vWorkspace requires a vCenter server if you are running in a VMware environment. I would recommend grabbing a trial copy of Server 2012 R2 from Microsoft, installing Hyper-V, then creating your vWorkspace servers on that.  Unfortunately, installing a hypervisor in a hypervisor (Hyper-V in VMware Workstation) is not supported so you will need to install it as your base operating system on whatever hardware you use. (There are workarounds for this, but performance takes a huge hit.) I would recommending going here to get some basic information. 
I want to learn Virtual Desktop Infrastructure (VDI). Can someone point me in the right direction?I have a core i7 with 32GB of Ram and VMware workstation.What can be combined into a small footprint?
v_Workspace Home Lab