Process for preparing anisotropic oleum dopes of polyamides by polymerizing in sulfur trioxide
BACKGROUND OF THE INVENTION 
     A. Field of the Invention 
     This invention relates to a novel process for preparing anisotropic oleum dopes of aromatic polyamides from which useful films, fibers and/or coatings may be shaped. 
     B. Description of the Prior Art 
     Anisotropic oleum dopes of aromatic polyamides, a process for preparing the same and the spinning thereof into fibers are described in the prior art, for example, in U.S. Pat. Nos. 3,671,542; 3,767,756; 3,801,528; 3,804,791; 3,819,587, 3,827,998; 3,836,498; 3,869,419; 3,869,429; and 3,969,420. According to the prior art process a diamine and diacid chloride are first reacted in a suitable organic solvent (e.g. a 2 to 1 mixture of hexamethylphosphoramide and N-methyl-2-pyrrolidone) at a low temperature (below 60° C.) with stirring until a crumb-like solid consisting of polymer and solvent is obtained. The crumb is then thoroughly washed with water to remove the solvent therefrom and dried. Finally, appropriate amounts of the resulting dried polymer and oleum are combined with vigorous stirring until an anisotropic oleum dope is obtained. This process has several disadvantages. In the first place, the process requires the time consuming and expensive step of transferring the polyamide from one solvent to another. Also, the process requires the use of relatively expensive diacid chlorides. 
     It is an object of the present invention to provide a simpler, more economical and less time consuming process for preparing anisotropic oleum dopes of aromatic polyamides. 
     Other objects and advantages of the invention will become apparent from the following detailed description thereof. 
     SUMMARY OF THE INVENTION 
     This invention provides a novel process for preparing anisotropic oleum dopes of aromatic polyamides from relatively inexpensive and commercially available materials. The process comprises reacting substantially equimolar amounts of at least one diamine monomer selected from the group consisting of diamines of the formulas ##STR1## with at least one non-diamine monomer of the formula 
     
         Z--Ar.sub.2 --Z                                            (III) 
    
     in sulfur trioxide (SO 3 ) initially containing (i.e. before contact of the monomers therewith) from 0 to 20% by weight sulfuric acid (H 2  SO 4 ) for a period of time sufficient to obtain in solution a polyamide having an inherent viscosity of at least 0.1 (as measured in the manner hereinafter described), wherein n is 1, 2, 3 or 4 and Ar 1  and Ar 2  are each a radical selected from the group consisting of ##STR2## where &#34;a&#34; is a hydrogen, bromine, fluorine or chlorine atom, Z is --COOH or --CX 3  where X is a bromine or chlorine atom. Monomers in which each &#34;a&#34; is hydrogen are referred to herein as unsubstituted monomers while those in which at least one &#34;a&#34; is a halogen atom are referred to herein as substituted monomers. Sufficient amounts of the monomers are used to provide a dope having a polymer (solids) concentration above its critical concentration point. &#34;Critical concentration point&#34; is defined in the prior art (e.g. U.S. Pat. No. 3,671,542) to be that polymer concentration below which the dope is isotropic and above which the dope is anisotropic. As hereinafter described, dopes prepared by the process of this invention may comprise either a sulfonated or unsulfonated polyamide in oleum. 
     Preferably, the process is carried out by dissolving the monomers in pure (i.e. 100%) SO 3  under anhydrous conditions at a temperature below which polymerization thereof occurs to form a monomer solution, then, raising the temperature of the monomer solution until polymerization of the monomers occurs at a reasonable (or desired) rate and, finally, continuing polymerization under anhydrous conditions for a period of time sufficient to obtain polymer having an inherent viscosity of at least 0.1 (film-forming polymer) and, preferably, at least 0.4 (fiber-forming polymer). The resulting anisotropic oleum dope may be used in a conventional manner to provide films, coatings or fibers. Fibers, for example, may be shaped therefrom by wet or dry-jet wet spinning techniques. Preferably, the monomer solution is formed by first dissolving a sufficient amount of the non-diamine monomer(s) in SO 3  to provide a single phase and then dissolving the diamine monomer(s) in the resulting single phase. 
     The process of this invention offers several important advantages over the above-described prior art process. One advantage is that dicarboxylic acids may be used rather than the more expensive diacid chlorides. Another advantage is that SO 3  serves both as a polymerization and dope solvent thereby eliminating the need for two solvents and the associated processing steps required in transferring the polyamide from one solvent to another. Yet another advantage is that SO 3  is relatively inexpensive, readily available and may be recovered and reused. 
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     The process of this invention comprises polymerizing at least one diamine monomer with at least one non-diamine monomer in sulfur trioxide (SO 3 ) initially containing from 0% (100% SO 3 ) to 20% (80% SO 3  or 80% oleum) by weight sulfuric acid. As the initial sulfuric acid concentration of the polymerization solvent increases from 0%, the molecular weight of the polymer prepared therein decreases. In general, as the initial sulfuric acid concentration of the polymerization solvent increases from about 20% by weight anisotropic dopes are increasingly difficult to obtain due to the low molecular weight of the polymer prepared therein and eventually are no longer obtainable. Preferably, the process is carried out using SO 3  having an initial sulfuric acid concentration of zero (i.e. pure SO 3 ) as the polymerization solvent. Since SO 3  is hygroscopic, the process is preferably carried out under anhydrous conditions. Water formed during polymerization of the monomers is taken up by the SO 3 , that is, reacts with SO 3  to form sulfuric acid. Therefore, as the polymerization proceeds, the sulfuric acid concentration of the resulting solution increases and the SO 3  or oleum concentration thereof decreases. Generally, anisotropic dopes prepared by the process of this invention wherein pure of 100% SO 3  is used as polymerization solvent have an oleum concentration in the range of from 60 to 70%. 
     From the standpoint of commercially availability and cost, preferred diamines for use in carrying out the process of this invention are p-phenylenediamine sulfate (PPD-S) and substituted p-phenylenediamines, such as: 2-chloro-p-phenylenediamine sulfate (2-chloro-PPD-S); 2,5- or 2,6-dichloro-p-phenylenediamine sulfate (2,6-dichloro-PPD-S); and 2,3,5,6-tetrafluoro-p-phenylenediamine (tetrafluoro-PPD) and the sulfate thereof (tetrafluoro-PPD-S). For the same reasons preferred non-diamine monomers are terephthalic acid (TA) and 1,4-bis(trichloromethyl)benzene (BTMB). PPD-S and TA is particularly preferred combination of monomers. 
     Polymerization of unsubstituted monomers in SO 3  under conditions (hereinafter described) which yield polyamides of maximum molecular weight also yields sulfonated polyamides, for example: the polymerization of TA and PPD-S in SO 3  yields poly(p-phenylene terephthalamide) containing on the average two sulfonate groups per polymer repeat unit, the sulfonate groups being attached on the diamine ring in the 2,5- or 2,6-position. However, as shown hereinafter in Example 5, sulfonation of the polyamide can be effectively reduced or eliminated by using as monomers TA (or BTMB) and a substituted diamine monomer. When the process is carried out using instead of TA or BTMB another unsubstituted non-diamine monomer, then the non-diamine moiety of the resulting polyamide is sulfonated. However, sulfonation of the non-diamine moiety can also be reduced or eliminated by using substituted non-diamine monomers. 
     According to one embodiment of the invention, the process is carried out by replacing up to about 30 mole % of the Formula (I) monomer(s) (e.g. PPD-S) with hydrazine sulfate (Hy-S). Generally, Hy-S is used in a slight molar excess (e.g. up to 5 mole %) of the stoichiometric amount required to react with the Formula (II) monomer(s). Dopes prepared according to this embodiment of the invention contain polymers consisting essentially of recurring units of the formulas: ##STR3## wherein at least 70 mole % of the units are (a) units. 
     It is also contemplated that small amounts (up to 5 mole %) of one or more of the monomers may be replaced with an equivalent molar amount of another functionally similar (e. (e.g. diacid) aromatic polyamide-forming monomer such as metaphenylenediamine or isophthalic acid so long as the anisotropy of dopes is retained. 
     Preferably, the SO 3  is cooled during dissolution of the monomers to minimize or avoid any degradation thereof. (Dissolution of each monomer in SO 3  is exothermic). Preferably, the non-diamine monomer (e.g. TA) is first incrementally dissolved in chilled SO 3  and then the diamine monomer (e.g. PPD-S) is added incrementally thereto and dissolved while maintaining the temperature of the SO 3  below that at which significant polymerization of the monomers occurs. Then, the resulting monomer solution is heated to effect polymerization. (TA and PPD-S polymerize in SO 3  at temperature of about 80° C. or higher.) In dissolving the non-diamine monomer in SO 3  two distinct immiscible phases or layers are initially present, an upper phase consisting essentially of SO 3  and a lower phase consisting essentially of a monomer-SO 3  complex. As the concentration of monomer (e.g. TA) increases, the size of the upper phase diminishes while that of the lower phase increases until only the complex phase is present. Preferably, sufficient non-diamine monomer is incrementally added to chilled (e.g. 5° C.) SO 3  with stirring to provide a single phase (i.e. only the complex). There are several important advantages in providing a single phase. In the first place, SO 3  boils at a temperature (44.6° C.) below that t which the monomers polymerize in SO 3  (e.g. TA and PPD-S do not polymerize in SO 3  at temperatures below 80° C. at atmospheric pressure). Thus, if a two-phase system were used, it would not be possible to effectively polymerize the monomers in SO 3  without pressurizing the system to prevent SO 3  from boiling. Secondly, the diamine monomer is less susceptible to degradation when dissolved in the complex rather than in SO 3 . Thirdly, the higher monomer concentration required to form the single-phase system gives rise to dopes of higher solids concentration which translates to lower capital and manufacturing costs. Generally, when a single-phase is present, R (moles SO 3  /moles non-diamine monomer) will be equal to or greater than 8.5 and equal to or less than 13.5 (i.e. 8.5&gt;R&lt;13.5). After dissolution of the non-diamine monomer, an equivalent molar amount of diamine monomer is then incrementally added to the chilled complex with stirring until a homogeneous monomer solution is obtained. The temperature of the monomer solution is then raised to effect polymerization. 
     When TA and PPD-S are used as monomers in practicing the process of this invention, polymer of the highest molecular weight is obtained by using the following conditions: 
     (1) 100% SO 3  as solvent 
     (2) equimolar amounts of TA and PPD-S 
     (3) sufficient amounts of TA to provide an R value (moles SO 3  /moles TA) of about 11 
     (4) a polymerization temperature of about 100° C. and 
     (5) reaction time of about 8 hours. 
     With regard to (1), all other conditions being held the same, the concentration of the SO 3  solvent used in producing the dopes is directly proportional to the molecular weight of the resulting polymer, that is, the higher the concentration of the SO 3 , the higher the molecular weight of the polymer produced therein. 
     With regard to (2), if an excess amount of either monomer is used, polymer of lower molecular weight is produced although excess PPD-S (0.5 to 10 mole %) has less effect on molecular weight than a corresponding excess of TA. 
     With regard to (3) and (4), if the R value is increased or reduced from a value of about 11 or the reaction temperature is raised or lowered from about 100° C., polymer of lower molecular weight is produced. 
     With regard to (5), while the inherent viscosity of the polymer does not significantly change as the polymerization time is increased, sulfonation of the polymer continues with time. 
     The above conditions also produce polymer of highest molecular weight when all or a portion of the TA is replaced with an equivalent molar amount of BTMB or when PPD-S is replaced with an equivalent molar amount of a substituted p-phenylenediamine, such as tetrafluoro-PPD-S. When monomers having a biphenyl or naphthylene radical are used, slightly different conditions may be needed to produce polymer of maximum molecular weight. However, such conditions can easily be determined. 
     Dopes prepared by the process of this invention may be spun into fiber in a conventional manner. Dopes comprising sulfonated polyamides are preferably heated to a temperature between about 70° C. and 100° C. and extruded into aqueous sulfuric acid which preferably has a concentration between about 10% and about 50%. When the dope is held at temperatures above about 100° C. for a period of time, the sulfonated polyamide tends to slowly lose molecular weight. Preferably, the dopes are diluted at 30° C. to about 20% solids with oleum having an SO 3  concentration between 0 and 20%. The diluted dopes retain their anisotropic characteristics. 
    
    
     The following examples are given for purposes of further illustrating the invention. In the examples inherent viscosity (η inh ) values are measured by dilution at 25° C. of a portion of the dope with 96% H 2  SO 4  to a given polymer concentration. Unless otherwise specified, inherent viscosities are determined herein using a polymer concentration of 0.84 g/dl of solvent. 
     EXAMPLE 1 
     This example illustrates the solubility of TA in 100% SO 3  as a function of TA concentration. For purposes of investigating the solubility of TA in SO 3 , the effect of incrementally dissolving TA in 100% SO 3  was studied. At certain concentrations, two clear, immiscible phases were observed, a lower phase and a less dense upper phase. Separation of both layers followed by ice quenching demonstrated that the less dense upper layer was pure (100%) SO 3 . The TA was contained quantitatively in the lower layer. TA precipitated upon aqueous dilution over ice. When the concentration of TA was increased the relative volume of the lower layer became larger until at a concentration of R (moles SO 3  /moles TA) less than 13 only one homogeneous layer was observed. By varying R from 63 to 7, it was observed that: 
     (1) at R≧7.6, TA was soluble in SO 3  at about 45° C. 
     (2) at R≧8.7, TA was soluble in SO 3  at 24° C. 
     (3) at 8.7≦R&lt;13, only one layer was present 
     (4) at R&gt;13, two immiscible layers were present 
     The results of the investigation are given in Table I. 
     
                                           TABLE I                                 
__________________________________________________________________________
TA-SO.sub.3 COMPLEX FORMATION AS A FUNCTION                               
OF RELATIVE CONCENTRATION.sup.a                                           
           Upper                                                          
                Lower Mass  SO.sub.3 in                                   
                                   R        TA in                         
REAGENTS   Layer                                                          
                Layer Balance                                             
                            Lower  (Mole SO.sub.3 /TA                     
                                            Separated                     
TA     SO.sub.3                                                           
           Weight.sup.b                                                   
                Weight.sup.b                                              
                      [Handling                                           
                            Layer.sup.d                                   
                                   in Lower Layer (g).sup.e               
(g)                                                                       
   (mole)                                                                 
       (g) (g SO.sub.3)                                                   
                (TA-SO.sub.3                                              
                      Loss (g)].sup.c                                     
                            (g)                                           
                               (mole)                                     
                                   Layer)   (Upper)                       
                                                 (Lower)                  
__________________________________________________________________________
1.00                                                                      
   .006                                                                   
       32.18                                                              
           23.97                                                          
                7.07  -2.14 6.07                                          
                               .076                                       
                                   12.64    0.00                          
2.00                                                                      
   .012                                                                   
       29.03                                                              
           15.17                                                          
                13.75 -2.11 11.75                                         
                               .147                                       
                                   12.23                                  
3.00                                                                      
   .018                                                                   
       31.68                                                              
           11.66                                                          
                21.21 -1.81 18.21                                         
                               .227                                       
                                   12.60    0.05 2.85                     
3.00                                                                      
   .018                                                                   
       31.81                                                              
           11.22                                                          
                21.40 -2.19 18.40                                         
                               .230                                       
                                   12.80                                  
4.00                                                                      
   .024                                                                   
       30.34                                                              
           2.98 28.67 -2.69 24.67                                         
                               .308                                       
                                   12.80    0.01 3.91                     
5.00                                                                      
   .030                                                                   
       30.86.sup.f                                                        
           0    34.21 -1.65 29.21                                         
                               .365                                       
                                   12.12                                  
6.00                                                                      
   .036                                                                   
       32.18                                                              
           0    36.46 -1.72 30.46                                         
                               380 10.54                                  
7.00                                                                      
   .042                                                                   
       31.09                                                              
           0    36.21 -1.88 29.21                                         
                               .365                                       
                                   8.69                                   
8.00.sup. g                                                               
   .048                                                                   
       31.29                                                              
           0    37.28 -2.01 29.28                                         
                               .366                                       
                                   7.60                                   
9.00.sup.h                                                                
   .054                                                                   
       32.24                                                              
           0                       ˜7                               
__________________________________________________________________________
 .sup.a All samples heated to 45° C. while stirring, then cooled to
 23° C. before layer separation.                                   
 .sup.b Separated with separatory funnel,                                 
 .sup.c Mass balance = Weight (SO.sub.3 + TA) - weight of separated layers
 quantitative transfer was precluded because of affinity of SO.sub.3 for  
 glass walls of separatory funnel.                                        
 .sup.d SO.sub.3 in lower layer = weight of lower layer - total weight of 
 TA.                                                                      
 .sup.e Upper and lower layers coagulated independently over ice.         
 Appearance of TA in upper layer only because lower layer globules adherin
 to wall of separatory funnel washed down with upper layer.               
 .sup.f Transfer of SO.sub.3 from weighing vessel to separatory funnel    
 yielded 0.18g SO.sub.3 &#34;loss&#34;.                                           
 .sup.g TA soluble in SO.sub.3 at 45° C., but precipitate observed 
 at 23° C.                                                         
 .sup.h TA insoluble in SO.sub.3 at 45° C.                         
 
    
     EXAMPLE 2 
     This example illustrates the preparation of an oleum anisotropic dope of poly(disulfonated-p-phenylene terephthalamide). 
     A four-liter resin kettle was equipped with two Friedrich condensers protected from atmospheric moisture by calcium sulfate-filled drying tubes and a motor-driven, 316 stainless steel, double-helix stirrer. After 3,628 g (45.315 moles) of SO 3  had been added, the kettle was placed in a chilled bath (5° C.) for 0.5 hour. Then 700.00 g (4.213 moles) of TA was added incrementally with stirring over one hour. After the cooling bath was removed, stirring was continued at ambient temperature for one hour, then at 50° C. for an additional hour to effect solution. After the oily, amber liquid was cooled to 5° C., PPD-S was added carefully with stirring in 25 g increments over three hours until ˜600 g of the total 868.91 g (4.213 moles) had been added. At this point, the stirrer began to stall. The kettle was allowed to warm to ambient temperature overnight. After the kettle was placed in an oil bath at 60° C. and after stirring could be reinitiated, the remaining PPD-S was added. After a homogeneous monomer solution had formed, the temperature was raised to 100° C. Viscosity of the clear isotropic dope increased for 4 hours, at which time the dope began to exhibit brilliant shear opalescence as yellow streaks near the kettle wall. The opalescence proceeded inwardly toward the stirrer shaft until, within five minutes, the anisotropic brilliance permeated the entire solution. As the transformation progressed, SO 3  ceased to reflux from the condensers. Heating was terminated after 11 hours. The inherent viscosity profile appeared as follows: 
     
         ______________________________________                                    
Time (Hr)        .sup.η inh                                           
______________________________________                                    
5                .75                                                      
7                1.55                                                     
9                1.47                                                     
11               1.41                                                     
______________________________________                                    
 
    
     EXAMPLE 3 
     This example illustrates the effect of monomer concentration on the molecular weight of the resulting polyamide. 
     Following the procedure of Example 2 several anisotropic dopes (five) were prepared using a polymerization temperature of 100° C. wherein the monomer concentration was varied from dope to dope in the manner shown in Table II. The initial amounts of monomers and SO 3 , polymer solids and η inh  were determined and are also given in Table II. 
     
                       TABLE II                                                    
______________________________________                                    
EFFECT OF MONOMER CONCENTRATION ON                                        
MOLECULAR WEIGHT                                                          
                        R                                                 
     MOLES              Moles   Polymer                                   
                                       Maximum                            
TA   PPD·H.sub.2 SO.sub.4                                        
                SO.sub.3                                                  
                        (SO.sub.3 /TA)                                    
                                Solids,%                                  
                                       .sup.η inh                     
______________________________________                                    
.030 .030       .397    13.2    27.8   0.82                               
.036 .036       .385    10.7    32.5   1.44                               
.042 .042       .350    8.3     38.4   1.06                               
.048 .048       .375    7.8     39.9   0.84                               
.060 .060       .360    6.0     46.8   0.41                               
______________________________________                                    
 
    
     The results given in Table II show that polymerization of TA and PPD-S in SO 3  at 100° C. yielded maximum inherent viscosity when R was 10.7 (32.5% polymer solids). 
     EXAMPLE 4 
     This example illustrates the effect of SO 3  solvent concentration on polymerization. 
     Four dopes were made following the same procedure described in Example 2 in which a solution of TA and PPD-S in solvent (SO 3  or oleum) was polymerized at 100° C. Each dope was prepared in the same manner with the exception that the strength of the solvent was varied from dope to dope and ranged from 100% SO 3  to 61.2% SO 3  (i.e. 61.2% oleum). Table III below summarizes each dope preparation. 
     
                                           TABLE III                               
__________________________________________________________________________
POLYMERIZATION OF TA AND PPD-S                                            
SULFATE IN OLEUM IN SO.sub.3 At 100° C.                            
                      MOLE RATIO                                          
      % SO.sub.3 After                                                    
                      Before  After   R                                   
Solvent                                                                   
      Dissolution                                                         
              % SO.sub.3 After                                            
                      Polymerization                                      
                              Polymerization                              
                                      Moles % Polymer                     
                                                  Maximum                 
% SO.sub.3                                                                
      of PPD-S                                                            
              Polymeriazation                                             
                      H+/PPD  H+/Polymer                                  
                                      SO.sub.3 /TA                        
                                            Solids                        
                                                  .sup.η inh          
                                                        Comments          
__________________________________________________________________________
61.2  54.2    34.1    4.0     6.0     5.7   35.1  0.10  Isotropic         
82.1  72.2    50.3    2.3     4.3     9.0   36.6  0.51  Aniso-            
                                                        tropic            
                                                        after 0.5         
                                                        hr.               
90.0  79.2    57.0    1.7     3.7     9.0   36.6  0.90  Aniso-            
                                                        tropic            
                                                        after 0.5         
                                                        hr.               
100.0 88.3    66.8    1.0     3.0     9.5   35.2  1.55  Aniso-            
                                                        tropic            
                                                        after 0.5         
                                                        hr.               
__________________________________________________________________________
 
    
     The results in Table III show that polymer of maximum inherent viscosity (η inh ) was obtained when 100% SO 3  was used as the polymerization solvent and that η inh  decreases with decreasing SO 3  concentration until at some SO 3  concentration below 82.1% anisotropic dopes were no longer obtainable. 
     EXAMPLE 5 
     This example illustrates the polymerization of TA and substituted diamine monomers in 100% SO 3  to obtain anisotropic dopes in which the polyamide contains 0.5, 1.0 or 1.5 --SO 3  H groups per repeat unit. 
     Three anisotropic dopes were prepared using the procedure described in Example 3 except that in each instance a substituted diamine monomer was used instead of PPD-S. The substituted diamine monomer used in each instance, the amounts of materials employed and the results obtained are given in the following table. 
     
                                           TABLE IV                                
__________________________________________________________________________
POLYMERIZATION OF TA AND SUBSTITUTED DIAMINES IN SO.sub.3                 
                    Sulfonate                                             
                    Groups per                                            
                           Moles  Moles                                   
                                      Moles SO.sub.3                      
                                            Polymer                       
                                                 Maximum                  
                                                       Polymerization     
Diamine Monomer     Repeat Unit                                           
                           Diamine/TA                                     
                                  SO.sub.3                                
                                      Moles TA                            
                                            Solids,%                      
                                                 .sup.η inh           
                                                       Temp. °     
__________________________________________________________________________
                                                       C.                 
 ##STR4##          0       .010/.010                                      
                                  .133                                    
                                      13.3  18.0 2.20  80                 
 ##STR5##          1.5     1.66/1.66                                      
                                  22.66                                   
                                      13.7  23.5 1.23  100                
 ##STR6##          0.5     .007/.007                                      
                                  0.08                                    
                                      11.4  23.9 1.13  100                
Control PPD-S      2.0                                                    
__________________________________________________________________________
 
    
     the polymerization of 2,3,5,6-tetrafluoro-PPD and TA in SO 3  yielded an anisotropic dope of poly(tetrafluoro-para-phenyleneterephthalamide). The polymerization of 2-chloro-PPD-S and TA and of 2,6-dichloro-PPD-S and TA in SO 3  yielded anisotropic dopes of chlorinated polyamides consisting of repeating units of the formula ##STR7## in the case of 2-chloro-PPD-S and of the formula ##STR8## in the case of 2,6-dichloro-PPD-S. 
     EXAMPLE 6 
     This example illustrates the polymerization of 1,4-bis(trichloromethyl)benzene with PPD-S in SO 3  to obtain highly anisotropic dopes. 
     In a dry three-necked 125 ml Grignard flask equipped with a mechanical stirrer fitted with a Teflon™ stirring paddle and a Friedrich condenser fitted with a calcium sulfate-containing drying tube was placed 37.47 g (0.468 mol) of sulfur trioxide which was cooled in an ice bath. Incrementally in ˜1 gram portions over 5-10 minutes was added with stirring 13.00 g (0.0416 mole) of 1,4-bis(trichloromethyl)benzene (BTMB). The initial color of the BTMB-SO 3  complex was bright orange, then yellow. The ice bath was removed. Stirring was continued as the flask contents warmed to room temperature. A homogeneous, green solution was obtained. (Solubility of BTMB in SO 3  at 23° C. was ˜0.4 g/ml.) After the BTMB-SO 3  complex was again chilled in an ice bath, 8.579 g (0.0416 mol) of PPD-S were added incrementally in 0.5 g portions over 30 minutes with stirring. After the ice/water bath was removed, stirring was continued for one hour afterwhich the flask was placed in an oil bath at 100° C. The light-green solution immediately began to foam and thicken. After 15 minutes, the reaction mixture appeared yellowish-tan and muddy. After 30 minutes the solution became clear, light amber and more viscous. After 1.5 hours, this isotropic dope was transformed within one minute into a yellow, opaque anisotropic dope exhibiting increasingly brilliant shear opalescence. As the transformation was completed, reflux of SO 3  from the condenser terminated. Fibers of 2 ft. length were drawn from this dope by insertion and removal of a glass rod. 
     With initial heating and during initial stages of polymerization (0-3 hours), HCl was evolved. HCl presence was established by bubbling into a 1% aqueous AgNO 3  solution and identification as AgCl. After 6 hours, thin films of dope were coagulated in water. The films maintained their integrity with little or no swelling after being submerged for 24 hours in water. Polymerization was discontinued after 15 hours. The inherent viscosity profile (measured at a polymer concentration of 0.364%) was as follows: 
     
         ______________________________________                                    
Time             .sup.η inh                                           
______________________________________                                    
2                1.14                                                     
5                1.19                                                     
8.5              1.18                                                     
15               0.95                                                     
______________________________________                                    
 
    
     Dope samples were taken after 2 and 5 hours of polymerization for elemental analysis. Polymer was obtained by quenching the samples in water, neutralizing with 2% aqueous Na 2  CO 3 , washing with water and finally with acetone and vacuum drying (100° C./12 hrs/50 mm Hg). Elemental analysis (C, H, N, S) revealed monosulfonation after 5 hours. 
     EXAMPLE 7 
     This example illustrates the polymerization of TA, PPD-S and hydrazine sulfate (Hy-S) in SO 3  at 100° C. to provide an anisotropic dope of a copolymer consisting of recurring units of the formula ##STR9## 
     Several dopes were prepared by polymerizing PPD-S, Hy-S and TA in SO 3  at 100° C. wherein the mole ratio of PPD-S to Hy-S per mole of TA was varied from dope to dope. The dopes were prepared by the procedure given in Example 1 by adding PPD-S and Hy-S to TA-SO 3  complex (single phase) to form a monomer solution the temperature of which was raised to 100° C. to effect polymerization. The results of the polymerizations are given in Table IV along with certain processing conditions. 
     
                                           TABLE V                                 
__________________________________________________________________________
POLYMERIZATION OF PPD-S, Hy-S AND TA IN SO.sub.3 AT 100° C.        
                                       Polymer Conc.                      
                                       (g/dl)                             
                                       Used For                           
Equivalents                                                               
         MOLES             Polymer                                        
                                 Maximum                                  
                                       Determining                        
PPD-S/Hy-S/TA                                                             
         PPD-S                                                            
              Hy-S TA  SO.sub.3                                           
                           Solids (%)                                     
                                 .sup.η inh                           
                                       .sup.η inh                     
                                               Comments                   
__________________________________________________________________________
.9/.1/1.0                                                                 
         0.03792                                                          
              0.00421                                                     
                   0.04213                                                
                       0.386                                              
                           33.96 0.78  .81     Anisotropic                
                                               After 2.5                  
                                               hours                      
.7/.3/1.0                                                                 
         0.02949                                                          
              0.01264                                                     
                   0.04213                                                
                       0.376                                              
                           30.28 0.43  .76     Anisotropic                
                                               after 3.75                 
                                               hours                      
.5/.5/1.0                                                                 
         0.021065                                                         
              0.021065                                                    
                   0.04213                                                
                       0.379                                              
                           25.73 0.29  .70     Isotropic                  
                                               after 6                    
                                               hrs.; no                   
                                               shear                      
                                               opalescence                
0/1.0/1.0                                                                 
         0    0.04213                                                     
                   0.04213                                                
                       0.375                                              
                           14.30 1.94  .50     Isotropic                  
__________________________________________________________________________
 
    
     In the foregoing examples TA (99.9% purity) BTMB (99% purity), stabilized SO 3 , 96% H 2  SO 4 , PPD and substituted PPD&#39;s were all obtained commercially. PPD was vacuum distilled from Sn or Zn to 99.7% purity (titration in acetic acid with HClO 4 ). Para-phenylenediamine sulfates (e.g. PPD-S) were obtained in 80-90% yield at &gt;99.6% purity (aqueous titration with NaOH) by diamine dissolution in 22% H 2  SO 4  (e.g. 52 g PPD-S/1500 ml 22% H 2  SO 4 ). After decolorizing the solution with activated charcoal (100° C.), filtering (Celite) and cooling (0° C.), the crystals were filtered, washed with absolute ethanol and dried under vacuum at 80° C.