119293060
Gamma-ray spectra of hexane in gas phase and liquid phase
Theoretical gamma-ray spectra of molecule hexane have been calculated and compared with the experimental results in both gas (Surko et al, 1997) and liquid (Kerr et al, 1965) phases. The present study reveals that in gas phase not all valence electrons of hexane exhibit the same probability to annihilate a positron. Only the positrophilic electrons in the valence space dominate the gamma-ray spectra, which are in good agreement with the gas phase measurement. When hexane is confined in liquid phase, however, the intermolecular interactions ultimately eliminate the free molecular orientation and selectivity for the positrophilic electrons in the gas phase. As a result, the gamma-ray spectra of hexane become an averaged contribution from all valence electrons, which is again in agreement with liquid phase measurement. The roles of the positrophilic electrons in annihilation process for gas and liquid phases of hexane have been recognized for the first time in the present study.
206352395
The attachment of amino fragment to purine: inner-shell structures and spectra.
The impact of the amino fragment (-NH(2)) attachment on the inner-shell structures and spectra of unsubstituted purine and the purine ring of adenine are studied. Density functional theory calculations, using the LB94/TZ2P//B3LYP/TZVP model, reveal significant site-dependent electronic structural changes in the inner shell of the species. A condensed Fukui function indicates that all of the N and C sites, except for N((1)) and C((5)), demonstrate significant electrophilic reactivity (f(-) > 0.5 in |e|) in the unsubstituted purine. Once the amino fragment binds to the C((6)) position of purine to form adenine, the electrophilic reactivity of these N and C sites is greatly reduced. As expected, the C((6)) position experiences substantial changes in energy and charge transfer, owing to the formation of the C-NH(2) bond in adenine. The present study reveals that the N1s spectra of adenine inherit the N1s spectra of the unsubstituted purine, whereas the C1s spectra experience significant changes although purine and adenine have geometrically similar carbon frames. The findings also indicate that the attachment of the NH(2) fragment to purine exhibits deeply rooted influences to the inner-shell structures of DNA/RNA bases. The present study suggests that some fragment-based methods may not be applicable to spectral analyses in the inner shell.
14421267
Constraining the evolution of dark energy with type Ia supernovae and gamma-ray bursts
Aims. The behavior of the dark energy equation of state (EOS) is crucial in distinguishing different cosmological models. With a model independent approach, we constrain the possible evolution of the dark energy EOS. Methods. Gamma-ray bursts (GRBs) of redshifts up to z > 6 are used, in addition to type Ia supernovae (SNe Ia). We separate the redshifts into 4 bins and assume a constant EOS parameter for dark energy in each bin. The EOS parameters are decorrelated by diagonalizing the covariance matrix. And the evolution of dark energy is estimated out of the uncorrelated EOS parameters. Results. By including GRB luminosity data, we significantly reduce the confidence interval of the uncorrelated EOS parameter whose contribution mostly comes from the redshift bin of 0.5 < z < 1.8. At high redshift where we only have GRBs, the constraints on the dark energy EOS are still very weak. However, we can see an obvious cut at about zero in the probability plot of the EOS parameter, from which we can infer that the ratio of dark energy to matter most probably continues to decrease beyond redshift 1.8. We carried out analyses with and without including the latest BAO measurements, which themselves favor a dark energy EOS of w< −1. If they are included, the results show some evidence of an evolving dark energy EOS. If not included, however, the results are consistent with the cosmological constant within 1σ for redshift 0 < z 0. 5a nd 2σ for 0.5 z < 1.8.
122814293
Constraints on generalized Chaplygin gas model including gamma-ray bursts
Generalized Chaplygin gas (whose equation of state is p GCG = − A/ρ α G CG ) was proposed as a candidate for uni fi cation of dark energy and dark matter. We investigate constraints on this model with the latest observed data. We test the model with type-Ia supernovae (SNe Ia), cosmic microwave background (CMB) anisotropy, X-ray gas mass fractions in clusters, and gamma-ray bursts (GRBs). We calibrate the GRB luminosity relations without assuming any cosmological models using SNe Ia. We show that GRBs can extend the Hubble diagram to higher redshifts ( z > 6 ). The GRB Hubble diagram is well behaved and delineates the shape of the Hubble diagram well. We measure A s ≡ A /ρ α +1 GCG , 0 = 0 . 68 +0 . 04 − 0 . 08 (where ρ GCG , 0 is the energy density today) and α = − 0 . 22 +0 . 15 − 0 . 13 at the 1 σ con fi dence level using all the datasets. Our results rule out the standard Chaplygin gas model ( α = 1 ) at the 3 σ con fi dence level. The Λ CDM is allowed at the 2 σ con fi dence level. We fi nd that acceleration could have started at a redshift of z ∼ 0 . 70 . The concordance of the generalized Chaplygin gas model with the age estimate of an old high redshift quasar is found. In addition, we show that GRBs can break the degeneracy between the generalized Chaplygin gas model and the XCDM model.
73619195
Probing the cosmographic parameters to distinguish between dark energy and modified gravity models
Aims. In this paper we investigate the deceleration, jerk and snap parameters to distinguish between the dark energy and modified gravity models using high redshift gamma-ray bursts (GRBs) and supernovae (SNe). Methods. We first derive the expressions of deceleration, jerk and snap parameters in dark energy and modified gravity models. In order to constrain the cosmographic parameters, we calibrate the GRB luminosity relations without assuming any cosmological models using SNe Ia. Then we constrain the model parameters (including dark energy and modified gravity models) using type Ia supernovae and gamma-ray bursts. Finally we calculate the cosmographic parameters. GRBs can extend the redshift-distance relation up to high redshifts, because they can be detected to high redshifts. Results. We find that the statefinder pair (r, s) could not be used to distinguish between some dark energy and modified gravity models, but these models could be differentiated by the snap parameter. Using the model-independent constraints on cosmographic parameters, we conclude that the ΛCDM model is consistent with current data.
14831898
Processing and Breakdown Localization Rresults For an L-Band Standing-Wave Cavity
An L-band (1.3 GHz), normal-conducting, 5-cell, standing-wave cavity that was built as a prototype capture accelerator for the ILC is being high-power processed at SLAC. The goal is to demonstrate stable operation at 15 MV/m with 1 msec, 5 Hz pulses and the cavity immersed in a 0.5 Telsa solenoidal magnetic field. This paper summarizes the performance that was ultimately achieved and describes a novel analysis of the modal content of the stored energy in the cavity after a breakdown to determine on which iris it occurred.
127622395
Ward identity of two-loop diagrams in SUSY