13174963
(TAML)FeIV O complex in aqueous solution: synthesis and spectroscopic and computational characterization.
Recently, we reported the characterization of the S = (1)/ 2 complex [Fe (V)(O)B*] (-), where B* belongs to a family of tetraamido macrocyclic ligands (TAMLs) whose iron complexes activate peroxides for environmentally useful applications. The corresponding one-electron reduced species, [Fe (IV)(O)B*] (2-) ( 2), has now been prepared in >95% yield in aqueous solution at pH > 12 by oxidation of [Fe (III)(H 2O)B*] (-) ( 1), with tert-butyl hydroperoxide. At room temperature, the monomeric species 2 is in a reversible, pH-dependent equilibrium with dimeric species [B*Fe (IV)-O-Fe (IV)B*] (2-) ( 3), with a p K a near 10. In zero field, the Mössbauer spectrum of 2 exhibits a quadrupole doublet with Delta E Q = 3.95(3) mm/s and delta = -0.19(2) mm/s, parameters consistent with a S = 1 Fe (IV) state. Studies in applied magnetic fields yielded the zero-field splitting parameter D = 24(3) cm (-1) together with the magnetic hyperfine tensor A/ g nbeta n = (-27, -27, +2) T. Fe K-edge EXAFS analysis of 2 shows a scatterer at 1.69 (2) A, a distance consistent with a Fe (IV)O bond. DFT calculations for [Fe (IV)(O)B*] (2-) reproduce the experimental data quite well. Further significant improvement was achieved by introducing hydrogen bonding of the axial oxygen with two solvent-water molecules. It is shown, using DFT, that the (57)Fe hyperfine parameters of complex 2 give evidence for strong electron donation from B* to iron.
45940461
STATUS OF THE FERMI @ ELETTRA PHOTOINJECTOR
The new FERMI@Elettra photoinjector is presently undergoing high-power testing and characterization at MAXlab in Lund, Sweden. This effort is a collaboration between Sincrotrone Trieste, MAX-lab and UCLA. The 1.6-cell RF gun cavity and the focusing solenoid were successfully designed and built by the Particle Beam Physics Laboratory at UCLA, delivered to Sincrotrone Trieste at the beginning of 2008, and installed in the linac tunnel at MAX-lab. Use of the MAX-lab facility will allow the FERMI project to progress significantly with the photoinjector while waiting for the completion of the new linac building extension at Sincrotrone Trieste. We report here on the high-power conditioning of the RF cavity and the first beam tests. STATUS OF THE FERMI@ELETTRA PHOTOINJECTOR∗ M. Trovò† , L. Badano, S. Biedron, D. Castronovo, F. Cianciosi, P. Craievich, M.D. Danailov, G. D’Auria, M. Ferianis, S.V. Milton, G. Penco, L. Pivetta, L. Rumiz, D. Wang, Sincrotrone Trieste, Trieste, Italy M. Eriksson, D.Kumbaro, F. Lindau, MAX-lab, Lunds Universitet, Lund, Sweden H. Badakov, A. Fukasawa, B. O’Shea, J. Rosenzweig, UCLA Department of Physics and Astronomy, Los Angeles, CA 90095
120931097
Stripline beam position monitor for the MIT-Bates South Hall Ring
The MIT-Bates South Hall Ring (SHR) is an electron storage ring currently being commissioned. It is designed to operate at an RF frequency of 2856 MHz with all of the 1812 buckets filled and a circulating current of 80 mA or greater. This leads to a small charge per bunch and the requirement for beam position monitors. Since there will be 31 such monitors in the vacuum system, it is important to suppress trapped modes which may excite coupled bunch instabilities. The stripline monitor built for the SHR is a stainless steel structure, designed to be manufactured using standard machining techniques and commercial feedthroughs. With proper 50 Ohm matching and a geometry derived from insight from MAFIA calculations, the monitor was constructed having a nearly flat RF response up through 10 GHz over the range of measurement. The stripline electronics allows the measurements with 0.1 mm resolution, maintains orbital harmonics information past the 10th harmonic, and operates over a dynamic range of 1 mA to greater than 80 mA of beam current.<<ETX>>
55356715
PROGRESS OF THE eRHIC ELECTRON RING DESIGN
Over the past year, a baseline design of the electron ring for the eRHIC hadron-lepton collider has been developed. This site-specific design is based on the understanding of the existing RHIC machine performance and its possible upgrades. The design includes a full energy polarized electron beam injector to ensure operational reliability and to provide high integrated luminosity. The electron ring energy range is 5 to 10 GeV. The electron beam emittance, the electron beam path length, and the interaction region optics have to be adjustable over wide ranges depending on the ion species and energy for collisions. We describe the design features and expected machine performance. The results of recent beam polarization and beam-beam studies are also discussed.
124623797
HESYRL 200 MeV linac single bunch energy spectrum measurement
The HESYRL 200-MeV electron linac was completed in December 1987, and has been running well. A careful study of the single-bunch energy spectrum for the linac was done. The measurement shows that the energy spread of the linac is +or-0.4%. The energy spectrum is quite stable and repeatable, and the resolution and accuracy are found to be satisfactory.<<ETX>>
55429266
STUDY OF THE ENERGY CHIRP EFFECTS ON SEEDED FEL SCHEMES AT SDUV-FEL
In this paper, theoretical and simulation study of the energy chirp effects on the HGHG and EEHG schemes are present. It is found that the central wavelength and output bandwidth of EEHG can be nearly immune to the beam energy chirp by properly setting the strengths of the chicanes. Experimental studies for both these two schemes have been carried out at the SDUV-FEL to demonstrate the theoretical predictions.
17295428
Influences of the magnetic coupling process on the spectrum of a disk covered by the corona
Context. Recently, much attention has been paid to the magnetic coupling (MC) process, which is supported by the very high emissivity indexes observed in Seyfert 1 galaxy MCG-6-30-15 and GBHC XTE J1650-500. But the rotational energy transferred from a black hole is simply assumed to be radiated away from the surrounding accretion disk in the black-body spectrum, which is obviously not consistent with the observed hard power-law X-ray spectra. Aims. We introduce a corona into the MC model to make it more compatible with observations. Methods. We describe the model and the procedure of a simplified Monte Carlo simulation, compare the output spectra in the cases with and without the MC effects, and discuss the influences of the three parameters involved in the MC process on the output spectra. Results. It is shown that the MC process augments radiation fluxes in the UV or X-ray band. The emergent spectrum is affected by the BH spin and magnetic field strength at the BH horizon, while it is almost unaffected by the radial profile of the magnetic field at the disk. Conclusions. Introducing corona into the MC model will improve the fitting of the output spectra from AGNs and GBHCs.
55579613
Computer simulation of the Maryland Transport Experiment
The longitudinal dynamics of the high-perveance long-pulse electron beam in the Maryland Transport Experiment is examined for the special case of an initially parabolic bunch. Because the longitudinal dynamics can depend on details of time-dependent transverse beam parameters which are difficult to measure, sensitivity studies using r-z simulations have been used to demonstrate that the details of longitudinal beam evolution are insensitive to transverse mismatch, and the bunch length evolution can be accurately described by the one-dimensional envelope equation with the "geometry factor" appropriately chosen. Comparison of experimental data to r,z simulation and to the envelope solution is presented.<<ETX>>
9083411
Improved analysis for the baryon masses to order Lambda(QCD) / m(Q) from QCD sum rules
We use the QCD sum rule approach to calculate the masses of the Lambda_Q and Sigma_Q baryons to the Lambda_{QCD}/m_Q order within the framework of heavy quark effective theory. We compare the direct approach and the covariant approach to this problem. Two forms of currents have been adopted in our calculation and their effects on the results are discussed. Numerical results obtained in both direct and covariant approaches are presented. The splitting between spin 1/2 and 3/2 doublets derived from our calculation is {\Sigma_Q^*}^2-\Sigma_Q^2\simeq 0.35\pm 0.03 GeV^2 which is in good agreement with the experiment.
18266887
A model of the light curves of Gamma-Ray Bursts
Aims. An extreme Kerr black hole (BH) surrounded by a precessing disk is invoked to explain the light curves of gamma-ray bursts (GRBs) based on the coexistence of the Blandford-Znajek (BZ) and the magnetic coupling (MC) processes. Methods. The overall shape of the light curves and the duration of GRBs are interpreted by the evolution of the halfopening angle of the magnetic flux on the BH horizon, and the complex temporal structures are modulated by the precession and nutation of the jet powered by the BZ process. Results. The time profile of the emission exhibits a fast rise and a slow decay due to the effect of the evolution of the half-opening angle. The light curves of several GRBs are well fitted by this model with only six free parameters.
118275882
Longitudinal Beam Dynamics with Space Charge in an FEL Driver Accelerator