Photovoltaics

Photovoltaics (PV) is the conversion of light into electricity using semiconducting materials that exhibit the photovoltaic effect, a phenomenon studied in physics, photochemistry, and electrochemistry. The photovoltaic effect is commercially utilized for electricity generation and as photosensors.
A photovoltaic system employs solar modules, each comprising a number of solar cells, which generate electrical power. PV installations may be ground-mounted, rooftop-mounted, wall-mounted or floating. The mount may be fixed or use a solar tracker to follow the sun across the sky.
PV has become the cheapest source of electrical power in regions with a high solar potential, with a bid for pricing as low as 0.01567 US$/kWh in Qatar in 2020. Panel prices have dropped by the factor of 4 between 2004 and 2011. This competitiveness opens the path to a global transition to sustainable energy, which would be required to help mitigate global warming. The emissions budget for to meet the 1.5 degree target would be used up in 2028 if emissions remain on the current level. However, the use of PV as a main source requires energy storage systems or global distribution by high-voltage direct current power lines causing additional costs, as well as a number of other specific disadvantages such as unstable power generation and the requirement for power companies to compensate for too much solar power in the supply mix by having more reliable conventional power supplies in order to regulate demand peaks and potential undersupply.
Solar PV has specific advantages as an energy source: once installed, its operation generates no pollution and no greenhouse gas emissions, it shows simple scalability in respect of power needs and silicon has large availability in the Earth's crust, but other materials required in PV system manufacture such as silver will eventually constrain further growth in the technology. Other major constraints identified are competition for land use and lack of labor in making funding applications. Production and installation does cause pollution and greenhouse gas emissions and there are no viable systems for recycling the panels once they are at the end of their lifespan after 10 to 30 years.
Photovoltaic systems have long been used in specialized applications as stand-alone installations and grid-connected PV systems have been in use since the 1990s. Photovoltaic modules were first mass-produced in 2000, when German environmentalists and the Eurosolar organization received government funding for a ten thousand roof program.
Advances in technology and increased manufacturing scale have in any case reduced the cost, increased the reliability, and increased the efficiency of photovoltaic installations. 
Net metering and financial incentives, such as preferential feed-in tariffs for solar-generated electricity, have supported solar PV installations in many countries. More than 100 countries now use solar PV.
In 2019, worldwide installed PV capacity increased to more than 635 gigawatts (GW) covering approximately two percent of global electricity demand. After hydro and wind powers, PV is the third renewable energy source in terms of global capacity. The International Energy Agency expects a growth by 700 - 880 GW from 2019 to 2024.
In 2020, a rooftop photovoltaic system recoups the energy needed to manufacture it in 1.28 years in Ottawa, Canada, 0.97 years in Catania, Italy, and 0.4 years in Jaipur, India.
PV has grown as an energy source primarily as a result of technological development delivering decreasing costs.
Etymology.
The term "photovoltaic" comes from the Greek φῶς ("phōs") meaning "light", and from "volt", the unit of electromotive force, the volt, which in turn comes from the last name of the Italian physicist Alessandro Volta, inventor of the battery (electrochemical cell). The term "photovoltaic" has been in use in English since 1849.
Solar cells.
Photovoltaics are best known as a method for generating electric power by using solar cells to convert energy from the sun into a flow of electrons by the photovoltaic effect.
Solar cells produce direct current electricity from sunlight which can be used to power equipment or to recharge a battery. The first practical application of photovoltaics was to power orbiting satellites and other spacecraft, but today the majority of photovoltaic modules are used for grid-connected systems for power generation. In this case an inverter is required to convert the DC to AC. There is still a smaller market for stand alone systems for remote dwellings, boats, recreational vehicles, electric cars, roadside emergency telephones, remote sensing, and cathodic protection of pipelines.
Photovoltaic power generation employs solar modules composed of a number of solar cells containing a semiconductor material. Copper solar cables connect modules (module cable), arrays (array cable), and sub-fields. Because of the growing demand for renewable energy sources, the manufacturing of solar cells and photovoltaic arrays has advanced considerably in recent years.
Cells require protection from the environment and are usually packaged tightly in solar modules.
Photovoltaic module power is measured under standard test conditions (STC) in "Wp" (watts peak). The actual power output at a particular place may be less than or greater than this rated value, depending on geographical location, time of day, weather conditions, and other factors. Solar photovoltaic array capacity factors are typically under 25%, which is lower than many other industrial sources of electricity.
Manufacturing.
Overall the
manufacturing process of creating solar photovoltaics is simple in that it does
not require the culmination of many complex or moving parts. Because of the
solid state nature of PV systems they often have relatively long lifetimes,
anywhere from 10 to 30 years. To increase electrical output of a PV
system, the manufacturer must simply add more photovoltaic components and
because of this economies of scale are important for manufacturers as costs
decrease with increasing output.
While there are many types of PV systems known to be effective, crystalline silicon PV accounted for around 90% of the worldwide production of PV in 2013. Manufacturing silicon PV systems has several steps. First, polysilicon is processed from mined quartz until it is very pure (semi-conductor grade). This is melted down when small amounts of boron, a group III element, are added to make a p-type semiconductor rich in electron holes. Typically using a seed crystal, an ingot of this solution is grown from the liquid polycrystalline. The ingot may also be cast in a mold. Wafers of this semiconductor material are cut from the bulk material with wire saws, and then go through surface etching before being cleaned. Next, the wafers are placed into a phosphorus vapor deposition furnace which lays a very thin layer of phosphorus, a group V element, which creates an n-type semiconducting surface. To reduce energy losses, an anti-reflective coating is added to the surface, along with electrical contacts. After finishing the cell, cells are connected via electrical circuit according to the specific application and prepared for shipping and installation.
Crystalline silicon photovoltaics are only one type of PV, and while they represent the majority of solar cells produced currently there are many new and promising technologies that have the potential to be scaled up to meet future energy needs. As of 2018, crystalline silicon cell technology serves as the basis for several PV module types, including monocrystalline, multicrystalline, mono PERC, and bifacial.
Another newer technology, thin-film PV, are manufactured by depositing semiconducting layers of perovskite, a mineral with semiconductor properties, on a substrate in vacuum. The substrate is often glass or stainless-steel, and these semiconducting layers are made of many types of materials including cadmium telluride (CdTe), copper indium diselenide (CIS), copper indium gallium diselenide (CIGS), and amorphous silicon (a-Si). After being deposited onto the substrate the semiconducting layers are separated and connected by electrical circuit by laser scribing. Perovskite solar cells are a very efficient solar energy converter and have excellent optoelectronic properties for photovoltaic purposes, but their upscaling from lab-sized cells to large-area modules is still under research. Thin-film photovoltaic materials may possibly become attractive in the future, because of the reduced materials requirements and cost to manufacture modules consisting of thin-films as compared to silicon-based wafers. In 2019 university labs at Oxford, Stanford and elsewhere reported perovskite solar cells with efficiencies of 20-25%.
Other possible future PV technologies include organic, dye-sensitized and quantum-dot photovoltaics. Organic photovoltaics (OPVs) fall into the thin-film category of manufacturing, and typically operate around the 12% efficiency range which is lower than the 12–21% typically seen by silicon based PVs. Because organic photovoltaics require very high purity and are relatively reactive they must be encapsulated which vastly increases cost of manufacturing and meaning that they are not feasible for large scale up. Dye-sensitized PVs are similar in efficiency to OPVs but are significantly easier to manufacture. However these dye-sensitized photovoltaics present storage problems because the liquid electrolyte is toxic and can potentially permeate the plastics used in the cell. Quantum dot solar cells are solution processed, meaning they are potentially scalable, but currently they peak at 12% efficiency.
Economics.
There have been major changes in the underlying costs, industry structure and market prices of solar photovoltaics technology, over the years, and gaining a coherent picture of the shifts occurring across the industry value chain globally is a challenge. This is due to: "the rapidity of cost and price changes, the complexity of the PV supply chain, which involves a large number of manufacturing processes, the balance of system (BOS) and installation costs associated with complete PV systems, the choice of different distribution channels, and differences between regional markets within which PV is being deployed". Further complexities result from the many different policy support initiatives that have been put in place to facilitate photovoltaics commercialisation in various countries.
Renewable energy technologies have generally gotten cheaper since their invention.
Hardware costs.
In 1977 crystalline silicon solar cell prices were at $76.67/W.
Although wholesale module prices remained flat at around $3.50 to $4.00/W in the early 2000s due to high demand in Germany and Spain afforded by generous subsidies and shortage of polysilicon, demand crashed with the abrupt ending of Spanish subsidies after the market crash of 2008, and the price dropped rapidly to $2.00/W. Manufacturers were able to maintain a positive operating margin despite a 50% drop in income due to innovation and reductions in costs. In late 2011, factory-gate prices for crystalline-silicon photovoltaic modules suddenly dropped below the $1.00/W mark, taking many in the industry by surprise, and has caused a number of solar manufacturing companies to go bankrupt throughout the world. The $1.00/W cost is often regarded in the PV industry as marking the achievement of grid parity for PV, but most experts do not believe this price point is sustainable. Technological advancements, manufacturing process improvements, and industry re-structuring, may mean that further price reductions are possible. The average retail price of solar cells as monitored by the Solarbuzz group fell from $3.50/watt to $2.43/watt over the course of 2011. In 2013 wholesale prices had fallen to $0.74/W. This has been cited as evidence supporting Swanson's law, an observation similar to the famous Moore's Law that states that solar cell prices fall 20% for every doubling of industry capacity.
Note that the prices mentioned above are for bare modules, another way of looking at module prices is to include installation costs. In the US, according to the Solar Energy Industries Association, the price of installed rooftop PV modules for homeowners fell from $9.00/W in 2006 to $5.46/W in 2011. Including the prices paid by industrial installations, the national installed price drops to $3.45/W. This is markedly higher than elsewhere in the world, in Germany homeowner rooftop installations averaged at $2.24/W. The cost differences are thought to be primarily based on the higher regulatory burden and lack of a national solar policy in the USA.
By the end of 2012 Chinese manufacturers had production costs of $0.50/W in the cheapest modules. In some markets distributors of these modules can earn a considerable margin, buying at factory-gate price and selling at the highest price the market can support ('value-based pricing').
Levelised cost of electricity.
The levelised cost of electricity (LCOE) is the cost per kWh based on the costs distributed over the project lifetime, and is thought to be a better metric for calculating viability than price per wattage. LCOEs vary dramatically depending on the location. The LCOE can be considered the minimum price customers will have to pay the utility company in order for it to break even on the investment in a new power station. Grid parity is roughly achieved when the LCOE falls to a similar price as conventional local grid prices, although in actuality the calculations are not directly comparable. Large industrial PV installations had reached grid parity in California in 2011. Grid parity for rooftop systems was still believed to be much farther away at this time. Many LCOE calculations are not thought to be accurate, and a large amount of assumptions are required. Module prices may drop further, and the LCOE for solar may correspondingly drop in the future.
Because energy demands rise and fall over the course of the day, and solar power is limited by the fact that the sun sets, solar power companies must also factor in the additional costs of supplying a more stable alternative energy supplies to the grid in order to stabilize the system, or storing the energy somehow (current battery technology cannot store enough power). These costs are not factored into LCOE calculations, nor are special subsidies or premiums that may make buying solar power more attractive. The unreliability and temporal variation in generation of solar and wind power is a major problem. Too much of these volatile power sources can cause instability of the entire grid.
As of 2017 power-purchase agreement prices for solar farms below $0.05/kWh are common in the United States, and the lowest bids in some Persian Gulf countries were about $0.03/kWh. The goal of the United States Department of Energy is to achieve a levelised cost of energy for solar PV of $0.03/kWh for utility companies.
Subsidies and financing.
Financial incentives for photovoltaics, such as feed-in tariffs (FITs), are often been offered to electricity consumers to install and operate solar-electric generating systems, and in some countries such subsidies are the only way photovoltaics can remain economically profitable. In Germany FIT subsidies are generally around €0.13 above the normal retail price of a kWh (€0.05). PV FITs have been crucial for the adoption of the industry, and are available to consumers in over 50 countries as of 2011. Germany and Spain have been the most important countries regarding offering subsidies for PV, and the policies of these countries have driven demand in the past. Some US solar cell manufacturing companies have repeatedly complained that the dropping prices of PV module costs have been achieved due to subsidies by the government of China, and the dumping of these products below fair market prices. US manufacturers generally recommend high tariffs on foreign supplies to allow them remain profitable. In response to these concerns, the Obama administration began to levy tariffs on US consumers of these products in 2012 to raise prices for domestic manufacturers. Under the Trump administration the US government imposed further tariffs on US consumers to restrict trade in solar modules. The USA, however, also subsidies the industry, offering consumers a 30% federal tax credit to purchase modules. In Hawaii federal and state subsidies chop off up to two thirds of the installation costs.
Some environmentalists have promoted the idea that government incentives should be used in order to expand the PV manufacturing industry to reduce costs of PV-generated electricity much more rapidly to a level where it is able to compete with fossil fuels in a free market. This is based on the theory that when the manufacturing capacity doubles, economies of scale will cause the prices of the solar products to halve.
In California PV reached grid parity in 2011, which is usually defined as PV production costs at or below retail electricity prices (though often still above the power station prices for coal or gas-fired generation without their distribution and other costs). However, in many countries there is still a need for more access to capital to develop PV projects. To solve this problem securitization has been proposed and used to accelerate development of solar photovoltaic projects. For example, SolarCity offered the first U.S. asset-backed security in the solar industry in 2013.
Solar cell efficiencies.
Solar cell efficiencies vary from 6% for amorphous silicon-based solar cells to 44.0% with experimental multiple-junction concentrated photovoltaics. Solar cell energy conversion efficiencies for commercially available photovoltaics are around 14–22%.
Other.
Photovoltaic power is also generated during a time of day that is close to peak demand (precedes it) in electricity systems with high use of air conditioning. Since large-scale PV operation requires back-up in the form of spinning reserves, its marginal cost of generation in the middle of the day is typically lowest, but not zero, when PV is generating electricity. This can be seen in Figure 1 of this paper:. For residential properties with private PV facilities networked to the grid, the owner may be able earn extra money when the time of generation is included, as electricity is worth more during the day than at night. 
One journalist theorised in 2012 that if the energy bills of Americans were forced upwards by imposing an extra tax of $50/ton on carbon dioxide emissions from coal-fired power, this could have allowed solar PV to appear more cost-competitive to consumers in most locations.
Conventionally, direct current (DC) generated electricity from solar PV must be converted to alternating current (AC) used in the power grid, at an average 10% loss during the conversion. Because the batteries used in electric vehicles use DC, the owner of such products may be able to achieve some higher efficiencies if he/she is somehow able to plug the battery directly into the solar cell. An additional efficiency loss occurs in the transition back to DC for battery driven devices and vehicles.
Current developments.
For best performance, terrestrial PV systems aim to maximize the time they face the sun. Solar trackers achieve this by moving PV modules to follow the sun.. Static mounted systems can be optimized by analysis of the sun path. PV modules are often set to latitude tilt, an angle equal to the latitude, but performance can be improved by adjusting the angle for summer or winter. Generally, as with other semiconductor devices, temperatures above room temperature reduce the performance of photovoltaic modules.
A number of solar modules may also be mounted vertically above each other in a tower, if the zenith distance of the Sun is greater than zero, and the tower can be turned horizontally as a whole and each module additionally around a horizontal axis. In such a tower the modules can follow the Sun exactly. Such a device may be described as a ladder mounted on a turnable disk. Each step of that ladder is the middle axis of a rectangular solar panel. In case the zenith distance of the Sun reaches zero, the "ladder" may be rotated to the north or the south to avoid a solar module producing a shadow on a lower one. Instead of an exactly vertical tower one can choose a tower with an axis directed to the polar star, meaning that it is parallel to the rotation axis of the Earth. In this case the angle between the axis and the Sun is always larger than 66 degrees. During a day it is only necessary to turn the panels around this axis to follow the Sun. Installations may be ground-mounted (and sometimes integrated with farming and grazing) or built into the roof or walls of a building (building-integrated photovoltaics).
Efficiency.
The electrical efficiency of a PV cell is a physical property which represents how much electrical power a cell can produce for a given Solar irradiance. The basic expression for maximum efficiency of a photovoltaic cell is given by the ratio of output power to the incident solar power (radiation flux times area)
The efficiency is measured under ideal laboratory conditions and represents the maximum achievable efficiency of the PV cell or module. Actual efficiency is influenced by temperature, irradiance and spectrum.
The most efficient type of solar cell to date is a multi-junction concentrator solar cell with an efficiency of 46.0% produced by Fraunhofer ISE in December 2014. The highest efficiencies achieved without concentration include a material by Sharp Corporation at 35.8% using a proprietary triple-junction manufacturing technology in 2009, and Boeing Spectrolab (40.7% also using a triple-layer design). The US-based specialty gallium arsenide (GaAs) PV manufacturer Alta Devices produces commercial cells with 26% efficiency claiming to have "the world's most efficient solar" single-junction cell dedicated to flexible and lightweight applications. For Silicon solar cell, the US company SunPower remains the leader with a certified module efficiency of 22.8%, well above the market average of 15–18%. However, competitor companies are catching up like the South Korean conglomerate LG (21.7% efficiency) or the Norwegian REC Group (21.7% efficiency).
There is an ongoing effort to increase the conversion efficiency of PV cells and modules, primarily for competitive advantage. In order to increase the efficiency of solar cells, it is important to choose a semiconductor material with an appropriate band gap that matches the solar spectrum. This will enhance the electrical and optical properties. Improving the method of charge collection is also useful for increasing the efficiency. There are several groups of materials that are being developed. Ultrahigh-efficiency devices (η>30%) are made by using GaAs and GaInP2 semiconductors with multijunction tandem cells. High-quality, single-crystal silicon materials are used to achieve high-efficiency, low cost cells (η>20%).
Recent developments in organic photovoltaic cells (OPVs) have made significant advancements in power conversion efficiency from 3% to over 15% since their introduction in the 1980s. To date, the highest reported power conversion efficiency ranges from 6.7% to 8.94% for small molecule, 8.4%–10.6% for polymer OPVs, and 7% to 21% for perovskite OPVs. OPVs are expected to play a major role in the PV market. Recent improvements have increased the efficiency and lowered cost, while remaining environmentally-benign and renewable.
Several companies have begun embedding power optimizers into PV modules called smart modules. These modules perform maximum power point tracking (MPPT) for each module individually, measure performance data for monitoring, and provide additional safety features. Such modules can also compensate for shading effects, wherein a shadow falling across a section of a module causes the electrical output of one or more strings of cells in the module to decrease.
One of the major causes for the decreased performance of cells is overheating. The efficiency of a solar cell declines by about 0.5% for every 1 degree Celsius increase in temperature. This means that a 100 degree increase in surface temperature could decrease the efficiency of a solar cell by about half. Self-cooling solar cells are one solution to this problem. Rather than using energy to cool the surface, pyramid and cone shapes can be formed from silica, and attached to the surface of a solar panel. Doing so allows visible light to reach the solar cells, but reflects infrared rays (which carry heat).
Effect of the temperature.
The performance of a photovoltaic (PV) module depends on the environmental conditions, mainly on the global incident irradiance G on the module plane. However, the temperature T of the p–n junction also influences the main electrical parameters: the short‐circuit current ISC, the open‐circuit voltage VOC, and the maximum power Pmax. The first studies about the behavior of PV cells under varying conditions of G and T date back several decades ago.1-4 In general, it is known that VOC shows a significant inverse correlation with T, whereas for ISC that correlation is direct, but weaker, so that this increment does not compensate for the decrease of VOC. As a consequence, Pmax reduces when T increases. This correlation between the output power of a solar cell and its junction working temperature depends on the semiconductor material,2 and it is due to the influence of T on the concentration, lifetime, and mobility of the intrinsic carriers, that is, electrons and holes, inside the PV cell.
The temperature sensitivity is usually described by some temperature coefficients, each one expressing the derivative of the parameter it refers to with respect to the junction temperature. The values of these parameters can be found in any PV module data sheet; they are the following:
– β Coefficient of variation of VOC with respect to T, given by ∂VOC/∂T.
– α Coefficient of variation of ISC with respect to T, given by ∂ISC/∂T.
– δ Coefficient of variation of Pmax with respect to T, given by ∂Pmax/∂T.
Techniques for estimating these coefficients from experimental data can be found in the literature. Few studies analyse the variation of the series resistance with respect to the cell or module temperature. This dependency is studied by suitably processing the current–voltage curve. The temperature coefficient of the series resistance is estimated by using the single diode model or the double diode one. 
Growth.
Solar photovoltaics is growing rapidly and worldwide installed capacity reached about 515 gigawatts (GW) by 2018. The total power output of the world's PV capacity in a calendar year is now beyond 500 TWh of electricity. This represents 2% of worldwide electricity demand. More than 100 countries use solar PV. 
China is followed by the United States and Japan, while installations in Germany, once the world's largest producer, have been slowing down.
In 2017 a study in Science estimated that by 2030 global PV installed capacities will be between 3,000 and 10,000 GW. The EPIA/Greenpeace Solar Generation Paradigm Shift Scenario (formerly called Advanced Scenario) from 2010 shows that by the year 2030, 1,845 GW of PV systems could be generating approximately 2,646 TWh/year of electricity around the world. Combined with energy use efficiency improvements, this would represent the electricity needs of more than 9% of the world's population. By 2050, over 20% of all electricity could be provided by photovoltaics.
Michael Liebreich, from Bloomberg New Energy Finance, anticipates a tipping point for solar energy. The costs of power from wind and solar are already below those of conventional electricity generation in some parts of the world, as they have fallen sharply and will continue to do so. He also asserts, that the electrical grid has been greatly expanded worldwide, and is ready to receive and distribute electricity from renewable sources. In addition, worldwide electricity prices came under strong pressure from renewable energy sources, that are, in part, enthusiastically embraced by consumers.
Deutsche Bank sees a "second gold rush" for the photovoltaic industry to come. Grid parity has already been reached in at least 19 markets by January 2014. Photovoltaics will prevail beyond feed-in tariffs, becoming more competitive as deployment increases and prices continue to fall.
In June 2014 Barclays downgraded bonds of U.S. utility companies. Barclays expects more competition by a growing self-consumption due to a combination of decentralized PV-systems and residential electricity storage. This could fundamentally change the utility's business model and transform the system over the next ten years, as prices for these systems are predicted to fall.
In 2019 China leads with 205 GW installed. Second is European Union with 132 GW. Second State is USA with 76 GW. Third is Japan with 63 GW. 10th is France with 10 GW. Installed capacity is rapidly increased in 4 Years. 
Leading in PV part of whole electricity system is Honduras with 14.8%.
As of 2019, Vietnam has the highest installed capacity in Southeast Asia, about 4.5 GW. The annualized installation rate of about 90 W per capita per annum places Vietnam among world leaders.
Drivers and Barriers to Growth
Generous Feed-in tariff (FIT) and supporting policies such as tax exemptions are found to be the key proximate drivers of Vietnam's solar PV boom. Underlying drivers include the government's desire to enhance energy self-sufficiency and the public's demand for local environmental quality. 
A key barrier is limited transmission grid capacity.
Environmental impacts of photovoltaic technologies.
Types of impacts
While solar photovoltaic (PV) cells are promising for clean energy production, their deployment is hindered by production costs, material availability, and toxicity. Data required to investigate their impact are sometimes affected by a rather large amount of uncertainty. The values of human labor and water consumption, for example, are not precisely assessed due to the lack of systematic and accurate analyses in the scientific literature.
Life cycle assessment (LCA) is one method of determining environmental impacts from PV. Many studies have been done on the various types of PV including first generation, second generation, and third generation. Usually these PV LCA studies select a cradle to gate system boundary because often at the time the studies are conducted, it is a new technology not commercially available yet and their required balance of system components and disposal methods are unknown.
A traditional LCA can look at many different impact categories ranging from global warming potential, ecotoxicity, human toxicity, water depletion, and many others.
Most LCAs of PV have focused on two categories: carbon dioxide equivalents per kWh and energy pay-back time (EPBT). The EPBT is defined as " the time needed to compensate for the total renewable- and non-renewable- primary energy required during the life cycle of a PV system". A 2015 review of EPBT from first and second generation PV suggested that there was greater variation in embedded energy than in efficiency of the cells implying that it was mainly the embedded energy that needs to reduce to have a greater reduction in EPBT. One difficulty in determining impacts due to PV is to determine if the wastes are released to the air, water, or soil during the manufacturing phase. Research is underway to try to understand emissions and releases during the lifetime of PV systems.
Impacts from first-generation PV
Crystalline silicon modules are the most extensively studied PV type in terms of LCA since they are the most commonly used. Mono-crystalline silicon photovoltaic systems (mono-si) have an average efficiency of 14.0%. The cells tend to follow a structure of front electrode, anti-reflection film, n-layer, p-layer, and back electrode, with the sun hitting the front electrode. EPBT ranges from 1.7 to 2.7 years. The cradle to gate of CO2-eq/kWh ranges from 37.3 to 72.2 grams.
Techniques to produce multi-crystalline silicon (multi-si) photovoltaic cells are simpler and cheaper than mono-si, however tend to make less efficient cells, an average of 13.2%. EPBT ranges from 1.5 to 2.6 years. The cradle to gate of CO2-eq/kWh ranges from 28.5 to 69 grams. Some studies have looked beyond EPBT and GWP to other environmental impacts. In one such study, conventional energy mix in Greece was compared to multi-si PV and found a 95% overall reduction in impacts including carcinogens, eco-toxicity, acidification, eutrophication, and eleven others.
Impacts from second generation
Cadmium telluride (CdTe) is one of the fastest-growing thin film based solar cells which are collectively known as second generation devices. This new thin film device also shares similar performance restrictions (Shockley-Queisser efficiency limit) as conventional Si devices but promises to lower the cost of each device by both reducing material and energy consumption during manufacturing. Today the global market share of CdTe is 5.4%, up from 4.7% in 2008. This technology's highest power conversion efficiency is 21%. The cell structure includes glass substrate (around 2 mm), transparent conductor layer, CdS buffer layer (50–150 nm), CdTe absorber and a metal contact layer.
CdTe PV systems require less energy input in their production than other commercial PV systems per unit electricity production. The average CO2-eq/kWh is around 18 grams (cradle to gate). CdTe has the fastest EPBT of all commercial PV technologies, which varies between 0.3 and 1.2 years.
Copper Indium Gallium Diselenide (CIGS) is a thin film solar cell based on the copper indium diselenide (CIS) family of chalcopyrite semiconductors. CIS and CIGS are often used interchangeably within the CIS/CIGS community. The cell structure includes soda lime glass as the substrate, Mo layer as the back contact, CIS/CIGS as the absorber layer, cadmium sulfide (CdS) or Zn (S,OH)x as the buffer layer, and ZnO:Al as the front contact. CIGS is approximately 1/100th the thickness of conventional silicon solar cell technologies. Materials necessary for assembly are readily available, and are less costly per watt of solar cell. CIGS based solar devices resist performance degradation over time and are highly stable in the field.
Reported global warming potential impacts of CIGS range from 20.5 – 58.8 grams CO2-eq/kWh of electricity generated for different solar irradiation (1,700 to 2,200 kWh/m2/y) and power conversion efficiency (7.8 – 9.12%). EPBT ranges from 0.2 to 1.4 years, while harmonized value of EPBT was found 1.393 years. Toxicity is an issue within the buffer layer of CIGS modules because it contains cadmium and gallium. CIS modules do not contain any heavy metals.
Impacts from third generation
Third-generation PVs are designed to combine the advantages of both the first and second generation devices and they do not have Shockley-Queisser limit, a theoretical limit for first and second generation PV cells. The thickness of a third generation device is less than 1 µm.
One emerging alternative and promising technology is based on an organic-inorganic hybrid solar cell made of methylammonium lead halide perovskites. Perovskite PV cells have progressed rapidly over the past few years and have become one of the most attractive areas for PV research. The cell structure includes a metal back contact (which can be made of Al, Au or Ag), a hole transfer layer (spiro-MeOTAD, P3HT, PTAA, CuSCN, CuI, or NiO), and absorber layer (CH3NH3PbIxBr3-x, CH3NH3PbIxCl3-x or CH3NH3PbI3), an electron transport layer (TiO, ZnO, Al2O3 or SnO2) and a top contact layer (fluorine doped tin oxide or tin doped indium oxide).
There are a limited number of published studies to address the environmental impacts of perovskite solar cells. The major environmental concern is the lead used in the absorber layer. Due to the instability of perovskite cells lead may eventually be exposed to fresh water during the use phase. These LCA studies looked at human and ecotoxicity of perovskite solar cells and found they were surprisingly low and may not be an environmental issue. Global warming potential of perovskite PVs were found to be in the range of 24–1500 grams CO2-eq/kWh electricity production. Similarly, reported EPBT of the published paper range from 0.2 to 15 years. The large range of reported values highlight the uncertainties associated with these studies. Celik et al. (2016) critically discussed the assumptions made in perovskite PV LCA studies.
Two new promising thin film technologies are copper zinc tin sulfide (Cu2ZnSnS4 or CZTS), zinc phosphide (Zn3P2) and single-walled carbon nano-tubes (SWCNT). These thin films are currently only produced in the lab but may be commercialized in the future. The manufacturing of CZTS and (Zn3P2) processes are expected to be similar to those of current thin film technologies of CIGS and CdTe, respectively. While the absorber layer of SWCNT PV is expected to be synthesized with CoMoCAT method. by Contrary to established thin films such as CIGS and CdTe, CZTS, Zn3P2, and SWCNT PVs are made from earth abundant, nontoxic materials and have the potential to produce more electricity annually than the current worldwide consumption. While CZTS and Zn3P2 offer good promise for these reasons, the specific environmental implications of their commercial production are not yet known. Global warming potential of CZTS and Zn3P2 were found 38 and 30 grams CO2-eq/kWh while their corresponding EPBT were found 1.85 and 0.78 years, respectively. Overall, CdTe and Zn3P2 have similar environmental impacts but can slightly outperform CIGS and CZTS. Celik et al. performed the first LCA study on environmental impacts of SWCNT PVs, including a laboratory-made 1% efficient device and an aspirational 28% efficient four-cell tandem device and interpreted the results by using mono-Si as a reference point. the results show that compared to monocrystalline Si (mono-Si), the environmental impacts from 1% SWCNT was ∼18 times higher due mainly to the short lifetime of three years. However, even with the same short lifetime, the 28% cell had lower environmental impacts than mono-Si.
Organic and polymer photovoltaic (OPV) are a relatively new area of research. The tradition OPV cell structure layers consist of a semi-transparent electrode, electron blocking layer, tunnel junction, holes blocking layer, electrode, with the sun hitting the transparent electrode. OPV replaces silver with carbon as an electrode material lowering manufacturing cost and making them more environmentally friendly. OPV are flexible, low weight, and work well with roll-to roll manufacturing for mass production. OPV uses "only abundant elements coupled to an extremely low embodied energy through very low processing temperatures using only ambient processing conditions on simple printing equipment enabling energy pay-back times". Current efficiencies range from 1–6.5%, however theoretical analyses show promise beyond 10% efficiency.
Many different configurations of OPV exist using different materials for each layer. OPV technology rivals existing PV technologies in terms of EPBT even if they currently present a shorter operational lifetime. A 2013 study analyzed 12 different configurations all with 2% efficiency, the EPBT ranged from 0.29 to 0.52 years for 1 m2 of PV. The average CO2-eq/kWh for OPV is 54.922 grams.
Applications.
Photovoltaic systems.
A photovoltaic system, or solar PV system is a power system designed to supply usable solar power by means of photovoltaics. It consists of an arrangement of several components, including solar panels to absorb and directly convert sunlight into electricity, a solar inverter to change the electric current from DC to AC, as well as mounting, cabling and other electrical accessories. PV systems range from small, roof-top mounted or building-integrated systems with capacities from a few to several tens of kilowatts, to large utility-scale power stations of hundreds of megawatts. Nowadays, most PV systems are grid-connected, while stand-alone systems only account for a small portion of the market.
Photo sensors.
Photosensors are sensors of light or other electromagnetic radiation. A photo detector has a p–n junction that converts light photons into current. The absorbed photons make electron–hole pairs in the depletion region. Photodiodes and photo transistors are a few examples of photo detectors. Solar cells convert some of the light energy absorbed into electrical energy.
Advantages.
The 122 PW of sunlight reaching the Earth's surface is plentiful—almost 10,000 times more than the 13 TW equivalent of average power consumed in 2005 by humans. This abundance leads to the suggestion that it will not be long before solar energy will become the world's primary energy source. Additionally, solar electric generation has the highest power density (global mean of 170 W/m2) among renewable energies.
Solar power is pollution-free during use, which enables it to cut down on pollution when it is substituted for other energy sources. For example, MIT estimated that 52,000 people per year die prematurely in the U.S. from coal-fired power plant pollution and all but one of these deaths could be prevented from using PV to replace coal. Production end-wastes and emissions are manageable using existing pollution controls. End-of-use recycling technologies are under development and policies are being produced that encourage recycling from producers.
PV installations could ideally operate for 100 years or even more with little maintenance or intervention after their initial set-up, so after the initial capital cost of building any solar power plant, operating costs are extremely low compared to existing power technologies.
Grid-connected solar electricity can be used locally thus reducing transmission/distribution losses (transmission losses in the US were approximately 7.2% in 1995).
Compared to fossil and nuclear energy sources, very little research money has been invested in the development of solar cells, so there is considerable room for improvement. Nevertheless, experimental high efficiency solar cells already have efficiencies of over 40% in case of concentrating photovoltaic cells and efficiencies are rapidly rising while mass-production costs are rapidly falling.
In some states of the United States, much of the investment in a home-mounted system may be lost if the homeowner moves and the buyer puts less value on the system than the seller. The city of Berkeley developed an innovative financing method to remove this limitation, by adding a tax assessment that is transferred with the home to pay for the solar panels. Now known as PACE, Property Assessed Clean Energy, 30 U.S. states have duplicated this solution.
There is evidence, at least in California, that the presence of a home-mounted solar system can actually increase the value of a home. According to a paper published in April 2011 by the Ernest Orlando Lawrence Berkeley National Laboratory titled An Analysis of the Effects of Residential Photovoltaic Energy Systems on Home Sales Prices in California:
Disadvantages.
PV has been a well-known method of generating clean, emission-free electricity. PV systems are often made of PV modules and inverter (changing DC to AC). PV modules are mainly made of PV cells, which has no fundamental difference from the material used for making computer chips. The process of producing PV cells is energy-intensive and involves highly poisonous and environmentally toxic chemicals. There are a few PV manufacturing plants around the world producing PV modules with energy produced from PV. This counteractive measure considerably reduces the carbon footprint of the manufacturing process of PV cells. Management of the chemicals used and produced during the manufacturing process is subject to the factories' local laws and regulations.
For behind-the-meter rooftop photovoltaic systems, the energy flow becomes two-way. When there is more local generation than consumption, electricity is exported to the grid, allowing for net metering. However, electricity networks traditionally are not designed to deal with two-way energy transfer, which may introduce technical issues. An over-voltage issue may come out as the electricity flows from these PV households back to the network. There are solutions to manage the over-voltage issue, such as regulating PV inverter power factor, new voltage and energy control equipment at electricity distributor level, re-conductor the electricity wires, demand side management, etc. There are often limitations and costs related to these solutions.
High generation during the middle of the day reduces the net generation demand, but higher peak net demand as the sun goes down can require rapid ramping of utility generating stations, producing a load profile called the duck curve.
There is no silver bullet in electricity or energy demand and bill management, because customers (sites) have different specific situations, e.g. different comfort/convenience needs, different electricity tariffs, or different usage patterns. Electricity tariff may have a few elements, such as daily access and metering charge, energy charge (based on kWh, MWh) or peak demand charge (e.g. a price for the highest 30min energy consumption in a month). PV is a promising option for reducing energy charges when electricity prices are reasonably high and continuously increasing, such as in Australia and Germany. However, for sites with peak demand charge in place, PV may be less attractive if peak demands mostly occur in the late afternoon to early evening, for example in residential communities. Overall, energy investment is largely an economic decision and it is better to make investment decisions based on systematic evaluation of options in operational improvement, energy efficiency, onsite generation and energy storage.
PhotoVoltaics in Media.
Video Games.
Major Titles
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