
Cobalt(II) oxide

Cobalt(II) oxide is an inorganic compound that has been described as an olive-green or gray solid. It is used extensively in the ceramics industry as an additive to create blue colored glazes and enamels as well as in the chemical industry for producing cobalt(II) salts. A related material is cobalt(II,III) oxide, a black solid with the formula Co3O4.
Structure and properties.
CoO crystals adopt the periclase (rock salt) structure with a lattice constant of 4.2615 Å.
It is antiferromagnetic below 16 °C.
Preparation.
Cobalt(II) oxide is prepared by oxidation of cobalt powder with air or by thermal decomposition of cobalt(II) nitrate or the carbonate.
Cobalt(II,III) oxide decomposes to cobalt(II) oxide at 950 °C:
It may also be prepared by precipitating the hydroxide, followed by thermal dehydration:
Reactions.
As can be expected, cobalt(II) oxide reacts with mineral acids to form the corresponding cobalt salts:
Applications.
Cobalt(II) oxide has for centuries used as a coloring agent on kiln fired pottery. The additive provides a deep shade of blue named cobalt blue. The band gap (CoO) is around 2.4 eV.
It also is used in cobalt blue glass.