referring to the flow diagram of fig1 a known high temperature gasifier ( 10 ), for example , the koppers - totzek gasifier as typically described in u . s . pat . no . 2 , 702 , 743 , is supplied with a carbonaceous fuel such as coal ( 11 ) in a pulverized form , steam ( 12 ), and oxygen ( 13 ). the carbonaceous fuel can encompass all grades of coal , coke , petroleum coke , char , heavy residuals , oil , or pumpable slurries of carbonaceous materials . the coal may be entrained with steam and oxygen into the gasifier , as with the koppers - totzek process , or alternatively the steam can be replaced with water which serves to slurry the coal for feeding of the gasifier , as in the well - known texaco coal gasification process . the carbonaceous fuel is partially combusted in the gasifier by known methods to produce a gas ( 14 ) rich in carbon monoxide and hydrogen . gasification may occur at absolute pressures ranging from one atmosphere to about 50 atmospheres . gas ( 14 ) leaves the gasifier with 20 - 50 volume percent hydrogen , at a temperature of at least 2000 ° f . to a maximum of about 3500 ° f . steam and oxygen addition to the gasifier is regulated to ensure that a maximum amount of the carbon contained in the carbonaceous fuel is completely gasified . molten slag ( 38 ) may be recovered from the bottom of the gasifier and a portion of remaining ash and small amounts of ungasified fuel can be entrained with the gas ( 14 ) leaving the gasifier . in the case of gasifying a high sulfur content illinois coal by means of the known koppers - totzek process , the gasification of 991 pounds of such coal would typically require 842 pounds of 98 vol . % purity oxygen and 364 pounds of steam to yield 100 moles of raw gas ( 14 ) having the following typical analysis : ______________________________________ volume % ______________________________________co 49 . 80co . sub . 2 7 . 11h . sub . 2 29 . 94n . sub . 2 + ar 0 . 74h . sub . 2 s 0 . 88cos 0 . 06h . sub . 2 o 11 . 13so . sub . 2 0 . 00nh . sub . 3 + hcn 0 . 34total 100 . 00______________________________________ following the flow diagram of fig1 the raw gas above then enters a non - catalyzed organic sulfur reduction stage ( 15 ) where a recycle gas ( 36 ) having the following typical composition is introduced : ______________________________________ volume % ______________________________________ h . sub . 2 2 . 5 co 1 . 0 co . sub . 2 10 . 0 n . sub . 2 56 . 2 h . sub . 2 o 26 . 0 s . sub . 2 0 . 7 h . sub . 2 s 2 . 0 so . sub . 2 1 . 0 cos 0 . 3 cs . sub . 2 0 . 3 total 100 . 0______________________________________ the above composition is representative of using a multi - stage claus process ( 34 ) elsewhere in the overall process . if a different sulfur recovery process is employed , the composition of the recycle gas will be different from the one given above . nitrogen contained in the above gas can be kept at only 1 - 3 volume percent if pure oxygen rather than air is used for firing of the claus furnace ( 34 ). alternatively , nitrogen could be essentially deleted from the recycle claus tailgas ( 36 ) by employing only catalytic stages within the claus process . a feature of the invention is that the sulfur recovery process ( 34 ) used elsewhere in the overall process need not be a claus unit but , instead , may be a direct sulfur recovery process , such as the stretford process , which is incapable of removing organic sulfur compound such as cos and , as such , was heretofore restricted in its practical use for prior known sulfur recovery processes . organic sulfur compounds are present to varying degrees within any coal gasification process and include cos , cs 2 , and at times various mercaptan compounds such as methyl mercaptan . these compounds are easily reduced at high temperature with hydrogen and are also reduced with water vapor , although water vapor is less effective as a reducing agent than hydrogen . to prevent the accumulation of organic sulfur compounds it is necessary that their net reduction equate to the rate of their net formation while preferably minimizing their steady - stage concentrations . this has been found to be best accomplished in accordance with the invention by employing the organic sulfur reduction stage ( 15 ) previously described . the reason for this is that the organic sulfur compounds are most concentrated with the recycle gas stream ( 36 ) introduced to the stage , while simultaneously the maximum hydrogen concentration is apparent in the raw gas ( 14 ) leaving the gasifier . within the organic sulfur reduction stage ( 15 ) each of the organic sulfur compounds introduced with the recycle gas is reduced typically at an extent of 70 to nearly 100 percent by means primarily of the following reactions : any sulfur dioxide contained in the recycle gas ( 36 ) is predominantly converted to h 2 s by means of eqn . 4 . the reduction reactions occurring within this stage ( 15 ) are most exothermic , but there is a net tendency to instead cool the gas to typically 1800 °- 2000 ° f . due to the sensible heat of the co 2 , n 2 , and h 2 o predominantly present in the recycle gas . this cooling effect freezes any molten slag particles which might be entrained with the hot gas ( 14 ) leaving the gasifier . freezing of slag particles is useful in avoiding adhesion of slag to equipment surfaces elsewhere in the process . as shown on fig1 a portion of the recycle gas ( 37 ) might , but not ordinarily , be introduced directly to the gasifier ( 10 ) as a means of moderating gasifier temperature . in addition , the water vapor in this gas ( 37 ) may serve to replace some or all of the steam ( 12 ) ordinarily fed to the gasifier . when the tailgas ( 37 ) is added to the gasifier it is preferred that it be introduced away from the immediate vicinity of the flame zone so as not to directly contact carbon before the carbon is gasified with the oxygen ( 13 ) and steam ( 12 ), thereby avoiding additional formation of organic sulfur compounds . gas ( 16 ) leaves the organic sulfur reduction stage ( 15 ) and then enters the so 2 reduction stage ( 17 ) as shown on fig1 . here so 2 ( 18 ), or an so 2 mixture of at least about 50 volume % concentration , from an external process is introduced . within this stage ( 17 ) the so 2 is converted quite exothermically with hydrogen by means of eqns . 4 and 5 . in addition , the h 2 s present in the gas as would be produced , for example , by eqn . 4 , would reduce additional so 2 to sulfur vapor in accordance with eqn . 6 . some cos may form as by eqn . 3 , but relatively little cos would form to the slower reaction rate of co . any cos so formed would ultimately be recovered ( 31 ) and then reduced in the organic sulfur reduction stage ( 15 ). some cs 2 and traces of mercaptans can also form , but would be formed at less than 50 ppm by volume . like cos , the cs 2 and mercaptans would also be ultimately recovered ( 31 ) for reduction within the organic sulfur reduction stage ( 15 ) of the disclosed invention . whenever the so 2 added to the so 2 reduction stage ( 17 ) is in a quantity of about 50 pounds per million btu of net calorific content of coal used , the gas ( 20 ) leaving the so 2 reduction stage ( 17 ) would have the following typical composition on a nitrogen and argon - free basis : ______________________________________volume % % of total sulfur in gas______________________________________co 37 . 66 -- co . sub . 2 18 . 21 -- h . sub . 2 15 . 18 -- h . sub . 2 s 7 . 34 67 . 53cos 0 . 62 5 . 70h . sub . 2 o 19 . 52 -- so . sub . 2 0 . 04 0 . 37s . sub . 2 1 . 43 26 . 31cs . sub . 2 0 . 00 ( 50 ppm ) 0 . 09total 100 . 0 100 . 00______________________________________ nitrogen content of the above gas would range from 1 - 10 volume percent , depending on the sulfur recovery process ( 34 ) selected later in the overall process . as can be seen above , over 90 % of the sulfur in the exit gas ( 20 ) is converted to h 2 s plus s 2 . as so 2 reacts within the so 2 reduction stage ( 17 ), heat is generated in accordance with eqns . 4 and 5 . this heat serves to raise the gas temperature . gas temperature is maintained at about 2000 ° f . by removing excess heat , as by the generation of steam ( 19 ). as steam is generated , a portion of the sulfur vapors condense and liquid sulfur ( 21 ) may be recovered at the bottom of the stage . this condensation of sulfur provides additional driving force for eqns . 5 and 6 to proceed . as sulfur condenses on heat exchange surfaces , the heat exchange surfaces are protected by liquid sulfur from any high temperature gas phase corrosion . gas ( 20 ) leaves the so 2 reduction stage ( 17 ) and then enters a heat recovery unit ( 22 ), for example , a waste heat boiler , where additional steam ( 25 ) is generated as the gas is cooled . nearly 100 % of the remaining sulfur vapor condenses as the gas is cooled and the condensed sulfur ( 23 ) flows out of the heat recovery unit ( 22 ). gas ( 26 ) leaving the heat recovery unit is yet above the temperature , i . e ., dewpoint , at which water vapor would begin to condense , thereby avoiding plugging or corrosion problems . it is preferred that the gas ( 26 ) not be cooled to less than 340 ° f ., nor that water used for this steam generation be introduced to the heat exchange surfaces at less than 340 ° f . this is because liquid sulfur displays the anomalous property of having a sharp viscosity increase in the vicinity of 340 ° f . above 340 ° f . the liquid sulfur is sufficiently fluid to permit recovery while simultaneously avoiding buildup of sulfur on heat exchange surfaces . sulfur ( 24 ) recovered from both the so 2 reduction stage ( 17 ) and the the heat recovery unit ( 22 ) can be contaminated with particulates which are entrained with the gas leaving the gasifier . in the usual application of the invention this is expected to be of little consequence , since the primary intent of the process is to dispose of sulfur contained in so 2 , and forming frozen elemental sulfur is well recognized as the most environmentally acceptable method . if the sulfur ( 24 ) is to be sold it may be purified , for example , by dissolving it in a solvent such as carbon disulfide , filtering out the particulates and evaporating and recycling the solvent . in many ways the accumulation of particulates upon the liquid sulfur surface can be beneficial , for example , this reduces the quantity of residual particulates which must be scrubbed from the gas later in the process . gas ( 26 ) leaves the heat recovery unit ( 22 ) and then enters a system ( 27 ) whereby residual entrained particulates are scrubbed from the gas , for example , by the use of recirculating water through one or more venturi scrubbers . as the particulates are scrubbed from the gas , the gas is simultaneously cooled and water ( 30 ) is consequently condensed from the gas . gas may then be compressed , if necessary . following the step ( 27 ) comprising cooling , cleaning , and compressing , the gas ( 29 ) is then treated by known methods ( 31 ) for the removal of sulfur compounds to thereby yield a sulfur - containing gas ( 33 ) as well as sulfur - free gas ( 32 ) which is valued as a by - product for its content of co and h 2 which were unconverted in the overall process of the invention . as an alternative to the step ( 31 ) comprising the removal of sulfur compounds , fig1 shows that all or a portion ( 28 ) of the sulfur - containing gas leaving the particulate removal system ( 27 ) may be sent to an external process , for example , a combustion process , where so 2 generated upon combustion could be recovered by a regenerable so 2 removal process , with the so 2 so removed then sent to the so 2 reduction stage ( 17 ) of the disclosed invention . the sulfur - containing gas ( 33 ) from the sulfur removal step would ordinarily contain up to about 70 percent of the sulfur so added from the so 2 charged to the so 2 reduction stage ( 17 ). this sulfur - containing gas ( 33 ) would be sent to a known sulfur recovery process ( 34 ), such as the claus process or the stretford process , where most of this sulfur contained in the feed is converted to elemental form ( 35 ). all known sulfur recovery processes ( 34 ) are incapable of removing 100 percent of the sulfur fed to said process . degree of sulfur recovery would typically range from 70 - 95 percent within the sulfur recovery unit , depending on the type of process selected or on optimal economic considerations . current environmental restrictions usually prevent discharge of the 5 - 30 percent unconverted sulfur contained in the effluent gas ( 36 ) of the selected sulfur recovery process ( 34 ), even when this tailgas is first incinerated before discharge to the atmosphere . it is therefore necessary to treat this tailgas ( 36 ) for removal of contained sulfur . as an alternative to the known tailgas treatment units , this disclosed invention teaches that it would be more practical to instead feed the tailgas ( 36 ) to the organic sulfur reduction stage ( 15 ) as shown on fig1 . the two - stage concept of this disclosed invention offers superior advantages in recycling of the gas , since prior known methods employing gasifiers for the reduction of so 2 are not well suited for accommodating organic sulfur compounds which are characteristically heavily concentrated in the tailgas ( 36 ) of a sulfur recovery unit . the process of fig1 results in essentially 100 percent overall conversion of sulfur from the carbonaceous fuel plus external so 2 ( 18 ) to elemental form . additionally , a minimal amount of steam ( 12 ) is used to result in a minimal amount of overall water ( 30 ) which is condensed from the process , and this condensed water is free of tars and other carcenogenic hydrocarbons . in addition , any vent gases to the atmosphere are eliminated . such vent gases are encountered , for example , with known alternate processes employed for the treatment of sulfur - containing gases . in addition , a sulfur - free gas ( 32 ) is produced which contains co 2 produced by the overall reduction of so 2 as well as surplus h 2 and co which are valuable . in the event that so 2 available from an external source ranges between 50 to about 150 pounds per million btu of net calorific heat content of the carbonaceous fuel to be gasified , the simplified flow diagram depicted by fig2 would be preferred for practice of the invention . the major distinction between the flow diagram of fig2 versus fig1 is that in fig2 the known sulfur recovery process ( 34 ) of fig1 for example , the claus or stretford process , is eliminated . the reason for this is that when the so 2 to be reduced is relatively high , a per - pass reduction of up to about 75 percent of the so 2 to elemental sulfur is possible within the so 2 reduction stage ( 48 ). by a careful consideration to the gas processing steps it is possible to prepare a sulfur - containing gas which would be more practically reduced within the organic sulfur reduction stage ( 46 ) of the invention rather than in a known sulfur recovery process to thereby still achieve an overall sulfur recovery of essentially 100 percent while simultaneously avoiding the cost and associated energy input of a sulfur recovery unit . when so 2 addition ( 19 ) to the so 2 reduction stage ( 48 ) equates to about 150 pounds per million btu of net calorific heat content of the carbonaceous fuel used , gas ( 51 ) would exit this stage with the following representative composition : ______________________________________ volume % % of total sulfur in gas______________________________________co 14 . 17 -- co . sub . 2 35 . 20 -- h . sub . 2 4 . 21 -- n . sub . 2 + argon 0 . 75 -- h . sub . 2 s 5 . 20 19 . 42cos 0 . 60 1 . 27h . sub . 2 o 27 . 76 -- so . sub . 2 2 . 82 5 . 59s . sub . 2 9 . 29 73 . 72cs . sub . 2 0 . 00 ( 23 ppm ) 0 . 00total 100 . 00 100 . 00______________________________________ after recovery of heat ( 53 ) and selective condensation of sulfur vapor ( 54 ) the gas ( 57 ) is cooled , cleaned , and compressed ( 58 ) along with simultaneous condensation of water ( 59 ). remarks on these steps are the same as generally apply to the flow diagram depicted by fig1 . the cleaned gas ( 60 ) shown on fig2 is now sent ordinarily to a known process ( 65 ), such as the well - known rectisol process , where co 2 ( 67 ) generated on a net basis from the coal is selectively removed from the gas . this recovered co 2 ( 67 ) would typically contain 0 - 20 ppm by volume of sulfur compounds , of which most would be h 2 s . this quantity is within limits of current environmental regulations . the co 2 removal process ( 65 ) can also be designed to recover inert compounds , in particular , nitrogen and argon which enter the process on a net basis . after co 2 is removed by the known co 2 removal step ( 65 ) there is left over a gas ( 68 ) rich in sulfur compounds but which additionally contains a favorable amount of h 2 and co . this h 2 , in particular , enhances the extent of sulfur compounds reduction which is possible within the organic sulfur reduction stage ( 46 ) to which this gas would be recycled . the hydrogen contained in the recycle gas ( 68 ), like the hydrogen in the gasifier exit gas ( 45 ), is ultimately converted at steady - state conditions to water ( 59 ) which is condensed in the gas cooling and cleaning operation ( 58 ). the co in the gas recycled ( 68 ) to the organic sulfur reduction stage ( 46 ), like the co present in the gasifier exit gas ( 45 ), is ideally converted to co 2 on an overall steady - state basis , for example , by eqn . 3 , and additionally by the well - known water gas shift reaction , i . e ., to thereby generate additional hydrogen . the water gas shift reaction ( eqn . 18 ) is somewhat exothermic and contributes to the heat input of the process . the extent of conversion of co to h 2 by the water gas shift reaction is enhanced by the fact that the h 2 produced is consumed by the desirable reduction of so 2 with h 2 in accordance with eqns . 4 and 5 . although the reactions involved with co are acceptably rapid at the temperatures employed in practice of the invention , the co reactions are still somewhat slower than those involving the consumption of hydrogen . therefore , as shown on fig2 it is possible to enhance performance of the overall process by employing , as an option , an additional processing step ( 62 ) comprising the use of a known sulfur - resistant co shift catalyst . here a sulfur - resistant co shift catalyst , such as one composed of cobalt and molybdenum , is used to convert all or a portion of the co contained in the cleaned gas ( 60 ) to hydrogen and carbon dioxide by reaction with steam ( 63 ) in accordance with eqn . 18 . coincidentally with the co shift reaction most of the so 2 contained in the gas ( 60 ) would be reduced to h 2 s , while a portion of the cos would also be hydrolyzed to h 2 s . following co 2 removal ( 65 ), a gas ( 68 ) rich in hydrogen and h 2 s would be sent to the organic sulfur reduction stage ( 46 ) of the disclosed invention . steam ( 63 ) would be added to the co shift operation ( 62 ). this steam addition is minimized by employing appropriate gas humidification and dehumidification unit operations within the co shift facilities ( 62 ). care must be taken in the process shown in fig2 that inert compounds such as nitrogen and argon do not accumulate . ordinarily these inert compounds would be removed along with co 2 ( 67 ) in the co 2 removal step ( 65 ). however , as with the case of fig1 all or a portion ( 61 ) of the clean gas may be taken from the system after the gas cooling and cleaning operation ( 58 ) and thereafter sent to an external process , for example , a combustion process , with so 2 so formed in said external process recovered by a regenerable so 2 removal process , with the so 2 so recovered then sent to the so 2 reduction stage ( 48 ) of the disclosed invention . this bleed stream ( 61 ) so taken to an external process would beneficially serve to purge inert compounds such as nitrogen from the system .