the compounds of tile present invention have several key portions in the molecule . those groups include ( a ) a sulfate group , ( b ) a hydroxy propyl linkage group to silicone polymer , and ( c ) a silicone polymer that contains water - soluble polyoxyalkylene groups . these groups and their positioning in the molecule result in unique properties for the molecule . these include emulsification properties , wetting properties , particularly for hydrophobic pigments , and a lubricious skin feel . this combination of properties has heretofore been unattainable in one molecule . x , y and z are integers and are independently ranging from 0 to 20 ; m is selected from the group consisting of na , k , and nh 4 . illustrative of the sequence for the preparation of the compounds of the present is as follows ; in a 30 % aqueous solution the disodium salt of a sulfate ( ph 10 . 4 ) is reacted will an epoxy dimethicone copolyol to produce the sulfate of the present invention the compounds of the present invention are very good ingredients in a variety of applications that require the presence of both the sulfate and hydroxy group . these applications include personal care applications where the materials function as very mild detergents and foaming agents . in a preferred embodiment x , y , and z are each zero . the silicone compounds useful as intermediates for the preparation of the compounds present invention are commercially available from siltech llc , dacula ga . sulfate salts useful as intermediates for the preparation of the compounds present invention are commercially available from a variety of sources . into a suitable vessel equipped with thermometer , agitation and heating capabilities specified amount of water . next the specified amount of sulfate is added under good agitation . the ph is adjusted to 10 . 3 with koh if needed . the reaction mass is heated to 70 - 80 ° c . and epoxy silicone is added over i hour . the exotherm is watched so that the temperature does not exceed 95 ° c . if that temperature is reached , cooling is applied and the addition suspended . after the addition is complete the reaction mass is held at between 80 - 90 ° c . for four hours . during that time the % epoxide becomes vanishingly low . into a suitable vessel equipped with thermometer , agitation and heating capabilities is added grams of water . next add the specified number of grams of sulfate ( example 8 ) under good agitation . the ph is adjusted to 10 . 3 with the koh . the reaction mass is heated to 70 - 80 degree . c . next add grams of epoxy silicone ( example 1 ). addition is made over a 1 hour time period . the exotherm is watched so that the temperature does not exceed 95 degree . c . after the addition is complete the reaction mass is held at between 80 - 90 degree . c . for four hours . during that time the % epoxide becomes vanishingly low . example 11 is repeated , only this time the specified amount of water is added and the specified quantity and type of silicone epoxide and sulfate are added replacing the quantity and type in example 11 . the compounds of the present invention are in aqueous solution or emulsion and generally range from 20 - 60 % solids . the preferred range is 30 - 40 % solids . the products are used without purification . they are clear liquids having a light color . traditional dimethicone copolyol compounds have been used in urethane foam . however , the ability to control the water - soluble groups and the hydroxyl containing groups independently from each other has been lacking . the compounds of the present invention have polyoxyalkylene groups present in two different and independent groups . this allows for the ability to tailor products that have the desired balance of polyoxyethylene groups , polyoxypropylene groups , hydroxyl groups and sulfate groups independently from each other . sulfated surfactants are preferred in this application to phosphate groups due in part to the better foam stability . the products of the present invention have copious foam and a very lubricious feel on the skin . they are high molecular weight , consequently do not penetrate the skin causing sting and irritation . finally , the compounds have a sulfate group linked through a hydroxy linking group to a silicone .