T-matrix method

The T-matrix method is a computational technique of light scattering by nonspherical particles originally formulated by Peter C. Waterman (1928–2012) in 1965.
The technique is also known as null field method and extended boundary technique method (EBCM). In the method, matrix elements are obtained by matching boundary conditions for solutions of Maxwell equations.
Definition of the T-Matrix.
The incident and scattered electric field are expanded into spherical vector wave functions (SVWF), which are also encountered in Mie scattering. They are the fundamental solutions of the vector Helmholtz equation and
can be generated from the scalar fundamental solutions in spherical coordinates, the spherical Bessel functions of the first kind and the spherical Hankel Functions. Accordingly, there are two linearly independent sets of solutions
denoted as formula_1 and formula_2, respectively. They are also called regular and propagating SVWFs, respectively. With this, we can write the incident field as
formula_3
The scattered field is expanded into radiating SVWFs:
formula_4
The T-Matrix relates the expansion coefficients of the incident field to those of the scattered field. 
formula_5
The T-Matrix is determined by the scatterer shape and material and for a given incident field allows one to calculate the scattered field.
Calculation of the T-Matrix.
The standard way to actually calculate the T-Matrix method is the Null-Field Method, that relies on the Stratton-Chu equations. They basically state that the electromagnetic fields outside a given volume can be expressed as integrals over the surface enclosing the volume involving only the tangential components of the fields on the surface. If the observation point is located inside this volume, the integrals vanish.
By making use of the boundary conditions for the tangential field components on the scatterer surface
formula_6 and formula_7, where formula_8 is the normal vector to the scatterer surface, one can derive an integral representation of the scattered field in terms of the tangential components of the internal fields on the scatterer surface. A similar representation can be derived for the incident field.
By expanding the internal field in terms of SVWFs and exploiting their orthogonality on spherical surfaces, one arrives at an expression for the T-Matrix. The T-matrix can also be computed from far field data. This approach avoids numerical stability issues associated with the Null-Field Method 
Numerical codes for the evaluation of the T-Matrix can be found online .