Charge conservation

In physics, charge conservation is the principle that the total electric charge in an isolated system never changes. The net quantity of electric charge, the amount of positive charge minus the amount of negative charge in the universe, is always "conserved". Charge conservation, considered as a physical conservation law, implies that the change in the amount of electric charge in any volume of space is exactly equal to the amount of charge flowing into the volume minus the amount of charge flowing out of the volume. In essence, charge conservation is an accounting relationship between the amount of charge in a region and the flow of charge into and out of that region, given by a continuity equation between charge density formula_1 and current density formula_2.
This does not mean that individual positive and negative charges cannot be created or destroyed. Electric charge is carried by subatomic particles such as electrons and protons. Charged particles can be created and destroyed in elementary particle reactions. In particle physics, charge conservation means that in reactions that create charged particles, equal numbers of positive and negative particles are always created, keeping the net amount of charge unchanged. Similarly, when particles are destroyed, equal numbers of positive and negative charges are destroyed. This property is supported without exception by all empirical observations so far.
Although conservation of charge requires that the total quantity of charge in the universe is constant, it leaves open the question of what that quantity is. Most evidence indicates that the net charge in the universe is zero; that is, there are equal quantities of positive and negative charge.
History.
Charge conservation was first proposed by British scientist William Watson in 1746 and American statesman and scientist Benjamin Franklin in 1747, although the first convincing proof was given by Michael Faraday in 1843.
Formal statement of the law.
Mathematically, we can state the law of charge conservation as a continuity equation:
where formula_4 is the electric charge accumulation rate in a specific volume at time , formula_5 is the amount of charge flowing into the volume and formula_6 is the amount of charge flowing out of the volume; both amounts are regarded as generic functions of time. 
The integrated continuity equation between two time values reads:
The general solution is obtained by fixing the initial condition time formula_8, leading to the integral equation:
The condition formula_10 corresponds to the absence of charge quantity change in the control volume: the system has reached a steady state. From the above condition, the following must hold true:
therefore, formula_5 and formula_6 are equal (not necessarily constant) over time, then the overall charge inside the control volume does not change. This deduction could be derived directly from the continuity equation, since at steady state formula_14 holds, and implies formula_15.
In electromagnetic field theory, vector calculus can be used to express the law in terms of charge density (in coulombs per cubic meter) and electric current density (in amperes per square meter). This is called the charge density continuity equation
The term on the left is the rate of change of the charge density at a point. The term on the right is the divergence of the current density at the same point. The equation equates these two factors, which says that the only way for the charge density at a point to change is for a current of charge to flow into or out of the point. This statement is equivalent to a conservation of four-current.
Mathematical derivation.
The net current into a volume is
where is the boundary of oriented by outward-pointing normals, and is shorthand for , the outward pointing normal of the boundary . Here is the current density (charge per unit area per unit time) at the surface of the volume. The vector points in the direction of the current.
From the Divergence theorem this can be written
Charge conservation requires that the net current into a volume must necessarily equal the net change in charge within the volume.
The total charge "q" in volume "V" is the integral (sum) of the charge density in "V"
So, by the Leibniz integral rule
Equating (1) and (2) gives
Since this is true for every volume, we have in general
Connection to gauge invariance.
Charge conservation can also be understood as a consequence of symmetry through Noether's theorem, a central result in theoretical physics that asserts that each conservation law is associated with a symmetry of the underlying physics. The symmetry that is associated with charge conservation is the global gauge invariance of the electromagnetic field. This is related to the fact that the electric and magnetic fields are not changed by different choices of the value representing the zero point of electrostatic potential formula_24. However the full symmetry is more complicated, and also involves the vector potential formula_25. The full statement of gauge invariance is that the physics of an electromagnetic field are unchanged when the scalar and vector potential are shifted by the gradient of an arbitrary scalar field formula_26:
In quantum mechanics the scalar field is equivalent to a phase shift in the wavefunction of the charged particle:
so gauge invariance is equivalent to the well known fact that changes in the phase of a wavefunction are unobservable, and only changes in the magnitude of the wavefunction result in changes to the probability function formula_29. This is the ultimate theoretical origin of charge conservation.
Gauge invariance is a very important, well established property of the electromagnetic field and has many testable consequences. The theoretical justification for charge conservation is greatly strengthened by being linked to this symmetry. For example, gauge invariance also requires that the photon be massless, so the good experimental evidence that the photon has zero mass is also strong evidence that charge is conserved.
Even if gauge symmetry is exact, however, there might be apparent electric charge non-conservation if charge could leak from our normal 3-dimensional space into hidden extra dimensions.
Experimental evidence.
Simple arguments rule out some types of charge nonconservation. For example, the magnitude of the elementary charge on positive and negative particles must be extremely close to equal, differing by no more than a factor of 10−21 for the case of protons and electrons. Ordinary matter contains equal numbers of positive and negative particles, protons and electrons, in enormous quantities. If the elementary charge on the electron and proton were even slightly different, all matter would have a large electric charge and would be mutually repulsive.
The best experimental tests of electric charge conservation are searches for particle decays that would be allowed if electric charge is not always conserved. No such decays have ever been seen.
The best experimental test comes from searches for the energetic photon from an electron decaying into a neutrino and a single photon:
but there are theoretical arguments that such single-photon decays will never occur even if charge is not conserved. 
Charge disappearance tests are sensitive to decays without energetic photons, other unusual charge violating processes such as an electron spontaneously changing into a positron, 
and to electric charge moving into other dimensions.
The best experimental bounds on charge disappearance are: