To my knowledge no because VPLEX works only on a block level. 
Currently I have a VNX5700 connected to a VPLEX local.  I will be adding a new VNX7600 to the same VPLEX local and performe a migration of the data.  My question is can CIFS be migrated using VPLEX data mobility without any impact to production?  Block level can. 
Migrating CIFS via VPLEX