other than where otherwise indicated or understood , all numbers expressing quantities of ingredients or reaction conditions used herein are to be understood as modified in all instances by the term “ about ”. in addition , it is understood that the term “ metals ” also includes metalloids . in formula ( ii ), when r 1 is methyl or ethyl , and in formula ( v ), m is preferably 1 . 5 to 3 , more preferably 2 to 3 . the styryleneoxy groups may be unsubstituted , or may contain substituents on the phenyl group , such as one or more c 1 - c 6 - alkyl groups , c 1 - c 6 - alkoxy groups , and / or other groups that will not interfere with electrolysis . the compounds of formula ( ii ), in which r 1 is methyl or ethyl , i . e ., sulfonate - or sulfate - capped , alkoxylated trim ethylol - ethane or propane compounds , are preferred compounds of the invention . such compounds , in which ao is eo or po , are preferred , and those in which ao is eo are more preferred . most preferred are the propane derivatives of formula ( ii ), in which r 1 is ethyl . electrolyte solutions containing , and methods of reducing misting in electrolyte solutions by adding , either alone or in a mixture with one or more compounds of formula ( i ), one or more compounds of formula ( ix ), in which r 3 is represented by formula ( xi ), r 5 is preferably c 3 - c 6 alkyl , and z is preferably 2 to 3 , more preferably 3 , as well as those in which the r 3 group is represented by formula ( x ), where r 3 is hexyl , octyl , an octyl / decyl mixture , or decyl , and where the r 4 group is represented by formula ( xii ), are preferred . the above alkoxylated compounds may be readily produced by alkoxylating the corresponding alcohols and / or amines by methods well known to those skilled in the art , e . g ., by reacting the alcohols and / or amines with the desired quantities of alkylene oxides . the compounds in formula ( dc ), in which the r 3 group is represented by formula ( x ), where r 3 is decyl , and where the r 4 group is represented by formula ( xii ), may be readily produced by reacting a n , n - dimethyl tertiary amine with either 1 , 3 - propanesultone or with sodium chloroacetate , according to standard techniques described in the literature . the anti - misting agents - the novel compounds and / or the compounds not previously known to be useful as anti - misting agents - according to this invention are useful in reducing or minimizing the misting problems that may be present in electrowinning compositions , electroplating compositions , and / or electroforming compositions and / or in procedures that utilize aqueous electrolyte solutions of metals ions or aqueous electrolyte dispersions of metals in metallic form , as well as with waste solutions containing dissolved metals . in all cases , it being understood that the metals / metalloids may be present in ionic form and / or in elementary form . and in the electrolysis of metals from aqueous electrolyte solutions containing the metal ( s ) to be captured , the utility of the compounds according to the present invention is not dependent on the particular metal ( s ) present in the electrolyte solutions . the anti - misting agents of the present invention are effective in quantities as low as a few parts per million , based on the electrolyte composition , e . g ., from 2 - to - 100 ppm , preferably from 2 - to - 30 ppm , and most preferably from 5 - to - 25 ppm . in an electrowinning application , they may be added to the aqueous strip solution used in the stripping stage following the solvent extraction stage , or to the metal - pregnant aqueous solution that results from the stripping of the organic phase in the stripping stage , or , preferably , to the metal - containing electrolyte / strip aqueous phase in the electrowinning tankhouse . there are a number of electroplating methods for which the demisting agents of the invention may be used . materials , such as strip steel , may be plated in plating tanks where coils of steel are unrolled in a continuous basis , fed through a series of preparation steps , and then into the plating tank . wire that is uncoiled from the spools or reels on which it was wound , may be passed through various processing steps and then plated , with metals , such as copper , copper alloys , zinc , iron , iron alloys , nickel , nickel alloys , gold , or silver , as individual strands . stampings , moldings , and castings are typically mounted onto specially - designed plating racks for electroplating . small parts , e . g ., dipping baskets and plating barrels made of inert plastic materials , may be electroplated using bulk plating methods . where parts are large and only smaller areas of the parts are to be plated , brush placing is used , i . e ., using plating tools which are shaped anode materials covered with an absorbent material saturated with the plating solution . insoluble anodes are used exclusively in the plating baths of the present invention . chromium plating solutions utilize lead - tin , lead - antimony , or just lead anodes ; gold and other precious metal plating processes use stainless steel anodes , keeping inventory costs down . however , the use of insoluble anodes may , unfortunately , also result in side effects . in alkaline cyanide solutions , the generation and buildup of carbonates is accelerated as a result of the use of insoluble anodes , along with a significant reduction in alkalinity . in acidic solutions , the ph decreases , requiring frequent adjustments . in sulfamate nickel plating solutions , insoluble anodes , and even slightly passive soluble anodes , partially oxidize the sulfamate ion to form sulfur - bearing compounds which change the character and performance of the deposit . ( see kirk - othmer , supra ). the synthesis of the sulfoalkyl derivatives of the compound of formula i ( i . e ., those in which b =( ch 2 ) q so 3 y ) may typically be accomplished as a two - step reaction that may be performed in the same reaction vessel . the first step of the reaction involves the addition of sodium metal to the alkoxylated polyol ( i . e ., one of the compounds from formula ( ii )-( vi )) to form the corresponding terminal sodium alkoxide . the second step of the reaction is the addition of 1 , 3 - propane sultone to the sodium alkoxide formed in the first step . toluene ( or other inert organic solvent ) is used as the solvent throughout the process . the sulfonate - capped derivatives of the compounds of formula ( i ) in which b = ch 2 chohch 2 so 3 y ( 2 - hydroxypropanesulfonate ) may also typically be accomplished as a two - step reaction ( known as a williamson synthesis ) that may be performed in the same reaction vessel , preferably in an inert organic solvent , such as toluene . the first step of the reaction involves the addition of sodium metal to the alkoxylated polyol ( i . e ., one of the compounds from formula ( ii )-( vi )), as above , in order to form the corresponding terminal sodium alkoxide . the second step of the reaction is the addition of 3 - chloro - 2 - hydroxy - 1 - propanesulfonic acid sodium salt to the sodium alkoxide formed in the first step , and the product is recovered by addition of water to the organic phase after cooling . the aqueous phase is then isolated . the production of the sulfate - capped derivatives of the compounds of formula ( i ), in which b = so 3 y , may be accomplished by starting with the same ethoxylated polyols ( i . e ., one of the compounds from formula ( ii )-( vi )) described above and converting their terminal hydroxyl groups to sulfates by reactions known in the art . alternatively , the terminal hydroxyl may be capped by reacting them with allyl chloride , and then adding sulfuric acid across the double bond to give a slightly different type of sulfate cap . the alkoxylated compounds of formula ( i ) above , may be readily prepared by alkoxylating the corresponding alcohols and / or amines by methods well known to those skilled in the art , e . g ., by reacting the alcohols and / or amines with the desired quantities of alkylene oxides . such syntheses are illustrated and / or exemplified in synthetic detergents , a . s . davidsohn and b . milwidsky , seventh edition , longmanscientific and technical , 1987 , pp . 178 - 191 , and kirk - othmer , encyclopedia of chemical technology , 3rd edition , volume 9 , john wiley and sons , new york , 1980 , p . 437 , among other places . the compounds of formula ( ix ) are classified as betaines . the compounds , in which the r 3 group is represented by formula ( xi ) and the r 4 group is represented by formula ( xiii ), are called sulfobetaines betaines . such compounds , where z = 3 , are called 3 -[( 3 - alkylamino - propyl )- n , n - dimethylammonio ]- propane sulfonates or 2 - hydroxy - 3 -[( 3 - alkylamino - propyl )- n , n - dimethylammonio ]- propane sulfonates ( if the r 5 group is c 1 , then replace “ alkyl ” with “ methyl ”; if the r 5 group is c 2 , then replace “ alkyl ” with “ ethyl ”; if the r 5 group is c 3 , then replace “ alkyl ” with “ propyl ”, and so on ). the first step in the synthesis in both cases is the reaction of 3 -( dimethylamino ) propyl amine with an ester under standard transamidification conditions to generate the corresponding amide . in the second step , the resulting amide is reacted with either the 1 , 3 - propane sultone or 2 - hydroxy - 3 - chloropropanesulfonic acid under conditions known in the art . the compounds of formula ( ix ), in which the r 3 group is represented by formula ( x ) and the r 4 group is represented by formula ( xiii ), are classified as alkyl n , n - dimethylsulfonates . the synthesis of the compounds is accomplished by the reaction of 1 , 3 - propane sultone or 2 - hydroxy - 3 - chloropropanesulfonic acid with a n - alkyl - n , n - dimethyl amine in anhydrous acetone using , conditions known in the art . these compounds of formula ( ix ), in which the r 3 group is represented by formula ( x ) and the r 4 group is represented by formula ( xii ), are classified as alkyl n , n - dimethylglycines . the synthesis of the compounds is accomplished by the reaction of sodium chloroacetate with a n - alkyl - n , n - dimethyl amine in water . after the reaction is complete , there is no need to further purify of the product . the invention is further illustrated , but not limited , by the following examples , the compounds for which were prepared by first reacting ethylene oxide with triethanolamine , then reacting the resulting product with 1 , 2 - propylene oxide . to a 5000 ml round bottom flask equipped with a dean - stark trap / condenser / drying tube , a mechanical stirrer , and a pressure - equalizing funnel , was added 199 . 5 g ( 0 . 45 mol ) trimethylolpropane that has reacted with seven moles of ethylene oxide and 2 . 75 - 3 l of toluene . the solution was refluxed for four hours to remove any water ( azeotrope using the dean - stark trap ). the dean - stark trap was then removed , and the condenser was replaced with a dry condenser . the temperature of the reaction flask was kept at just the refluxing temperature of toluene ( overheating causes the solution to darken considerably ). to the reaction flask was then added 31 . 05 g ( 1 . 35 mol , 1 mol equivalents to the hydroxyl groups of the trimethylolpropane containing seven ethyleneoxy groups ) of sodium metal , washed with hexane prior to use , over a one hour period . addition of the sodium metal resulted in a substantial increase in temperature . the solution was then stirred for four additional hours . while there was some sodium still in the reaction vessel , it was completely consumed in the next phase of the reaction . 1 , 3 - propane sultone ( 165 . 0 g , 1 . 35 mol ) was transferred to the addition funnel along with 400 ml of toluene . the addition of the 1 , 3 - propane sultone was performed over a 20 - 30 minute period . addition of the 1 , 3 - propane sultone was carefully monitored because of the extreme temperature increase at the beginning of the addition , and the formation of an intractable solid at the end of the addition . the solution was stirred as the 1 , 3 - propane sultone was added , and continued to be stirred until the formation of the solid product caused the mechanical stirrer to stop , then the toluene was decanted off while still hot . to remove the solid , the contents of the flask had to be dried using a vacuum pump and the solid broken apart with a steel rod . the solid was collected , crushed , and washed with hot toluene . the crushed solid was dried using a vacuum of 500 millitorr , and was pulverized using a mortar and pestle . the yields from three runs of this preparation were 95 . 45 %, 91 . 37 %, and 97 . 8 % respectively ( this preparation is typical for formula i compounds ). the following is a typical reaction for the synthesis of the alkyl n , n - dimethylglycines . to a 500 ml flask 3 necked flask equipped with a condenser , a mechanical stirrer , and the other opening sealed with a teflon stopper was added 92 . 70 g n - decyl - n , n - dimethyl amine ( 0 . 50 mol ) and 58 . 25 g sodium choloroacetate ( 0 . 50 mol ) dissolved in 151 . 0 g of water . the solution was heated to 90 ° c . using a silicon oil bath . the temperature was kept constant throughout the reaction using a temperature probe connected to the hotplate . the stirring rate was kept at 250 rpm throughout the reaction . after three hours a sample was taken and potentiometrically titrated with 0 . 1 m naoh using standard techniques . since there was no free amine present (& lt ; 1 %) the reaction was terminated . the yield from the reaction was quantitative . ( this preparation is typical for alkyl n , n - dimethylglycines .) in order to demonstrate the anti - misting characteristics of these products , two compounds of the invention : the tri - sodium sulfopropyl ether of trimethylolpropane containing seven ethyleneoxy groups ( compound a ) and the tri - sodium sulfopropyl ether of triethanolamine containing six polyoxypropylene groups and eleven polyoxyethylene groups ( compound b ) were tested against five hundred ml samples of copper electrolyte solution ( 50 g / l cu + 2 , 0 . 2 g / l co + 2 , 1 . 5 g / l fe + 3 , 170 g / l sulfuric acid ) in a jacketed beaker controlled at 45 ° c ., with mist being generated by passing air through a fine frit ( 4 - 8 micron ) scintered glass bubbler in the copper electrolyte . the mist was sampled by suctioning air through a sampling tube 1 . 5 inches above the liquid level , the tube being connected to a water trap . at timed intervals , the water from the trap was titrated with sodium hydroxide to a bromphenol blue endpoint to determine the amount of acid contained therein , the results in the table being calculated in millimoles of sulfuric acid captured per hour . the results of the anti - misting tests are shown in table 1 : three anti - misting agents according to the invention ( compound a [ from example 2 , where m is ˜ 3 ], the sodium sulfopropyl ether of monoethanolamine containing six propylene oxide groups and eleven ethylene oxide groups , where in is ˜ 3 [ compound c ] and monoethanolamine containing six propylene oxide groups and eleven ethylene oxide groups reacted with only two moles of propane sultone for each mole of the monoethanolamine , where m is ˜ 2 [ compound d ]) and monoethanolamine contacted with six moles of propylene oxide and eleven moles of ethylene oxide ( compound 1 , the preferred embodiment from u . s . pat . no . 6 , 843 , 479 ), and a blank run with no anti - misting agents , were tested in an electrowinning apparatus with guar added as a smoothing agent . the basis for all three new molecules is either compound 1 or trimethylolpropane containing seven ethyleneoxy groups . the three anti - misting agents according to the invention tested were : the results demonstrated that compound a provided a clean , even plate . the plate of compound b was almost as good quality as that of compound a . however , the plate of compound c showed that it had a slight tendency to form nodules . earlier testing demonstrated that the plate for compound 1 contained substantial nodule growth which not only results in a poor plate quality for copper recovery , but also can produce hazardous electrical conditions in the cell . for each 16 - hour run , 35 l of electrolyte was prepared with concentrations of 38 g / l cu , 2 g / l fe 3 + , 0 . 1 g / l co , 0 . 01 g / l cl , and 175 g / l h 2 so 4 . this was accomplished by dissolving appropriate levels of cuso 4 , fe 2 ( so 4 ) 3 , coso 4 , nacl , and h 2 so 4 in deionized water . each solution was then split into two 5 - gal buckets to feed the electrowinning for two days at eight hours each day . an electrowinning cell , housing one cathode and two anodes , was made from pvc plastic and fitted with a water jacket in order that the cell could be maintained at a given temperature . the cathodes were cut from stainless steel with a surface plating area of about 3 in × 3 in ( 0 . 0625 ft 2 counting both sides ) and a thickness of slightly less than one - sixteenth inch ; the anodes were lead plates and slightly smaller in width and height than the cathode . the electrolyte in the cell , while running , measured 11 cm deep × 8 cm wide × 12 . 5 cm long , for a volume of 1 . 1 l , and it was pumped into and out of the cell at a rate of 28 ml / min , in order to achieve a 3 g / l drop in cu concentration across the cell . the current density used in the experiments was 30 a / ft 2 ( within the typical tankhouse current densities of between 12 and 38 a / ft 2 ), and based on the surface area of the cathode , the current needed to flow to the cell was calculated to be 3 . 75 a . at the beginning of each test , 0 . 07 g ( 4 ppm ) of galactasol ® 40h4cd guar gum derivative and 0 . 175 g ( 10 ppm ) of the potential demisting agent for that run were added , while stirring with an impeller , to one of the two buckets containing the electrolyte . the jacket for the electrowinning cell was filled with deionized water and hooked up to a recirculating water bath in order to maintain the electrolyte in the cell at 45 ° c . the inlet tube for the cell was run through a peristaltic pump set to 28 ml / min and placed into the bucket containing the spiked electrolyte , which had been warmed up on a hot plate to ˜ 45 ° c ., with the exit tube being placed in a clean , empty 5 - gal bucket . the 1200 ml of warm electrolyte was added to the cell to fill it to the appropriate level ( in order that the submerged area of the cathode was 0 . 0625 ft 2 ). the anode and cathode were hooked up to a constant current power supply , and the pump was turned on . once the lines were full and the electrolyte was flowing through the cell , the power supply was turned on and set to 3 . 75a continuous current . this arrangement was run for eight hours before turning off the power supply , the water bath supplying the jacket , and the peristaltic pump , and the wire to the cathode from the power supply was unhooked in order to prevent current backflow . after allowing the cathode to sit in the bath overnight , the cathode was dried , weighed , and photographs were taken of it . the above procedure was repeated the following day with the second batch of tests solutions . again , after allowing the cathode to sit in the bath overnight , the cathode was dried , weighed , and photographs were taken of it . the electrowinning tests for compound a and compound d ( compound c was not checked ) were repeated in a 40 - hour run in order to ensure no obvious negative characteristics of the copper deposit . each 40 - hour run required 70 l of electrolyte , split into five 14 - l batches , each batch receiving 0 . 056 g ( 4 ppm ) of the guar polymer and 0 . 14 g ( 10 ppm ) of the demisting agent being evaluated . these runs confirmed that compound a produces high quality plates and compound d tends to produce plates having a limited number of small nodules . the extraction circuit kinetics tests were run using the cognis standard quality control test method in order to determine whether the tested anti - misting agents were too soluble in the organic phase or have an adverse effect on phase separation in the extraction stripping phase . a 4 - l batch of 10 v / v % llx ® 984n mixed ketoxime / aldoxime extraction reagents was made up in conoco ® 170exempt aliphatic diluent . one - liter of cognis qc electrolyte ( i . e . solution contains 35 ± 0 . 7 g / l cu ( as the sulfate ) and 160 ± 2 g / l h 2 so 4 ) batches ( six in total ) were spiked to levels of 20 and 50 ppm ( three with 20 ; three with 50 ), respectively , with each of compounds a , c and d ( from example 3 ). one liter of qc electrolyte , without any demisting agent , was run through the qc test as a control batch . a 400 - ml sample of the uk 984n reagent solution was contacted with 400 ml of one of the electrolyte solutions for 3 minutes by shaking vigorously in a 1 - l separatory funnel . the solutions were allowed to separate , a sample of the equilibrated organic ( e . o .) was taken , and 350 ml of the organic was placed in a 1 - l baffled beaker . an impeller was lowered into the organic solution in order that the top of the polypropylene hub of the impeller was at the surface level of the organic . the impeller was started up at 1750 rpm and 350 ml of a control feed ( 6 . 0 g / l cu , 3 . 0 g / l fe + 3 , ph = 2 . 0 ) was added over five seconds . a sample of the emulsion was taken at 30 seconds to obtain a sample of the organic ( e30 ). the mixing continued for 300 seconds total at which time the mixer was stopped . the time required for a complete separation of the phases was then determined ( phase break time ). a sample of the organic after 300 seconds of mixing ( e300 ) was then taken . the organic and aqueous phases were transferred to a 1 - l separatory funnel and allowed to separate again . a 325 - ml sample of that organic was placed in a 1 - l baffled beaker and a clean impeller was placed at the same level as the extraction test . the impeller was started up at 1750 rpm and 325 ml of the same qc electrolyte as the first contact was added over 5 seconds . a sample of the emulsion was taken at 30 seconds to obtain a sample of the organic ( s30 ). the mixing continued for 300 seconds total , at which time the mixer was stopped , and the phase break time was then determined . a sample of the organic phase was then taken ( s300 ), with the results for the seven kinetics tests shown in table 1 . the above extraction circuit kinetics data demonstrates that compound a and compound c do not have any substantial impact on the solvent extraction performance . however , compound d does appear to have a small negative impact on phase separation . surface tensions were measured on qc electrolyte with compounds a , c and d , fc1100 , and mistop at levels of 5 , 10 , 20 , and 40 ppm . the results are shown in table 3 . based on the above surface tension comparisons , compounds a , b , and c are equally effective in lowering the surface tension of the electrolyte as the commercially - accepted fc1100 . surface tension measurement of qc electrolyte containing various concentrations of anti - misting agents were performed as the reduction in surface tension is a good indicator of mist suppression behavior . these measurements were carried out utilizing a fisher surface tensiomat 21 in manual mode utilizing the du nouy methodology ( standard method ). results for the most preferred compounds of the invention may be found in table 1 ; compound e ( n - decyl - n , n - dimethylglycine ), compound f ( n - octyl - n , n - dimethylglycine ), compound g ( n - dodecyl - n , n - dimethylglycine ). fc - 1100 , from 3m , is the commercially accepted anti - misting agent . in order to measure acid mist suppression of anti - misting agents of formula ( lx ), these compounds were added to an operating electrowinning cell . the electrolytic cell was made of 3 / 16 ″ thick lexan plastic and measured 3 . 5 ″ in width , 8 . 5 ″ in length , and 6 . 5 ″ in depth . an overflow weir was placed near the exit side of the cell and measures five inches in height . an entrance baffle , also 5 ″ in length , was placed near the electrolyte entrance . along the top of the cell , nine squarecut grooves were cut to allow the anode and cathode busbars to sit on cell . centered 0 . 5 ″ beneath the 4 th groove cut , a 5 / 16 ″ hole was bored out to serve as a sample port . two 0 . 5 ″ holes were bored in the opposite ends of the cell to serve as feed entrance and exits . the entrance hole was bored at 4 . 25 ″ from the bottom of the cell , and the exit hole was bored at 2 . 5 ″ above the bottom of the cell . teflon - taped fittings were screwed into the ends to provide for tubing attachments . anodes and cathodes were cut in order to fit the electrowinning cell . lead anodes were cut from 1 / 16 ″ thick lead sheet and measure 3 ″× 5 . 25 ″. the anodes were attached to a copper busbar with two small threaded screws and 12 gauge copper wire was run between the two anodes in series . the last anode was connected with 12 gauge copper wire to the positive terminal of the dc power supply . cathodes were made from 1 / 16 ″ thick stainless steel 316 ( ss316 ), and had the same dimensions as the anodes . similarly to the anode , the cathode was attached to a copper busbar with a threaded screw with 12 gauge copper wire connections between cathodes . the busbar was connected to the negative terminal on the dc power supply . the collection of acid mist was accomplished by drawing the mist through a reservoir of water in an erlenmeyer flask at a constant flow rate ( 1800 ml / min through a 1 / 16 ″ inlet nozzle ). after a timed interval , the water from the reservoir was titrated with a standardized sodium hydroxide solution to a phenolphthalein endpoint . the amount of sodium hydroxide used in the titration was then used to determine the relative amount of acid mist . copper electrolyte was prepared in 40 l batches and included : 35 g / l cu , 2 g / l fe 3 + , and 1780 g / l h 2 so 4 . this was done by dissolving appropriate levels of cuso 4 , fe 2 ( so 4 ) 3 , and h 2 so 4 in deionized water . analysis of the solution was performed prior to running by aas . approximately 15 ppm of galactasol ® 40h4cd guar solution was added to the electrolyte for cathode smoothing purposes . an anti - misting agent was then added at the appropriate concentration , and the entire solution was thoroughly mixed prior to introduction into the ew cell . the electrolyte was introduced into the electrolytic cell at a flow rate of 30 ml / min via a peristaltic pump . the electrolyte reservoir was placed in a re - circulating water bath in order to control the temperature to between 40 ° c . and 42 ° c . a stir bar was placed in the electrolytic cell to ensure proper mixing . once the electrolyte had reached 40 ° c ., the dc power was turned on and voltage and amperage adjusted to give 4 . 10 a at 5 . 0 to 5 . 2 v . this should provide a current density of ˜ 300 a / m 2 , in a single - cathode arrangement . the electrolytic reaction was allowed to proceed for three hours . after three hours , the sample probe and tubing were rinsed with a few aliquots of di water into the water trap to qualitatively transfer any residual acid on the interior surfaces of the probe and tubing . a few drops of phenolphthalein were added to the water in the erlenmeyer flask . the acid mist / water sample was then titrated with standardized 0 . 1 m naoh . the endpoint of the titration is indicated by a change in color of the solution from clear to pink . the amount of naoh is proportional to the acid mist generated and the results of the analysis are shown in table 2 for the most preferred betaines ( compounds e , f , and g ). mist values for the 40 and 50 ppm concentrations of compound g in table 2 were very low due to foaming on the surface of the electrowinning solution . at no other time was any foaming noticed for the other compounds in the electrowinning trials at concentrations up to 100 ppm . effect of anti - misting agent on extraction circuit kinetics of compounds of formula ( ix ) extraction circuit kinetics were obtained using a two extraction / one strip stage ( 2e / 1s ) circuit in order to determine whether the anti - misting agents had a negative effect on the organic phase or the phase separation times . the counter - current 2e / 1s system was comprised of lexan mix boxes ( 180 ml capacity ), each containing an impeller mixer which agitates the solution in the mix - box portion of the stage . the residence time of the cell was 180 seconds . the impellers were run at 1750 rpm and the continuity of the system was kept organic continuous . initial levels of pregnant leach solution ( pls ), strip electrolyte ( se ), and loaded organic ( lo ) were added to the appropriate mix boxes . an initial equilibrium was established with the organic by pre - contacting fresh organic reagent with strip electrolyte prior to addition into the circuit . pls was fed into the system at a rate of 15 ml / min . organic ( either 10 % v / v or 30 % v / v lix ® 984n in shellsol d70 ) was pumped from an overflow surge tank into the circuit at a rate of 30 ml / min . strip electrolyte was also pumped in at a rate of 30 ml / min . all circuit stages were kept at ambient temperature with the exception of the strip stage . the strip stage was heated to between 40 ° and 42 ° c . the circuit was run for a minimum of 24 hours of operation . synthetic electrolyte (˜ 35 g / l cu , 2 g / l fe 3 + , 180 g / l h 2 so 4 , 15 ppm guar ) was pre - dosed with a specific concentration of mist suppressant . as this solution was run through the circuit , samples were taken to determine if there were any issues with kinetics or circuit metallurgy . overall organic entrainment and phase - break times were determined for the two lix ® 984n concentrations ( 10 % and 30 %). samples were taken after approximately 24 hours of total circuit run time and analyzed for metal concentrations in the various circuit operations ( strip , e1 , e2 , raffinate streams ). the results of the analysis may be found in table 3 . the only negative impact on solvent extraction by the most preferred anti - misting agents ( compounds e , f , and g ) occurred when using compound g . at low concentration ( 10 ppm ), compound g was noted to cause a stable emulsion layer to form in the strip stage . this emulsion layer did not break and was stable for well over 24 hours , filling the settler box nearly to its full depth . no emulsion layers were noted with compounds e or f at any dosage concentration . entrainments for compounds e or f were in the 100 - 300 ppm range , which is consistent with industrial levels . all other results in table 3 are consistent with normal operating values . copper was plated for 8 - 22 hours using the same conditions as described in example 1 in order to inspect the quality of the copper deposited . the quality of the cathode was determined by a visual inspection using microscopy at low power ( approximately 125 × magnifications ). the cathode produced using compounds e , f , g and fc - 1100 was of high quality and had essentially smooth plates with little to no nodulation .