as we have previously stated in the objects occupying the summary of this invention , much prior research in this field shows that to have matched sizes of phosphate and coke as the charge in a phosphorus furnace is highly beneficial and results in a more efficient operation . experimental data show that the capacity of a phosphorus furnace can be increased about 12 percent by changing from unmatched to matched charge sizes . at the same time , this research showed that there was a marked decrease in furnace pressure fluctuations which occurred when unmatched sizes of nodules and coke were replaced by matched sizes of these materials . this has , as stated , reduced electrical energy consumption by approximately ten percent . as shown in fig1 i have provided a small scale ( bench scale ) apparatus suitable for experimental agglomerations which comprises an extended lengthwise cylinder or drum 1 , provided with a feed end 2 and a discharge end 3 . referring to fig2 and 3 , the end of the drum 2 is provided with a circular feed opening 4 , while the discharge end 3 of the drum has located inwardly therefrom in spaced relation a movable retaining ring 5 . the retaining ring 5 is provided with a circular opening 6 and there are welded to the retaining ring three nuts 7 spaced at 120 ° intervals around the circumference of the ring . each of the nuts 7 receive screws 8 which are adapted to be tightened against the surface of the inside of the cylinder . to the discharge end of the drum there is welded a circular overlapping flange 10 to which is in turn secured a strap 11 by means of bolts 27 and nuts 28 . to the center of strap 11 there is welded a universal joint 13 whose outer end forms a drill shaft 14 . it can be seen that the shaft 14 is received by the chuck 15 of a mounted drill 16 . the electric drill 16 is suitably fastened to a wooden block 18 which is in turn bolted fast to a table 19 . the table 19 is provided with a suitable discharge opening 20 immediately below the drum and below which opening is placed a dish 21 to receive the discharged material . the drum 1 is mounted to rest on four rollers or casters 22 , which casters are suitably fastened to baseplate 23 attached to the table 19 . the table 19 has suitable leg blocks 24 which support the table away from the main surface of the work area . at the power end of the table there is mounted thereon a variac type of solenoid control through which the power cord 26 for the drill 16 passes . in this manner it can be seen that the rotating speed of the drum or cylinder can be regulated from the discharge end . the strap 11 can be removed for servicing or removal of the retaining ring 5 . at the feed end of the drum , there is welded an l - shaped flange 29 which strikes the arm of a counter 30 mounted on the table 19 . due to the fact that the speed with which the drum or cylinder is rotated in its mounting may vary and may be extended for periods of time , it is necessary that a source of cooling air be supplied for the motor of the electric drill in the embodiment of the invention shown . therefore , we have indicated that a hose 31 for cooling air should be mounted over the motor by suitable means in order to direct a blast of air on the motor for cooling . an apparatus of the type illustrated in the embodiment shown in fig1 and 3 has been used quite successfully for preparing small quantities of agglomerated materials . in an apparatus which i have constructed of this type , the drum is a cylinder ten inches in diameter by eighteen inches long . it is fabricated from 16 - gauge a . i . s . i . type 304 stainless steel . the critical speed of the rotating cylinder is the speed above which solid material will be carried around on the inside surface of the drum by centrifugal force . this speed is determined by r = 76 . 5 /√ d , where d is the diameter of the cylinder in feet and r is the critical speed in revolutions per minute . the critical speed of the apparatus shown in fig1 is 84 rpm . the variable speed drive is a 1 / 4 - inch industrial electric drill . full speed is 1760 rpm , but the speed can be reduced by controls on the electric drill . close speed control is achieved by inserting a variable speed reducer in the motor circuit , such as a variac speed control commonly used with laboratory equipment . operation for periods up to 30 minutes at speeds lower than 84 rpm will cause the motor to overheat and burn up unless supplemental cooling is applied . to provide the necessary cooling , part of the motor housing was removed and compressed air from the laboratory supply was applied on the motor winding at a rate of 18 liters per minute . the drum is turned by a 1 / 4 - inch shaft which fits in the chuck on the electric drill which also permits the drum to be readily and easily removed from the assembly . the entire assembly , as seen , is mounted on a wooden block , as shown , and the apparatus is light enough to permit it to be readily moved about the laboratory ; and it is small enough to be placed under most laboratory hoods . as will be obvious , the mixing in the laboratory experiments was done for the most part in a batch fashion , in a suitable tub , bowl or other container , as will be indicated by the examples which follow hereafter . of course , referring more particularly to fig4 it can readily be seen that any number of commercial type mixers , agglomerators and dryers for indurating the agglomerates can be employed . one is diagrammatically shown in fig4 wherein a mixer of the cylindrical rotating type 34 is mounted in sequence with a cylindrical rotating agglomerator 36 . the mixture is fed into the feed end of the mixer 35 and discharged into the agglomerator from the discharge end 37 , where it is received by the feed end 38 of the agglomerator and moved there through to the discharge end 39 . the agglomerator 36 would be provided with a sparger 40 . the agglomerated material would be discharged into the chute 41 which enters the dryer 42 , which is in turn fed by hot air entering through the tube 43 and discharged through the tube 44 . within the dryer the agglomerated material is discharged on a moving belt 46 where it is indurated by the heat and discharged at point 47 in the process . the following examples are offered to illustrate properly the use of the apparatus which is the subject of my invention and the process employed , as well as the composition of matter which is produced as a new composition . metallurgical coke was purchased for use as a reducing carbon to make elemental phosphorus . the incoming coke was dried and screened on a 10 - mesh screen to remove fines before the reducing carbon was blended with phosphate and silica . the minus 10 - mesh coke fines were accumulated as a solid waste . the pile of coke fines absorbed moisture from rainfall , and some extraneous material larger than 10 - mesh in size accumulated in the pile . a sample from the fines pile was obtained ; the moisture content was determined to be 8 . 2 percent . part of the sample was screened on a 12 - mesh u . s . sieve ( openings 1 . 68 mm ) to obtain material for agglomeration experiments . the plus 12 - mesh material was rejected . a sample of merchant - grade wet - process phosphoric acid ( 52 - 54 % p 2 o 5 ) was obtained from a railroad car . wet , screened coke and phosphoric acid were mixed by hand in a plastic container in proportions of 330 grams of coke ( wet basis ) and 64 grams of acid . ninety grams of water were added . thirty - six grams of reagent aqua ammonia ( 29 % nh 3 ) were added . the quantity of ammonia added was inadequate for the complete neutralization of the phosphoric acid ; the n : p 2 o 5 weight ratio of the product was 0 . 26 , assuming all the ammonia reacted . the temperature of the mixture increased to 70 ° c . when ammonia was added . the mixture was fed to the agglomerator shown in fig1 in six equal portions at a rate of about 74 grams per minute . the agglomerator drum rotated at a speed of 45 rpm , or approximately half its critical speed . the drum was horizontal during the experiment . the mixture discharged from the drum as rounded agglomerates after a retention time estimated to be 20 to 30 seconds . the freshly formed agglomerates were easily deformed . they fell about 1 inch onto an improvised ramp and rolled down the ramp into a container . a jet of compressed air was used to assist the agglomerates in rolling down the ramp . the agglomerates were dried 3 hours at 120 ° c . in a drying oven . the dried material contained 9 . 5 percent p 2 o 5 and 1 . 9 percent n . essentially all of the material was formed into agglomerates larger than the openings in a no . 6 u . s . sieve ( 3 . 36 - mm openings ), and the average diameter of the agglomerates was estimated to be 3 / 8 - inch ( 9 . 5 mm ). the average crushing strength of a 3 / 8 - inch diameter agglomerate was 11 pounds . an experiment similar to that described in example i was carried out using sludge acid as the binder instead of merchant - grade wet - process phosphoric acid . a sample of sludge acid was obtained from material that had settled out in a railroad car used to transport the merchant - grade acid . the sludge was formed by post - precipitation of impurities in the acid during transit . the usual p 2 o 5 content of the sludge acid is 38 percent . a mixture was prepared containing the following constituents . 440 grams of wet coke fines ( 405 grams on a dry basis ) the p 2 o 5 content of the dried agglomerates was estimated to be 9 . 0 percent , and the nitrogen content was calculated to be 4 . 9 percent with a n : p 2 o 5 weight ratio of 0 . 52 . although some ammonia volatilized without reacting , it is believed that the sludge acid was neutralized to diammonium phosphate . the crushing strength of 3 / 8 - inch agglomerates was 7 pounds . florida pebble phosphate was crushed to provide some material smaller than 6 mesh in size . fifty - nine percent was minus 6 mesh , plus 12 mesh and 42 percent minus 12 mesh . a 500 - gram sample of the phosphate fines was mixed with 50 grams of water in a plastic container . the damp mixture was placed in the laboratory agglomerator shown in fig1 . the agglomerator was operated batchwise during this experiment by installing a plate over the discharge end . the drum had a slope of 3 °; the drum sloped toward the discharge end . the drum was rotated at a speed of 60 rpm . merchant - grade wet - process phosphoric acid was injected into the tumbling material through openings in a stainless steel sparger tube . the sparger was placed in the 5 o &# 39 ; clock position as viewed from the feed end ; the drum rotated counterclockwise . the sparger was about 1 inch from the wall of the drum . one hundred grams of the acid was sparged into the bed of material over a 9 - minute period beginning at the start of rotation . fifty - five grams of anhydrous ammonia was sparged into the drum through openings in another stainless steel tube . the ammonia added was adequate to make diammonium phosphate , but no allowance was made for unreacted ammonia . the ammonia sparger was about 1 inch from the cylinder wall , and it was located at the 4 o &# 39 ; clock position as viewed from the feed end . the ammonia was added over a 15 - minute period beginning at the start of rotation . rotation of the drum was continued for 5 more minutes , making the total time of rotation 20 minutes . a metal spatula was used to divert material spilled from the sparger area toward the feed end of the drum . the batch of agglomerates was removed from the drum and dried 4 hours in a laboratory oven at 120 ° c . the average size of the agglomerates was approximately 1 / 4 - inch . eighty - nine percent was plus 6 mesh . the average crushing strength of 1 / 4 - inch agglomerates was 9 pounds . an agglomerating experiment was carried out using the same equipment and procedure as that described in example iii . the formulation was as follows . the screen analyses of the indurated agglomerates showed that 80 percent of the material was larger than 6 mesh and 20 percent was smaller than this mesh size . the average size of the agglomerates was about 1 / 4 - inch . the crushing strength of 1 / 4 - inch agglomerates was 8 pounds . this example illustrates the manner in which waste tailing from phosphate ore beneficiation would be agglomerated and used as phosphorus furnace charge . this example is based on background information on phosphate ore processing and beneficiation . the phosphate agglomeration processes given in examples iii and iv are applied in preparing an agglomerated self - fluxing phosphate mixture suitable for use in phosphorus furnaces . heretofore , clay present in phosphate ores has been utilized as a binder in preparing agglomerated phosphates for furnace feed . clay is the binder in making green briquets and compacted flakes , and these agglomerates are more readily prepared when the phosphate contains a relatively large amount of clay . in nodulizing , clay in the phosphate reduces both the temperature of incipient fusion and the energy required for agglomeration . nodulizing kiln linings are rapidly deteriorated when the phosphate contains no clay as an impurity . clay has an adverse effect on phosphorus furnace operations . agglomerated phosphate containing clay must be calcined to indurate and stabilize the crystal structure of the material in order for the material to be used successfully for the production of phosphorus . with an agglomerated phosphate - clay mixture the material begins to fuse and consolidate above the zone of reduction , and this prevents gases generated by the reduction reactions from flowing uniformly through the furnace charge . however , lump phosphates which contain no clay can be used successfully in phosphorus furnaces without calcination . a publication entitled &# 34 ; phosphorus furnace operations -- how are they affected by various types of phosphate charges ?&# 34 ; by j . c . barber and e . c . marks , journal of metals , december 1962 , gives more detailed information on the effect of various types of phosphates on furnace operation . in phosphate ore beneficiation , clay is separated from the ore in hydroseparators and cyclones . clay is in the overflow and is discarded as waste slimes . in florida the underflow generally undergoes flotation to separate the phosphate values from the quartz impurity . the quartz comes out as flotation tailing -- another solid waste from ore beneficiation . however , the tailing can be used in building roads and dikes , and in some cases the tailing has been used to dewater slimes . phosphate concentrate is produced from beneficiation by the flotation process . for the present example , phosphate concentrate is mixed with flotation tailing in proportions needed to provide a sio 2 : cao weight ratio of 0 . 85 . the mixture is self - fluxing ; that is , the phosphate contains enough sio 2 to combine with the cao . proportions are 73 percent phosphate concentrate and 27 percent flotation tailing . ( the concentrate contained 30 . 5 % p 2 o 5 .) about 4 . 6 percent of the p 2 o 5 in the mixture comes from waste tailing . composition of the mixture is as follows . ______________________________________ p . sub . 2 o . sub . 5 23 . 4 percent cao 35 . 1 percent sio . sub . 2 29 . 8 percent fe . sub . 2 o . sub . 3 1 . 0 percent al . sub . 2 o . sub . 3 1 . 2 percent______________________________________ the mixture of phosphate concentrate and flotation tailing normally consists of particles smaller than 16 - mesh -- a size that is readily agglomerated by the laboratory apparatus shown in fig1 . fig4 illustrates the arrangement of plant equipment to be used in agglomerating and indurating the mixture of concentrate and tailing . the following proportions of materials are put in the rotary mixer . 0 . 160 ton of sludge acid containing about 38 % p 2 o 5 water provides sufficient liquid phase for agglomeration and the sludge acid is the binder . operation is continuous and the materials flow from the mixer into the agglomerator . anhydrous ammonia is sparged into the agglomerator at a rate of 0 . 060 ton per ton of phosphate feed . the green agglomerates discharge onto a wire mesh belt which conveys the material under a drying hood . the agglomerates are heated to a temperature of about 250 ° f . by hot air . the indurated agglomerates are screened on a 6 - mesh screen and the fines are recycled to the mixer . about 10 percent of the indurated agglomerates is fines . the plus 6 - mesh agglomerates , containing 24 . 7 percent p 2 o 5 , are fed to the phosphorus furnace with sufficient coke needed for reduction . no silica rock is required . a phosphorus plant produces elemental phosphorus at a rate of 109 tons per day . furnace gases are treated in an electrostatic precipitator to remove particulate matter , and the gases are then contacted with water sprays in a spray condenser consisting of an open cylindrical chamber . the mixture of water and liquid phosphorus flows from the condenser to a sump ; liquid phosphorus collects in the bottom of the sump and the water overflows into another sump . the water is recirculated to the spray condenser by pumping . the gas mixture leaving the spray condenser consists of noncondensable gases ( co , co 2 , ch 4 , and n 2 ) and uncondensed phosphorus vapor . the gases are exhausted by wet vaccum pumps ( nash hytor pumps ) using condenser water as the fluid in the pumps . the gases are pumped to a surface condenser ( tubular ) for further cooling and condensation of elemental phosphorus . the condenser tubes are irrigated by spraying condenser water inside the tubes . liquid phosphorus recovered in the spray condenser and surface condenser is pumped to storage tanks where it is stored under water to keep it from burning . the water is saturated with elemental phosphorus and phosphorus particles become suspended in the water . water contaminated in this manner is commonly called &# 34 ; phossy &# 34 ; water . in this example phossy water is generated at a rate of 1300 gallons per ton of phosphorus produced , and the water contains 1700 ppm of elemental phosphorus . the quantity of elemental phosphorus is 1 . 0 ton per day . phossy water is treated in a clarifier at a rate of 99 gallons per minute . a commercial flocculating agent is added to aid in the clarification process . overflow is the clarified water , and its rate is 97 gallons per minute . underflow from the clarifier contains the settled solids which are treated to recover phosphorus values . composition of the overflow is as follows : ______________________________________ grams per liter______________________________________elemental phosphorus 120fluorine 10p . sub . 2 o . sub . 5 17nh . sub . 3 9______________________________________ the overflow is returned to the phosphorus condensing system . however , accumulations of dissolved salts make it necessary to bleed off clarified water at a rate of 6 gallons per minute and replace this water with fresh water . the fluoride content of the water is not permitted to exceed 10 grams per liter to assure that fluosilicate concentrations do not reach saturation . clarified water bled from the system is mixed with plant cooling water to give a mixture containing about 23 ppm of elemental phosphorus . the mixture is further clarified by settling in a 14 - acre pond . pond overflow contains an average of 0 . 3 to 0 . 4 ppm of elemental phosphorus , but sometimes the phosphorus content at the pond outlet will go up to 1 . 0 to 2 . 0 ppm . the pond overflow discharges to a receiving stream . elemental phosphorus is very toxic to marine animals . published information [&# 34 ; toxicity of yellow phosphorus to herring ( clupea harengus ), atlantic salmon ( salmo salar ), lobster ( homarus americanus ), and beach flea ( gammarus oceanicus )&# 34 ; v . zitko , d . e . aiken , s . n . tibbo , k . w . t . besch , and j . m . anderson , journal of fisheries research board canada , 27 , no . 1 , 21 - 29 , 1970 ] has shown that elemental phosphorus contents of water as low as 40 parts per billion will kill some species of marine animals . consequently , the phossy water treating method described in this example is not adequate for water pollution abatement , but heretofore no better abatement technology was known . this example shows how wastewater from a phosphorus plant can be used as feedstock for making a suspension fertilizer and thereby avoid the discharge of any water waste contaminated with elemental phosphorus . phosphorus is produced at a rate of 109 tons per day and phossy water from the condensing system containing 1700 ppm of elemental phosphorus is treated in a clarifier at a rate of 99 gpm . overflow from the clarifier contains 120 ppm of elemental phosphorus and the rate is 97 gallons per minute . a stream of clarified water is bled off to control the concentration of dissolved fluosilicates . the bleedoff rate is 6 gallons per minute . the bleedoff water is treated in a stacked disk centrifuge at a rate of 29 gallons per minute . ( the centrifuge is operated about 20 percent of the time to treat bleedoff water .) the centrifuge overflow rate is 25 gallons per minute and the overflow contains 12 ppm of elemental phosphorus . an ortho suspension fertilizer ( 13 . 5 - 38 - 0 ) is produced at the same site by three - step neutralization of merchant - grade wet - process phosphoric acid at a rate of 20 tons per hour . ( the suspension fertilizer plant operates about 35 percent of the time .) the n : p 2 o 5 weight ratio is 0 . 33 . attapulgite clay is added to keep the diammonium phosphate crystals in suspension . the quantity of materials needed to make one ton ( 2 , 000 pounds ) of the suspension fertilizer is as follows : ______________________________________phosphoric acid 1 , 407 poundsanhydrous ammonia 328 poundswater 350 poundsclay 30 pounds______________________________________ water is evaporated in the first stage of neutralization which occurs at the boiling point ( 230 ° f .). also , water is evaporated in an evaporative cooler . total loss of water by evaporation is 115 pounds per ton of 13 . 5 - 38 - 0 suspension fertilizer . the 350 pounds of water added per ton of suspension fertilizer is to replace water lost by evaporation and to provide dilution water for the process . the centrifuge overflow is used as feedstock instead of water . the elemental phosphorus content of the suspension fertilizer is less than 1 ppm -- a concentration that causes no phytotoxicity problem in fluid fertilizers . furthermore , the elemental phosphorus is rapidly oxidized when applied to the soil (&# 34 ; detoxification of white phosphorus in soil &# 34 ; by hinrich l . bohn , journal of agricultural and food chemistry , vol . 18 , no . 6 , 1970 .) the centrifuge overflow supplies 0 . 7 percent of the nutrients in 13 . 5 - 38 - 0 suspension fertilizer and reduces the nitrient cost $ 1 . 00 per ton of fertilizer produced . the three - step neutralization as above - discussed includes the following steps , where three ammoniators are employed in series . ( a ) placing the clarified water from the centrifuge in the first two ammoniators , one of which is equipped with an evaporative cooler ; ( d ) agitating with ammonia in all three ammoniators , to produce as a product 13 . 5 - 38 - 0 orthophosphate base suspension fertilizer . a two stage ammoniation can be carried out in a similar manner , to produce an 11 - 39 - 0 ortho suspension fertilizer as will be discussed in the next example . phossy water generated in a 109 ton per day phosphorus plant is treated as described in example vii . centrifuge overflow water is obtained at a rate of 25 gpm and the water contains 12 ppm of elemental phosphorus . ortho suspension fertilizer ( 11 - 39 - 0 ) is produced by a two - step ammoniation process . the n : p 2 o 5 weight ratio is in the range of 0 . 27 to 0 . 33 -- the weight ratio resulting in the highest solubility of nutrients . from 0 . 1 to 0 . 5 percent fluosilicic acid is added as a crystal modifier to form small needlelike monoammonium phosphate crystals as described in u . s . defensive publication no . t986 , 001 , sept . 4 , 1979 . centrifuge overflow water is used as feedstock in place of water normally used . the centrifuge overflow water supplies the fluosilicic acid needed to modify the size and shape of monoammonium phosphate crystals , and no fluosilicic acid is added . the fluosilicic acid content of the suspension fertilizer is 0 . 23 percent . thus it will be seen that i have provided an apparatus suitably adapted to meet the object and features hereinbefore set forth . it will further be seen that i have provided a method or process well adapted for a batch type laboratory embodiment but obviously applicable to continuous processes following the same steps to achieve the same ends . from the foregoing it will be seen that the invention is well adapted to attain all of the ends and objects together with other advantages which are obvious and which are inherent to the apparatus , the method or process , and that a new composition of matter has been invented . while i have shown and described particular embodiments of my invention , modifications and variations thereof will occur to those skilled in the art . i wish it to be understood , therefore , that the appended claims are intended to cover such modifications and variations which are within the true scope and spirit of my invention .