivity) The surface morphology and conducting network on the ITO films were characterized by non contact and current atomic force microscopy. It was found that conducting paths were only partially connected for the nanoparticle ITO dispersion films, whereas the sol gel ITO films had a more uniformly distributed conducting network on the surface. We also used the sol gel ITO films to fabricate a simple liquid crystal display (LCD) device to demonstrate the excellent properties of our films.