Cellulose gel dispersion: From pure hydrogel suspensions to encapsulated oil in water emulsions.
Cellulose hydrogel particles were fabricated from molecularly dissolved cellulose/IL solutions. The characteristics of the formed hydrogels (cellulose content, particles' size and porosity) were determined as a function of cellulose concentration in the precursor solutions. There is a significant change in the hydrogel structure when the initial cellulose solution concentration increases above about 7 9%wt. These changes include increase of the cellulose content in the hydrogel, and decrease in its pore size. The finest cellulose particle dispersions can be obtained using low concentration cellulose/IL solutions (cellulose concentration in dispersion less than 2%wt. or hydrogels (concentration less than 1%wt. in a dispersing medium consisting of IL with no more than 20%wt. water. Stable paraffin oil in water emulsions are achieved by mixing oil and water with cellulose/IL solutions. The optimal conditions for obtaining the finest particles (about 20mm in diameter) are attained using cellulose solutions of concentration between 0.7 and 4%wt. at temperature of 70degC and oil/cellulose mass ratios between 1 and 1.5.
Colloids and surfaces. B, Biointerfaces