Methods for applying no mix cements
CROSS REFERENCE TO RELATED APPLICATIONS 
     This application is a continuation-in-part of application Ser. No. 843,316, filed March 24, 1986 now abandoned. 
    
    
     TECHNICAL FIELD 
     The present invention relates to methods and compositions for the application or placement of cementitious compositions which do not require premixing with water. 
     BACKGROUND OF THE INVENTION 
     At present, it is essential that all cementitious compositions are mixed with water before placement in order to obtain the proper characteristics of the final product. Some type of mixing is and has always been required. Some manufacturers of premixes have put the dry premix in a hole and then recommended adding the water. Some have put premixes in bags and dropped the mixes while in bags through the water, then after the bags are in place, letting water penetrate through the bag to the mix. However, these systems have not allowed full hydration. Mortar mixers, concrete mixers, hand mixing or other types of wet mixing have been utilized to obtain a uniform distribution of the appropriate amount of water in the cement. According to the prior art, the quantity of water to be mixed with the cement must be controlled to a very narrow range, and too little or too much water will produce an ineffective or unusable material. Cementitious mixtures could not be placed in a dry state directly into water or on to a wet surface without first wetting and mixing the dry components. 
     SUMMARY OF THE INVENTION 
     The present invention relates to dry cementitious compositions which have finely divided particles of at least one cement binder. The cement may be Portland cement, gypsum, high aluminum cement, or mixtures thereof, but not restricted thereto. Magnesium phosphate or other fast-setting compounds may also be used. The major proportion of particles have approximately the same drop rate in water, so that when poured through water according to the invention, the material does not appreciably segregate. 
     These compositions may further include a filler component of sand or aggregate particles, provided that the major portion of those particles have a drop rate in water which is approximately the same as the cement particles. Also, the cementitious mixture should be able to absorb and/or combine with water in the amount approximating 50% by volume. The higher the amount of water the cementitious mixture can tolerate, the better the finished product. 
     It is possible to use other additives in these compositions. Such additives may include, but are not limited to, accelerators, water reducing compounds, pumping aids, water absorbing compounds, waterproofing agents, polymers, drying shrinkage inhibitors, wet shrinkage inhibitors, lime, pigments and the like, and may be added to improve or impart a particular property to the composition. 
     The invention also relates to a method for making these compositions. These methods include providing the cement binder in the form of finely divided particles and adjusting the drop rate of the major portion of particles to approximately the same range. Filler components, if added, are treated the same. When fillers are added, it is preferable to mix the dry ingredients to a homogenous consistency. 
     The invention also contemplates various methods for installing cement products upon a substrate which comprises saturating the substrate with an amount of water which is substantially in excess of the normal amount of dry components which are subsequently added. The dry powder is added without mixing in a manner such that it combines with a portion of the water and displaces the remainder of the water. The applied combination is then allowed to cure to a final product. 
     An alternate method according to the invention for applying the cementitious compositions of the invention onto a substrate includes providing a bulk concrete retainer of vessel means, filling the vessel means with an amount of water in excess that needed for hydration of a predetermined amount of cementitious composition which is to be applied upon the substrate, introducing a dry cementitious composition of finely divided particles of at least one cement binder into the water in the vessel means in a manner such that the cementitious composition combines with a portion of the water to completely hydrate the dry composition while displacing the remainder of the water, directing the hydrated cementitious composition to a substrate for placement thereupon, and allowing the hydrated cementitious mixture to cure to a solid mass. 
     Specific methods are further described hereinbelow. 
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     The invention relates to dry cementitious compositions which are poured, troweled or sprayed through excess water or onto wet surfaces without mixing to hydrate the cement component and obtain high strength products after setting and curing. Cementitious compositions of Portland cements, gypsums, high alumina cements, other specialty cements and combinations, as well as other chemicals such as magnesium phosphates, all have been successfully used, the only limitation being that at least one component of the cementitious composition is hydrated by or reacts with water. 
     When the formulations of these cementitious compositions are properly controlled, the problems of thorough wetting of the cement without overwetting, of segregation of components, and of loss of compressive strength of the cured product are greatly reduced or eliminated. 
     Where cement coatings are desired, the surface area to be coated is first prewetted and saturated with water. The dry cementitious mixture is placed on the surface, instantly reacting with the wet surface. If additional layers or a greater thickness of the coating is needed, the first cement layer can be prewetted and the dry composition sprayed directly thereupon to increase the thickness and structural strength of the overall coating. 
     On horizontal surfaces, the area to be poured with cement is first flooded with water, then the dry cementitious compositions of the invention can be poured into the water. The excess water is displaced by the cementitious composition, and the composition is then allowed to cure. This provides a fast, simple installation of cement without the need for tools, mixing apparatus, water measurement aids or the like. For floor levelings, for example, the floor can be flooded to form puddles in low areas. The dry cementitious composition is then sprinkled in the areas where puddles are formed, and allowed to cure. Thus, the floor is easily levelled by this procedure. 
     Another method for applying cements to a substrate such as a floor or wall includes the preparation of ready-set cement or concrete in a bulk concrete container. This container is a tank, trough or other water-retaining apparatus which is used to initially prepare hydrated cementitious compositions before placing these materials in position on the substrate by guniting, pouring, or spraying. The container is filled with an amount of water in excess of that needed to hydrate the amount of cement to be applied. Thereafter, the dry cementitious components are poured into the water as described above. 
     Before the composition can cure, it is sprayed or directed to the desired location, where it is then applied to the substrate and allowed to cure. The setting time of the composition can be controlled by the type and amount of cement binder used, as well as by the addition of retarder compounds, if necessary. After the cement is applied, it is then allowed to cure to a solid mass. 
     Alternately, the dry cementitious components can be pumped or sprayed onto a saturated substrate as described above. This provides the end user with a wide, versatile range of installation methods from which they can choose the most appropriate for a particular application or end use. 
     Controlling the rate of hydration may lead to many applications. For instance, for coating vertical surfaces, a very fast setting material can be used to eliminate the problems of running, sagging or failure to bond. Where mortar for bricklaying is desired, a material with a longer set time will allow the operator sufficient time to work with the material. For situations where the surface particles have not been properly wetted, additional water may be applied to the surface for more activation and further finishing. 
     In the past, there has always been difficulty in controlling the amount of water for the patching of highways or other horizontal surfaces. This problem is solved by this invention because the amount of water is controlled by the formulation of the dry cementitious composition itself. For example, water can be placed into a footing, post hole, mortar joint or tub, or pothole and then the dry cementitious material may be placed by pouring, spraying, or screening into the cavity until the desired level is reached. Excess water, if present, is displaced from the hole by the dry material. The rate of setting of the cementitious mixture can be designed to meet the needs of the particular application. The amount of water required depends on the specific composition and application used. 
     For the placement of concrete foundations, a hole is first prepared, then filled with the required amount of water. If desired, forms can be used to help contain the water. The dry material can be then poured directly into the foundation area to the desired height, thus displacing the excess water, if any. After the material cures, the foundation is complete. 
     In certain circumstances, a cavity could have a small percentage of water placed into it and then the first part of the cementitious mixture placed into the water. While this placement is taking place, additional water could then be placed into the hole by various methods simultaneously with the placement of the rest of the cementitious mixture. When the final quantity of the cementitious mixture is reached, the entire surface area could be sprayed for troweling or other finishing purposes as could be done when the entire mixture is poured through water. 
     In the situation where the cavity is porous and cannot hold water, it is possible to thoroughly wet the surfaces of the hole and then introduce a fast setting cementitious mixture. It is then possible to fill the lined hole with water and proceed as above. 
     The control of density and size of the dry and size of the dry components and the rate of drop through water is essential for the proper performance of the cementitious mixtures. The ability to use materials of various sizes and densities, whose drop rate would otherwise be higher if a slow setting cementitious mixture was used, is enhanced by the increased rate of the water activation of the cementitious particles to form a homogeneous mixture. 
     The use of specific cementitious compositions may be varied or adjusted to meet the needs of the particular application. The most ideal situation is to balance the drop rate for all the dry ingredients and to control the setting time of the cement so that all particles will be properly hydrated and integrated with the aggregates, if any. In this manner, masonry walls can be built up with dry mortars which are hydrated after installation. Precast and prestressed sections are put in place, the dry mixture is placed in water in the joints and the surface can be wetted down for complete activation of the cement binder. The setting time of the binders can be accelerated to a few seconds or slowed up for days, depending upon the selection of cement component. 
     The system can be used with any normal additives acceptable to the specific composition. In some compositions, no curing agent is required. Furthermore, the compositions may contain numerous chemicals or additives that are compatible to the system for the purpose of improving or imparting certain properties. Additives such as accelerators, water reducers, bonding agents, curing agents, or pumping or waterproofing aids may be added to the compositions of the invention. These additives or modifying agents can be added to the water or to the cement mix, in any order or combination. 
     The examples show the success of adding cementitious compositions to water after the water is in place. 
     When dry, preblended materials are used, there is a much greater potential for higher quality finished product. 
     If aggregates are found to be too heavy, smaller aggregates or lighter weight aggregates can be used to keep the density of the overall system in balance. 
     The present invention provides the following: 
     1. Dry cement can be used. 
     2. Cement and sand can be used. 
     3. Cement, sand and aggregates can be used. 
     4. All types of cements can be used. 
     5. All types of cementitious particles, such as gypsums, limes and so forth can be used. 
     6. All types of chemical cements, even with water soluble parts, can be used. 
     7. No wet mixing or blending equipment is required. 
     8. No addition of water to mixes is required before placement, avoiding all equipment costs and clean up. 
     9. When placements under deep water conditions where tremes, elephant trunks or pipes would be required, the material under this formula can be placed dry in the tube and activated by available water at the end of the line, thus keeping all conveyances clear of wet cement. 
     10. When cement contents are too low in mixtures to prevent proper strength development or prevent overadsorption of water, resulting in weak or segregated mixes, more cement may be added, or water absorption material may be added, to prevent excess water from decreasing the quality of the mix. 
     Present cement mixes with less than 20 percent by weight of a cementitious binder should have some additional water absorption agent in the mix to prevent overwatering and segregation. Ideally, cementitious compositions of the mixtures should have the maximum amount of water absorbency possible. The higher the ratio of chemical bonded water to the binder, the better and more versatile a product will be achieved. 
     Cementitious mixtures containing more than 20 percent by weight cement may or may not need additional cement or water absorbers, depending on the application. Generally, at least 35 percent by weight of a cement binder is preferred for use in the compositions and methods of this invention. 
     While using liquids other than water, such as two component thermosetting organic compounds, an aggregate or sand can be dropped through the liquid or chemicals, causing the final mixture to be blended by gravity or by the solid ingredients passing through the liquid, which will result in a hardened mass of aggregate or sand and chemical. 
    
    
     EXAMPLES 
     The scope of the invention is further described in connection with the following examples which are set for the for the sole purpose of illustrating the preferred embodiments of the invention and which are not to be construed as limiting the scope of the invention. 
     The first 9 of the following examples are cementitious materials that were poured into a 4&#34;×8&#34; cylinder which was filled with water. The material was poured until it reached a level of about 1/2&#34; below the top of the cylinder. The cementitious material was then allowed to cure. The results are described in Table I. 
     EXAMPLE 1 
     
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Substance (common sand/cement mix)                                        
                       Percentage                                         
______________________________________                                    
Portland Cement Type I 20%                                                
Sand                   80%                                                
Set time is 20 hours.                                                     
Compressive strength at 24 hours is 0.0 psi (too                          
little cement)                                                            
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     EXAMPLE 2 
     
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Substance         Percentage                                              
______________________________________                                    
Portland Cement Type I                                                    
                  90%                                                     
Sand              10%                                                     
Set time 12 hours.                                                        
Compressive strength at 24 hours is 1,100 psi.                            
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     EXAMPLE 3 
     
         ______________________________________                                    
Substance         Percentage                                              
______________________________________                                    
Portland Cement Type I                                                    
                  50%                                                     
Sand              50%                                                     
Set time 16 hours.                                                        
Compressive strength at 24 hours is 600 psi.                              
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     EXAMPLE 4 
     (Comparative Example) 
     
         ______________________________________                                    
Substance         Percentage                                              
______________________________________                                    
Portland Cement Type I                                                    
                  50%                                                     
Pea Gravel        50%                                                     
Set time 16 hours.                                                        
Compressive strength at 24 hours is 0.0 psi.                              
(different drop rates).                                                   
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     EXAMPLE 5 
     
         ______________________________________                                    
Substance          Percentage                                             
______________________________________                                    
Portland Cement Type II                                                   
                   50%                                                    
Plaster of Paris   50%                                                    
Set time is 10 minutes.                                                   
Compressive strength at 24 hours is 1,600 psi.                            
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     EXAMPLE 6 
     
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Substance         Percentage                                              
______________________________________                                    
High Alumina Cement                                                       
                  80%                                                     
Sand              20%                                                     
Set time is 12 hours.                                                     
Compressive strength at 24 hours is 1,100 psi.                            
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     EXAMPLE 7 
     
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Substance         Percentage                                              
______________________________________                                    
High Alumina Cement                                                       
                  20%                                                     
Sand              80%                                                     
Set time is 20 hours.                                                     
Compressive strength at 24 hours is 0.0 psi. (too                         
little cement).                                                           
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     EXAMPLE 8 
     
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Substance          Percentage                                             
______________________________________                                    
High Alumina Cement                                                       
                   25%                                                    
Portland Cement Type III                                                  
                   25%                                                    
Lithium Carbonate   1%                                                    
Sand               49%                                                    
Set time is 5 minutes.                                                    
Compressive strength at 24 hours is 1,100 psi.                            
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     EXAMPLE 9 
     
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Substance         Percentage                                              
______________________________________                                    
Magnesium Oxide   30%                                                     
Ammonium Phosphate                                                        
                  10%                                                     
Sand              60%                                                     
Set time is 5 minutes.                                                    
Compressive strength at 24 hours is 1,100 psi.                            
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     EXAMPLE 10 
     A test was run wherein the resin and hardener were of approximate equal density in an epoxy formulation. The resin and hardener were poured into a container without premixing, then the aggregate was dropped through the resin and hardener, forming a homogenous mixture which set into a hardened mass. The formula is given below. 
     
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Substance         Percentage                                              
______________________________________                                    
Resin:                                                                    
Dow DER 331       13.1%                                                   
Epoxy Resin                                                               
Furfural Alcohol  3.3%                                                    
Hardener:                                                                 
Dow DEH 58        3.5%                                                    
Diethylene Triamine                                                       
modified with                                                             
Bisphenol A                                                               
E6TPP Borg Warner 3.5%                                                    
Triphenyl Phosphate                                                       
Sand              76.6%                                                   
Set time is 30 minutes.                                                   
Compressive strength at 24 hours is 1,500 psi.                            
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     This test illustrates that various two component thermosetting organic materials can be applied without mixing. Such materials include polyesters, epoxies, polyurethanes and others. According to the invention, the resin and hardener are formulated into portions of substantially similar or identical densities, then poured into place without premixing. Then, the introduction of an additive or filler, such as sand or aggregate, into the poured materials, blends these components to a homogeneous mixture which is capable of curing to a hardened mass. 
     While is apparent that the invention herein disclosed is well calculated to fulfill the objects above stated, it will be appreciated that numerous modifications and embodiments may be devised by those skilled in the art, and it is intended that the appended claims cover all such modifications and embodiments as fall within the true spirit and scope of the present invention.