Flexible Aqueous Lithium Ion Battery with High Safety and Large Volumetric Energy Density.
A flexible and wearable aqueous lithium ion battery is introduced based on spinel Li1.1 Mn2 O4 cathode and a carbon coated NASICON type LiTi2 (PO4 )3 anode (NASICON=sodium ion super ionic conductor) Energy densities of 63 Wh kg( 1) or 124 mWh cm( 3) and power densities of 3 275 W kg( 1) or 11.1 W cm( 3) can be obtained, which are seven times larger than the largest reported till now. The full cell can keep its capacity without significant loss under different bending states, which shows excellent flexibility. Furthermore, two such flexible cells in series with an operation voltage of 4 V can be compatible with current nonaqueous Li ion batteries. Therefore, such a flexible cell can potentially be put into practical applications for wearable electronics. In addition, a self chargeable unit is realized by integrating a single flexible aqueous Li ion battery with a commercial flexible solar cell, which may facilitate the long time outdoor operation of flexible and wearable electronic devices.
Angewandte Chemie