A Series of Layered Assemblies of Hydrogen Bonded, Hexagonal Networks of C3 Symmetric p Conjugated Molecules: A Potential Motif of Porous Organic Materials.
Hydrogen bonded porous organic crystals are promising candidates for functional organic materials due to their easy construction and flexibility arising from reversible bond formation dissociation. However, it still remains challenging to form porous materials with void spaces that are well controlled in size, shape, and multiplicity because even well designed porous frameworks often fail to generate pores within the crystal due to unexpected disruption of hydrogen bonding networks or interpenetration of the frameworks. Herein, we demonstrate that a series of C3 symmetric p conjugated planar molecules (Tp, T12, T18, and Ex) with three 4,4' dicarboxy o terphenyl moieties in their periphery can form robust hydrogen bonded hexagonal networks (H HexNets) with dual or triple pores and that the H HexNets stack without interpenetration to yield a layered assembly of H HexNet (LA H HexNet) with accessible volumes up to 59% Specifically, LA H HexNets of Tp and T12 exhibit high crystallinity and permanent porosity after desolvation (activation) SABET 788 and 557 m(2) g( 1) respectively, based on CO2 sorption at 195 K. We believe that the present design principle can be applied to construct a wide range of two dimensional noncovalent organic frameworks (2D nCOFs) and create a pathway to the development of a new class of highly porous functional materials.
Journal of the American Chemical Society