the present invention will be further described by means of the following preferred embodiments without restricting the scope of the invention . 0 . 90 kg of 2 , 6 - diacetylpyridine ( 99 %), 2 . 56 kg of phosphorus pentoxide ( p 2 o 5 ), and a solution of 2 . 14 kg of 2 , 4 - dichloro - 6 - methylaniline ( 100 %) were solubilized in 20 l of tetrahydrofuran . the mixture was stirred for 15 min and then heated under reflux for 18 hours at 70 ° c . after completion of the reaction , the obtained suspension was cooled to 20 ° c ., stirred for 30 min and then filtered and washed with 6 l of tetrahydrofuran . the filtrate , having a volume of 26 l , was concentrated under vacuum ( 250 mm hg , 55 ° c .). the volume was reduced by rotary evaporation up to a final concentrate of 3 . 5 l . 20 l of methanol were added so as to obtain crystallization . the resulting suspension ( 23 . 5 l ) was filtered and washed with 6 l of methanol , thus resulting in a volume of 27 l . the humid product ( 1 . 38 kg ) resulting from the filtration was set under drying condition in free air for one night . this gave a first fraction of 1 . 36 kg of 2 , 6 - bis [ 1 -( 2 , 4 , 6 - trimethylphenylimino ) ethyl ] pyridine in 51 % yield . the filtrate ( 27 l ) was concentrated as described above up to a final concentrate of 2 . 5 kg . 4 l of methanol were added . the resulting suspension was agitated for 1 hour at room temperature and washed with 0 . 4 l of methanol . a second fraction of 50 g was in this way obtained . thus , a total of 1400 g of 2 , 6 - bis [ 1 -( 2 , 4 , 6 - trimethylphenylimino ) ethyl ] pyridine in 53 % yield were obtained . a reaction with iron ( ii ) dichloride was carried out as described by qian et al ., organometallics 2003 , 22 , 4312 - 4321 . 140 kg sylopol 2107 , a spray - dried silica gel from grace , was calcinated at 600 ° c . for 6 hours . a mixture of 509 g ( 0 . 84 mol ) of 2 , 6 - bis [ 1 -( 2 , 4 - dichloro - 6 - methylphenylimino ) ethyl ] pyridine iron ( ii ) dichloride , prepared according to the above - mentioned procedure under a ), 4131 g ( 8 . 4 mol ) of bis ( n - butylcyclopentadienyl ) hafnium dichloride , commercially available from crompton , and 195 l of mao ( 4 . 75 m in toluene , 926 mol ) was stirred at 20 ° c . for 2 h and after cooling to 0 ° c . subsequently added while stirring to 140 kg of the pretreated support material b ). the solution was added with a flow rate lower than 100 kg / h . the obtained product was stirred for further 30 minutes and heated to 40 ° c . the solid was dried under reduced pressure until it was free - flowing . after sieving , 320 kg of catalyst were obtained ( residual solvent : 41 %). the polymerization was carried out in a fluidized - bed reactor having a diameter of 3 . 7 m in the presence of the mixed catalyst described above . the reaction temperature was 105 ° c ., the pressure in the reactor was 25 bar , the reaction gas had the following composition : 49 vol % ethylene , 5 . 1 vol % hexane , 0 . 6 vol % hexene , 45 vol % nitrogen , 1 . 5 kg / h trihexylaluminum ( 2 wt % in hexane ). the output was 5 . 5 t / h . the mdpe polyethylene so obtained had a density of 0 . 939 g / cm 3 and a mfr ( 190 / 21 . 6 ) of 28 g / 10 min . the mdpe , conveniently added with 700 ppm of a conventional processing additive , namely polybatch ® amf 705 ( available from a . schulman ) was used as a first polyethylene component , whose main properties are shown in table 1 below , while lupolen 3220 f , which is a ldpe commercially available from basell polyolefine gmbh having a density of 0 . 930 g / cm 3 , and a mfr ( 190 / 2 . 16 ) of 0 . 9 g / 10 min , was used as a second polyethylene component in an amount of 11 % by weight . in examples 2 - 4 a first and a second polyethylene components as those described in example 1 were used , except for the amount of ldpe , which was set to 20 %, 30 % and , respectively , 40 % by weight . density is the polymer density mfr ( 190 / 21 . 6 ) is the melt flow rate according to standard iso 1133 , condition g eta ( vis ) is the intrinsic viscosity as determined according to iso 1628 - 1 and eta ( gpc ) is the viscosity as determined by gpc according to din 55672 , with 1 , 2 , 4 - trichlorobenzene , at 140 ° c . m w is the weight average molar mass ; m n is the number average molar mass m z is the z - average molar mass gpc % at molar mass 1 mio is the % by weight according to gel permeation chromatography below a molar mass of 1 mio g / mol . — hc ═ ch 2 is the amount of vinyl groups total - ch 3 is the amount of ch 3 - groups per 1000 c including end groups . innovex ll6910aa , which is a conventional lldpe prepared by the use of a ziegler - natta catalyst commercially available from bp ( density equal to 0 . 936 g / cm 3 , mfr ( 190 / 2 . 16 ) of 1 . 0 g / 10 min ), conveniently added with 700 ppm polybatch ® amf 705 , was used as a first polyethylene component , whose properties are shown in table 2 , while lupolen 3220 f was used as a second polyethylene component in an amount of 11 %, 20 %, 30 % and , respectively , 40 % by weight . lupolen 3721 c , which is a mdpe prepared by the use of a chromium catalyst commercially available from basell ( density equal to 0 . 937 g / cm 3 , mfr ( 190 / 21 . 6 ) of 12 . 5 g / 10 min ), was used as a first polyethylene component , whose properties are shown in table 3 , while lupolen 3220 f was used as a second polyethylene component . the polyethylene compositions of example 1 - 12 were homogenized and granulated on a zsk 30 ( werner pfleiderer ) with screw combination 8a . the processing temperature was 220 ° c ., the screw speed 250 / min , the output of 20 kg / h . each polyethylene composition of the examples above was extruded into films by blown film extrusion on a weber film extruder equipped with a collapsing device with wooden flatted boards . the diameter of the ring die was 50 mm , the gap width was 2 / 50 and the angle along which the cooling air is blown onto the extruded film was 45 °. no filters were used . the 25d extruder with a screw diameter of 30 mm and a screw speed of 50 turns per min gave an output of 5 . 1 kg / h . the blow - up ratio was 1 : 2 and the haul - off speed 4 . 9 m / 10 min . the height of the frost line was 160 mm . films with a thickness in the order of 50 μm were obtained . the specific thickness of each film , as well as the processing properties and optical and mechanical properties of the different films , are summarized in tables 4 and 5 . nmr samples were placed in tubes under inert gas and , if appropriate , melted . the solvent signals served as internal standard in the 1 h - and 13 c - nmr spectra and their chemical shift was converted into the values relative to tms . the degree of branching in the individual polymer fractions was determined by the method of holtrup ( w . holtrup , makromol . chem . 178 , 2335 ( 1977 )) coupled with 13 c - nmr . the density [ g / cm 3 ] was determined in accordance with iso1183 . the determination of the values m n , m w , m z and of the molar mass distribution m w / m n derived therefrom was carried out by means of high - temperature gel permeation chromatography on a waters 150 c using a method based on din 55672 and the following columns connected in series : 3x shodex at 806 ms , 1x shodex ut 807 and 1x shodex at - g under the following conditions : solvent : 1 , 2 , 4 - trichlorobenzene ( stabilized with 0 . 025 % by weight of 2 , 6 - di - tert - butyl - 4 - methylphenol ), flow : 1 ml / min , 500 μl injection volume , temperature : 140 ° c . the columns were calibrated with polyethylene standards with molar masses of from 100 bis 10 7 g / mol . the evaluation was carried out by using the win - gpc software of fa . hs - entwicklungsgesellschaft für wissenschaftliche hard - and software mbh , ober - hilbersheim . for the purposes of the present invention , the expression mfr ( 190 / 21 . 6 ), known also as “ high load melt flow rate ”, has been determined at 190 ° c . under a load of 21 . 6 kg in accordance with iso 1133 , condition g . for the purposes of the present invention , the expression mfr ( 190 / 2 . 16 ) has been determined at 190 ° c . under a load of 2 . 16 kg in accordance with iso 1133 , condition d . in order to determine the reflection properties of the films , gloss measurements were carried out according to iso 2813 on a reflectometer at impingement angles of 20 ° and 60 °, on at least 5 pieces of film with a thickness of 50 μm . the haze was determined by astm d 1003 - 00 on a byk gardener haze guard plus device on at least 5 pieces of film 10 × 10 cm with a thickness of 50 μm . the clarity was determined by astm d 1746 - 03 on a byk gardener haze guard plus device , calibrated with calibration cell 77 . 5 , on at least 5 pieces of film 10 × 10 cm with a thickness of 50 μm . in order to determine the puncture resistance of films under shock loading , the dart drop was determined by astm d 1709 , method a on 10 film samples having a thickness of 50 μm . in order to determine the strength of the films under dynamic loading , dynamic tests were carried out according to din 53373 , so as to obtain the fracture energy w s up to the first tear and the total fracture energy w tot for the penetration . the tensile strength test was performed according to iso 527 both in machine direction ( md ) and at right angle to the machine direction , known as transverse direction ( td ) the tear propagation test , otherwise known as elmendorf method , was performed according to iso 6383 / 2 .