the present invention provides sintered metal oxide articles , and preferably iron oxide articles , of desired mechanical properties , such as high strength , and an interconnected pore structure capable of efficient filtering of gases and liquids . in accordance with the invention , metal oxide powder is subjected to a heat treatment to transform at least a portion of the oxide into a different oxide . the heat treatment is conducted at temperatures less than the melting points of the oxides and for suitable holding times to sinter the powder into a unitary oxide article . the powders used in the present invention are said to consist essentially of metal oxide in that such powders are substantially free from other compounds and additives such as binders , reducing agents , and the like . heating regimes for sintering are chosen to cause the oxidation and / or deoxidation of the oxide such that it is transformed to a different oxide , with several oxidation / deoxidation cycles possible . although not wishing to be bound by theory , it is believed that oxygen transport during deoxidation and / or oxidation contributes to effective sintering and the resulting desired mechanical properties and uniformity in appearance and interconnected pore structure of the sintered article body . the invention thus obviates the need for sintering additives and high sintering pressures . the present invention is described with specific reference to iron oxide articles , and specifically iron oxide filters , that are made by sintering iron oxide powders . the scope of the invention , however , includes articles of other metal oxide materials , of any form and intended use , that are made by sintering metal oxide powders that undergo oxidation and / or deoxidation during the sintering process . in cited embodiments , sintered iron oxide filters are produced in accordance with the present invention . for example , in one embodiment , hematite ( α - fe 2 o 3 ) filters are made from magnetite ( fe 3 o 4 ) powder . in another embodiment , hematite filters are made from hematite powder , which transforms to magnetite and back to hematite during sintering . in yet another embodiment , magnetite filters are made from hematite powder . the filters are made in a sintering process wherein metal oxide powder is placed into a mold and hand - pressed into a compact and subjected to a suitable heat treatment to cause sintering into a unitary body and oxidative / deoxidative transformation of the powder . preferred molds are alumina rings typically having an inner diameter of from about 10 to about 70 mm , and a height of from about 3 to about 60 mm . the powder particles are of any suitable size for sintering such as , for example , about 50 to about 200 microns . such powders are readily available . the heat treatment of the invention is selected based on the thermal properties of iron oxides . in air at atmospheric pressure , hematite is stable at elevated temperatures up to about 1350 ° c . but decomposes to magnetite at higher temperatures up to about 1450 ° c . because magnetite begins to decompose to wustite feo at temperatures above 1450 ° c ., this represents an upper limit of sintering temperatures in atmospheric air . for subatmospheric pressures , suitable sintering temperatures are lower according to the pressure within a vacuum furnace . in cited embodiments of the present invention , vacuum sintering typically occurs at a pressure within the range of about 10 − 4 to about 10 − 5 torr , wherein hematite begins to decompose to magnetite at about 750 ° c . and magnetite begins to melt at about 1300 ° c . the process is optimized on the premise that higher sintering temperatures allow for shorter sintering times . at pressures of about 10 − 4 to about 10 − 5 torr , efficient sintering occurs at 950 ° c . to 1250 ° c ., preferably at 1000 ° c . to 1250 ° c ., and more preferably at 1150 ° c . to 1200 ° c . embodiments of the present invention are further described with reference to the following non - limiting examples . in all examples , the iron oxide materials , namely hematite and magnetite , are distinguished by stoichiometry and magnetic properties . hematite filters were made from magnetite powder according to an embodiment of the present invention . magnetite powder was obtained my milling thin - walled magnetite structures produced in accordance with u . s . pat . nos . 5 , 786 , 296 and 5 , 814 , 164 , which are incorporated herein by reference . the powder was separated on commercial sieves into fractions according to the following particle size ranges ( in microns ): 160 to 100 , 100 to 80 , 80 to 50 and & lt ; 50 . portions of each powder fraction were poured into closed - ended molds to form multiple ( e . g ., at least three ) samples of each powder fraction . the molds were in the form of alumina rings having an internal diameter of about 11 mm and a height of about 8 mm , placed on a platinum plate serving as the mold bottom . each sample was compacted by hand with a metal rod to a density of from about 2 . 3 to about 3 . 5 g / cm 3 , and placed at room temperature into an electrically heated and unsealed furnace for subsequent heat treatment in atmospheric air . groups of samples were subjected to the following separate heat treatments ( all heating rates were about 2 ° c . per minute ), based on the inventors &# 39 ; finding that the sintering process in air was inefficient below around 1350 ° c . but efficient for temperatures up to around 1450 ° c . : ( a ) samples of all powder fractions were heated to about 1300 ° c . and held for about three hours ( thus causing a transformation from magnetite to hematite ), then heated to about 1450 ° c . and held for about 15 minutes ( thus causing a transformation from hematite to magnetite ), and then furnace cooled ( thus causing a transformation from magnetite to hematite ) ( as used herein , “ furnace cooled ” refers to cooling by leaving samples in the furnace after sintering and turning off the furnace power ), ( b ) samples of powder fractions 160 to 100 microns , 100 to 80 microns , and 80 to 50 microns were heated to about 1450 ° c . and held for about 15 minutes ( during which heating , the magnetite transforms to hematite and back to magnetite ), then cooled to about 1300 ° c . and held for about three hours ( thus causing a transformation from magnetite to hematite ), and then furnace cooled . ( c ) samples of powder fractions 160 to 100 microns were heated to about 1200 ° c . and held for about three hours ( thus causing a transformation from magnetite to hematite ), then heated to about 1450 ° c . and held for about 15 minutes ( thus causing a transformation from hematite to magnetite ), and then furnace cooled ( thus causing a transformation from magnetite to hematite ). as described , each of the heat treatments resulted in more than one transformation between magnetite and hematite . after the samples were cooled to about room temperature , they were removed from the molds . the resulting hematite samples had substantially the same appearance and properties regardless of variations in the heat treatments employed . the sample densities were within the range of about 2 . 3 to about 3 . 4 g / cm 3 , which is about 45 to about 65 percent of hematite bulk density ( i . e ., corresponding to a porosity of about 55 to about 35 percent , respectively ). the samples were mechanically strong enough to be ground by common abrasives , and were characterized by an open interconnected pore structure capable of effective filtration of liquids . this example thus demonstrates a relatively simple method for making strong , uniform iron oxide filters , particularly hematite filters , in accordance with the present invention . hematite filters were made from hematite powder according to an embodiment of the present invention . hematite powder was obtained my milling thin - walled hematite structures produced in accordance with u . s . pat . nos . 5 , 786 , 296 and 5 , 814 , 164 , which are incorporated herein by reference . the powder was separated according to size and placed into molds according to example 1 . samples ( e . g ., at least three ) were heated at a rate of about 2 ° c . per minute to about 1450 ° c ., held for about three hours ( thus causing a transformation from hematite to magnetite ), and furnace cooled ( thus causing a transformation from magnetite to hematite ). the resulting sintered hematite samples could be removed from their molds but were mechanically weak such that they were crushed by slight hand pressure . in an effort to improve mechanical strength , additional powder samples were heated to about 1300 ° c . and held for about three hours , then heated to about 1450 ° c . to about 1500 ° c ., and held for about one hour ( thus causing a transformation from hematite to magnetite ), and then furnace cooled ( thus causing a transformation from magnetite to hematite ). the sintered samples showed only a marginal increase in strength . as such , substantially monotonic heating followed by monotonic cooling was found to be inefficient for producing hematite filters from hematite powder . however , when more cooling / heating steps were added to the heat treatment to provide more oxidation / deoxidation cycles , the resulting hematite samples showed a significant increase in strength . for example , powder samples were heated to about 1250 ° c . and held for about three hours , then heated to about 1450 ° c . and held for about 15 minutes ( thus causing a transformation from hematite to magnetite ), then cooled to about 1250 ° c . and held for about 15 minutes ( thus causing a transformation from magnetite to hematite ), then heated again to about 1450 ° c . and held for about 15 minutes ( thus causing a transformation from hematite to magnetite ), then cooled again to about 1250 ° c . and held for about three hours ( thus causing a transformation from magnetite to hematite ), and then furnace cooled . the resulting sintered hematite samples were strong enough to be ground by common abrasives . moreover , the resulting samples were uniform in appearance and were characterized by an open interconnected pore structure . although not wishing to be bound by theory , the significant increase in filter strength resulting from the several oxidation / deoxidation cycles may be due to oxygen transport within the sintered body contributing to effective sintering , and to the resulting mechanical properties and uniformity of the sintered article body having an interconnecting pore structure . magnetite filters were made from hematite powder according to an embodiment of the present invention . hematite powder was made and separated according to size and placed into molds according to example 2 . samples ( e . g ., at least three ) were placed in a vacuum furnace at a pressure of about 10 − 4 to about 10 − 5 torr , heated at a rate of about 8 - 9 ° c . per minute to about 1210 ° c . to about 1250 ° c . and held for about 5 to about 30 minutes ( thus causing a transformation from hematite to magnetite ), and then furnace cooled while maintaining vacuum ( thus preventing a transformation from magnetite to hematite , which would occur in air ). the sintered magnetite filters were easily removed from their molds , and were mechanically strong enough to be ground by common abrasives . the sample densities were within the range of about 2 . 3 to about 3 . 4 g / cm 3 , which is about 45 to about 65 percent of magnetite bulk density ( i . e ., corresponding to a porosity of about 55 to about 35 percent , respectively ), typically increasing with a decrease in the initial hematite particle size . the sintered samples were uniform and were characterized by an open interconnected pore structure . magnetite filters were made from magnetite powder . magnetite power was made , separated according to size and placed into molds according to example 1 . samples ( e . g ., at least three ) were placed in a vacuum furnace at a pressure of about 10 − 4 to about 10 − 5 torr , heated at a rate of about 8 ° c . per minute to about 1250 ° c . and held for about 30 minutes , and then furnace cooled . in this example , the iron oxide ( magnetite ) powder did not undergo any transformation to any other iron oxide during sintering . the resulting sintered magnetite filters were significantly weaker and much less uniform than the magnetic filters made from hematite powder as described in example 3 . notably , the weaker magnetite samples in example 4 had , on average , higher densities ( up to about 4 g / cm 3 ) than the magnetite samples produced in example 3 . while not wishing to be bound by theory , this unusual inverse relation between strength and density indicates that in producing samples of high strength the oxidation / deoxidation cycles are more important than simple densification . the hematite and magnetite filters formed according to examples 1 to 3 were evaluated against standard glass filters with known pore sizes . the pore size of each hematite and magnetite filter was estimated by determining their ability to filter freshly prepared suspensions of fe ( oh ) 3 , caco 3 and al ( oh ) 3 . filtration efficiency for all filters was evaluated by measuring the water filter productivity (“ wfp ”), which is the volume of water filtrated per filter unit surface area per unit time , for a given pressure . the results of the filtration testing are shown in table i . the filtration efficiencies for the filters produced in accordance with examples 1 to 3 were found to be much greater than efficiencies for glass filters of comparable pore sizes . for example , for a hematite filter made in accordance with example 1 from magnetite powder and having a pore size up to about 40 microns , the wfp was found to be 829 cm 3 / cm 2 min at a pressure of about 10 torr . by comparison , a glass filter having a similar pore size has a wpf of about 100 cm 3 / cm 2 min at the same pressure . as another example , for a hematite filter made in accordance with example 1 from magnetite powder and having a pore size up to about 15 microns , the wfp was found to be 186 cm 3 / cm 2 min at a pressure of about 10 torr . by comparison , a glass filter having a similar pore size has a wpf of about 3 cm 3 / cm 2 min at the same pressure . inspection of table i reveals several structure - property relationships for the sintered filters of the present invention . for example , for a given sintering process , a decrease in powder particle size results in a decrease in filter pore size and an increase in filter density . also , a decrease in powder particle size results in a decrease in wfp . the mechanical strength of filters 1 to 3 , as listed in table i , was evaluated on the basis of crush strength . crush strength was measured by polishing cylindrical filter samples , having diameters of about 10 to about 11 millimeters and heights of about 5 to about 6 millimeters , to obtain smooth , parallel top and bottom surfaces . the samples were wrapped by a polyethylene film , placed in a press ( compressive force about 39 kn ), and compressed at a rate of about 0 . 4 atm / sec . the moment of sample crush was distinctly seen on a press manometer . these filters were found to have crush strengths of about 30 atm , about 200 atm and about 260 atm , respectively , showing a strong inverse correlation with powder particle size . this expected inverse correlation is an additional indication that the filters of the present invention possess a normal interconnected pore structure . the results of the filtration demonstrate that the methods of the present invention result in the production of strong iron oxide articles having an interconnected pore structure suitable for efficient filtering . the present invention provides a novel method of making sintered metal oxide articles . the sintered articles of the invention are characterized by desired mechanical properties , such as high strength , and an interconnected pore structure . those with skill in the art may recognize various modifications to the embodiments of the invention described and illustrated herein . such modifications are meant to be covered by the spirit and scope of the appended claims .