
Tungsten pentoxide

Tungsten pentoxide () was reported in early literature but proved to have the stoichiometry W18O49. Sometimes called mineral blue, it is a blue solid formed by the reaction of tungsten trioxide, WO3, and tungsten metal at 700 °C. 
Intermediate oxides of tungsten.
There are a number of these unusual intermediate oxides formed from reacting metal and trioxide namely, W20O58, W24O70. W18O49 contains both octahedral and pentagonal bipyramidal co-ordination of the metal atoms by oxygen.