Acicular magnetic iron based alloy particles for magnetic recording and method of producing the same
This is a continuation of application Ser. No. 07/388,025, filed Jul. 31, 1989, now abandoned. 
    
    
     BACKGROUND OF THE INVENTION 
     The present invention relates to acicular magnetic iron based alloy particles for magnetic recording having high coercive force, high saturation magnetization, excellent stability against oxidation and excellent S.F.D. (Switching Field Distribution), and further having good dispersibility ascribed to excellent wetting property and deagglomeration property with respect to a binder, in particular, a binder containing a resin having an acid functional group, or a large specific surface area, and a method of producing such particles. 
     With the recent development of smaller-sized and ligther-weight magnetic recording apparatuses, the necessity for a recording medium having a higher performance such as a magnetic tape and a magnetic disk has been increasing more and more. In other words, a magnetic recording medium is required to have a higher recording density, higher output characteristic, in particular, an improved frequency characteristic and a lowered noise level. 
     The properties in which magnetic particles are required to have in order to satisfy the above-described demands on a magnetic recording medium, particularly, magnetic characteristics are a high coercive force and a large saturation magnetization. 
     Magnetic particles suitable for high-output and high-density recording, namely, magnetic particles having a high coercive force and a large saturation magnetization have recently been developed rapidly. As magnetic particles having such characteristics, acicular magnetic iron based alloy particles obtained by heat-treating acicular goethite particles or acicular hematite particles in a reducing gas are known and put to practical use. 
     The coercive force of acicular magnetic iron based alloy particles is dependent on the shapes of the particles, in particular, to the aspect ratio (major axis:minor axis) and has a tendency of aggrandizing with the increase in the aspect ratio (major axis:minor axis). The saturation magnetization has a tendency of increasing with the acceleration of reduction by raising the reducing temperature. The coercive force and the saturation magnetization have reverse correlation. That is, with the progress of reduction, the saturation magnetization is enhanced but the shapes of the particles are collapsed, thereby reducing the coercive force. Thus, acicular magnetic iron based alloy particles having both high coercive force and large saturation magnetization are strongly demanded. 
     Acicular magnetic iron based alloy particles having a high coercive force and a large saturation magnetization are very unstable. More specifically, since the acicular magnetic iron based alloy particles used for a magnetic recording medium are very fine particles having a particle size of not more than 1 μm, the surface activity of the particles is so large that when they are taken out into air after reduction, they rapidly react with the oxygen in air to ignite and release heat. In addition, the oxidation reaction converts these particles into oxides, thereby greatly reducing the magnetic characteristics, in particular, the saturation magnetization, so that it is impossible to obtain acicular magnetic iron based alloy particles having a large saturation magnetization which is an objective of the present invention. For these reasons, acicular magnetic iron based alloy particles having excellent stability against oxidation are strongly demanded. 
     There is no end to the recent demand for the improvement of the properties of acicular magnetic iron based alloy particles. In addition to a high coercive force, a larger saturation magnetization, an excellent stability against oxidation, and an excellent S.F.D. (Switching Field Distribution) is strongly demanded. This fact is clear from the descriptions in Japanese Patent Application Laid-Open (KOKAI) No. 63.26821 (1988): &#34;FIG. 1 shows the relationship between the S.F.D. value, and the recording and reproducing output of the above-described magnetic disc. . . . The relationship between the S.F.D. value, and the recording and reproducing output is linear, as is obvious from FIG. 1, which proves that the use of ferromagnetic particles having a small S.F.D. value enhances the recording and reproducing output. That is, in order to increase the recording and reproducing output, the S.F.D. value is preferably as small as possible. In order to obtain a higher output more than the ordinary one, it is necessary that the S.F.D. value is not more than 0.6.&#34; 
     It is pointed out that a resin having an OH group, which has conventionally been widely used as a resin for magnetic recording media is disadvantageous in that the resin needs to contain a large amount of dispersant in order to disperse magnetic particles in a binder and, as a result, the dispersant remaining in the coated film has influence on the surface properties of the coated film such as viscosity, which causes a defect in operation due to a change in the ambient temperature or the like. To solve this problem, the recent tendency is to reduce the amount of dispersant mixed with a binder as much as possible or not used, and various investigations have been made on the kind of the resin, the surface properties of magnetic particles, etc. As the resin, a resin having a COOH group or an SO 4  Na group has been put to use in place of the resin having an OH group, and as to the magnetic particles, the improvement of the wetting property and the deagglomeration property with respect to the resin having an acid functional group such as a COOH group, an SO 4  Na group, etc. is strongly demanded in order to enhance the dispersibility of a binder. 
     It is known that the noise level of a magnetic recording medium has a tendency of lowering in proportion to the specific surface area of acicular magnetic iron based alloy particles. This phenomenon is shown in, for example, &#34;FIG. 1&#34; of Japanese Patent Application Laid-Open (KOKAI) No. 58-159231 (1983). 
     &#34;FIG. 1&#34; shows the relationship between the noise level of a magnetic tape produced from magnetic metal particles and the specific surface area of the particles used. The noise level linearly lowers with the increase in the specific surface area of the particles. Acicular magnetic iron based alloy particles are, therefore, strongly required to have as large a specific surface area as possible. 
     Various attempts have heretofore been made to improve the properties of acicular magnetic iron based alloy particles. For example, the following methods are known: a method of coating starting material particles such as acicular goethite particles and acicular hematite particles with a cobalt compound in advance and thereafter heat-treating the particles in a reducing atmosphere [Japanese Patent Application Laid-Open (KOKAI) No. 54-122664 (1979) and Japanese Patent Publication No. 58-55203 (1983)]; a method of coating starting material particles with a boron compound in advance and thereafter heat-treating the particles in a reducing atmosphere [Japanese Patent Application Laid-Open (KOKAI) No. 57-57459 (1982), Japanese Patent Publication No. 54-42832 (1979), Japanese Patent Application Laid-Open (KOKAI) Nos. 58-48611 (1983), 58-46607 (1983), 59-32881 (1984), 59-5603 (1984), 61-174304 (1986), 61-186410 (1986) and Japanese Patent Publication No. 59-32881 (1984 )]; and a method of coating starting material particles with a water soluble boron compound and the water-soluble salts of Al, Cr, Ge, Nd and the like in advance, and thereafter heat-treating the particles in a reducing atmosphere [Japanese Patent Application Laid-Open (KOKAI) No. 61-186410 (1986)]. 
     Acicular magnetic iron based alloy particles having a high coercive force, a large saturation magnetization, an excellent stability against oxidation and an excellent S.F.D. are now in the strongest demand, but no acicular magnetic iron based alloy particles having all these properties together have been produced by any known method. 
     More specifically, although acicular magnetic iron based alloy particles having a high coercive force and a large saturation magnetization are generally obtained by the above-described known methods, for example, the stability of saturation magnetization of the acicular magnetic iron based alloy particles produced by the process described in Japanese Patent Application Laid-Open (KOKAI) No. 58.46607 (1983) is about 10 to 30%, and the stability of saturation magnetization of the acicular magnetic iron based alloy particles produced by the process described in Japanese Patent Application Laid-Open (KOKAI) No. 59-5603 (1984) is about 15%, both being insufficient. The S.F.D. of the conventional acicular magnetic iron based alloy particles are also unsatisfactory as will be described later. 
     Accordingly, acicular magnetic iron based alloy particles which have a high coercive force, a high saturation magnetization, an excellent stability against oxidation and an excellent S.F.D., and further have a good dispersibility ascribed to excellent wetting property and deagglomeration property with respect to a binder, in particular, a binder containing a resin having an acid functional group, or a large specific surface area in addition to the above properties are strongly demanded. 
     As a result of studies undertaken by the present inventors in order to meet such demand, it has been found that acicular magnetic iron based alloy particles containing 1.5 to 10 mol % of B based on Fe (calculated as B) and 1.5 to 10 mol % of Co based on Fe (calculated as Co) in the vicinity of the surfaces of the particles which are produced by coating the surfaces of acicular goethite particles with a boron compound and a cobalt compound, heat-treating the thus obtained particles in a temperature range of 300° to 600° C. to obtain acicular hematite particles coated with a boron oxide and a cobalt oxide, and heat-treating the thus obtained acicular hematite particles in a temperature range of 300° to 500° C. in a reducing atmosphere, have a high coercive force, a large saturation magnetization, an excellent stability against oxidation and an excellent S.F.D. 
     It has also been found that by coating the surfaces of the acicular goethite particles further with an aluminum compound and/or a nickel compound so that 1.0 to 10 mol % of Al based on Fe (calculated as Al) and/or 0.3 to 10 mol % of Ni based on Fe (calculated as Ni) in addition to B and Co described above is contained in the vicinity of the surfaces of the acicular magnetic iron based alloy particles, the thus obtained acicular magnetic iron based alloy particles have a good dispersibility ascribed to excellent wetting property and deagglomeration property with respect to a binder, in particular, a binder containing a resin having an acid functional group in addition to the above properties. 
     It has also been found that by coating the surfaces of the acicular goethite particles further with a silicon compound so that Si in amount of 1.0 to 10 mol % of SiO 2  based on Fe (calculated as SiO 2 ) in addition to B and Co described above are contained in the vicinity of the surfaces of the acicular magnetic iron based alloy particles, the thus obtained acicular magnetic iron based alloy particles obtained have a large specific surface area in addition to the above properties. 
     The present invention has been made on the basis of these findings. 
     SUMMARY OF THE INVENTION 
     In a first aspect of the present invention, there is provided acicular magnetic iron based alloy particles for magnetic recording, containing 1.5 to 10 mol % of B based on Fe (calculated as B) and 1.5 to 10 mol % of Co based on Fe (calculated as Co) in the vicinity of the surfaces of said particles and having a saturation magnetization of not less than 125 emu/g and an S.F.D. value of not more than 0.50. 
     In a second aspect of the present invention, there is provided acicular magnetic iron based alloy particles for magnetic recording comprising acicular magnetic iron based alloy particles containing 1.5 to 10 mol % of B based on Fe (calculated as B), 1.5 to 10 mol % of Co based on Fe (calculated as Co) and 1.0 to 10 mol % of Al based on Fe (calculated as Al) and/or 0.3 to 10 mol % of Ni based on Fe (calculated as Ni) in the vicinity of the surfaces of said particles and having a saturation magnetization of not less than 125 emu/g and an S.F.D. value of not more than 0.50. 
     In a third aspect of the present invention, there is provided acicular magnetic iron based alloy particles for magnetic recording comprising acicular magnetic iron based alloy particles containing 1.5 to 10 mol % of B based on Fe (calculated as B), 1.5 to 10 mol % of Co based on Fe (calculated as Co) and Si in amount of 1.0 to 10 mol % of SiO 2  based on Fe (calculated as SiO 2 ) or Si in amount of 1.0 to 10 mol % of SiO 2  based on Fe (calculated as SiO 2 ) and 1.0 to 10 mol % of Al based on Fe (calculated as Al) and having a saturation magnetization of not less than 125 emu/g and an S.F.D. value of not more than 0.50. 
     In a fourth aspect of the present invention, there is provided a process for producing acicular magnetic iron based alloy particles for magnetic recording containing boron and cobalt in the vicinity of the surfaces thereof and having a saturation magnetization of not less than 125 emu/g and an S.F.D. value of not more than 0.50, comprising the steps of: coating the surfaces of acicular goethite particles with a boron compound and a cobalt compound; heat-treating said particles in a temperature range of 300° to 600° C. to obtain acicular hematite particles coated with a boron oxide and a cobalt oxide; and heat-treating said acicular hematite particles in a temperature range of 300° to 500° C. in a reducing atmosphere. 
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     (1) Acicular magnetic iron based alloy particles according to the present invention which contain 1.5 to 10 mol % of B based on Fe (calculated as B) and 1.5 to 10 mol % of Co based on Fe (calculated as Co) in the vicinity of the surfaces of the particles, have a high coercive force of not less than 1,400 Oe, a large saturation magnetization of not less than 125 emu/g, and a change of saturation magnetization of not more than 15%, preferably not more than 10%, and a small S.F.D. value of not more than 0.50. 
     (2) Acicular magnetic iron based alloy particles according to the present invention which contain 1.5 to 10 mol % of B based on Fe (calculated as B), 1.5 to 10 mol % of Co based on Fe (calculated as Co) and 1.0 to 10 mol % of Al based on Fe (calculated as Al) and/or 0.3 to 10 mol % of Ni based on Fe (calculated as Ni) in the vicinity of the surfaces of the particles, have a high coercive force of not less than 1,400 Oe, a large saturation magnetization of not less than 125 emu/g, and a change of saturation magnetization of not more than 15%, preferably not more than 10%, a small S.F.D. value of not more than 0.50, and a good dispersibility ascribed to excellent wetting property and deagglomeration property with respect to a binder, in particular, a binder containing a resin having an acid functional group. 
     (3) Acicular magnetic iron based alloy particles according to the present invention which contain 1.5 to 10 mol % of B based on Fe (calculated as B), 1.5 to 10 mol % of Co based on Fe (calculated as Co) and Si in amount of 1.0 to 10 mol % of SiO 2  based on Fe (calculated as SiO 2 ), or Si in amount of 1.0 to 10 mol % of SiO 2  Si based on Fe (calculated as SiO 2 ) and 1.0 to 10 mol % of Al based on Fe (calculated as Al) in the vicinity of the surfaces thereof, have a high coercive force of not less than 1,400 Oe, a large saturation magnetization of not less than 125 emu/g, and a change of saturation magnetization of not more than 15%, preferably not more than 10%, a small S.F.D. value of not more than 0.50, and a large specific surface area of not less than 45.0 m 2  /g. 
     Acicular magnetic iron based alloy particles according to the present invention are produced by coating the surfaces of acicular goethite particles with: 
     (1) a boron compound and a cobalt compound; 
     (2) a boron compound, a cobalt compound, and an aluminum compound and/or a nickel compound; or 
     (3) a boron compound, a cobalt compound and a silicon compound, or a silicon compound and an aluminum compound, 
     heat-treating the thus obtained particles in a temperature range of 300° to 600° C. to obtain coated acicular hematite particles, and heat-treating the thus obtained acicular hematite particles in a temperature range of 300° to 500° C. in a reducing atmosphere. 
     (1) Acicular magnetic iron based alloy particles which is an object of the present invention, having a high coercive force, a large saturation magnetization, an excellent stability against oxidation and an excellent S.F.D. cannot be obtained either in the case of coating the starting material particles only with a boron compound or a cobalt compound, or in the case of introducing boron an/or cobalt elements into the starting material particles, as will be shown in the later-described comparative examples. That is, it is only by coating the starting material particles with a boron compound and a cobalt compound that acicular magnetic iron based alloy particles according to the present invention are obtained. 
     (2) Acicular magnetic iron based alloy particles according to the present invention containing aluminum in addition to boron and cobalt in the vicinity of the surfaces of the particles have a large resin adsorption, as will be shown in the later-described examples, so that it is clear that these particles have an excellent wetting property with a binder containing a resin, in particular, a resin having an acid functional group in addition to the properties described in (1). 
     Acicular magnetic iron based alloy particles according to the present invention containing nickel in addition to boron and cobalt in the vicinity of the surfaces of the particles are excellent in the initial dispersibility, as will be shown in the later-described examples, so that it is clear that these particles have an excellent deagglomeration property with a binder containing a resin, in particular, a resin having an acid functional group in addition to the properties described in (1). 
     Acicular magnetic iron based alloy particles according to the present invention containing aluminum and nickel in addition to boron and cobalt in the vicinity of the surfaces of the particles are excellent in the gloss, as will be shown in the later-described examples, so that it is clear that these particles have an excellent dispersibility ascribed to excellent wetting property and deagglomeration property with a binder containing a resin, in particular, a resin having an acid functional group in addition to the properties described in (1). 
     (3) Acicular magnetic iron based alloy particles according to the present invention containing boron, cobalt and silicon, or silicon and aluminum in the vicinity of the surfaces of the particles have a large specific surface area in addition to the properties of the particles containing boron and cobalt in the vicinity of the surfaces thereof described in (1). 
     The acicular goethite particles used in the present invention can be produced by any ordinary method such as a method of oxidizing a suspension containing ferrous hydroxide and having a pH of not less than 11 obtained by mixing an aqueous ferrous salt solution and not less than an equivalent of an alkali solution, by passing an oxygen-containing gas thereinto at a temperature of not higher than 80° C. [Japanese Patent Publication No. 39-5610 (1964)] and a method of oxidizing a suspension containing FeCO 3  obtained by reacting an aqueous ferrous salt solution with an alkali carbonate, by passing an oxygen-containing gas thereinto Japanese Patent Application Laid Open (KOKAI) No. 50-80999 (1975)]. By changing reaction conditions, additives, etc. in these method, it is possible to use particles having a particle length of 0.1 to 0.4 μm and an aspect ratio (major axis:minor axis) of 5:1 to 20:1. In the producing reaction of the goethite particles, the metal ions of Co, Ni, Zn, Mn, Cu, etc. which are generally added in order to improve the properties of the acicular magnetic iron based alloy particles may be added. 
     In order to obtain acicular magnetic iron based alloy particles having a preferable S.F.D. value, especially, an S.F.D. value of not more than 0.47, the acicular goethite particles having a uniform particle size and being free of dendrites which are obtained by the latter method are used as the starting material particles. In particular, when acicular goethite particles having a uniform particle size, being free of dendrites, having a particle length of 0.18 to 0.3 μm and a large aspect ratio (major axis:minor axis), especially an aspect ratio of not less than 10:1 are used, it is possible to obtain acicular magnetic iron based alloy particles having a more preferable S.F.D. value especially an S.F.D. value of not more than 0.45. 
     As the acicular goethite particles of the starting material of the present invention, those disclosed in U.S. Pat. Nos. 4,133,677, 4,130,158, 4,437,881, 3,652,334 and 4,773,931, Japanese Patent Publications No. 55-29577 (1980), No. 60-11446 (1985) and No. 59-48768 (1984), Japanese Patent Application No. 63-325436 (1988) and U.S. patent application Ser. No. 07/342152 are usable. 
     As the boron compound in the present invention, KBO 2 , H 3  BO 3 , HBO 2 , B 2  O 3 , etc. are usable. The coating of acicular goethite particles with a boron compound is carried out by mixing an aqueous solution containing boron with the acicular goethite particles, stirring the mixture, filtering out the particles and drying the thus obtained particles. The amount of boron coating the particle surfaces is 1.5 to 10 mol % based on Fe (calculated as B). If it is less than 1.5 mol %, sintering of particle and sintering between particles is caused, thereby making it difficult to obtain acicular magnetic iron based alloy particles having a high coercive force. If it is more than 10 mol %, the progress of reduction is obstructed, thereby making it difficult to obtain acicular magnetic iron based alloy particles which are objective particles of the present invention. 
     As the cobalt compound in the present invention, cobalt sulfate, cobalt nitrate, cobalt acetate, cobalt chloride, cobalt hydroxide, etc. are usable. The coating of acicular goethite particles with a cobalt compound is carried out by mixing an aqueous solution containing cobalt with the acicular goethite particles, stirring the mixture, neutralizing the mixture with an aqueous alkaline solution or an aqueous acid solution, if necessary, filtering out the particles and drying the thus obtained particles. The amount of cobalt coating the particle surfaces is 1.5 to 10.0 mol % based on Fe (calculated as Co). If it is less than 1.5 mol %, the saturation magnetization is not more than 125 emu/g and the S.F.D. value exceeds 0.50, thereby making is difficult to obtain the acicular magnetic iron based alloy particles which are objective particles of the present invention. Even if it is more than 10.0 mol %, it is possible to obtain the acicular magnetic iron based alloy particles which are objective particles of the present invention, but it is meaningless that the acicular magnetic iron based alloy particles contain Co more than necessary. 
     As the aluminum compound in the present invention, aluminum sulfate, aluminum nitrate, aluminum chloride, aluminum hydroxide, sodium aluminate, alumina sol and the like are usable. The coating of acicular goethite particles with an aluminum compound is carried out by mixing an aqueous solution containing aluminum with the acicular goethite particles, stirring the mixture, neutralizing the mixture with an aqueous alkaline solution or an aqueous acid solution, if necessary, filtering out the particles and drying the thus obtained particles. The amount of aluminum coating the particle surfaces is 1.0 to 10.0 mol %, preferably 1.0 to 5 mol % based on Fe (calculated as Al). If it is less than 1.0 mol %, the wetting property with a resin is sufficient, thereby making it difficult to obtain acicular magnetic iron based alloy particles having a sufficient resin adsorption, or it is difficult to obtain acicular magnetic iron based alloy particles having a large specific surface area. If it is more than 10.0 mol %, the magnetic characteristics such as the coercive force and the saturation magnetization of the acicular magnetic iron based alloy particles obtained are greatly reduced. 
     As the nickel compound in the present invention, nickel sulfate, nickel nitrate, nickel chloride, nickel hydroxide, etc. are usable. The coating of acicular goethite particles with a nickel compound is carried out by mixing an aqueous solution containing nickel with the acicular goethite particles, stirring the mixture, neutralizing the mixture with an aqueous alkaline solution or an aqueous acid solution, if necessary, filtering out the particles and drying the thus obtained particles. The amount of nickel coating the particle surfaces is 0.3 to 10.0 mol % based on Fe (calculated as Ni). If it is less than 0.3 mol %, the reducing-temperature lowering-effect is not obtained, and since the deagglomeration property of the particles is insufficient, the improvement of the initial dispersibility, which is one of the objects of the present invention, is insufficient. If it is more than 10.0 mol %, the magnetic crystalline anisotropy become smaller, thereby making it difficult to obtain acicular magnetic iron based alloy particles having a high coercive force, and the saturation magnetization is apt to be lowered. 
     As the silicon compound in the present invention, colloidal silica, water glass, aqueous silicic acid, silica sol, etc. are usable. The coating of acicular goethite particles with a silicon compound is carried-out by mixing an aqueous solution containing a silicon compound with the acicular goethite particles, stirring the mixture, neutralizing the mixture with an aqueous alkaline solution or an aqueous acid solution, if necessary, filtering out the particles and drying the thus obtained particles. The amount of silicon coating the particle surfaces is 1.0 to 10.0 mol % based on Fe (calculated as SiO 2 ). If it is less than 1.0 mol %, it is difficult to obtain the iron based alloy particles having a large specific surface area. If it is more than 10.0 mol %, the saturation magnetization of the acicular magnetic iron based alloy particles obtained is unfavorably lowered. 
     When the surfaces of acicular goethite particles are coated with a boron compound, cobalt compound, aluminum compound, nickel compound, and silicon compound, the order of coating may be selected as desired, or coating of such compounds may be carried out simultaneously. 
     The heat-treating temperature in the present invention is 300° to 600° C. If it is lower than 300° C., since high densification of the particles is difficult, it is difficult to retain the shapes of the particles at the time of heat-treating in the subsequent reduction process, thereby lowering the coercive force of the acicular magnetic iron based alloy particles, and whereby it is also difficult to provide an S.F.D. value of not more than 0.5. The reason why the S.F.D. value is not improved is that when the heat-treating temperature is lower than 300° C., recrystallization is insufficient, resulting in the nonuniformity in the shape anisotropy due to the distribution of the shapes of the particles after reduction and the nonuniformity in the crystalline anisotropy due to the structural distribution of Fe, B and Co. If the heat-treating temperature is higher than 600° C., sintering of particle and sintering between particles is caused, thereby collapsing the shapes of the particles. 
     The heat-treating temperature in a reducing atmosphere in the present invention is 300° to 500° C. If it is lower than 300° C., the reduction is insufficient for obtaining acicular magnetic iron based alloy particles having a large saturation magnetization. If it is higher than 500° C., sintering of particle and sintering between particles is caused, thereby collapsing the shapes of the particles and lowering the coercive force of the acicular magnetic iron based alloy particles obtained. 
     The acicular magnetic iron based alloy particles according to the present invention has a particle length of 0.1 to 0.4 μm, and an aspect ratio (major axis:minor axis) of 5:1 to 15:1. 
     The acicular magnetic iron based alloy particles after reduction of the present invention can be taken out into air by a known method such as a method of dipping the acicular magnetic iron based alloy particles in an organic solvent such as toluene and a method of replacing the atmosphere after reduction with an inert gas and gradually increasing the oxygen content in the inert gas so as to finally achieving the gradual oxidization of the innert gas by air. 
     The acicular magnetic iron based alloy particles according to the present invention obtained in this way have: 
     (1) a coercive force not less than 1,400 Oe, preferably not less than 1450 Oe; a saturation magnetization of not less than 125 emu/g, preferably not less than 130 emu/g; a change of saturation magnetization of not more than 15%, preferably not more than 10%; and an S.F.D. value of not more than 0.50, preferably not more than 0.47; 
     (2) a gloss of not less than 100%, preferably not less than 110% at a dispersion time of 50%; a gloss of not less than 120%; preferably not less than 130% at a dispersion time of 100%; and a resin adsorption of not less than 1.1 g, preferably not less than 1.4 g; in addition to the properties described in (1); or 
     (3) a specific surface area of not less than 45.0 m 2  /g, preferably not less than 48 m 2  /g in addition to the properties described in (1). 
     The acicular magnetic iron based alloy particles of the present invention having the above-described properties are suitable as the magnetic particles for high-density and high-output recording which are now in the strongest demand. 
     The present invention will be more precisely explained while referring to Examples as follows. 
     However, the present invention is not restricted to Examples under mentioned. From the foregoing description, one skilled in the art can easily ascertain the essential characteristics of this invention, and without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions. 
     EXAMPLES 
     In each of the following Examples and Comparative Examples; 
     (i) The particle length and the aspect ratio (major axis:minor axis) of the acicular magnetic iron based alloy particles are expressed by the average values measured in electron microphotographs. 
     (ii) The magnetic characteristics of the acicular magnetic iron based alloy particles were measured by using a vibrating sample magnetometer VSM-3S-15, produced by Toei Kogyo K.K. and applying an external magnetic field up to 10 KOe. 
     (iii) The stability against oxidation is expressed by Δσs/σs (%) which shows the changes of the saturation magnetization (%) of the sample allowed to stand for 7 days at a temperature of 60° C. and a relative humidity of 90%. 
     (iv) The S.F.D. value was obtained by using a sheet test piece having a squareness ratio of 0.85 obtained by the following method. The differentiation curve of the magnetization major roop around coercivity of the sample was obtained by using a differentiation circuit of the magnetometer and the half power width of the differentiation curve was measured and the half power width was divided by the coercive force of the peak value of the curve. 
     A magnetic coating was prepared by charging the following components into a 100-cc plastic bottle in the following ratio and dispersing them with a paint conditioner for 8 hours. The sheet test piece was obtained by applying the magnetic coating to polyethylene film of 25 μm thick to a thickness of 50 μm by using an applicator, and drying the coated film in a magnetic field of 3 to 5 KGauss. 
     
         ______________________________________                                    
3-mmφ steel ball                                                      
                   800    parts by weight                                 
Magnetic iron based                                                       
                   100    parts by weight                                 
alloy particles                                                           
Polyurethane resin 20     parts by weight                                 
having a sodium                                                           
sulfonate group                                                           
Cyclohexanone      83.3   parts by weight                                 
Methylethyl ketone 83.3   parts by weight                                 
Toluene            83.3   parts by weight                                 
______________________________________                                    
 
    
     (v) The resin adsorption is expressed by the difference between the weight of the resin concentration of the resin liquid having the following composition and the weight of the resin concentration of the supernatant liquid of the coating obtained by charging 20 g of acicular magnetic iron based alloy particles, 56 g of the resin liquid and 120 g of 3-mmφ stainless steel balls into a 100-ml plastic bottle and dispersing them with a paint conditioner for 60 minutes and subjected to centrifugal separation. The weights of both resin concentrations were measured as the nonvolatile matter. 
     
         ______________________________________                                    
Composition of resin liquid                                               
______________________________________                                    
Solids content of resin                                                   
                      3.57   wt %                                         
MEK                   32.14  wt %                                         
Toluene               32.14  wt %                                         
Anone                 32.14  wt %                                         
______________________________________                                    
 
    
     (vi) The dispersibility is expressed by the gloss of the coated film obtained by applying a coating to PET film by an applicator. The coating was produced by charging 15 g of acicular magnetic iron based alloy particles, the resin liquid having the following composition and 120 g of 3-mmφ stainless steel balls into a 100-ml plastic bottle and dispersing them with a paint conditioner for a predetermined time. The dispersing time required for the saturation of the gloss was assumed to be 100%, and the gloss at that time is expressed as the criterion of the dispersibility. The gloss at a dispersion time of 50% is expressed as the criterion of the initial dispersibility. 
     
         ______________________________________                                    
Composition of resin liquid                                               
______________________________________                                    
Resin                 3.57   g                                            
MEK                   15.17  g                                            
Toluene               15.17  g                                            
Cyclohexanone         15.17  g                                            
______________________________________                                    
 
    
     The gloss of the coated film was measured by a glossmeter produced by Nihon Denshoku Kogyo K.K. at an incident angle of 60° C., and the value is expressed by % on the assumption that the gloss of the standard sheet was 89.0%. 
     Production of acicular hematite particles 
     Examples 1 to 10, Comparative Examples 1 to 9 
     Example 1 
     100 g of acicular goethite particles having a particle length of 0.21 μm and a aspect ratio (major axis:minor axis) of 12:1 was suspended in 1 l of water. 
     To the suspension, 10.0 g (equivalent to 10.0 wt % based on the acicular goethite particles) of H 3  BO 3  and 13.0 g (equivalent to 13.0 wt % based on the acicular goethite particles) of Co(CH 3  COO) 2 .4H 2  O were added and the suspension was stirred for 10 minutes. The pH of the suspension was 6.2. NH 4  OH was then added until the pH of the suspension became 9.3. The acicular α-FeOOH particles were filtered out and dried, thereby obtaining the acicular α-FeOOH particles coated with boron and cobalt. 
     50 g of the thus obtained acicular goethite particles coated with boron and cobalt were heat-treated at 400° C. in air to obtain acicular hematite particles coated with a boron oxide and a cobalt oxide. According to the observation of the electron microphotographs, the particles had an average particle length of 0.19 μm and an average aspect ratio (major axis:minor axis) of 11:1. 
     Examples 2 to 10, Comparative Examples 1 to 9 
     Acicular hematite particles were obtained in the same way as in Example 1 except that the kind of the acicular goethite particles, the kind and the content of a boron compound and the time for mixing the boron compound, the kind and the content of a cobalt compound and the time of existence of the cobalt compound and the temperature in the heat-treating process were varied. 
     The main conditions for producing these particles and the properties of these particles obtained are shown in Table 1. 
     Production of acicular magnetic iron based alloy particles 
     Examples 11 to 20, Comparative Examples 10 to 20 
     Example 11 
     20 g of the acicular hematite particles coated with boron oxide and cobalt oxide obtained in Example 1 were reduced by a hydrogen gas at 410° C. for 6 hours, thereby obtaining acicular magnetic iron based alloy particles. 
     The surfaces of the acicular magnetic iron based alloy particles obtained by reduction were coated with a stable oxide film so as to prevent rapid oxidation when they were taken out into air. As a result of X-ray fluorometry, it was found that the particles contained 4.7 mol % of B based on Fe and 4.5 mol % of Co based on Fe. According to the observation of the electron microphotographs, the particles had an average particle length of 0.15 μm and an average aspect ratio (major axis:minor axis) of 7:1. As to the magnetic characteristics, the coercive force (Hc) was 1,530 Oe, the saturation magnetization (σs) was 133 emu/g, the of saturation magnetization was 8.0% and the S.F.D. value was 0.43. 
     Examples 12 to 20, Comparative Examples 10 to 20 
     Acicular magnetic iron based alloy particles were obtained in the same way as in Example 11 except that the kind of the acicular hematite particles, and the time and the temperature in the heat-treating process were varied. 
     The main conditions for producing these particles and the properties of these particles obtained are shown in Table 2. 
     Surface coating of acicular goethite particles 
     Examples 21 to 39, Reference Examples 1 to 4 
     Example 21 
     100 g of acicular goethite particles having an average particle length of 0.21 μm and an average aspect ratio (major axis:minor axis) of 12:1 was suspended in 1 l of water. 
     To the suspension, 10.0 g (equivalent to 10.0 wt % based on the acicular goethite particles) of H 3  BO 3 , 13.0 g (equivalent to 13.0 wt % based on the acicular goethite particles) of Co(CH 3  COO) 2 .4H 2  O and 12 g (equivalent to 12 wt % based on the acicular goethite particles) of Al(NO 3 ) 3 .9H 2  O were added and the suspension was stirred for 10 minutes. The pH of the suspension was 4.4. NH 4  OH was then added until the pH of the suspension became 9.3. The acicular α-FeOOH particles were filtered out and dried, thereby obtaining the acicular α-FeOOH particles coated with boron compound, cobalt compound and aluminum compound. 
     Examples 22 to 39, Reference Examples 1 to 4 
     Acicular α-FeOOH particles coated with various compounds were obtained in the same way as in Example 21 except that the kind of the acicular goethite particles, the kind and the content of a boron compound, the kind and the content of a cobalt compound and the kind and the content of an aluminum compound or a nickel compound or the kinds and the contents of both alumina and nickel compounds were varied. 
     The main conditions for producing these particles and the properties of these particles obtained are shown in Tables 3 and 4. 
     Production of acicular hematite particles 
     Examples 40 to 58, Comparative Examples 5 to 8 
     Example 40 
     50 g of the acicular goethite particles coated with boron, cobalt and aluminum obtained in Example 21 were heat-treated at 400° C. in air to obtain acicular hematite particles coated with a boron oxide, a cobalt oxide and an aluminum oxide. According to the observation of the electron microphotographs, the particles had an average particle length of 0.19 μm and an average aspect ratio (major axis:minor axis) of 11:1 by average value. 
     Examples 41 to 58, Reference Examples 5 to 8 
     Acicular hematite particles were obtained in the same way as in Example 40 except that the temperature in the heat-treating process was varied. 
     The main conditions for producing these particles and the properties of these particles obtained are shown in Tables 5 and 6. 
     Production of Acicular Magnetic Iron Based Alloy Particles 
     Examples 59 to 77, Reference Examples 9 to 12 
     Example 59 
     20 g of the acicular hematite particles coated with a boron oxide, a cobalt oxide and an aluminum oxide obtained in Example 40 were reduced by a hydrogen gas at 420° C. for 6 hours, thereby obtaining acicular magnetic iron based alloy particles. 
     The surfaces of the acicular magnetic iron based alloy particles obtained by reduction were coated with a stable oxide film so as to prevent rapid oxidation when they were taken out into air. As a result of X-ray fluorometry, it was found that the particles contained 4.7 mol % of B based on Fe, 4.5 mol % of Co based on Fe and 2.6 mol % of Al based on Fe. According to the observation of the electron microphotographs, the particles had an average particle length of 0.15 μm and an average aspect ratio (major axis:minor axis) of 7:1. As to the magnetic characteristics, the coercive force (Hc) was 1,540 Oe, the saturation magnetization (σs) was 133 emu/g, the oxidative stability was 8.0% and the S.F.D. value was 0.42. The resin adsorption content was 1.4. As to the dispersibility, the gloss at a dispersion time of 50% was 110% and the gloss at a dispersion time of 100% was 120%. 
     Examples 60 to 77,  Reference Examples 9 to 12 
     Acicular magnetic iron based alloy particles were obtained in the same way as in Example 59 except that the kind of the acicular hematite particles and the temperature in the heat-treating process were varied. 
     The main conditions for producing these particles and the properties of these particles obtained are shown in Tables 7 and 8. 
     Surface coating of acicular goethite particles 
     Examples 78 to 90, Reference Examples 13 to 14 
     Example 78 
     100 g of acicular goethite particles having an average particle length of 0.20 μm and an average aspect ratio (major axis:minor axis) of 13:1 was suspended in 1 l of water. 
     To the suspension, 10.0 g (equivalent to 10.0 wt % based on the acicular goethite particles) of H 3  BO 3 , 13.0 g (equivalent to 13.0 wt % based on the acicular goethite particles) of Co(CH 3  COO) 2 .4H 2  O and 9.5 g (equivalent to 9.5 wt % based on the acicular goethite particles) of colloidal silica were added and the suspension was stirred for 10 minutes. The pH of the suspension was 6.1. NH 4  OH was then added until the pH of the suspension became 9.3. The acicular α-FeOOH particles were filtered out and dried, thereby obtaining the acicular α-FeOOH particles coated with boron compound, cobalt compound and silicon compound. 
     Examples 79 to 90, Reference Example 13 and 14 
     Acicular α-FeOOH particles coated with various compounds were obtained in the same way as in Example 78 except that the kind of the acicular goethite particles, the kind and the content of a boron compound, the kind and the content of a cobalt compound, the kind and the content of a silicon compound and the kind or the content of an aluminum compound, if any, were varied. 
     The main conditions for producing these particles and the properties of these particles obtained are shown in Tables 9 and 10. 
     In the case of using water glass as the silicon compound for coating the acicular goethite particles, after the water glass was added to the suspension with the pH adjusted to 9.3, the suspension was stirred for 10 minutes, and then acetic acid was added to adjust the pH of the suspension to 7.0 to 7.5. 
     Production of acicular hematite particles 
     Examples 91 to 105, Comparative Examples 15 to 16 
     Example 91 
     50 g of the acicular goethite particles coated with boron compound, cobalt compound and silicon compound obtained in Example 78 were heat-treated at 400° C. in air to obtain acicular hematite particles coated with a boron oxide, a cobalt oxide and a silicon oxide. According to the observation of the electron microphotographs, the particles had an average particle length of 0.19 μm and an average aspect ratio (major axis:minor axis) of 11:1. 
     Examples 92 to 105, Reference Examples 15 and 16 
     Acicular hematite particles were obtained in the same way as in Example 91 except that the temperature in the heat-treating process was varied. 
     The main conditions for producing these particles and the properties of these particles obtained are shown in Tables 11 and 12. 
     Production of Acicular Magnetic Iron Based Alloy Particles 
     Examples 106 to 120, Reference Examples 17 and 18 
     Example 106 
     20 g of the acicular hematite particles coated with a boron oxide, a cobalt oxide and an aluminum oxide obtained in Example 91 were reduced by a hydrogen gas at 410° C. for 6 hours, thereby obtaining acicular magnetic iron based alloy particles. 
     The surfaces of the acicular magnetic iron based alloy particles obtained by reduction were coated with a stable oxide film so as to prevent rapid oxidation when they were taken out into air. As a result of X-ray fluorometry, it was found that the particles contained 4.7 mol % of B based on Fe, 4.5 mol % of Co based on Fe and 2.4 mol % of Si based on Fe (calculated as SiO 2 ). According to the observation of the electron microphotographs, the particles proved to have an average particle length of 0.15 μm and an average aspect ratio (major axis:minor axis) of 7:1. As to the magnetic characteristics, the coercive force (Hc) was 1,560 Oe, the saturation magnetization (σs) was 133 emu/g, the changes of saturation magnetization was 8.0% and the S.F.D. was 0.43. 
     Examples 107 to 120, Comparative Examples 17 and 18 
     Acicular magnetic iron based alloy particles were obtained in the same way as in Example 106 except that the kind of the acicular hematite particles and the temperature in the heat-treating process were varied. 
     The main conditions for producing these particles and the properties of these particles obtained are shown in Tables 13 and 14. 
     
                                           TABLE 1                                 
__________________________________________________________________________
Examples                                                                  
       Acicular goethite particles                                        
and                Aspect ratio                                           
                            Boron compound                                
                                          Cobalt compound                 
Comparative                                                               
       Process                                                            
            Particle                                                      
                   (Major axis:Minor                                      
                                Content                                   
                                     Existence       Content              
                                                          Existence       
Examples                                                                  
       (*)  length (μm)                                                
                   axis)    Kind                                          
                                (wt %)                                    
                                     (**) Kind       (wt                  
                                                          (**)            
__________________________________________________________________________
Example 1                                                                 
       A    0.21   12:1     H.sub.3 BO.sub.3                              
                                10   (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Example 2                                                                 
       A    0.21   12:1     H.sub.3 BO.sub.3                              
                                10   (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          22.0 (a)             
Example 3                                                                 
       A    0.21   12:1     H.sub.3 BO.sub.3                              
                                20   (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Example 4                                                                 
       A    0.21   12:1     B.sub.2 O.sub.3                               
                                5.5  (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Example 5                                                                 
       A    0.21   12:1     H.sub.3 BO.sub.3                              
                                10   (a)  Co(NO.sub.3).sub.2.6H.sub.2     
                                                     14.9 (a)             
Example 6                                                                 
       A    0.21   12:1     H.sub.3 BO.sub.3                              
                                10   (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Example 7                                                                 
       A    0.21   12:1     H.sub.3 BO.sub.3                              
                                10   (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Example 8                                                                 
       A    0.15    9:1     H.sub.3 BO.sub.3                              
                                10   (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Example 9                                                                 
       B    0.15   10:1     H.sub.3 BO.sub.3                              
                                10   (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Example 10                                                                
       B    0.22   13:1     H.sub.3 BO.sub.3                              
                                10   (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Comparative                                                               
       A    0.21   12:1     H.sub.3 BO.sub.3                              
                                2.5  (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Example 1                                                                 
Comparative                                                               
       A    0.21   12:1     --  --   --   Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Example 2                                                                 
Comparative                                                               
       A    0.21   12:1     H.sub.3 BO.sub.3                              
                                10   (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          2.8  (a)             
Example 3                                                                 
Comparative                                                               
       A    0.21   12:1     H.sub.3 BO.sub.3                              
                                10   (a)  --         --   --              
Example 4                                                                 
Comparative                                                               
       A    0.21   12:1     H.sub.3 BO.sub.3                              
                                10   (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Example 5                                                                 
Comparative                                                               
       A    0.21   12:1     H.sub.3 BO.sub.3                              
                                10   (a)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Example 6                                                                 
Comparative                                                               
       A    0.20   11:1     H.sub.3 BO.sub.3                              
                                10   (a)  Co(CH.sub.3 COO).sub.           
                                          2.4H.sub.2 O                    
                                                     13.0 (b)             
Example 7                                                                 
Comparative                                                               
       A    0.22   13:1     H.sub.3 BO.sub.3                              
                                10   (b)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (a)             
Example 8                                                                 
Comparative                                                               
       A    0.22   12:1     H.sub.3 BO.sub.3                              
                                10   (b)  Co(CH.sub.3 COO).sub.2.4H.sub.2 
                                          O          13.0 (b)             
Example 9                                                                 
__________________________________________________________________________
                       Examples and         Acicular hematite particles   
                       Comparative Heat-treatment                         
                                            Particle                      
                                                   Aspect ratio           
                       Examples    temperature (°C.)               
                                            length (μm)                
                                                   (Major axis:Minor      
__________________________________________________________________________
                                                   axis)                  
                       Example 1   400      0.19   11:1                   
                       Example 2   400      0.19   11:1                   
                       Example 3   400      0.19   11:1                   
                       Example 4   400      0.19   11:1                   
                       Example 5   400      0.19   11:1                   
                       Example 6   350      0.20   11:1                   
                       Example 7   500      0.19   10:1                   
                       Example 8   400      0.14    8:1                   
                       Example 9   400      0.12    8:1                   
                       Example 10  400      0.19   11:1                   
                       Comparative Example 1                              
                                   400      0.17   11:1                   
                       Comparative Example 2                              
                                   400      0.17   10:1                   
                       Comparative Example 3                              
                                   400      0.19   11:1                   
                       Comparative Example 4                              
                                   400      0.19   11:1                   
                       Comparative Example 5                              
                                   650      0.12    9:1                   
                       Comparative Example 6                              
                                   250      0.21   12:1                   
                       Comparative Example 7                              
                                   400      0.18   10:1                   
                       Comparative Example 8                              
                                   400      0.17   11:1                   
                       Comparative Example 9                              
                                   400      0.17   11:1                   
__________________________________________________________________________
 (Note)                                                                   
 (*) Process A: Aqueous sodium carbonate is used as aqueous alkali        
 solution.                                                                
 Process B: Aqueous sodium hydroxide is used as aqueous alkali solution.  
 (**) (a): Existent on the surfaces of acicular goethite particles.       
 (b): Existent in aqueous ferrous sulfate.                                
 
    
     
                                           TABLE 2                                 
__________________________________________________________________________
       Kind of acicular     Acicular magnetic iron                        
       hematite particle                                                  
                Heat-Treatment in                                         
                            based alloy particles                         
Examples and                                                              
       (Example No. and                                                   
                reducing atmosphere   Coercive                            
                                           Saturation                     
Comparative                                                               
       Comparative                                                        
                Temperature                                               
                       Time B/Fe Co/Fe                                    
                                      force He                            
                                           magnetization                  
Examples                                                                  
       Example No.)                                                       
                (°C.)                                              
                       (Hour)                                             
                            (mol %)                                       
                                 (mol %)                                  
                                      (Oe) σs (emu/g)               
__________________________________________________________________________
Example 11                                                                
       Example 1                                                          
                410    6    4.7  4.5  1530 133                            
Example 12                                                                
       Example 2                                                          
                390    6    4.9  7.3  1590 135                            
Example 13                                                                
       Example 3                                                          
                420    6    8.3  4.6  1550 131                            
Example 14                                                                
       Example 4                                                          
                410    6    4.6  4.5  1520 134                            
Example 15                                                                
       Example 5                                                          
                410    6    4.7  4.4  1530 133                            
Example 16                                                                
       Example 6                                                          
                410    6    4.7  4.5  1510 130                            
Example 17                                                                
       Example 7                                                          
                410    6    4.7  4.5  1540 134                            
Example 18                                                                
       Example 8                                                          
                410    6    4.7  4.5  1550 135                            
Example 19                                                                
       Example 9                                                          
                410    6    4.7  4.5  1550 134                            
Example 20                                                                
       Example 10                                                         
                410    6    4.7  4.5  1570 136                            
Comparative                                                               
       Example 1                                                          
                310    6    4.7  4.5  1210 112                            
Example 10                                                                
Comparative                                                               
       Example 2                                                          
                510    6    4.7  4.5  1180 137                            
Example 11                                                                
Comparative                                                               
       Comparative                                                        
                390    6    1.2  4.4  1100 138                            
Example 12                                                                
       Example 1                                                          
Comparative                                                               
       Comparative                                                        
                380    6    --   4.4   890 140                            
Example 13                                                                
       Example 2                                                          
Comparative                                                               
       Comparative                                                        
                410    6    4.6  1.0  1480 123                            
Example 14                                                                
       Example 3                                                          
Comparative                                                               
       Comparative                                                        
                420    6    4.5  --   1450 120                            
Example 15                                                                
       Example 4                                                          
Comparative                                                               
       Comparative                                                        
                410    6    4.7  4.5  1240 132                            
Example 16                                                                
       Example 5                                                          
Comparative                                                               
       Comparative                                                        
                410    6    4.7  4.5  1370 123                            
Example 17                                                                
       Example 6                                                          
Comparative                                                               
       Comparative                                                        
                410    6    4.7  4.5  1540 132                            
Example 18                                                                
       Example 7                                                          
Comparative                                                               
       Comparative                                                        
                390    6    1.0  4.5  1100 138                            
Example 19                                                                
       Example 8                                                          
Comparative                                                               
       Comparative                                                        
                390    6    1.1  4.5  1110 138                            
Example 20                                                                
       Example 9                                                          
__________________________________________________________________________
                 Acicular magnetic iron based alloy particles             
                 Change of                                                
Examples and     saturation   Particle                                    
                                     Aspect ratio                         
Comparative Examples                                                      
                 magnetization (%)                                        
                          S.F.D.                                          
                              length (μm)                              
                                     (Major axis:Minor axis)              
__________________________________________________________________________
Example 11       8.0      0.43                                            
                              0.15   7:1                                  
Example 12       8.0      0.42                                            
                              0.14   6:1                                  
Example 13       8.0      0.43                                            
                              0.16   7:1                                  
Example 14       8.0      0.43                                            
                              0.15   7:1                                  
Example 15       7.0      0.43                                            
                              0.15   7:1                                  
Example 16       7.0      0.44                                            
                              0.15   7:1                                  
Example 17       8.0      0.43                                            
                              0.15   7:1                                  
Example 18       8.0      0.46                                            
                              0.10   6:1                                  
Example 19       8.0      0.49                                            
                              0.10   6:1                                  
Example 20       9.0      0.48                                            
                              0.16   9:1                                  
Comparative Example 10                                                    
                 5.0      0.42                                            
                              0.15   7:1                                  
Comparative Example 11                                                    
                 15.0     0.65                                            
                              0.07   4:1                                  
Comparative Example 12                                                    
                 11.0     0.57                                            
                              0.06   3:1                                  
Comparative Example 13                                                    
                 10.0     0.66                                            
                              0.05   3:1                                  
Comparative Example 14                                                    
                 12.0     0.56                                            
                              0.16   7:1                                  
Comparative Example 15                                                    
                 14.0     0.58                                            
                              0.16   7:1                                  
Comparative Example 16                                                    
                 15.0     0.64                                            
                              0.08   5:1                                  
Comparative Example 17                                                    
                 11.0     0.53                                            
                              0.14   6:1                                  
Comparative Example 18                                                    
                 15.0     0.54                                            
                              0.15   7:1                                  
Comparative Example 19                                                    
                 13.0     0.61                                            
                              0.06   3:1                                  
Comparative Example 20                                                    
                 18.0     0.60                                            
                              0.07   3:1                                  
__________________________________________________________________________
 
    
     
                                           TABLE 3                                 
__________________________________________________________________________
Acicular goethite particles                                               
                 Aspect ratio                                             
                          Boron compound                                  
                                   Cobalt compound                        
     Process                                                              
          Particle                                                        
                 (Major axis:Minor                                        
                              Content         Content                     
Examples                                                                  
     (*)  length (μm)                                                  
                 axis)    Kind                                            
                              (wt %)                                      
                                   Kind       (wt %)                      
__________________________________________________________________________
21   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
22   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
23   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
24   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
25   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
26   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
27   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
28   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
29   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub. 2.4H.sub.2       
                                              13.0                        
30   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
31   A    0.21   12:1     B.sub.2 O.sub.3                                 
                              5.5  Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
32   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(NO.sub.3).sub.2.6H.sub.2 O          
                                              14.9                        
33   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
34   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
35   A    0.15    9:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
36   B    0.15   10:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
37   B    0.22   13:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
38   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              20.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              13.0                        
39   A    0.21   12:1     H.sub.3 BO.sub.3                                
                              10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2        
                                              22.0                        
__________________________________________________________________________
                      Aluminum compound                                   
                                   Nickel compound                        
                              Content         Content                     
                 Examples                                                 
                      Kind    (wt %)                                      
                                   Kind       (wt %)                      
__________________________________________________________________________
                 21   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              12   --         --                          
                 22   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              18   --         --                          
                 23   Alumina sol                                         
                              8.1  --         --                          
                 24   Alumina sol                                         
                              22.4 --         --                          
                 25   --      --   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              1.4                         
                 26   --      --   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              15.0                        
                 27   --      --   Ni(NO.sub.3).sub.2.6H.sub.2 O          
                                              1.7                         
                 28   --      --   Ni(NO.sub.3).sub.2.6H.sub.2 O          
                                              17.3                        
                 29   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              12   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              1.4                         
                 30   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              18   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              1.4                         
                 31   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              12   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              1.4                         
                 32   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              12   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              1.4                         
                 33   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              12   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              1.4                         
                 34   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              12   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              1.4                         
                 35   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              12   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              1.4                         
                 36   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              12   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              1.4                         
                 37   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              12   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              1.4                         
                 38   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              12   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              1.4                         
                 39   Al(NO.sub.3).sub.3.9H.sub.2 O                       
                              12   Ni(CH.sub.3 COO).sub.2.4H.sub.2        
                                              1.4                         
__________________________________________________________________________
 (Note)                                                                   
 (*) Process A: Aqueous sodium carbonate is used as aqueous alkali        
 solution.                                                                
 Process B: Aqueous sodium hydroxide is used as aqueous alkali solution.  
 
    
     
                                           TABLE 4                                 
__________________________________________________________________________
                   Boron compound                                         
                            Cobalt compound                               
Reference                                                                 
      Acicular goethite particles                                         
                       Content         Content                            
Example                                                                   
      Kind         Kind                                                   
                       (wt %)                                             
                            Kind       (wt %)                             
__________________________________________________________________________
1     The same acicular goethite                                          
                   H.sub.3 BO.sub.3                                       
                       10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2 O             
                                       13.0                               
      particles as those used in                                          
      Example 21.                                                         
2     The same acicular goethite                                          
                   H.sub.3 BO.sub.3                                       
                       10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2 O             
                                       13.0                               
      particles as those used in                                          
      Example 21.                                                         
3     The same acicular goethite                                          
                   H.sub.3 BO.sub.3                                       
                       10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2 O             
                                       13.0                               
      particles as those used in                                          
      Example 21.                                                         
4     The same acicular goethite                                          
                   H.sub.3 BO.sub.3                                       
                       10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2 O             
                                       13.0                               
      particles as those used in                                          
      Example 21.                                                         
__________________________________________________________________________
               Aluminum compound                                          
                           Nickel compound                                
         Reference     Content         Content                            
         Example                                                          
               Kind    (wt %)                                             
                            Kind       (wt %)                             
__________________________________________________________________________
         1     Al(NO.sub.3).sub.3.9H.sub.2 O                              
                       2.5  --         --                                 
         2     Al(NO.sub.3).sub.3.9H.sub.2 O                              
                       47.0 --         --                                 
         3     Al(NO.sub. 3).sub.3.9H.sub.2 O                             
                       --   Ni(CH.sub.3 COO).sub.2.4H.sub.2 O             
                                       0.3                                
         4     Al(NO.sub.3).sub.3.9H.sub.2 O                              
                       --   Ni(CH.sub.3 COO).sub.2.4H.sub.2 O             
                                       34.0                               
__________________________________________________________________________
 
    
     
                       TABLE 5                                                     
______________________________________                                    
                     Acicular hematite                                    
                    particles                                             
                                     Aspect                               
       Kind of acicular                                                   
                   Heat-             ratio                                
       goethite    treatment  Particle                                    
                                     (Major                               
       particles   Temperature                                            
                              length axis:Minor                           
Examples                                                                  
       (Example No.)                                                      
                   (°C.)                                           
                              (μm)                                     
                                     axis)                                
______________________________________                                    
40     21          400        0.19   11:1                                 
41     22          400        0.19   11:1                                 
42     23          400        0.19   11:1                                 
43     24          400        0.19   11:1                                 
44     25          400        0.19   11:1                                 
45     26          400        0.19   11:1                                 
46     27          400        0.19   11:1                                 
47     28          400        0.19   11:1                                 
48     29          400        0.19   11:1                                 
49     30          400        0.19   11:1                                 
50     31          400        0.19   11:1                                 
51     32          400        0.19   11:1                                 
52     33          350        0.20   11:1                                 
53     34          500        0.19   10:1                                 
54     35          400        0.14    8:1                                 
55     36          400        0.12    8:1                                 
56     37          400        0.19   11:1                                 
57     38          400        0.19   11:1                                 
58     39          400        0.19   11:1                                 
______________________________________                                    
 
    
     
                       TABLE 6                                                     
______________________________________                                    
                     Acicular hematite                                    
              Heat-  particles                                            
        Kind of acicular                                                  
                    treatment       Aspect ratio                          
        goethite particles                                                
                    Tempera- Particle                                     
                                    (Major                                
Reference                                                                 
        (Reference  ture     length axis:Minor                            
Examples                                                                  
        Example No.)                                                      
                    (°C.)                                          
                             (μm)                                      
                                    axis)                                 
______________________________________                                    
5       1           400      0.19   11:1                                  
6       2           400      0.19   11:1                                  
7       3           400      0.19   11:1                                  
8       4           400      0.19   11:1                                  
______________________________________                                    
 
    
     
                                           TABLE 7                                 
__________________________________________________________________________
                        Acicular magnetic iron based alloy particles      
Kind of acicular                                                          
             Heat-treatment in                          Change of         
hematite     reducing atmosphere            Coercive                      
                                                 Saturation               
                                                        saturation        
     particles                                                            
             Temperature                                                  
                    Time                                                  
                        B/Fe Co/Fe                                        
                                  Al/Fe                                   
                                       Ni/Fe                              
                                            force Hc                      
                                                 magnetization            
                                                        magnetization     
Examples                                                                  
     (Example No.)                                                        
             (°C.)                                                 
                    (hour)                                                
                        (mol %)                                           
                             (mol %)                                      
                                  (mol %)                                 
                                       (mol %)                            
                                            (Oe) σs                 
                                                        (%)u/g)           
__________________________________________________________________________
59   40      420    6   4.7  4.5  2.6  --   1540 133    8.0               
60   41      440    6   4.8  4.5  3.9  --   1520 131    8.0               
61   42      410    6   4.7  4.5  2.6  --   1530 133    8.0               
62   43      410    6   4.7  4.5  7.2  --   1530 132    7.0               
63   44      400    6   4.7  4.5  --   0.5  1540 134    8.0               
64   45      390    6   4.8  4.5  --   5.1  1530 133    8.0               
65   46      400    6   4.7  4.5  --   0.5  1540 135    8.0               
66   47      390    6   4.7  4.5  --   5.0  1520 133    8.0               
67   48      410    6   4.7  4.5  2.6  0.5  1540 134    8.0               
68   49      420    6   4.7  4.5  3.9  0.5  1520 132    8.0               
69   50      410    6   4.6  4.5  2.6  0.5  1540 133    8.0               
70   51      410    6   4.7  4.4  2.6  0.5  1530 132    8.0               
71   52      410    6   4.7  4.5  2.6  0.5  1500 130    7.0               
72   53      410    6   4.7  4.5  2.6  0.5  1550 135    8.0               
73   54      410    6   4.7  4.5  2.6  0.5  1550 135    8.0               
74   55      410    6   4.7  4.5  2.6  0.5  1550 134    8.0               
75   56      410    6   4.7  4.5  2.6  0.5  1560 136    9.0               
76   57      410    6   8.3  4.6  2.6  0.5  1570 131    8.0               
77   58      410    6   4.9  7.3  2.6  0.5  1600 138    7.0               
__________________________________________________________________________
                   Acicular magnetic iron based alloy particle            
                       Gloss (%)                                          
                       50% disper-                                        
                             100% disper-                                 
                                    Adsorbed resin                        
                                            Particle                      
                                                   Aspect ratio           
              Examples                                                    
                   S.F.D.                                                 
                       sion Time                                          
                             sion Time                                    
                                    content (g)                           
                                            length (μm)                
                                                   (Major axis:Minor      
__________________________________________________________________________
                                                   axis)                  
              59   0.42                                                   
                       110   120    1.4     0.15   7:1                    
              60   0.40                                                   
                       120   130    1.5     0.15   7:1                    
              61   0.42                                                   
                       110   120    1.4     0.15   7:1                    
              62   0.40                                                   
                       120   130    1.6     0.15   7:1                    
              63   0.43                                                   
                       100   120    1.1     0.15   7:1                    
              64   0.42                                                   
                       120   130    1.1     0.14   6:1                    
              65   0.43                                                   
                       100   120    1.1     0.15   7:1                    
              66   0.43                                                   
                       120   130    1.1     0.14   6:1                    
              67   0.42                                                   
                       120   130    1.4     0.15   7:1                    
              68   0.41                                                   
                       130   140    1.5     0.16   7:1                    
              69   0.42                                                   
                       120   130    1.4     0.15   7:1                    
              70   0.42                                                   
                       120   130    1.4     0.15   7:1                    
              71   0.42                                                   
                       120   130    1.4     0.16   7:1                    
              72   0.42                                                   
                       120   130    1.4     0.15   7:1                    
              73   0.45                                                   
                       120   130    1.4     0.10   6:1                    
              74   0.48                                                   
                       120   130    1.4     0.10   6:1                    
              75   0.47                                                   
                       120   130    1.4     0.16   9:1                    
              76   0.42                                                   
                       120   130    1.4     0.16   7:1                    
              77   0.39                                                   
                       120   130    1.4     0.14   6:1                    
__________________________________________________________________________
 
    
     
                                           TABLE 8                                 
__________________________________________________________________________
Kind of acicular        Acicular magnetic iron based alloy particles      
     hematite                                                             
             Heat-treatment in                          Change of         
Re-  particles                                                            
             reducing atmosphere            Coercive                      
                                                 Saturation               
                                                        saturation        
ference                                                                   
     (Reference                                                           
             Temperature                                                  
                    Time                                                  
                        B/Fe Co/Fe                                        
                                  Al/Fe                                   
                                       Ni/Fe                              
                                            force Hc                      
                                                 magnetization            
                                                        magnetization     
Examples                                                                  
     Example No.)                                                         
             (°C.)                                                 
                    (hour)                                                
                        (mol %)                                           
                             (mol %)                                      
                                  (mol %)                                 
                                       (mol %)                            
                                            (Oe) σs                 
                                                        (%)u/g)           
__________________________________________________________________________
9    5       410    6   4.7  4.5  0.5  --   1530 133    8.0               
10   6       450    6   4.7  4.5  10.3 --   1400 121    6.0               
11   7       410    6   4.7  4.5  --   0.1  1530 133    8.0               
12   8       380    6   4.7  4.5  --   12.0 1210 112    7.0               
__________________________________________________________________________
                   Acicular magnetic iron based alloy particles           
                       Gloss (%)                                          
             Reference 50% disper-                                        
                             100% disper-                                 
                                    Adsorbed resin                        
                                            Particle                      
                                                   Aspect ratio           
             Examples                                                     
                   S.F.D.                                                 
                       sion Time                                          
                             sion Time                                    
                                    content (g)                           
                                            length (μm)                
                                                   (Major axis:Minor      
__________________________________________________________________________
                                                   axis)                  
             9     0.43                                                   
                       70    100    1.1     0.15   7:1                    
             10    0.49                                                   
                       90    120    1.7     0.14   6:1                    
             11    0.43                                                   
                       70    100    1.1     0.15   7:1                    
             12    0.55                                                   
                       90    110    1.1     0.13   6:1                    
__________________________________________________________________________
 
    
     
                                           TABLE 9                                 
__________________________________________________________________________
Acicular goethite particles                                               
                 Aspect ratio                                             
                          Boron compound                                  
                                    Cobalt compound                       
     Process                                                              
          Particle                                                        
                 (Major axis:Minor                                        
                               Content         Content                    
Examples                                                                  
     (*)  length (μm)                                                  
                 axis)    Kind (wt %)                                     
                                    Kind       (wt %)                     
__________________________________________________________________________
78   A    0.20   13:1     H.sub.3 BO.sub.3                                
                               10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2       
                                               13.0                       
79   A    0.20   13:1     H.sub.3 BO.sub.3                                
                               10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2       
                                               13.0                       
80   A    0.20   13:1     H.sub.3 BO.sub.3                                
                               10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2       
                                               13.0                       
81   A    0.20   13:1     H.sub.3 BO.sub.3                                
                               10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2       
                                               13.0                       
82   A    0.20   13:1     H.sub.3 BO.sub.3                                
                               10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2       
                                               13.0                       
83   A    0.20   13:1     H.sub.3 BO.sub.3                                
                               10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2       
                                               13.0                       
84   A    0.20   13:1     B.sub.2 O.sub.3                                 
                               5.5  Co(CH.sub.3 COO).sub.2.4H.sub.2       
                                               13.0                       
85   A    0.20   13:1     H.sub.3 BO.sub.3                                
                               10.0 Co(NO.sub.3).sub.2.6H.sub.2 O         
                                               14.9                       
86   A    0.15   10:1     H.sub.3 BO.sub.3                                
                               10.0 Co(CH.sub.3 COO).sub.2 .4H.sub.2      
                                               13.0                       
87   B    0.15   11:1     H.sub.3 BO.sub.3                                
                               10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2       
                                               13.0                       
88   B    0.23   13:1     H.sub.3 BO.sub.3                                
                               10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2       
                                               13.0                       
89   A    0.20   13:1     H.sub.3 BO.sub.3                                
                               20.0 Co(CH.sub.3 COO).sub.2.4H.sub.2       
                                               13.0                       
90   A    0.20   13:1     H.sub.3 BO.sub.3                                
                               10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2       
                                               22.0                       
__________________________________________________________________________
                          Silicon compound                                
                                       Aluminum compound                  
                                  Content      Content                    
                     Examples                                             
                          Kind    (wt %)                                  
                                       Kind    (wt %)                     
__________________________________________________________________________
                     78   Colloidal silica                                
                                  9.5  --      --                         
                     79   Colloidal silica                                
                                  29.0 --      --                         
                     80   Colloidal silica                                
                                  19.0 Al(NO.sub.3).sub.3.9H.sub.2        
                                               12.0                       
                     81   Colloidal silica                                
                                  29.0 Alumina sol                        
                                               8.1                        
                     82   Colloidal silica                                
                                  19.0 Alumina sol                        
                                               22.4                       
                     83   Water glass                                     
                                  14.0 Alumina sol                        
                                               8.1                        
                     84   Colloidal silica                                
                                  19.0 Al(NO.sub.3).sub.3.9H.sub.2        
                                               12.0                       
                     85   Colloidal silica                                
                                  19.0 Al(NO.sub.3).sub.3.9H.sub.2        
                                               12.0                       
                     86   Colloidal silica                                
                                  19.0 Al(NO.sub.3).sub.3.9H.sub.2        
                                               12.0                       
                     87   Colloidal silica                                
                                  19.0 Al(NO.sub.3).sub.3.9H.sub.2        
                                               12.0                       
                     88   Colloidal silica                                
                                  19.0 Al(NO.sub.3).sub.3.9H.sub.2        
                                               12.0                       
                     89   Colloidal silica                                
                                  19.0 Al(NO.sub.3).sub.3.9H.sub.2        
                                               12.0                       
                     90   Colloidal silica                                
                                  19.0 Al(NO.sub.3).sub.3.9H.sub.2        
                                               12.0                       
__________________________________________________________________________
 (Note)                                                                   
 (*) Process A: Aqueous sodium carbonate is used as aqueous alkali        
 solution.                                                                
 Process B: Aqueous sodium hydroxide is used as aqueous alkali solution.  
 
    
     
                                           TABLE 10                                
__________________________________________________________________________
                   Boron compound                                         
                            Cobalt compound                               
Reference                                                                 
      Acicular goethite particles                                         
                       Content         Content                            
Examples                                                                  
      Kind         Kind                                                   
                       (wt %)                                             
                            Kind       (wt %)                             
__________________________________________________________________________
13    The same acicular goethite                                          
                   H.sub.3 BO.sub.3                                       
                       10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2 O             
                                       13.0                               
      particles as those used in                                          
      Example 78.                                                         
14    The same acicular goethite                                          
                   H.sub.3 BO.sub.3                                       
                       10.0 Co(CH.sub.3 COO).sub.2.4H.sub.2 O             
                                       13.0                               
      particles as those used in                                          
      Example 78.                                                         
__________________________________________________________________________
               Silicon compound                                           
                           Aluminum compound                              
         Reference     Content         Content                            
         Examples                                                         
               Kind    (wt %)                                             
                            Kind       (wt %)                             
__________________________________________________________________________
         13    Colloidal silica                                           
                       1.8  Al(NO.sub.3).sub.3.9H.sub.2 O                 
                                       12.0                               
         14    Colloidal silica                                           
                       48.0 Al(NO.sub.3).sub.3.9H.sub.2 O                 
                                       12.0                               
__________________________________________________________________________
 
    
     
                       TABLE 11                                                    
______________________________________                                    
                     Acicular hematite                                    
                    particles                                             
                                     Aspect                               
       Kind of acicular                                                   
                   Heat-             ratio                                
       goethite    treatment  Particle                                    
                                     (Major                               
       particles   Temperature                                            
                              length axis:Minor                           
Examples                                                                  
       (Example No.)                                                      
                   (°C.)                                           
                              (μm)                                     
                                     axis)                                
______________________________________                                    
91     78          400        0.19   11:1                                 
92     79          400        0.19   11:1                                 
93     80          400        0.19   11:1                                 
94     80          350        0.20   11:1                                 
95     80          500        0.19   10:1                                 
96     81          400        0.19   11:1                                 
97     82          400        0.19   11:1                                 
98     83          400        0.19   11:1                                 
99     84          400        0.19   11:1                                 
100    85          400        0.19   11:1                                 
101    86          400        0.14    8:1                                 
102    87          400        0.12    8:1                                 
103    88          400        0.19   11:1                                 
104    89          400        0.19   11:1                                 
105    90          400        0.19   11:1                                 
______________________________________                                    
 
    
     
                       TABLE 12                                                    
______________________________________                                    
                     Acicular hematite                                    
              Heat-  particles                                            
        Kind of acicular                                                  
                    treatment       Aspect ratio                          
        goethite particles                                                
                    Tempera- Particle                                     
                                    (Major                                
Reference                                                                 
        (Reference  ture     length axis:Minor                            
Examples                                                                  
        Example No.)                                                      
                    (°C.)                                          
                             (μm)                                      
                                    axis)                                 
______________________________________                                    
15      13          400      0.19   11:1                                  
16      14          400      0.19   11:1                                  
______________________________________                                    
 
    
     
                                           TABLE 13                                
__________________________________________________________________________
                        Acicular magnetic iron based alloy particles      
Kind of acicular                                                          
             Heat-treatment in                          Change of         
hematite     reducing atmosphere            Coercive                      
                                                 Saturation               
                                                        saturation        
     particles                                                            
             Temperature                                                  
                    Time                                                  
                        B/Fe Co/Fe                                        
                                  SiO.sub.2 /Fe                           
                                       Al/Fe                              
                                            force Hc                      
                                                 magnetization            
                                                        magnetization     
Examples                                                                  
     (Example No.)                                                        
             (°C.)                                                 
                    (hour)                                                
                        (mol %)                                           
                             (mol %)                                      
                                  (mol %)                                 
                                       (mol %)                            
                                            (Oe) σs                 
                                                        (%)u/g)           
__________________________________________________________________________
106  91      410    6   4.7  4.5  2.4  --   1560 133    8.0               
107  92      430    6   4.7  4.5  6.9  --   1620 131    5.0               
108  93      430    6   4.7  4.5  4.7  2.6  1580 133    7.0               
109  94      410    6   4.7  4.5  4.7  2.6  1540 130    6.0               
110  95      410    6   4.7  4.5  4.7  2.6  1590 135    7.0               
111  96      420    6   4.7  4.5  6.9  2.6  1610 130    5.0               
112  97      410    6   4.7  4.5  4.7  7.2  1570 132    7.0               
113  98      410    6   4.7  4.5  4.6  2.6  1580 133    7.0               
114  99      410    6   4.6  4.5  4.7  2.6  1580 132    7.0               
115  100     410    6   4.7  4.4  4.7  2.6  1570 135    7.0               
116  101     410    6   4.7  4.5  4.7  2.6  1590 135    7.0               
117  102     410    6   4.7  4.5  4.7  2.6  1590 134    7.0               
118  103     410    6   4.7  4.5  4.7  2.6  1600 135    8.0               
119  104     410    6   8.3  4.6  4.7  2.6  1610 131    8.0               
120  105     410    6   4.9  7.3  4.7  2.6  1640 138    6.0               
__________________________________________________________________________
                                Acicular magnetic iron based alloy        
                                particles                                 
                                    Specific surface                      
                                            Particle                      
                                                   Aspect ratio           
                           Examples                                       
                                S.F.D.                                    
                                    area (m.sup.2 /g)                     
                                            length (μm)                
                                                   (Major axis:Minor      
__________________________________________________________________________
                                                   axis)                  
                           106  0.43                                      
                                    49.8    0.15   7:1                    
                           107  0.44                                      
                                    53.3    0.15   7:1                    
                           108  0.42                                      
                                    51.6    0.15   7:1                    
                           109  0.42                                      
                                    52.0    0.16   7:1                    
                           110  0.42                                      
                                    51.0    0.15   7:1                    
                           111  0.42                                      
                                    55.0    0.15   7:1                    
                           112  0.40                                      
                                    57.6    0.15   7:1                    
                           113  0.42                                      
                                    51.1    0.15   7:1                    
                           114  0.42                                      
                                    51.3    0.15   7:1                    
                           115  0.41                                      
                                    51.1    0.15   7:1                    
                           116  0.45                                      
                                    49.9    0.10   6:1                    
                           117  0.48                                      
                                    51.3    0.10   6:1                    
                           118  0.47                                      
                                    54.5    0.16   9:1                    
                           119  0.42                                      
                                    51.0    0.16   7:1                    
                           120  0.40                                      
                                    50.9    0.14   6:1                    
__________________________________________________________________________
 
    
     
                                           TABLE 14                                
__________________________________________________________________________
Kind of acicular        Acicular magnetic iron based alloy particles      
     hematite                                                             
             Heat-treatment in                          Change of         
Re-  particles                                                            
             reducing atmosphere            Coercive                      
                                                 Saturation               
                                                        saturation        
ference                                                                   
     (Reference                                                           
             Temperature                                                  
                    Time                                                  
                        B/Fe Co/Fe                                        
                                  SiO.sub.2 /Fe                           
                                       Al/Fe                              
                                            force Hc                      
                                                 magnetization            
                                                        magnetization     
Examples                                                                  
     Example No.)                                                         
             (°C.)                                                 
                    (hour)                                                
                        (mol %)                                           
                             (mol %)                                      
                                  (mol %)                                 
                                       (mol %)                            
                                            (Oe) σs                 
                                                        (%)u/g)           
__________________________________________________________________________
17   15      410    6   4.7  4.5  0.5  2.6  1530 133    8.0               
18   16      450    6   4.7  4.5  11.4 2.6  1600 98     5.0               
__________________________________________________________________________
                                Acicular magnetic iron based alloy        
                                particles                                 
                          Reference Specific surface                      
                                            Particle                      
                                                   Aspect ratio           
                          Examples                                        
                                S.F.D.                                    
                                    area (m.sup.2 /g)                     
                                            length (μm)                
                                                   (Major axis:Minor      
__________________________________________________________________________
                                                   axis)                  
                          17    0.43                                      
                                    43.2    0.15   7:1                    
                          18    0.56                                      
                                    62.4    0.16   8:1                    
__________________________________________________________________________