Patch-type self-locking screw fasteners
This application is continuation of application Ser. No. 06/460,864, filed Jan. 25, 1983, now abandoned, which is a continuation of application Ser. No. 142,645, filed Apr. 22, 1980, now abandoned, which is a continuation of application Ser. No. 419,630, filed on Nov. 27, 1973, now abandoned, which is a division of application Ser. No. 226,147, filed Feb. 14, 1972, now U.S. Pat. No. 3,784,435, issued Jan 8, 1974, which in turn is a continuation-in-part of application Ser. No. 06/126,882, filed Apr. 19, 1971, now abandoned, which in turn is a continuation-in-part of application Ser. No. 05/036,960, filed May 13, 1970, and now abandoned. 
    
    
     BACKGROUND OF THE INVENTION 
     I. Field of the Invention 
     This invention relates to fasteners and in particular to self-locking metal screw threaded fasteners for locking cooperation with a complementary screw thread of a complementary member, a locking element comprising thermoplastic polymer being provided on the screw thread of the fasteners. 
     II. Description of the Prior Art 
     Villo U.S. Pat. No. 3,093,177 teaches that a patch for self-locking action may be formed on a bolt by degreasing the bolt in a hot alkali bath; locking the bolt in a special jig and heating the assembly to 475° F.; applying a shaped pellet of polyamide resin (nylon) to the heated bolt under a pressure of 100 psi; cooling the bolt to 350° F. while the plastic is under pressure; removing the pressure and then permitting the bolt to cool to room temperature. 
     Preziosi U.S. Pat. No. 3,294,139 also teaches that a screw fastener may be provided with a patch made of thermoplastic, such as nylon. The thermoplastic resin is applied to the fastener in powder form and then the fastener is heated sufficiently to melt the resin. 
     One disadvantage of the Preziosi patch-type threaded fasteners lies in the difficulty of obtaining close control over the thickness of the patch and, therefore, in a given production run of the fasteners, the patches vary widely in thickness. This fact may be verified by selecting a number of prior art patch bolts, the external screw threads of which are identical, within a narrow tolerance range of dimensions and screwing the bolts into nuts having internal screw threads that also lie in a narrow tolerance range of dimensions. With variations in the dimensions of the mating screw threads substantially climinated in this manner, variations in the breakaway torques through repeated cycles must be caused by variation in the thickness of the plastic patches, and it is found that the breakaway torques do vary over a wide range. 
     Both of the two prior art procedures for forming patches on fasteners require careful preparation of the metal surfaces of the fasteners to insure effective bonding of the plastic and, of course, such preparation steps increase the cost of production. In the Preziosi disclosure the metal is first cleaned by dipping in an acid solution and subsequently the fastener is preheated to drive off moisture. In the Villo disclosure, a bolt is given a preliminary alkali wash and if the bolt is to be cadmium plated after the patch is applied, the bolt must not only be treated with hot alkali but also must be pickled, rinsed, electro cleaned, rinsed again and finally dried before the patch is applied. Obviously these additional operations greatly increase the cost of the patch bolts, but the disclosure stress their importance in obtaining the necessary bond between the metal and the polymer patch. 
     Since both of the prior art disclosures require that the fastener be cleaned before the plastic material is applied, it would seem to be economical to degrease and/or otherwise clean large masses of the fastener in advance. Unfortunately, however, pre-cleaned fasteners are highly vulnerable to corrosion so that storing and handling the pre-cleaned fasteners in advance of applying the plastic patches results in deterioration of the metal surfaces to which the plastic is to be bonded. 
     Both of the above prior art patents disclose the patch material as extending from the root of the screw thread substantially beyond the crest, the crest being completely submerged. Thus the locking action is achieved by causing a mating complementary screw thread to penetrate relatively deeply into the patch to develop an extensive area of metal-to-plastic pressure contact to achieve adequate frictional resistance to loosening rotation between the two screw threads. Such drastic deformation of the plastic patch reduces the capability of the fastener for repeated use without excessive drop in the breakaway torque. The protruding patch can also interfere with the insertion of the bolt into a close clearance hole. 
     Duffy U.S. Pat. No. 3,498,352 discloses the application of a polyamide or polyester patch on a threaded fastener by first applying an adhesive to the area of the fastener over which the patch is to be formed. Thereafter, the fastener is heated and powdered plastic is spaced over the adhesive to form the desired patch. The primary disadvantage of this method is that is requires the use of an intermediate adhesive layer with its attendant higher cost and difficulty of application. 
     The preferred thermoplastics in the teachings of prior art patents are varieties of polyamide resins, with emphasis on Nylon 11 and Nylon 33, and in commercial practice these two resins are used almost exclusively. 
     Even those thermoplastic materials which have been utilized by the prior art in preparing patch-type fasteners tend to undergo some degree of crystallization during normal cooling from a molten state to room temperature and sustain a crystallization shrinkage of as high as 3 to 4 percent by volume. This crystallization shrinkage weakens the bond between the metal fastener and the patch material at the metal-to-plastic interface. This results in weakening of the bond between the plastic patch and the metal fastener which can result in premature failure of the fastener. 
     It would be desirable to improve the properties of patch-type fasteners of the prior art by providing a means to improve the bond between the plastic patch material and the metallic fastener element. Further, it would be desirable to provide a fastener in which the bond between the plastic patch material and the metallic fastener element and the properties of the patch material are improved by controlling the degree of crystallization that occurs in the patch material. 
     In addition, it would be desirable to provide both patch-type fasteners and a method for their manufacture in which the patch material is a crystallizable thermoplastic polymer having a higher shrinkage due to crystallization on cooling from a molten state to room temperature. Many of these thermoplastic polymeric materials have physical properties which are superior to those of thermoplastic materials used by the prior art in forming self-locking patch-type fasteners. However, they have been unsuitable for patch-type fasteners, prior to the present time, because of their crystallization and shrinkage on normal cooling. 
     SUMMARY OF THE INVENTION 
     This invention pertains to a self-locking patch-type fastener in which a patch of a crystallizable thermoplastic polymer is adherently bonded to the metal fastener element. 
     In carrying out the method of the present invention, a metal fastener element having a molten crystallizable thermoplastic polymer in contact therewith is cooled at a controlled rate from a temperature of about the melting point or higher of the polymeric material to the temperature below the glass transition temperature of the polymeric material. The cooling rate employed is sufficient to reduce crystallization of the polymeric material to a crystallization shrinkage of about 25 percent or less of the polymer&#39;s maximum crystallization volumetric shrinkage. The crystallizable thermoplastic polymeric material is preferably applied to the fastener in the form of a film. Most preferably, the polymeric material is a poly (alkylene) phthalate as exemplified by the material Mylar A, a Trademark of E. I. DuPont de Nemours Company. When the polymeric material is applied in the form of a film, it is preferably curved laterally to the peripheral curvature of the fastener and pressed against the fastener to cause the screw thread of the fastener to penetrate the film sufficiently to fix the position of the film relative to the fastener such that the material of the film melts and flows into the valleys of the screw thread of the fastener. The film may be either pressed against the upper side of the fastener while in a reclining position such that gravity promotes the spreading of the melted polymer circumferentially of the fastener or may be pressed against the under side of the fastener such that gravity opposes the tendency of the melted polymer to spread circumferentially of the fastener. In the latter case, the width of the polymeric locking element is narrowed and tends to increase in thickness along its longitudinal midline. 
     In applying work-shaping pressure against the flat ribbon of the polymeric material, the ribbon is preferably held relative to the threads of the fastener for a time sufficient to cause the heated crests of the threads engaging the ribbon to sever the ribbon into discrete segments. As a result of the severing of the ribbon into discreet segments, accurately predetermined quantities of the polymeric material are formed by the discreet segments which melt and flow into the valleys between adjacent crests of the threads. The polymeric material then bonds to adjacent flanks of the threads to form a unitary cohesive patch of solid material bonded to the threads of the fastener at the preselected locations thereof. The flat ribbon of the thermoplastic polymeric material will have a predetermined length and a width which is preferably less than 90° of the circumferential extent relative to the threads of the fastener. 
     The maximum volumetric shrinkage which occurs in crystallizable thermoplastic polymers due to the crystallization of a particular polymer are known values which are reported in literature. Thus, in describing the controlled degree of crystallinity of the polymeric patch material obtainable in accord with one aspect of our invention, reference is made to the degree of crystallization of the polymeric patch material in terms of a percentage of the maximum crystallization shrinkage for the polymer. Crystals form in a crystallizable thermoplastic polymer within the temperature range between the melting point of the polymer and the glass transition of the polymer. By controlling the cooling rate in accord with one aspect of the present invention, the polymer in cooling from the temperature of about its melting point to a temperature below its glass transition temperature is cooled at a rate sufficient to reduce the crystallization to a crystallization shrinkage of about 25 percent or less of the polymer&#39;s maximum crystallization shrinkage expressed in terms of volumetric shrinkage. The melting point of the crystallizable thermoplastic polymer, its glass transition temperature, and its crystallization shrinkage, expressed as a percentage of the maximum crystallization shrinkage of the polymer, can be readily determined by known test methods. Thus, the control of crystallization of the polymeric material is accurately and conveniently expressed in the present specification in terms of the crystallization shrinkage of the polymer as a percentage of the polymer&#39;s maximum crystallization shrinkage. 
     Preferably, the crystallizable thermoplastic polymer is applied to a heated metallic fastener element and the heat of the element is utilized in melting the thermoplastic polymer. By controlling the temperature of the heated fastener element and the time during which the polymer is permitted to flow due to the heat from the metallic element (termed the prequench time), the thickness of the polymer on the element and its degree of spreading relative to the peripheral surface of the element may be controlled. These factors have an effect upon the torque characteristics of the finished fastener and, thus, may be varied to control the characteristics of the fastener. 
     Many thermoplastic polymers are found to develop bubbles in various degrees when heated to a molten state. The presence of these bubbles may be controlled, to some extent, in the present process. For example, if the temperature of the polymer is increased, the buoyancy and exit rate of the bubbles will also be increased. Also, by extending the pre-quench time, more time can be permitted to allow escape of the bubbles. If desired, the bubbles can be retained within the polymer to give it a more cellular or spongy texture and an increased resiliency. 
     In accord with one aspect of the present invention, the characteristics of either a male or female threaded fastener having a polymeric patch thereon may be controlled by control of the characteristics of the patch material. By heating of the metallic fastener element prior to application thereof of the polymeric material, an adherent bond is obtained even-though the fastener element is not cleaned or degreased prior to heating. 
     In addition to providing novel methods, the present invention provides novel fasteners in which a crystallizable thermoplastic polymeric patch material is adherently bonded to the metal fastener element. The degree of crystallization of the polymeric patch material is controlled at a level about 25 percent or less of the maximum crystallization shrinkage of the polymer. Due to the reduced crystallization of the polymer, the bond between the patch material and the metallic fastener element is more adherent and the physical properties of the patch are improved in terms of the performance properties of the finished fastener. 
     A wide variety of crystallizable polymers may be employed as the patch material. In one aspect of the present invention, in which the degree of crystallization of the patch material is controlled through controlled cooling, the crystallization rate of the polymeric patch material is less than that of polyethylene. Polyethylene crystallizes quite rapidly so that it is very difficult to control the degree of crystallization of this material by control of its cooling rate from a molten state to a temperature below its glass transition temperature. 
     As an illustration of the crystallizable thermoplastic polymers that may be employed as the patch material in accord with the present invention, there are the poly(alkylene phthalates), including the poly(alkylene terephthalates) and poly(alkylene isophthalates). 
     Other thermoplastic polyester resins which may be employed as patch material include poly(alkylene alicyclic-alkylene phthalates); polyesters formed from the copolymerization of an aryl diol and an aliphatic dicarboxylic acid; polyesters formed from the copolymerization of diaryl diol and an aryl dicarboxylic acid, alkyl acyl polyesters, such as poly(glycollic ester). 
     Other exemplary classes include vinyl polymers and copolymers thereof such as poly(vinyl chloride), poly(vinylidene chloride), poly(vinyl fluoride) and poly(vinylidene fluoride); polypropylene and other polyolefins; ionomers, such as Surlyn-A (DuPont Trademark); acrylics such as poly(acrylonitrile) and its copolymers with vinyl chloride and vinylidene chloride; acrylic ester polymers such as poly(methyl methacrylate); poly(chlorotrifluoroethylene); poly(tetrafluoroethylene); polyamides, such as Nylon 66, Nylon 6, Nylon 610, Nylon 612, Nylon 11 and others; polycarbonates, such as those based on bisphenol A; poly (phenylene oxide); polysulfones, such as polyether sulfones, and acetal resins, such as Delrin 500, a DuPont Trademark. 
     To still further exemplify various representative polymeric materials which may be employed in the practice of the present invention, there are the poly(alkylene phthalates) having the general formula ##STR1## wherein x is an integer from 2 to 10, n is an integer of a magnitude sufficient to produce a molecular weight of at least about 10,000, and Ar is ##STR2## Such poly(alkylene phthalates) include the poly(alkylene terephthalates) and poly (alkylene isophthalates). These poly(alkylene phthalates) provide exceptional adhesion to the threaded fastener surfaces and produce a lower percent reduction in breakaway torque after, e.g., 15 cycles, than comparable polyamide and polycarbonate patches. Within this family, it is presently preferred to employ poly(ethylene terephthalate) because of its low cost and availability - particularly its availability in film form. 
     Other thermoplastic polyester resins which may be employed as the patch material include the following: poly (alkylene alicyclic-alkylene phthalates) having the general formula ##STR3## such as poly(1,4-cyclohexanedicarbinyl-terephthalate); polyesters formed from the copolymerization of an aryl diol and an aliphatic dicarboxylic acid and having the general formula ##STR4## such as poly(1,4-phenylene adipate); polyesters formed from the copolymerization of a diaryl diol and an aryl dicarboxylic acid and having the general formula ##STR5## such as poly 2,2-propane bis (4-phenyl-isophthalate-co-terephthalate) (50/50) ; alkyl acyl polyesters, such as poly(glycollic ester having the general formula ##STR6## and aryl acyl polyesters, such as poly(1,4-benzoic ester), having the general formula ##STR7## In Each of the foregoing general formulae x is an integer from 2 to 10, ##STR8## and lower alkyl- and halogen-substituted derivatives thereof, Al=alicyclic such as 1,4-cyclohexane, and A=CH 2 , C(CH 3 ) 2 , O or SO 2 . Also, n is an integer such that the molecular weight is at least 10,000. 
     Lower alkyl groups, as included in the above formulae may typically contain, for example, from 1 to about 6 carbon atoms while alicyclic groups, for example, may typically contain, from about 5 to about 12 carbon atoms. Aromatic groups, as exemplified by Ar in the above formulae, may typically contain from about 6 to about 18 carbon atoms. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     The features and advantages of the invention may be understood from the following detailed descriptions and the accompanying drawings. 
     In the drawings, which are to be regarded as merely illustrative: 
     FIG. 1 is a plan view of a highly heated metal screw fastener showing a plastic blank deposited thereon in preparation for the formation of a patch on the fastener; 
     FIG. 2 is a sectional view showing how the heated metal fastener with the plastic blank thereon shown in FIG. 1 is immobilized by clamping means that makes contact with the screw fastener at three circumferentially spaced points; 
     FIG. 3 is an enlarged section along the line 3--3 of FIG. 2 showing how the newly deposited plastic blank rests on the screw thread of the fastener before heat transfer from the screw thread to the plastic blank has had an opportunity to soften the material of the blank; 
     FIG. 4 is a sectional view similar to FIG. 2 showing how a pressure shoe is momentarily applied to the newly deposited plastic blank to form the plastic blank to the transverse curvature of the screw fastener and to cause the curved blank to be tacked to the fastener by slight penetration of the under side of the blank by the crests of the screw thread of the fastener; 
     FIG. 5 is a longitudinal sectional view of an enlarged scale along the line 5--5 of FIG. 4 showing the initial penetration of the plastic material by the crests of the screw thread which results from the momentary pressure applied to the plastic blank; 
     FIG. 6 is a fragmentary longitudinal sectional view similar to FIG. 5 with the pressure shoe withdrawn and showing the initial sagging of the plastic blank into the regions of the valleys of the screw thread; 
     FIG. 7 is a sectional view similar to FIG. 6 showing the end result of the melting and fusing period wherein the completely fused plastic material forms pools in the bottoms of the valleys of the screw thread; 
     FIG. 8 is a fragmentary sectional view illustrating the first step of a procedure for applying a plastic patch to the under side of a horizontally positioned screw-threaded fastener, the view showing how a plastic strip is initially deposited in a relatively cool cradle which is to serve as means for shaping the plastic strip to the curvature of the fastener; 
     FIG. 9 is a cross-sectional view similar to FIG. 8 showing a highly heated screw-threaded fastener initially positioned in the cradle on top of the plastic strip; 
     FIG. 10 is an enlarged cross section as taken along the line 10--10 of FIG. 9 showing the screw thread of the metal fastener resting on the plastic blank before sufficient heat transfer occurs from the fastener to the blank to appreciably melt the blank; 
     FIG. 11 is a similar cross-sectional view showing how a pressure shoe is momentarily applied to the reclining fastener to cause initial penetration of the plastic blank by the crests of the screw thread; 
     FIG. 12 is a longitudinal sectional view on an enlarged scale along the line 12--12 of FIG. 11 showing the initial penetration of the plastic material by the crests of the screw thread which results in the momentary pressure applied to the reclining fastener; 
     FIG. 13 is a cross-sectional view similar to FIG. 11 showing how the heated fastener sinks into the material of the plastic blank during the melting and fusing period that follows withdrawal of pressure from the fastener; and 
     FIG. 14 is an enlarged section along the line 14--14 of FIG. 13 showing how the completely melted plastic on the under side of the reclining fastener has climbed upward into the valleys of the screw thread on the under side of the fastener at the end of the melting and fusing period. 
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENT 
     The methods employed to apply the aforedescribed polymers to a threaded fastener will not be more specifically described. Firstly, with respect to the formation of a patch from crystallizable polymer resin, the threaded fastener is heated to a temperature sufficient to melt the polymer resin when the latter is applied to the fastener. However, the temperature of the threaded fastener is maintained below a temperature which would decompose or char the polymer resin when placed thereon. Preferably, the threaded fastener is heated to a temperature above the melting temperature of the polymer such that all of the polymer resin melts relatively rapidly to facilitate formation of a substantially uniform patch from end-to-end. As a general rule, the higher the temperature of the molten polymer, short of decomposition, the lower its viscosity and the more completely it will flow into the surface imperfections of the metal substrate to give maximum bond upon solidifying. 
     The application temperature determines the rate of melting and the rate at which the molten polymer flows into the threads and circumferentially on the fastener. In this respect, it is a factor in determining the self-locking torque characteristics that the finished patch will develop. The choice of temperature is governed, to some extent, by the mass of the fastener being produced; small fasteners cool more rapidly than large ones, so higher application temperatures can be used to insure that the polymer remains molten for the time required to attain the required extent of circumferential flow. 
     Usually, the threaded fastener is heated to a temperature about 100°-300° F. above the melting temperature of the polymer resin. Prior to heating the threaded fastener, it may be degreased with a suitable solvent such as carbon tetrachloride and/or it may be grit blasted using, e.g. powdered alumina. However, these steps are not necessary, although some enhancement may be obtained, since the temperature to which the fastener is heated (generally 700° F. to 850° F.) is generally sufficient to thermally degrease the threaded fastener. 
     After the threaded fastener is brought to the desired temperature, the thermoplastic polymer is applied to the fastener so that it extends longitudinally across a plurality of threads. This may be accomplished by applying the polymer in film, powder or even liquid form to the threaded fastener. If the polymer is applied in film form, as is presently preferred, it is so applied to the threads of a fastener with the aid of work-shaping pressure. The latter generally conforms the film to the curvature of the threaded fastener and applies some pressure to the film to force it into heat-transfer contact with the threads over substantially its entire length. The result of using work-shaping pressure is that the film is applied to the desired location on the fastener, is oriented in the desired direction, and melts substantially uniformly along its length without, for example, its edges curling inwards. 
     If the thermoplastic polymer is applied to the threaded fastener in powder or liquid form, suitable means may be employed to govern the flow of the polymer onto the fastener. For example, a metering device may be attached to an eye-dropper-like feeder tube having an exit end movable with respect to the fastener (e.g. by passing the fastener on a conveyor belt past the tube&#39;s end). The metering device can be governed to start and stop polymer powder or fluid moving through the feeder tube so that it is deposited in the desired amount and in the desired place on the threaded fastener. 
     The amount or thickness of the polymer material deposited on the threaded fastener is primarily a matter of choice, with the installation torque and breakaway torque generally increasing as the patch thickness increases. If the patch is too thick relative to the spacing available between male and female threaded members, the excess thickness is merely removed by the female member as the latter is threaded onto the male member. The remaining patch material continues to function effectively. In practice, the thickness of the patch will usually depend upon the size of the threaded fasteners and, particularly, upon the tolerances between male and female fasteners, as hereinafter explained. 
     As previously noted, it is preferred to employ the thermoplastic polymer in film form, because this provides excellent and convenient control over the geometry of the patch. Torque tests have demonstrated that the patch dimensions are highly repeatable using film as compared with using other forms such as powder. Use of the latter often results in substantially different thickness profiles across the width of the patch from one patch to another. 
     After the thermoplastic polymer material has been applied to the heated threaded fastener, it melts and flows into the valleys between the threads and is allowed to flow around the circumference of the fastener until it attains the width and the thickness required. At this point, it must be cooled below its melting point to preserve the requisite patch geometry. The period between application of the polymer to the heated fastener and the cooling or quenching step is hereinafter referred to as the prequench time. If necessary to obtain the desired geometry of patch, supplementary heating can be provided during the prequench time to insure that the polymer remains molten. 
     As will be more fully explained hereinafter, by choice of combination of application temperature, prequench time and size and thickness of polymer film used, and by practicing the process of the present invention, a given crystallizable polymer can be utilized to produce consistently any desired self-locking prevailing torque values from a designated range. The three variables can be regulated to compensate for each other, thereby accommodating useful changes that would facilitate the manufacture of self-locking threaded fasteners. As an example, a polymer film 1/4&#34;×1/2&#34;×0.014&#34; can be applied to a 154 &#34; SAE bolt to produce any level of breakaway torque desired between 20 and 150 inch-lbs by varying the temperature history; using a modified temperature history of application temperature and prequench time, a polymer film 1/8&#34;×1/2&#34;×0.028&#34; can be made to give torque values identical to those of the thinner film. Either film size can be made to give identical torque values on a loose fitting nut/bolt combination as on a close-fitting one. Within reasonable limits, one size of film can be made to produce the same torque for a large bolt as for a small. In addition to such versatility, the process makes possible close control and reproducibility in the manufacture of self-locking threaded fasteners by its economical simplicity and flexibility. 
     Heretofore, the length of prequench time has been pragmatically determined by the requirements for melting and consolidating the discrete particles of polymer powder, or to soften and press out a thick pellet. The application temperatures used are not usually much above the melt temperature of the polymer. The degree of crystallinity attained and therefore the torque characteristics imparted to the threaded fastener, are significantly effected by the rate of cooling. Failure to control the cooling rate results in variations in the quality of the finished patch. 
     By contrast, controlled cooling is made to serve several important functions in the process of this invention. Controlled cooling converts the amorphous, molten crystallizable polymer to a substantially amorphous solid; that is, it reduces the degree of crystallization that would cause shrinkage in the polymer and disruption or loss of polymer-metal bonding. Additionally, controlled cooling terminates the flow of molten polymer around the circumference of the fastener when the patch has attained the specified width and thickness. 
     In practicing the process of the present invention, a metallic fastener element having a crystallizable thermoplastic polymer in contact therewith is cooled at a controlled rate from a temperature of about the melting point or higher of the polymer to a temperature below the glass transition temperature of the polymer. The polymer is one which has a rate of crystallization less than that of polyethylene. Polyethylene has a rate of crystallization that is so rapid that its crystallization cannot be effectively controlled by control of its cooling rate from a molten state. Thus, the present invention does not include the use of polyethylene as a patch material. 
     During cooling of a thermoplastic crystallizable polymer from a molten to a solid state, there is a shrinkage of the polymer due to thermal contraction which may vary, depending on the particular polymer, from about 2 to about 5% by volume. Also, there is a shrinkage due to crystallization which is termed crystallization shrinkage. The process of the present invention does not alter the thermal contraction of the polymeric patch material or the thermal contraction of the metal fastener element. However, the process substantially reduces the degree of crystallization of the polymer which results in a substantial reduction in the crystallization shrinkage of the polymeric patch material. 
     While not bound by any theory, it is believed that during crystallization of a polymeric patch the polymer in forming a more ordered state of matter pulls away from the metal surface, thereby decreasing the strength of the polymer to metal bond. Also, the polymer generally becomes more brittle and undergoes crystallization shrinkage. 
     In defining the control of crystallization of the polymeric patch material obtainable by the present method, reference is made to the reduction of the crystallization shrinkage of the polymer in order to conveniently define the degree of crystallization of the polymer. However, this is not meant to imply that the mechanism by which the present process functions in controlling the properties of the patch material and the properties of the finished self-locking fastener involves merely a control of shrinkage. 
     Crystallization of a polymer occurs as the polymer cools through the temperature range from its melting point to its glass transition temperature. The values of maximum crystallization shrinkage for polymers are known values which are reported in the literature for the various crystallizable thermoplastic polymers. In accord with the present invention, the cooling rate employed is sufficient to reduce the crystallization of the polymer in cooling from its melting point to its glass transition temperature to a crystallization shrinkage of about 25% or less of the maximum crystallization shrinkage of the polymer expressed as a volumetric shrinkage. The volumetric shrinkage of the polymer may be determined by ASTM Procedure D-1505-68 entitled &#34;Density of Plastics by the Density Gradient Technique.&#34; To determine the crystallization shrinkage, the thermal contraction shrinkage is subtracted from the total volumetric shrinkage. The melting point of the thermoplastic polymer may be determined by ASTM Procedure D-2117-64 entitled &#34;Melting Point of Semicrystalline Polymers,&#34; and the glass transition temperature may be determined by ASTM Procedure D-696-70 entitled &#34;Coefficient of Linear Thermal Expansion of Plastics.&#34; In the latter procedure, the glass transition temperature is determined by observing the temperature at which the coefficient of linear thermal expansion increases sharply. 
     The rate of cooling of the hot fasteners and its polymer patch is controlled by the temperature of the cooling medium. Water is a convenient and economical medium for the range of 32° F. to 212° F. For very rapid cooling, as for fasteners of large mass and sensible heat, silicone oil cooled by dry ice can be used. 
     Controlled cooling, as described, produces crystallizable polymer patches which have excellent adherence to the fastener surface and are resilient so that they can be re-used and so that they seal with mating threaded surfaces. In contrast, if a controlled cooling step is not employed, the resulting patch adherence to the fastener is substantially reduced which may be sufficient to make the patch commercially unsuitable. 
     The herein-described crystallizable polymer patches may be used on cadmium-plated fasteners. However, to obtain commercially useful results, the cadmium must be plated on the fasteners after the patch is applied. That is, the patch is applied to a plain threaded fastener, e.g. of carbon steel, as described and, thereafter, cadmium is plated on the fastener by well-known techniques. 
     Referring now to the drawings and more specifically to FIGS. 1 to 7, a screw-threaded fastener, for example, a bolt 20 shown in FIG. 1 is heated as heretofore stated to a temperature above the melting point of the thermoplastic polymer and then a blank 22 of the polymer of a desired thickness and configuration is positioned longitudinally of the bolt on the threaded portion of the bolt. 
     Preferably the polymer is a poly(alkylene phthalate), e.g., &#34;Mylar A&#34;, a Trademark of DuPont, which melts at approximately 480° F. and the bolt is heated to a temperature that is substantially above 500° F. A preferred range is about 600° to about 850° F. The plastic material illustrated is in the form of a strip or tape that is 1/4&#34; wide and has a thickness of approximately 0.014&#34;. Referring to FIGS. 1 and 2 the plastic blank is an increment of the tape approximately 5/8&#34; long which is simply deposited on the screw thread of the heated fastener, the leading end of the blank being preferably spaced from the leading end of the screw thread of the bolt by at least 2 turns of the screw thread. FIG. 2 shows how the bolt 20 is initially immobilized by three clamp elements 24 which grip the bolt at three circumferentially spaced points. 
     In the brief time interval before the high temperature of the bolt has had time to appreciably affect the plastic material, the blank 22 simply rests on the crests of the screw as shown in FIGS. 2 and 3. Immediately after the blank is deposited on the screw thread of the fastener, however, a pressure shoe 25 under the pressure of suitable spring means 26(FIG. 4) makes momentary contact with the plastic blank 22 for the dual purpose of forming the blank transversely to the curvature of the bolt and of applying sufficient momentary pressure to &#34;tack&#34; the plastic blank to the bolt. The pressure of the shoe 25 against the blank is not sufficient to cause the crests of the screw threads to sever the blank into discrete sections but the applied pressure is sufficient to cause initial penetration of the crests of the screw thread (as shown in FIG. 5) because the highly heated crests melt the under side of the plastic blank locally along the region of each crest. The pressure of the pressure shoe 25 may have a duration of approximately 1 second. 
     It is characteristic of poly(alkylene) phthalate plastics that when the plastic is melted it adheres tenaciously to a highly heated metal surface. Thus when the pressure shoe 25 is retracted from the position shown in FIG. 5 the plastic blank is tacked to the bolt because of the adherence of the blank to the crests of the screw thread. It is important to note that the adherence is sufficient to keep the largely solid blank shaped to the curved cross-section of the bolt after the pressure shoe is retracted so that the transfer of heat from the bolt to the blank occurs effectively at the opposite longitudinal edges of the blank as well as along the longitudinal midline of the blank. 
     The prequench period begins with the initial penetration of the blank by the screw thread shown in FIG. 5 and continues after the retraction of the pressure shoe, until the plastic material of the blank is completely melted. Initially, as shown in FIG. 6, the softened blank sags into the regions of the valleys of the screw thread but when the plastic material is completely melted it forms pools 28 on the bottoms of the valleys of the screw thread as shown in FIG. 7 because of a surface tension phenomenon which causes the melted plastic to aggressively wet the metal of the fastener. 
     If the pressure shoe 25 is not applied to the blank 22 at the beginning of the prequench period, the newly deposited blank may tend to bow longitudinally so that the melting starts at the opposite ends of the blank. If the pressure shoe 25 is not used the blank does not immediately conform to the cross-sectional curvature of the bolt with the result that melting of the blank along its opposite longitudinal edges is delayed. With the pressure step omitted, the blank is not tacked to the heated bolt and may be free to squirm out of longitudinal alignment with the bolt and to curl away from the bolt. When the blank is not tacked to the bolt, the initial longitudinal bowing of the blank may cause uneven distribution of the melted plastic among the valleys of the screw thread, there being less melted plastic in the valleys near the opposite ends of the blank than in the valleys in the central region of the blank. 
     In the prequench period bubbles can be seen in the melted plastic and at least some of these bubbles as viewed under a microscope appear to be relatively large. At the end of the prequench period, however, the larger bubbles disappear but a relatively large number of small, less buoyant bubbles remain entrapped within the melted plastic. 
     The prequench period is terminated by controlled cooling of the heated fastener with the melted plastic thereon. In the preferred practice of the invention the controlled cooling is accomplished by quenching the heated fastener in water. 
     If the bolt is permitted to cool too slowly, the resultant patch is crystallized and will take on a murky or white color. The plastic is then relatively hard and brittle, and the bond between the plastic and the bolt is reduced in strength. In contrast, the controlled cooling of the plastic material results in a patch that is more clear with the patch having a desirable degree of resilience and adhering more tenaciously to the fastener. 
     In general, the duration of the prequench period varies inversely with the diameter of the screw fastener because the greater metal mass-to-surface ratio results in a slower heat loss rate in a given environment. The required duration of the prequench period also varies inversely with the temperature to which the fastener is initially heated. 
     The sensible, or stored, heat of the fastener depends on its mass the selected temperature to which it is heated prior to applying the polymer patch. From an initial temperature of 700° F., cooling in 70° F. air, a 1/8×1&#34; fastener will cool to 480° F. (the melting point of Mylar A) in approximately 50 seconds, a 5/8×1&#34; fastener will require 135 seconds and a 1/2×1&#34; fastener will require 200 seconds. A polymer film of 0.014&#34; thickness by 0.25&#34; width flows out to 0.4&#34; width in 30 seconds on a 3/8×1&#34; bolt, and in 25 seconds on a 1/2&#34; bolt, if both are heated to 700° F. Since the thread depth of the 1/2&#34; bolt is greater than for the 3/8&#34; volt, the torque levels obtained from the 1/2&#34; bolt would be lower than on the 3/8&#34; bolt for such identically sized patches. The torques would be substantially equal if the prequench time for the 1/2&#34; bolt were reduced to 18-20 seconds since this would result in a thicker, narrower patch. In any case, controlled cooling of the assembly results in the polymer being resilient and substantially amorphous (i.e., having a reduced degree of crystallinity). However, if the bolts are heated to only 600°-610° F., the times required for polymer flow to produce equal torque values will be increased, e.g. to 45 and 30 seconds respectively. In both such cases, but particularly for the 3/8&#34; bolt, the longer prequench times permits cooling in air to a lower temperature prior to quenching and the amount of crystallization is increased. 
     A screw fastener of small diameter may not store enough heat to melt and flow the plastic material as quickly as desired, and, in that event, heat may be applied during the prequench period to a small fastener to maintain the molten state of the polymer for the selected duration of the prequench period. 
     In a number of test runs, the Mylar A sheet material was employed in various thicknesses of approximately 0.005&#34;, 0.010&#34;, 0.015&#34; and 0.020&#34;, with the patches being applied to class 2A 1/4×16 bolts in the manner indicated in FIGS. 1-7. It was found that a blank of a thickness of 0.010&#34; results in sufficient plastic in the valleys of the screw thread to provide a desirable self-locking effect. 
     In all of the above tests the breakaway torque was higher than 7 inch-pounds on the 15th cycle. In one test run, Mylar blanks of approximately 0.010&#34; thickness were applied to the bolts that were cleaned in advance either by sandblasting or by dipping the bolts in a suitable degreasing agent such as carbon tetrachloride. The results were excellent but it was found that the results were also excellent if the bolts were taken from stock in the usual oily state and simply heated to the desired temperature without any pre-treatment. This was so, even when the heating step created an oxide coating on the metal surfaces. 
     A series of comparative tests to measure the effect on torque characteristics of varying the process parameters was conducted on 3/8×16 UNC2A×1&#34; hex head, SAE Grade 5 cap screws, plain finished, selected for uniformity of size. The test nuts employed were first burnished, then gauged to insure uniformity of thread diameter, case hardened by heat treatment, and re-gauged. 
     Mylar A tape of dimensions 3/4&#34; length disposed lengthwise on the fastener. 
     The following data was obtained from tests in which the bolts were preheated to 700° F., and the quenching medium was water at 70° F. The prequench times, at a 70° F. air temperature, were varied as indicated. The penetrometer hardness values are in units of 0.0001&#34; penetration and the test device was a modified Lab-Line Penetrometer. 
     
         __________________________________________________________________________
                Removal Cycles,                                           
Prequench Time,                                                           
         Installation                                                     
                breakaway torque, in-lbs                                  
                               Penetrometer                               
secs.    torque in-lbs.                                                   
                1  2 3 4 5 10                                             
                             15                                           
                               hardness                                   
__________________________________________________________________________
15       109    116                                                       
                   81                                                     
                     68                                                   
                       59                                                 
                         55                                               
                           35                                             
                             25                                           
                               34                                         
30       98     98 73                                                     
                     61                                                   
                       55                                                 
                         50                                               
                           30                                             
                             25                                           
                               32                                         
45       96     97 71                                                     
                     59                                                   
                       55                                                 
                         48                                               
                           30                                             
                             25                                           
                               20                                         
60       77     85 53                                                     
                     47                                                   
                       43                                                 
                         40                                               
                           33                                             
                             29                                           
                               17                                         
120      113    92 60                                                     
                     45                                                   
                       45                                                 
                         53                                               
                           32                                             
                             25                                           
                               14                                         
180      62     65 42                                                     
                     35                                                   
                       30                                                 
                         28                                               
                           25                                             
                             22                                           
                                4                                         
__________________________________________________________________________
 
    
     For the process conditions and bolt size employed in the above test, the Mylar A patch was found to begin crystallization after a prequench time of 135 seconds. Accordingly, the torque values for the 180 second prequench time show a marked drop at all cycles, indicating loss of durability. 
     The progression of melting of the Mylar A blank during the prequench periods in 70° F. air environment is from the polymer-metal interface toward the polymer-air interface, and for the conditions of the test it was found that approximately 50 seconds was required to obtain complete melting of the polymer at the air surface. When this &#34;skin&#34; finally melts, the rate of circumferential flow and spreading of the polymer increases sharply. As a result of the more rapid thinning of the patch, the installation and first five removal torques are seen to have decreased markedly when the prequench time exceeded 45 seconds. 
     Rapid hardening of the patch occurs as the prequench time approached the start of visible crystallization at 135 seconds. Accordingly, for the 120-second prequench time, the installation and first removal torque values were high, but the torque performance beyond the second removal did not maintain the relatively high level because of the increased brittleness and loss of durability from hardening. 
     In a second test series, the bolts were preheated to 850° F. for the application of the patch, and using the same 70° F. water quenching medium the following results were obtained. 
     
         ______________________________________                                    
                    Breakaway Torque, in-lbs.                             
Prequench                                                                 
        Installation                                                      
                    Removal Cycles                                        
Time, Secs.                                                               
        Torque, in.-lbs.                                                  
                    1      2    3    4   5   10  15                       
______________________________________                                    
 5      75          85     55   45   45  45  25  25                       
10      55          75     45   40   40  40  25  20                       
15      70          85     45   40   40  35  25  20                       
60      125         120    100  85   70  60  50  35                       
120     140         150    105  100  50  45  25  25                       
145     100         100    80   75   60  55  50  30                       
180     60          60     45   40   45  40  20  20                       
______________________________________                                    
 
    
     At the higher temperature of 850° F., the polymer blanks reached the molten state much more quickly than with a bolt temperature of 700° F. Consequently, the torque levels begin to decrease normally, since the patch thickness diminishes as the prequench time is increased. The onset of visible crystallization, in this case was about 140 seconds and produced the highest torque levels. However, as visible crystallization proceeds, the torque performance of the brittle patch declines sharply, as is characteristic of the crystallizable polymers. 
     To complete the comparison, a third test series was made wherein the bolts were heated to only 600° F. The following table shows the results. 
     
         ______________________________________                                    
                    Breakaway Torque, in-lbs.                             
Prequench                                                                 
        Installation                                                      
                    Removal Cycles                                        
Time, Secs.                                                               
        Torque, in-lbs.                                                   
                    1      2    3   4    5   10  15                       
______________________________________                                    
15      130         160    120  95  85   75  60  45                       
30      150         150    115  95  85   70  60  45                       
45      155         150    120  95  85   75  65  50                       
120      90         110     65  60  55   50  40  35                       
______________________________________                                    
 
    
     For the 600° F. application temperature, the beginning of visible crystallization was at about 50-55 seconds after the blank was applied, and the previously discussed loss of torque, due to crystalline brittleness, was very evident at 120 seconds. Because of the slower melting and flowing rate at 600° F., compared to that of the higher application temperatures, the patches are thicker and the prevailing torque levels are higher for equal prequench times. 
     Nylon 66 (a Trademark of DuPont) blanks of dimensions 3/4&#34;×1/4&#34;×0.020&#34; were also tested using the same 3/8&#34;-16UNC2A×1&#34; hex head SAE Grade 5 cap screws. The application temperature was 800° F., and because of the greater thickness of blank, the bolts were maintained in an environment of 600° F. heated air during the prequench period. Both 70° F. and 32° F. quenching water bath, and 70° F. and 250° F. air cooling were used in the test series, producing the following data. 
     
         __________________________________________________________________________
Prequench              Breakaway Torque, in-lbs.                          
Time, Secs.                                                               
      Quench Medium                                                       
               Installation                                               
                       Removal Cycles                                     
at 600° F.                                                         
      (Temperature °F.)                                            
               Torque, in-lbs.                                            
                       1  2  3  4  5  10                                  
                                        15                                
__________________________________________________________________________
20     70° water                                                   
               225     200                                                
                          150                                             
                             100                                          
                                80 75 65                                  
                                        50                                
20     70° air                                                     
               155     180                                                
                          150                                             
                             85 75 70 55                                  
                                        40                                
20    250° air                                                     
               210     175                                                
                          150                                             
                             85 70 65 50                                  
                                        35                                
60     70° water                                                   
               175     175                                                
                          110                                             
                             95 75 75 65                                  
                                        50                                
60     32° water                                                   
               175     180                                                
                          150                                             
                             125                                          
                                120                                       
                                   100                                    
                                      80                                  
                                        75                                
__________________________________________________________________________
 
    
     The greater thickness of Nylon 66 blank used, compared to that of the Mylar A tested results in much higher torque levels, as would be expected. The Nylon 66 does not tend to crystallize as much as Mylar A. However, the advantage of reducing crystallization can be seen in the improved durability, or torque retention, obtained when ice water was used for maximum cooling rate in the above test. 
     Hardness measurements were made on patches of several crystallizable polymers that had been applied to various application temperatures, prequench times and quenching rates. A Lab-Line Penetrometer was modified to apply the higher-than-normal needle loading required for plastics, compared to asphalts. The readings are in increments of 0.0001&#34; units, and are intended only to indicate relative hardness and the changes caused by the thermal history given the crystallizable polymers. 
     
         ______________________________________                                    
          Application               Penetro-                              
Polymer   Temperature °F.                                          
                       Thermal History                                    
                                    meter                                 
______________________________________                                    
66 Nylon               As received  15                                    
          800          70° water quench                            
                                    18                                    
          550          70° air cool                                
                                     2                                    
          550          70° water quench                            
                                     8                                    
Polypropylene          As received  75                                    
(Pro-Fax,.a                                                               
Trademark 450          70° water quench                            
                                    75                                    
of Hercules)                                                              
          450          70° air quench                              
                                    25-50                                 
          450          32° water quench                            
                                    148                                   
Mylar A                As received  20                                    
          800          70° water quench                            
                                    26                                    
          700          70° water quench                            
                                    33                                    
          600          70° water quench                            
                                    20                                    
          6-800        70° air cool                                
                                    2-6                                   
______________________________________                                    
 
    
     The lower penetrometer values in the above data are indicative of increased crystallization and hardness. 
     Hardness test covering a wide range of thermal treatments were conducted on Mylar A material as shown in the following table. 
     
         __________________________________________________________________________
Application                                                               
         Prequench                                                        
               Prequench                                                  
                     Quench     Penetrometer                              
Temperature °F.                                                    
         Time, secs.                                                      
               Temp °F.                                            
                     Temp. 1F                                             
                           Medium                                         
                                0.0001&#34;                                   
__________________________________________________________________________
Mylar, as received, no temperature history                                
                                20                                        
850      15    525   32    water                                          
                                24                                        
850      70° air cooled   2                                        
700      15    70    70    water                                          
                                34                                        
700      30    70    70    water                                          
                                32                                        
700      45    70    70    water                                          
                                20                                        
700      60    70    70    water                                          
                                17                                        
700      120   70    70    water                                          
                                14                                        
700      180   70    70    water                                          
                                 4                                        
700      70° air coolcd   4                                        
600      15    70    70    water                                          
                                20                                        
550      15    550   32    water                                          
                                25                                        
550      45    70    32    water                                          
                                 8                                        
550      70° air coo-ed   6                                        
__________________________________________________________________________
 
    
     It can be seen from the hardness test data that the thermal history given a crystallizable polymer can be utilized to vary and control the mechanical properties of the polymer, specifically to make it significantly harder or softer than it is in virgin state. Thus for a patch of given dimensions, the self-locking torque levels attained by the threaded fastener can be varied by altering the hardness of the polymer. 
     An alternate procedure for forming a plastic patch on a metal screw fastener is illustrated by FIGS. 8-14. To carry out this procedure a pressure shoe employed to form the plastic strip to the curved configuration of the screw fastener is a metal cradle 30 having a longitudinal cavity 32 that conforms to the cross-sectional curvature of the lower half of the horizontal screw fastener. 
     The first step is to deposited a plastic blank 34 in the bottom of the cavity 32 as indicated in FIG. 8 with the cradle at a temperature below the melting point of the plastic. The next step which is illustrated in FIG. 9 is to drop the heated screw fastener 35 into the cavity 32 onto the plastic blank 34. As shown in FIG. 10, the screw fastener initially rests on the plastic blank without appreciable penetration. Immediately, however, as the screw fastener 35 is placed under pressure of a momentary duration, such as one second, the plastic blank is tacked to the screw fastener by the crests of the screw thread of the fastener melting the plastic material and penetrating the plastic material to a degree such as indicated in FIG. 12. 
     As shown in FIG. 11 the momentary pressure may be provided by a pressure member 36 which advances downward against the upper side of the reclining screw fastener under pressure provided by spring means 38. Since the plastic blank is largely solid, the heated fastener 35 is spaced from the bottom of the cavity 32 by the plastic blank 34 as may be seen in FIGS. 11 and 12. In the course of the ensuing prequench period the plastic blank is completely melted to permit the screw fastener 35 to sink to the bottom of the cavity 32 as indicated in FIG. 13. 
     Here again the completely melted plastic seeks the valleys of the screw thread by a surface tension phenomenom and FIG. 14 shows hot the melted plastic forms pools 38 in the inverted valleys of the screw thread. It can be seen that FIG. 14 is substantially FIG. 7 turned upside down. 
     For a given bolt temperature and prequench time, there is a slight difference between the circumferential cross-sectional configuration of a patch produced by the first procedure illustrated by FIGS. 1-7 and the circumferential cross-sectional configuration of a patch produced by the second procedure illustrated by FIGS. 1-14. In the first procedure, gravity promotes the tendency of the melted plastic to spread circumferentially by surface tension whereas in the second procedure gravity opposes the circumferential spreading of the melted plastic. Thus a patch produced by the second procedure tends to be slightly narrower than a patch produced by the first procedure and its longitudinal edges tend to be tapered to lesser degree. In addition a patch produced by the second procedure may be slightly thicker along the longitudinal midline of the patch. For some installations the configuration produced by the second procedure is especially desirable for sealing action. 
     A feature of the invention is that the circumferential cross-sectional configuration of the patch may be controlled between the two extremes of the first and second procedures by simply rotating the bolt 180° in the cradle cavity 32 at a selected time in the prequench period. Thus, gravity opposes the tendency of the melted plastic to spread circumferentially by surface tension during the first part of the prequench period and gravity enforces the tendency of the melted plastic to spread circumferentially during the latter part of the prequench period. 
     It has been found that both applying a crystallizable thermoplastic polymer, e.g., a poly(alkylene phthalate), to a screw fastener and by incorporating a metal powder, e.g., aluminum, into the patch, excellent results were obtained due, perhaps to a certain amount of metal-to-metal contact. The resulting breakaway torque was increased and survived fifteen cycles of reuse. The amount of the aluminum powder may be about 5 to 40 percent by weight of the resin and best results were obtained in the range of about 15-20 percent by weight. Any suitable metal in finely divided form may be incorporated in a plastic patch but preferably a relatively soft metal such as aluminum or copper or a metal of intermediate hardness is employed. 
     In the production of a patch of a thermoplastic polymer, e.g., a poly(alkylene phthalate), the metal powder is incorporated into the polymer before it is fabricated into a sheet or strip form. As described, when metal particles are present in the thermoplastic patch material, the hardness of the metal particles is sufficient to provide increased bond strength between the patch material and the fastener. Also, the content of the metal particles is controlled such that they are present in an amount sufficient to increase the bond strength between the polymer and the fastener. 
     In determining whether a polymeric patch on a self-locking fastener has a substantially reduced crystallinity, as produced by the present invention, the patch may first be observed by X-ray diffraction or any other equivalent means to determine whether the patch material is substantially amorphous, e.g., having a reduced crystallinity. Following the initial determination that the material is substantially amorphous, the patch material may be stripped from the fastener and its density and volume may be measured. Then, by determining the chemical composition of the polymeric patch material, the maximum crystallization shrinkage and the thermal contraction shrinkage of the polymeric material may be determined. From this information, the degree of crystallization of the patch material expressed in terms of the volumetric crystallization shrinkage may be determined. To the extent that the maximum shrinkage contraction of the polymer has been altered by the polymer manufacturer through the inclusion of additive ingredients such as fillers or plasticizers, the thermal contraction shrinkage and the crystallization shrinkage of the polymer may be determined experimentally by controlled cooling of a polymer sample or samples from the melting point through the glass transition temperature of the polymer. 
     In a preferred form of the invention, the polymeric thermoplastic patch material has a crystallization rate which is higher than that of a polycarbonate polymer. Polycarbonates, although suitable in the present invention, have a relatively slow rate of crystallization and do not require as rapid a cooling rate to achieve the desired reduction in the degree of crystallization of the polymeric patch material.