The MTV Europe Music Award for Best Song was first award to a song performed by who?
MTV Europe Music Award for Best Song:  It was first awarded in 1994, when "7 Seconds" won it, and has been given out since. 7 Seconds (song):  It was released in 1994 as a single performed by Youssou N'Dour and Neneh Cherry.
Youssou N'Dour and Neneh Cherry