Non-aqueous electrolyte secondary battery and method for producing anode therefor
BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to a non-aqueous electrolyte secondary battery and a method for producing an anode therefor. In particular, the present invention is concerned with a carbon material for constituting the anode. 
     2. Description of the Prior Art 
     The non-aqueous electrolyte secondary batteries having anodes configured with an alkali metal such as lithium and the like have a high electromotive force (EMF), and are expected to have a high energy density as compared with that of the conventional nickel-cadmium batteries or lead-acid batteries. Therefore, researches have been made increasingly to develop the batteries of this category. In particular, a number of such researches have heretofore been made on the non-aqueous electrolyte battery having an anode configured with lithium. If Li as the alkali metal is used for its anode in a metal state, dendrite formation occurs in the course of charging process of the batteries configured with Li anodes, which renders problems of short-circuiting and poor reliability in such batteries. 
     In order to cope with these problems, an investigation has been made on an anode configured with an alloy of lithium of alkali metal and aluminum or lead. In such alloy anode, Li is absorbed in the anode alloy in the course of charging process and no dendrite develops. Thus, a battery having a higher reliability is produced. However, the discharge potential of such alloy anode is more noble by about 0.5 V than that of metal Li, the cell voltage of the battery configured with this alloy anode is lower by 0.5 V than that of the battery configured with the metal Li anode, which results in a lower energy density. 
     On the other hand, researches have been made on an anode configured with an intercalation compound of carbon which contains Li atoms intercalated therein. In this compound anode, Li is intercalated between the layers of carbon by charging, whereby the dendrite formation is effectively prevented. The discharge potential of this compound anode is noble only by about 0.1 V as compared with that of metal Li anode, and therefore, the decrease in the cell voltage of the battery is small. For the above-stated reasons, this compound anode can be regarded as a more preferable anode. 
     This compound anode, however, has a serious disadvantage. That is, the maximum amount of Li that can be intercalated in the carbon by charging is limited to the amount corresponding to a stoichiometric amount of C 6  Li, and in that case, the electric capacity of this compound anode amounts to 372 Ah/kg. In the charging-discharging cycle of a normal battery, the electric capacity of the anode is as small as 230 Ah/kg. 
     SUMMARY OF THE INVENTION 
     The object of the present invention is to provide a highly reliable non-aqueous electrolyte secondary battery having a higher energy density and free from short-circuiting due to the dendrite formation, for overcoming the above-mentioned disadvantages and deficiency of the prior art. 
     Another object of the present invention is to provide a method for producing an anode which can give such a non-aqueous electrolyte secondary battery. 
     The present invention provides a non-aqueous electrolyte secondary battery comprising a cathode capable of being charged and discharged, a non-aqueous electrolyte, and an anode capable of being charged and discharged, wherein the anode comprises a carbon material containing at least one member selected from the group consisting of 7-35 wt % of sulfur, 6.5-25 wt % of oxygen and 10.5-18.3 wt % of nitrogen, provided that if the carbon material contains at least two of these elements, the total amount of the elements does not exceed 35 wt %. 
     In one aspect of the present invention, the carbon material is the carbon residue of a thermal decomposition reaction of an organic compound containing at least one of sulfur, oxygen and nitrogen. 
     The method for producing an anode for a non-aqueous electrolyte secondary battery in accordance with the present invention comprises the step of heating an organic compound including at least one member selected from the group consisting of sulfur, oxygen, and nitrogen, together with at least one member selected from the group consisting of a metal halide and halogen in an inert atmosphere at 500°-1,400° C., thereby to obtain a carbon material containing at least one member selected from the group consisting of sulfur, oxygen, and nitrogen. 
     As the above-mentioned organic compound, a compound selected from the group consisting of a cyclic compound, a chain compound, derivatives thereof, and polymers thereof is employed. 
     According to the present invention, it is possible to obtain a highly reliable non-aqueous electrolyte secondary battery having a higher energy density having an excellent charge-discharge cycle characteristic, free from short-circuiting due to the dendrite formation. 
     While the novel features of the present invention are set forth particularly in the appended claims, the invention, both as to organization and content, will be better understood and appreciated, along with other objects and features thereof, from the following detailed description taken in conjunction with the attached drawings. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     FIG. 1 is a longitudinal cross-sectional view showing a non-aqueous electrolyte secondary battery in accordance one embodiment of the present invention. 
     FIG. 2 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing sulfur at various proportions. 
     FIG. 3 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing sulfur at various proportions. 
     FIG. 4 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing sulfur at various proportions. 
     FIG. 5 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing sulfur at various proportions. 
     FIG. 6 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing sulfur at various proportions. 
     FIG. 7 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing sulfur at various proportions. 
     FIG. 8 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing sulfur at various proportions. 
     FIG. 9 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing oxygen at various proportions. 
     FIG. 10 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing oxygen at various proportions. 
     FIG. 11 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing oxygen at various proportions. 
     FIG. 12 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing oxygen at various proportions. 
     FIG. 13 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing oxygen at various proportions. 
     FIG. 14 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing oxygen at various proportions. 
     FIG. 15 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing oxygen at various proportions. 
     FIG. 16 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing nitrogen at various proportions. 
     FIG. 17 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing nitrogen at various proportions. 
     FIG. 18 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing nitrogen at various proportions. 
     FIG. 19 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing nitrogen at various proportions. 
     FIG. 20 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing nitrogen at various proportions. 
     FIG. 21 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing nitrogen at various proportions. 
     FIG. 22 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing nitrogen at various proportions. 
     FIG. 23 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing nitrogen at various proportions. 
     FIG. 24 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing nitrogen at various proportions. 
     FIG. 25 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing nitrogen at various proportions. 
     FIG. 26 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing nitrogen at various proportions. 
     FIG. 27 is a diagram showing discharge curves at the first cycle of batteries configured with anodes comprising carbon materials containing nitrogen at various proportions. 
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     In the present study, it was found that when a carbon material containing at least one member of sulfur, oxygen or nitrogen is charged in a non-aqueous electrolyte containing an alkali metal ion such as Li + , Na +   or the like, the alkali metal is absorbed or intercalated in an anode in a manner similar to that of the prior art carbon anode, and when discharged, the absorbed alkali metal is released to the electrolyte in ionic state. In this manner, the alkali metal does not precipitate and a short-circuiting due to the dendrite formation will not occur. 
     It is considered that since the alkali metal ion absorbed or intercalated in the carbon material containing at least one member of sulfur, oxygen or nitrogen during the charging process is supplied with an electron from sulfur, oxygen or nitrogen possessing more electrons on the outermost orbit than carbon, the carbon material containing at least one member of sulfur, oxygen or nitrogen may constitute a stable compound. Therefore, the carbon material containing at least one member of sulfur, oxygen or nitrogen gives a higher capacity to an anode configured with the carbon material than that of the prior art carbon anode. 
     The sulfur content in the carbon material is suitably in a range of 7-35 wt %. The oxygen content in the carbon material is suitably in a range of 6.5-25 wt %, and the nitrogen content in the carbon material is suitably in a range of 10.5-18.3 wt %. If the content of sulfur, oxygen or nitrogen is less than the minimal value of the above-mentioned ranges, the capacity of the anode configured with the carbon material is small. On the contrary, if the content of sulfur, oxygen or nitrogen is more than the maximum value of the above-stated ranges, the charge-discharge cycle characteristic of the anode configured with the carbon material is deteriorated. More preferable range of sulfur is 10-35 wt %, and 15-35 wt % is most preferable. More preferable range of oxygen is 10-25 wt %, and 15-25 wt % is most preferable. Further, more preferable range of nitrogen is 13.5-18.3 wt %. 
     For the synthesis of the carbon material containing sulfur, it is preferable to employ, as its starting material, a heterocyclic compound containing one or more sulfur atoms such as thiophene, tetrahydrothiophene, polythiophene, thian, dithian, trithian, thiophthene, benzothiophene, thianthrene, derivatives thereof, polymers thereof, or the like. 
     Further, it is preferable to employ a chain compound containing one or more sulfur atoms such as methane thiol, ethane thiol, propane thiol, butane thiol, hexane thiol, heptane thiol, ethane dithiol, propane dithiol, dimethyl sulfide, diethyl sulfide, dipropyl sulfide, dimethyl disulfide, diethyl disulfide, dipropyl disulfide, derivatives thereof, polymers thereof, or the like. 
     For the synthesis of carbon materials containing oxygen, it is preferable to employ, as its starting material, a cyclic compound containing one or more oxygen atoms such as furan, polyfuran, tetrahydrofuran, pyran, dioxane, trioxane, dioxolan, oxolan, benzofuran, butyrolactone, chromene, chroman, benzoquinone, naphthol, naphthoquinone, phenol, phenolic resin, derivatives thereof, polymers thereof, or the like. 
     Further, it is preferable to employ a chain compound containing one or more oxygen atoms such as polyethers of polyethylene oxide, polypropylene oxide or the like, polyesters of polyethylene terephthalate, alkyd resin, maleic acid resin or the like, a polymer or copolymer of polyvinyl alcohol, alcohols such as ethanol or the like, aldehydes of acetoaldehyde or the like, or carboxylic acids such as acetic acid or the like. 
     For the synthesis of carbon materials containing nitrogen, it is preferable to employ, as its starting material, a cyclic compound containing one or more nitrogen atoms such as aniline or the like, or derivatives thereof, or polymers thereof, and a heterocyclic compound containing one or more nitrogen atoms such as pyrrole, polypyrrole, piperazine, pyrazine, pyrazole, triazine, triazole, quinoline, tetrahydroquinone, melamine, derivatives thereof, polymers thereof, or the like. 
     Further, it is preferable to employ a chain compound containing one or more nitrogen atoms such as dimethyl formamide, a chain nitrile or its derivative represented by acetonitrile, acrylonitrile, propionitrile, butyronitrile, pentanonitrile, polyacrylonitrile or its copolymerized product, or the like. 
     When heated, halogen or halide reacts with hydrogen in these compounds and releases hydrogen as a hydrogen halide, and thus has a function of preventing escape of sulfur, oxygen or nitrogen from the raw material. As the halogen, chlorine is preferable. As the halide, cupric or cuprous chloride, ferric or ferrous chloride, a nickel chloride and a palladium chloride are preferable. 
     In view of the capacity and the charge-discharge cycle performance, the heating temperature is preferably in a range of 500° C.-1400° C. If the temperature is lower than the above-mentioned range, the synthesis reaction does not proceed sufficiently. On the contrary, if the reaction temperature is higher than the above-mentioned range, sulfur, oxygen or nitrogen tends to be released from the carbon material, resulting in a decrease of the capacity of the anode configured with the obtained carbon material. A more preferable range of the heating temperature is 600°-1,000° C. 
     In the following paragraphs, the present invention will be described in more detail by way of examples with reference to the attached drawings. 
     EXAMPLE 1 
     In this example, a carbon material containing sulfur was synthesized in a reaction vessel by heating the starting material of thiophene or polythiophene which is a heterocyclic compound containing one or more sulfur atoms with chlorine, or methane thiol or dimethyl sulfide which is a chain compound containing a sulfur atom with chlorine, and the characteristic of thus obtained carbon material as an anode was investigated. 
     Further, as a comparative example, thermally decomposed or pyrolyzed carbon was obtained by introducing only benzene into a reaction tube, and was investigated in a similar manner. 
     First, the carbon material containing sulfur was synthesized in the following manner. 
     As the reaction vessel, a quartz tube was used. The reaction temperature was fixed at 900° C. After evacuating the reaction tube, the inside pressure of the reaction tube was returned to atmospheric pressure with nitrogen. Then, each of the starting materials of various proportions was introduced into the reaction tube, thereby to synthesize each of the carbon materials containing sulfur at various proportions as listed in Tables 1-4 below. In this process, thiophene, methane thiol and dimethyl sulfide were vaporized by heating and the resultant vaporized gases were introduced into the reaction tube using nitrogen as the carrier gas. In case of polythiophene, polythiphene was placed in the center of the reaction tube before introduction of chlorine. 
     
                       TABLE 1                                                     
______________________________________                                    
Sulfur Content Supply Amount (mole/hour)                                  
(wt %)         thiophene  chlorine                                        
______________________________________                                    
45             0.022      0.100                                           
35             0.042      0.100                                           
15             0.153      0.100                                           
7              0.352      0.100                                           
4              0.654      0.100                                           
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                       TABLE 2                                                     
______________________________________                                    
Sulfur Content Supply Amount (mole/hour)                                  
(wt %)         methane thiol                                              
                          chlorine                                        
______________________________________                                    
45             0.015      0.05                                            
35             0.020      0.05                                            
15             0.078      0.05                                            
7              0.176      0.05                                            
4              0.350      0.05                                            
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                       TABLE 3                                                     
______________________________________                                    
Sulfur Content Supply Amount (mole/hour)                                  
(wt %)         dimethyl sulfide                                           
                           chlorine                                       
______________________________________                                    
45             0.015       0.07                                           
35             0.020       0.07                                           
15             0.077       0.07                                           
7              0.177       0.07                                           
4              0.338       0.07                                           
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                       TABLE 4                                                     
______________________________________                                    
Sulfur Content Supply Amount (mole/hour)                                  
(wt %)         polythiophene                                              
                          chlorine                                        
______________________________________                                    
45             0.043      0.100                                           
35             0.062      0.100                                           
15             0.225      0.100                                           
7              0.526      0.100                                           
4              0.984      0.100                                           
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     Next, an anode plate was prepared as follows: after adding 10 g of polyvinylidene fluoride as a binder to 100 g of one of the sulfur containing carbon powders obtained in the above-mentioned manner, the resultant mixture was made into a paste by the use of dimethyl formamide, and then thus obtained paste was coated on a core material of nickel, and dried and rolled. 
     A cathode plate, on the other hand, was prepared as follows: after adding 10 g of carbon powder as the electrically conductive agent and 5 g of polyvinylidene fluoride as the binder to 100 g of LiMn 2  O 4  as the cathode active material, the resultant mixture was made into a paste by the use of dimethyl formamide, and then thus obtained paste was coated on a core material of titanium, and dried and rolled. 
     Then, an electrode assembly was configured by rolling up the above-mentioned anode plate together with the cathode plate and a separator made of porous propylene film, with the separator being interposed between the two electrodes to provide a spiral roll of electrodes. This spiral roll of electrodes was then assembled into a battery as shown in FIG. 1. 
     In FIG. 1, numeral 1 designates the cathode plate, numeral 2 the anode plate and numeral 3 the separator, respectively. The cathode plate 1 and the anode plate 2, respectively, have lead conductors 4 and 5 comprising the same materials as the core materials of the respective electrode plates. The spirally rolled-up electrode assembly is inserted in a vessel 8 with electrically insulating disks 6 and 7 made of polypropylene disposed on its top and bottom. After placing the electrode assembly in the vessel 8, which is then roll-grooved at its shoulder part, a non-aqueous electrolyte comprising propylene carbonate which dissolves lithium perchlorate (LiClO 4 ) by 1 mole/l is injected into the vessel. The vessel 8 is sealed with a sealing disk 9 of synthetic resin provided with a cathode terminal 10 by roll-caulking. 
     By employing the pyrolyzed carbon obtained from benzene of the comparative example, another anode was prepared similarly, and a battery was configured with this anode. 
     Batteries configured with the anodes of carbons each having a sulfur content of 4 wt %, 7 wt %, 15 wt %, 35 wt %, and 45 wt % are named &#34;a&#34;, &#34;b&#34;, &#34;c&#34;, &#34;d&#34;, and &#34;e&#34;, respectively. Further, a battery configured with the anode of the pyrolyzed carbon is named &#34;f&#34;. These batteries have a larger electric capacity in the cathode. The capacity of the batteries is determined by the capacity of the respective anodes. 
     Charge-discharge cycles were repeated for each of the batteries by charging it at a constant current of 0.5 mA/cm 2  up to 4.4 V and discharging it as low as 2.5 V. FIG. 2 through FIG. 5 each show the discharge curve at the first cycle. Further, Table 5 through Table 8 below each list the discharge capacity at the first cycle and the discharge capacity at the 500th cycle, as well as the maintenance rate of the discharge capacity at the 500th cycle to the first cycle. In each table, the discharge capacity represents the capacity for 1 g of the carbon anode containing sulfur or the pyrolyzed carbon anode (comparative example). 
     
                       TABLE 5                                                     
______________________________________                                    
         thiophen + chlorine (Present Invention)                          
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Sulfur Content                                                            
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
45         350            186 (53)                                        
35         343            254 (74)                                        
15         311            250 (80)                                        
 7         260            234 (90)                                        
 4         201            191 (95)                                        
C (Comparative                                                            
           170            165 (97)                                        
Example)                                                                  
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                       TABLE 6                                                     
______________________________________                                    
         methane thiol + chlorine (Present Invention)                     
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Sulfur Content                                                            
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
45         345            172 (50)                                        
35         330            254 (77)                                        
15         302            248 (82)                                        
 7         243            221 (91)                                        
 4         195            185 (95)                                        
C (Comparative                                                            
           170            165 (97)                                        
Example)                                                                  
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                       TABLE 7                                                     
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        dimethyl sulfide + chlorine (Present Invention)                   
                          Discharge capacity at                           
          Discharge capacity                                              
                          500th cycle (mAh/g)                             
Sulfur Content                                                            
          at first cycle  (capacity maintenance                           
(wt %)    (mAh/g)         rate (%))                                       
______________________________________                                    
45        330             168 (51)                                        
35        321             244 (76)                                        
15        300             249 (83)                                        
 7        245             218 (89)                                        
 4        193             181 (94)                                        
C (Comparative                                                            
          170             165 (97)                                        
Example)                                                                  
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                       TABLE 8                                                     
______________________________________                                    
         polythiophene + chlorine (Present Invention)                     
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Sulfur Content                                                            
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
45         361            180 (50)                                        
35         358            286 (80)                                        
15         324            275 (85)                                        
 7         270            248 (92)                                        
 4         215            206 (96)                                        
C (Comparative                                                            
           170            165 (97)                                        
Example)                                                                  
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     As clearly shown in these tables, each of the initial discharge capacities of the batteries configured with the anodes of the carbon materials containing sulfur is large as compared with that of the battery configured with the anode of the pyrolyzed carbon obtained from benzene. Furthermore, the initial capacity increases with the increase in the sulfur content in each of the batteries. On the other hand, the capacity maintenance rate decreases with the increase in the sulfur content. 
     The carbon anode containing sulfur by only 4 wt %, which is not sufficiently large, showed a capacity and a capacity maintenance rate substantially equivalent to those of the pyrolyzed carbon anode. 
     In view of the capacity and the charge-discharge performance required for a secondary battery, it is concluded that an electrode configured with the carbon material containing sulfur by 7-35 wt % is excellent as an anode for a non-aqueous electrolyte secondary battery. 
     EXAMPLE 2 
     In this example, a carbon material containing sulfur was synthesized in a reaction vessel by heating the starting material of dithian, which is a heterocyclic compound containing two sulfur atoms with cupric chloride, or ethane thiol, which is a chain compound containing a sulfur atom with ferric chloride. 
     The method for synthesizing the carbon material containing sulfur was similar to that of Example 1, except that cupric chloride and ferric chloride was introduced into the central part of the reaction tube in advance. Further, in cases of dithian and ethane thiol, they were heated to vaporize in advance and the vaporized gases were introduced into the reaction tube by using nitrogen as the carrier gas. Moreover, in case of cuptic chloride, the produced carbon material containing sulfur was deposited on the surface of the cupric chloride in a molten state. 
     On the other hand, the ferric chloride was vaporized and allowed to react with ethane thiol in a gas phase. In either case, only the produced carbon material containing sulfur was separated from the reaction mixture for configuring the anode. Each of Table 9 and Table 10 below lists the respective supplying proportion of dithian and cupric chloride of raw materials and the sulfur content in the produced carbon material. 
     
                       TABLE 9                                                     
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Sulfur Content Supply Amount (mole/hour)                                  
(wt %)         dithian  cupric chloride                                   
______________________________________                                    
45             0.032    0.20                                              
35             0.050    0.20                                              
15             0.188    0.20                                              
7              0.439    0.20                                              
4              0.803    0.20                                              
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                       TABLE 10                                                    
______________________________________                                    
Sulfur Content Supply Amount (mole/hour)                                  
(wt %)         ethane thiol                                               
                         ferric chloride                                  
______________________________________                                    
45             0.063     0.30                                             
35             0.080     0.30                                             
15             0.304     0.30                                             
7              0.704     0.30                                             
4              1.282     0.30                                             
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     By employing each of the synthesized carbon materials, a secondary battery was configured in a manner similar to that of Example 1, and the capacity and the charge-discharge performance were investigated. 
     Batteries configured with the anodes of the carbons each having a sulfur content of 4 wt %, 7 wt %, 15 wt %, 35 wt %, and 45 wt % are named &#34;g&#34;, &#34;h&#34;, &#34;i&#34;, &#34;j&#34;, and &#34;k&#34;, respectively. 
     Charge-discharge cycles were repeated for each of the batteries by charging it at a constant current of 0.5 mA/cm 2  up to 4.4 V and discharging it as low as 2.5 V. FIG. 6 and FIG. 7 each show the discharge curve at the first cycle. Further, Table 11 and Table 12 below list the discharge capacity at the first cycle and the discharge capacity at the 500th cycle, as well as the maintenance rate of the discharge capacity at the 500th cycle to the first cycle. In each table, the discharge capacity represents the capacity for 1 g of the carbon anode containing sulfur. 
     
                       TABLE 11                                                    
______________________________________                                    
        cupric chloride + chlorine (Present Invention)                    
                          Discharge capacity at                           
          Discharge capacity                                              
                          500th cycle (mAh/g)                             
Sulfur Content                                                            
          at first cycle  (capacity maintenance                           
(wt %)    (mAh/g)         rate (%))                                       
______________________________________                                    
45        340             177 (52)                                        
35        334             251 (75)                                        
15        307             252 (82)                                        
7         253             225 (89)                                        
4         198             186 (94)                                        
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                       TABLE 12                                                    
______________________________________                                    
         ethane thiol + ferric chloride                                   
         (Present Invention)                                              
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Sulfur Content                                                            
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
45         343            175 (51)                                        
35         335            251 (75)                                        
15         309            247 (80)                                        
7          250            215 (86)                                        
4          193            179 (93)                                        
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     As clearly shown in these tables, the initial discharge capacity increases with the increase in the sulfur content in each battery. On the other hand, the capacity maintenance rate decreases with the increase in the sulfur content. 
     The carbon anode containing sulfur by only 4 wt %, which is not sufficiently large, showed a capacity and a capacity maintenance rate substantially equivalent to those of the pyrolyzed carbon anode. 
     In view of the capacity and the charge-discharge performance required for a secondary battery, it is concluded that an electrode configured with the carbon material containing sulfur by 7-35 wt % is excellent as an anode for a non-aqueous electrolyte secondary battery. 
     EXAMPLE 3 
     While Li was used as an alkali metal to be intercalated in Example 1 and Example 2, sodium was used in this example. For the anodes of this example, carbon materials each having a sulfur content of 4 wt %, 7 wt %, 15 wt %, 35 wt %, and 45 wt % synthesized from polythiophene and chlorine of Example 1 were used. The procedure identical to that of Example 1 was followed except for the use of NaNiO 2  as the cathode active material and propylene carbonate which dissolved sodium perchlorate (NaClO 4 ) by 1 mole/l as the non-aqueous electrolyte. 
     By employing the pyrolyzed carbon obtained from benzene of the comparative example, another anode was prepared similarly, and a battery was configured with this anode. 
     Batteries configured with the anodes of the carbons each having a sulfur content of 4 wt %, 7 wt %, 15 wt %, 35 wt %, and 45 wt % are named &#34;l&#34;, &#34;m&#34;, &#34;n&#34;, &#34;o&#34;, and &#34;p&#34;, respectively. Further, a battery configured with the anode of the pyrolyzed carbon is named &#34;q&#34;. These batteries have a larger electric capacity in their cathode. The capacity of each of the batteries is determined by the capacity of the anodes. 
     Charge-discharge cycles were repeated for each of the batteries by charging it at a constant current of 0.5 mA/cm 2  up to 4.0 V and discharging it as low as 2.5 V. FIG. 8 shows the discharge curve at the first cycle. Further, Table 13 below lists the discharge capacity at the first cycle and the discharge capacity at the 500th cycle, as well as the maintenance rate of the discharge capacity at the 500th cycle to the first cycle. 
     
                       TABLE 13                                                    
______________________________________                                    
         polythiophene + chlorine (Present Invention)                     
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Sulfur Content                                                            
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
45         349            181 (52)                                        
35         343            264 (77)                                        
15         307            246 (80)                                        
 7         254            218 (86)                                        
 4         198            182 (92)                                        
C (Comparative                                                            
           152            143 (94)                                        
Example)                                                                  
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     As clearly shown in the table, the initial discharge capacity of the batteries configured with the anodes of the carbons containing sulfur is large as compared with that of the battery configured with the anode of the pyrolyzed carbon obtained from benzene. Moreover, the initial capacity increases with the increase in the sulfur content. On the other hand, the capacity maintenance rate decreases with the increase in the sulfur content. 
     The carbon anode containing sulfur by only 4 wt %, which is not sufficiently large, showed a capacity and a capacity maintenance rate substantially equivalent to those of the pyrolyzed carbon anode. 
     In view of the capacity and the charge-discharge performance required for a secondary battery, it is concluded that an electrode configured with the carbon material containing sulfur by 7-35 wt % is excellent as an anode for a non-aqueous electrolyte secondary battery. 
     As apparent from the above-mentioned results, even if Na is employed in the anode as the alkali metal to be absorbed or intercalated by charging, the electrode configured with the carbon material containing sulfur gives an excellent anode for a non-aqueous electrolyte secondary battery. 
     Although the description is limited to the anode configured with the carbon material synthesized from polythiophene and chlorine of Example 3 as the starting material, it is confirmed that a similar advantage is obtained with any anodes shown in Example 1 and Example 2 in a non-aqueous electrolyte secondary battery having an alkali metal of Na. 
     Although the description is limited to the anodes configured with the carbon materials synthesized from thiophene, methane thiol, dimethyl sulfide, polythiophene, dithian and ethane thiol of Example 1 through Example 3 as the starting material, it is confirmed that a similar advantage is obtained with any anodes configured with the carbon material synthesized from a heterocyclic compound containing one or more sulfur atoms such as tetrahydrothiophene, thian, trithian, thiophthene, benzothiophene, thianthrene or the like, derivatives thereof, polymers thereof or the like, and a chain compound containing one or more sulfur atoms such as propane thiol, butane thiol, hexane thiol, heptane thiol, ethane dithiol, propane dithiol, dimethyl sulfide, diethyl sulfide, dipropyl sulfide, dimethyl disulfide, diethyl disulfide, dipropyl disulfide, or the like, derivatives thereof, polymers thereof or the like, as the starting material. 
     EXAMPLE 4 
     In this example, a carbon material containing oxygen was synthesized in a reaction vessel by heating the starting material of furan, polyfuran or pyran, which is a heterocyclic compound containing one or more oxygen atoms with chlorine, or a polyethylene oxide, which is a chain compound with chlorine, and its characteristic as an anode was investigated. 
     Further, as a comparative example, another investigation was made on an electrode configured with a thermally decomposed or pyrolyzed carbon obtained from benzene. 
     First, the carbon material containing oxygen was synthesized in the following manner. 
     As the reaction vessel, a quartz tube was used and the reaction temperature was fixed at 750° C. After evacuating the reaction tube, the inside pressure of the reaction tube was returned to atmospheric pressure with nitrogen, and each of the starting materials of various proportions was introduced into the reaction tube to synthesize each of the carbon materials containing oxygen at various proportions as listed in Table 14 through Table 17 below. In this process, furan and pyran were vaporized by heating and the resultant vaporized gases were introduced into the reaction tube by using nitrogen as the carrier gas. Further, in the case of polyfuran and polyethylene oxide, they were placed in the center of the reaction tube before introduction of chlorine. 
     
                       TABLE 14                                                    
______________________________________                                    
Oxygen Content Supply Amount (mole/hour)                                  
(wt %)         furan     chlorine                                         
______________________________________                                    
30             0.020     0.08                                             
25             0.031     0.08                                             
10             0.098     0.08                                             
6.5            0.198     0.08                                             
3              0.341     0.08                                             
______________________________________                                    
 
    
     
                       TABLE 15                                                    
______________________________________                                    
Oxygen Content Supply Amount (mole/hour)                                  
(wt %)         pyran      chlorine                                        
______________________________________                                    
30             0.018      0.10                                            
25             0.029      0.10                                            
10             0.089      0.10                                            
6.5            0.181      0.10                                            
3              0.313      0.10                                            
______________________________________                                    
 
    
     
                       TABLE 16                                                    
______________________________________                                    
Oxygen Content Supply Amount (mole/hour)                                  
(wt %)         polyfuran  chlorine                                        
______________________________________                                    
30             0.024      0.07                                            
25             0.035      0.07                                            
10             0.112      0.07                                            
6.5            0.224      0.07                                            
3              0.388      0.07                                            
______________________________________                                    
 
    
     
                       TABLE 17                                                    
______________________________________                                    
Oxygen Content                                                            
             Supply Amount (mole/hour)                                    
(wt %)        polyethylene oxide                                          
                            chlorine                                      
______________________________________                                    
30            0.030         0.10                                          
25            0.043         0.10                                          
10            0.138         0.10                                          
6.5           0.275         0.10                                          
3             0.495         0.10                                          
______________________________________                                    
 
    
     Next, an anode plate was prepared by using each of the listed carbon materials in a manner similar to that in Example 1, and a secondary battery was assembled with the anode to investigate the capacity and the charge-discharge performance. 
     Batteries configured with the anodes of the carbons each having an oxygen content of 3 wt %, 6.5 wt %, wt %, 25 wt %, and 30 wt % are named &#34;A&#34;, &#34;B&#34;, &#34;C&#34;, &#34;D&#34;, and &#34;E&#34;, respectively. Further, a battery configured with the anode of the pyrolyzed carbon is named &#34;F&#34;. These batteries have a larger electric capacity in their cathode. The capacity of the batteries is determined by the capacity of the respective anodes. 
     Charge-discharge cycles were repeated for each of the batteries by charging it at a constant current of 0.5 mA/cm 2  up to 4.4 V and discharging it as low as 3.0 V. FIG. 9 through FIG. 12 each show the discharge curve at the first cycle. Further, Table 18 through Table 21 below each list the discharge capacity at the first cycle and the discharge capacity at the 500th cycle, as well as the maintenance rate of the discharge capacity at the 500th cycle to the first cycle. In each table, the discharge capacity represents the capacity for 1 g of the carbon anode containing oxygen or the pyrolyzed carbon anode (comparative example). 
     
                       TABLE 18                                                    
______________________________________                                    
          furan + chlorine (Present Invention)                            
                          Discharge capacity at                           
            Discharge capacity                                            
                          500th cycle (mAh/g)                             
Oxygen Content                                                            
            at first cycle                                                
                          (capacity maintenance                           
(wt %)      (mAh/g)       rate (%))                                       
______________________________________                                    
30          348           181 (52)                                        
25          341           266 (78)                                        
10          321           266 (83)                                        
  6.5       248           221 (89)                                        
 3          175           166 (95)                                        
C (Comparative                                                            
            163           156 (96)                                        
Example)                                                                  
______________________________________                                    
 
    
     
                       TABLE 19                                                    
______________________________________                                    
          pyran + chlorine (Present Invention)                            
                          Discharge capacity at                           
            Discharge capacity                                            
                          500th cycle (mAh/g)                             
Oxygen Content                                                            
            at first cycle                                                
                          (capacity maintenance                           
(wt %)      (mAh/g)       rate (%))                                       
______________________________________                                    
30          340           170 (50)                                        
25          330           244 (74)                                        
10          312           256 (82)                                        
  6.5       242           208 (86)                                        
 3          173           163 (94)                                        
C (Comparative                                                            
            163           156 (96)                                        
Example)                                                                  
______________________________________                                    
 
    
     
                       TABLE 20                                                    
______________________________________                                    
          polyfuran + chlorine (Present Invention)                        
                          Discharge capacity at                           
            Discharge capacity                                            
                          500th cycle (mAh/g)                             
Oxygen Content                                                            
            at first cycle                                                
                          (capacity maintenance                           
(wt %)      (mAh/g)       rate (%))                                       
______________________________________                                    
30          355           185 (52)                                        
25          348           268 (77)                                        
10          324           269 (83)                                        
  6.5       256           220 (86)                                        
 3          179           170 (95)                                        
C (Comparative                                                            
            163           156 (96)                                        
Example)                                                                  
______________________________________                                    
 
    
     
                       TABLE 21                                                    
______________________________________                                    
          polyethylene oxide + chlorine                                   
          (Present Invention)                                             
                          Discharge capacity at                           
            Discharge capacity                                            
                          500th cycle (mAh/g)                             
Oxygen Content                                                            
            at first cycle                                                
                          (capacity maintenance                           
(wt %)      (mAh/g)       rate (%))                                       
______________________________________                                    
30          350           186 (53)                                        
25          342           257 (75)                                        
10          319           258 (81)                                        
  6.5       247           210 (85)                                        
 3          173           163 (94)                                        
C (Comparative                                                            
            163           156 (96)                                        
Example)                                                                  
______________________________________                                    
 
    
     As clearly shown in these tables, the initial discharge capacity of the batteries configured with the anodes of the carbons containing oxygen is large as compared with that of the battery configured with the anode of the pyrolyzed carbon obtained from benzene. With the increase in the oxygen content, while the initial capacity increases, the capacity maintenance rate decreases. 
     The carbon anode containing oxygen by 3 wt %, which is not sufficiently large, showed a capacity and a capacity maintenance rate substantially equivalent to those of the pyrolyzed carbon anode. 
     In view of the capacity and the charge-discharge performance required for a secondary battery, it is concluded that an electrode configured with the carbon material containing oxygen by 6.5-25 wt % is excellent as an anode for a non-aqueous electrolyte secondary battery. 
     EXAMPLE 5 
     In this example, a carbon material containing oxygen was synthesized in a reaction vessel by heating the starting material of dioxane, which is a heterocyclic compound containing two oxygen atoms with ferric chloride, or polyvinyl alcohol, which is a chain compound containing oxygen atoms with cupric chloride, and the characteristic of an anode configured with the carbon material was investigated. 
     The method for synthesizing the carbon materials containing oxygen was similar to that of Example 4, except for the reaction temperature of 700° C. Dioxane was vaporized by heating and the resultant vaporized gas was introduced into the reaction tube by using nitrogen as the carrier gas. Further, cupric chloride and ferric chloride were previously introduced into the central part of the reaction tube. Further, when cupric chloride was employed, the produced carbon material containing oxygen was deposited on the surface of cupric chloride in a molten state. On the other hand, ferric chloride was vaporized and reacted with dioxane in a gas phase. In either case, only the produced carbon material containing oxygen was separated from the reaction mixture for configuring the anodes. Table 22 and Table 23 below each list the supplying proportions of dioxane and ferric chloride of raw materials and the oxygen content in the produced carbon material. 
     
                       TABLE 22                                                    
______________________________________                                    
Oxygen Content Supply Amount (mole/hour)                                  
(wt %)         dioxane   ferric chloride                                  
______________________________________                                    
30             0.101     0.40                                             
25             0.133     0.40                                             
10             0.398     0.40                                             
6.5            0.832     0.40                                             
3              1.447     0.40                                             
______________________________________                                    
 
    
     
                       TABLE 23                                                    
______________________________________                                    
Oxygen Content                                                            
              Supply Amount (mole/hour)                                   
(wt %)        polyvinyl alcohol                                           
                           cupric chloride                                
______________________________________                                    
30            0.118        0.30                                           
25            0.152        0.30                                           
10            0.465        0.30                                           
6.5           0.958        0.30                                           
3             1.702        0.30                                           
______________________________________                                    
 
    
     By employing each of the synthesized carbon materials, a secondary battery was configured in a manner similar to that of Example 1, and the capacity and the charge-discharge performance was investigated. 
     Batteries configured with the anodes of the carbons each having an oxygen content of 3 wt %, 6.5 wt %, 10 wt %, 25 wt %, and 30 wt % are named &#34;G&#34;, &#34;H&#34;, &#34;I&#34;, &#34;J&#34;, and &#34;K&#34;, respectively. These batteries have a larger electric capacity in their cathode. The capacity of the batteries are determined by the capacity of the anodes. 
     Charge-discharge cycles were repeated for each of the batteries by charging it at a constant current of 0.5 mA/cm 2  up to 4.4 V and discharging it as low as 3.0 V. FIG. 13 and FIG. 14 each show the discharge curve at the first cycle. Further, Table 24 and Table 25 below each list the discharge capacity at the first cycle and the discharge capacity at the 500th cycle, as well as the maintenance rate of the discharge capacity at the 500th cycle to the first cycle. In each table, the discharge capacity represents the capacity for 1 g of the carbon anode containing oxygen. 
     
                       TABLE 24                                                    
______________________________________                                    
         dioxane + ferric chloride (Present Invention)                    
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Oxygen Content                                                            
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
30         339            173 (51)                                        
25         331            245 (74)                                        
10         311            249 (80)                                        
6.5        239            206 (86)                                        
3          170            160 (94)                                        
______________________________________                                    
 
    
     
                       TABLE 25                                                    
______________________________________                                    
          polyvinyl alcohol + cupric chloride                             
          (Present Invention)                                             
                          Discharge capacity at                           
            Discharge capacity                                            
                          500th cycle (mAh/g)                             
Oxygen Content                                                            
            at first cycle                                                
                          (capacity maintenance                           
(wt %)      (mAh/g)       rate (%))                                       
______________________________________                                    
30          348           188 (54)                                        
25          340           255 (75)                                        
10          321           263 (82)                                        
6.5         252           219 (87)                                        
3           177           168 (95)                                        
______________________________________                                    
 
    
     As clearly shown in these tables, the initial discharge capacity increases with the increase in the oxygen content. On the other hand, the capacity maintenance rate decreases with the increase in the oxygen content. 
     The carbon anode containing oxygen by only 3 wt %, which is not sufficiently large, showed a capacity and a capacity maintenance rate substantially equivalent to those of the pyrolyzed carbon anode. 
     In view of the capacity and the charge-discharge performance required for a secondary battery, it is concluded that an electrode configured with the carbon material containing oxygen by 6.5-25 wt % is excellent as an anode for a non-aqueous electrolyte secondary battery. 
     EXAMPLE 6 
     As an alkali metal to be intercalated in the anode carbon, Na was employed in this example. For each of the anodes of this example, carbon materials each having an oxygen content of 3 wt %, 6.5 wt %, 10 wt %, 25 wt %, and 30 wt % synthesized from polyfuran and chlorine of Example 4 were used. The procedure identical to that of Example 1 was followed except for the use of NaNiO 2  as the cathode active material and propylene carbonate which dissolved sodium perchlorate (NaClO 4 ) by 1 mole/l as the non-aqueous electrolyte. 
     By employing the pyrolyzed carbon obtained from benzene of the comparative example, another anode was prepared similarly, and a battery was configured with this anode. 
     Batteries configured with the anodes of the carbons each having an oxygen content of 3 wt %, 6.5 wt %, 10 wt %, 25 wt %, and 30 wt % are named &#34;L&#34;, &#34;M&#34;, &#34;N&#34;, &#34;O&#34;, and &#34;P&#34;, respectively. Further, a battery configured with the anode of the pyrolyzed carbon is named &#34;Q&#34;. These batteries have a larger electric capacity in their cathode. The capacity of each of the batteries is determined by the capacity of the anodes. 
     Charge-discharge cycles were repeated for each of the batteries by charging it at a constant current of 0.5 mA/cm 2  up to 4.0 V and discharging it as low as 3.0 V. FIG. 15 shows the discharge curve at the first cycle. Further, Table 26 below lists the discharge capacity at the first cycle and the discharge capacity at the 500th cycle, as well as the maintenance rate of the discharge capacity at the 500th cycle to the first cycle. 
     
                       TABLE 26                                                    
______________________________________                                    
          polyfuran + chlorine (Present Invention)                        
                          Discharge capacity at                           
            Discharge capacity                                            
                          500th cycle (mAh/g)                             
Oxygen Content                                                            
            at first cycle                                                
                          (capacity maintenance                           
(wt %)      (mAh/g)       rate (%))                                       
______________________________________                                    
30          341           170 (50)                                        
25          331           248 (75)                                        
10          302           242 (80)                                        
  6.5       230           193 (84)                                        
 3          172           160 (93)                                        
C (Comparative                                                            
            152           143 (94)                                        
Example)                                                                  
______________________________________                                    
 
    
     As clearly shown in the table, the initial discharge capacity of the batteries configured with the anodes of the carbons containing oxygen is large as compared with that of the battery configured with the anode of the pyrolyzed carbon obtained from benzene. Further, while the initial capacity increases with the increase in the oxygen content, the capacity maintenance rate decreases with the increase in the oxygen content. 
     The carbon anode containing oxygen by only 3 wt %, which is not sufficiently large, showed a capacity and a capacity maintenance rate substantially equivalent to those of the pyrolyzed carbon anode. 
     In view of the capacity and the charge-discharge performance required for a secondary battery, it is concluded that an electrode configured with the carbon material containing oxygen by 6.5-25 wt % is excellent as an anode for a non-aqueous electrolyte secondary battery. 
     As apparent from the above-mentioned results, even if Na is employed as the alkali metal to be absorbed or intercalated in the anode by charging, the electrode configured with the carbon material containing oxygen of the present invention gives an excellent anode for a non-aqueous electrolyte secondary battery. 
     Although the description is limited to the anode configured with the carbon material synthesized from polyfuran and chlorine of Example 6 as the starting material, it is confirmed that a similar advantage is obtained with any anodes shown in Example 4 and Example 5, in a non-aqueous electrolyte secondary battery whose alkali metal is Na. 
     In Example 4 through Example 6, the description has exclusively been made on the anodes configured with the carbon materials synthesized by employing the starting materials of furan, polyfuran, pyran, dioxane, polyethylene oxide, and polyvinyl alcohol. However, it is confirmed that a substantially similar advantage is obtained with any anodes configured with the carbon material synthesized by employing the starting material of a cyclic compound containing one or more oxygen atoms such as tetrahydrofuran, trioxane, dioxolan, oxolan, benzofuran, butyrolactone, chromene, chroman, benzoquinone, naphthol, naphthoquinone, phenol, phenolic resin or the like, derivatives thereof, polymers thereof or the like, or polymers or copolymers of polyethers such as polypropylene oxide or the like, or polyesters such as polyethylene terephthalate, alkyd resin, maleic acid resin or the like, or a chain compound containing one or more oxygen atoms such as alcohols of ethyl alcohol, aldehydes of acetoaldehyde, carboxylic acids of acetic acid or the like. 
     EXAMPLE 7 
     In this example, a carbon material containing nitrogen was synthesized in a reaction vessel by heating the starting material of aniline or polyaniline which is a cyclic compound containing one or more nitrogen atoms with chlorine, or triazine, pyrazine or polypyrrole, which is a heterocyclic compound containing two or more nitrogen atoms with chlorine, or acetonitrile or polyacrylonitrile, which is a chain nitrile containing one or more nitrogen atoms with chlorine, and its characteristic as an anode was investigated. 
     Further, as comparative examples, additional investigations were made on the characteristics of a carbob material synthesized from a single starting material of pyridine, which is a heterocyclic compound containing only one nitrogen atom, another carbon material synthesized from pyridine and chlorine, and a thermally decomposed or pyrolyzed carbon obtained from benzene alone. 
     In the syntheses of these carbon materials containing nitrogen, the reaction temperature was fixed at 1,000° C. 
     As the reaction vessel, a quartz tube was used. After evacuating the reaction tube, the inside pressure of the reaction tube was returned to atmospheric pressure with nitrogen, and each of the starting materials of various proportions was introduced into the quartz tube to synthesize each of the carbon materials containing nitrogen at the various proportions as listed in Table 27 through Table 34 below. In this process, aniline, triazine, pyrazine, acetonitrile, and pyridine were vaporized by heating and the resultant vaporized gases were introduced into the reaction tube by using nitrogen as the carrier gas. Further, in case of polyaniline, polypyrrole and polyacrylonitrile, they were placed in the central part of the reaction tube before introduction of chlorine. 
     The carbon material synthesized from pyridine alone by heating has a nitrogen content of only 2.58% and contains a large quantity of carbon. 
     
                       TABLE 27                                                    
______________________________________                                    
Nitrogen Content                                                          
               Supply Amount (mole/hour)                                  
(wt%)          aniline    chlorine                                        
______________________________________                                    
7.2            0.090      0.10                                            
10.5           0.059      0.10                                            
13.5           0.045      0.10                                            
18.3           0.030      0.10                                            
18.9           0.029      0.10                                            
______________________________________                                    
 
    
     
                       TABLE 28                                                    
______________________________________                                    
Nitrogen Content                                                          
               Supply Amount (mole/hour)                                  
(wt %)         polyaniline                                                
                          chlorine                                        
______________________________________                                    
7.2            0.098      0.10                                            
10.5           0.068      0.10                                            
13.5           0.051      0.10                                            
18.3           0.037      0.10                                            
18.9           0.035      0.10                                            
______________________________________                                    
 
    
     
                       TABLE 29                                                    
______________________________________                                    
Nitrogen Content                                                          
               Supply Amount (mole/hour)                                  
(wt %)         triazine   chlorine                                        
______________________________________                                    
7.2            0.102      0.040                                           
10.5           0.065      0.040                                           
13.5           0.048      0.040                                           
18.3           0.034      0.040                                           
18.9           0.032      0.040                                           
______________________________________                                    
 
    
     
                       TABLE 30                                                    
______________________________________                                    
Nitrogen Content                                                          
               Supply Amount (mole/hour)                                  
(wt %)         pyrazine   chlorine                                        
______________________________________                                    
7.2            0.151      0.060                                           
10.5           0.101      0.060                                           
13.5           0.073      0.060                                           
18.3           0.051      0.060                                           
18.9           0.049      0.060                                           
______________________________________                                    
 
    
     
                       TABLE 31                                                    
______________________________________                                    
Nitrogen Content                                                          
               Supply Amount (mole/hour)                                  
(wt %)         polypyrrole                                                
                          chlorine                                        
______________________________________                                    
7.2            0.203      0.10                                            
10.5           0.135      0.10                                            
13.5           0.101      0.10                                            
18.3           0.071      0.10                                            
18.9           0.066      0.10                                            
______________________________________                                    
 
    
     
                       TABLE 32                                                    
______________________________________                                    
Nitrogen Content                                                          
               Supply Amount (mole/hour)                                  
(wt %)         acetonitrile                                               
                          chlorine                                        
______________________________________                                    
7.2            0.070      0.030                                           
10.5           0.047      0.030                                           
13.5           0.034      0.030                                           
18.3           0.025      0.030                                           
18.9           0.023      0.030                                           
______________________________________                                    
 
    
     
                       TABLE 33                                                    
______________________________________                                    
Nitrogen Content                                                          
               Supply Amount (mole/hour)                                  
(wt %)         polyacrylonitrile                                          
                            chlorine                                      
______________________________________                                    
7.2            0.102        0.040                                         
10.5           0.069        0.040                                         
13.5           0.051        0.040                                         
18.3           0.035        0.040                                         
18.9           0.034        0.040                                         
______________________________________                                    
 
    
     
                       TABLE 34                                                    
______________________________________                                    
Nitrogen Content                                                          
               Supply Amount (mole/hour)                                  
(wt %)         pyridine   chlorine                                        
______________________________________                                    
7.2            0.167      0.080                                           
10.5           0.068      0.080                                           
13.5           0.049      0.080                                           
18.3           0.035      0.080                                           
18.9           0.033      0.080                                           
______________________________________                                    
 
    
     Next, an anode plate was prepared by using each of the listed carbon materials in a manner similar to that in Example 1, and a secondary battery was assembled with the anode to investigate the capacity and the charge-discharge performance. 
     The electrodes and the configuration of the battery are the same as those of Example 1, except for the use of polypropylene carbonate solution which dissolves lithium trifluoromethane sulfonate (LiCF 3  SO 3 ) by 1 mole/l as the non-aqueous electrolyte. 
     Batteries configured with the anodes of the carbons each having a nitrogen content of 7.2 wt %, 10.5 wt %, 13.5 wt %, 18.3 wt %, and 18.9 wt % are named &#34;al&#34;, &#34;bl&#34;, &#34;cl&#34;, &#34;dl&#34;, and &#34;el&#34;, respectively. Further, a battery configured with the anode of the carbon synthesized from pyridine alone is named &#34;fl&#34;, and a battery configured with the anode of the pyrolyzed carbon (C) is named &#34;gl&#34;. These batteries have a larger electric capacity in their cathode. The capacity of each of the batteries is determined by the capacity of the anodes. 
     Charge-discharge cycles were repeated for each of the batteries by charging it at a constant current of 0.5 mA/cm 2  up to 4.4 V and discharging it as low as 3.0 V. FIG. 16 through FIG. 23 each show the discharge curve at the first cycle. Further, Table 35 through Table 42 below each list the discharge capacity at the first cycle and the discharge capacity at the 500th cycle, as well as the maintenance rate of the discharge capacity at the 500th cycle to the first cycle. In these tables, the discharge capacity represents the capacity for 1 g of the carbon anode containing sulfur or the pyrolyzed carbon. 
     
                       TABLE 35                                                    
______________________________________                                    
         aniline + chlorine (Present Invention)                           
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Nitrogen Content                                                          
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
 2.58      177            172 (97)                                        
(Comparative                                                              
Example)                                                                  
 7.2       185            176 (95)                                        
10.5       258            243 (94)                                        
13.5       286            263 (92)                                        
18.3       310            254 (82)                                        
18.9       319            217 (68)                                        
C (Comparative                                                            
           175            170 (97)                                        
Example)                                                                  
______________________________________                                    
 
    
     
                       TABLE 36                                                    
______________________________________                                    
         polyaniline + chlorine (Present Invention)                       
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Nitrogen Content                                                          
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
 2.58      177            172 (97)                                        
(Comparative                                                              
Example)                                                                  
 7.2       189            178 (94)                                        
10.5       261            243 (93)                                        
13.5       290            267 (92)                                        
18.3       314            264 (84)                                        
18.9       322            219 (68)                                        
C (Comparative                                                            
           175            170 (97)                                        
Example)                                                                  
______________________________________                                    
 
    
     
                       TABLE 37                                                    
______________________________________                                    
         triazine + chlorine (Present Invention)                          
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Nitrogen Content                                                          
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
 2.58      177            172 (97)                                        
(Comparative                                                              
Example)                                                                  
 7.2       185            174 (94)                                        
10.5       249            229 (92)                                        
13.5       286            257 (90)                                        
18.3       310            260 (84)                                        
18.9       317            219 (69)                                        
C (Comparative                                                            
           175            170 (97)                                        
Example)                                                                  
______________________________________                                    
 
    
     
                       TABLE 38                                                    
______________________________________                                    
         pyrazine + chlorine (Present Invention)                          
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Nitrogen Content                                                          
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
 2.58      177            172 (97)                                        
(Comparative                                                              
Example)                                                                  
 7.2       182            173 (95)                                        
10.5       256            236 (92)                                        
13.5       284            253 (89)                                        
18.3       306            251 (82)                                        
18.9       314            220 (70)                                        
C (Comparative                                                            
           175            170 (97)                                        
Example)                                                                  
______________________________________                                    
 
    
     
                       TABLE 39                                                    
______________________________________                                    
         polypyrrole + chlorine (Present Invention)                       
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Nitrogen Content                                                          
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
 2.58      177            172 (97)                                        
(Comparative                                                              
Example)                                                                  
 7.2       185            176 (95)                                        
10.5       260            239 (92)                                        
13.5       287            258 (90)                                        
18.3       310            260 (84)                                        
18.9       318            223 (70)                                        
C (Comparative                                                            
           175            170 (97)                                        
Example)                                                                  
______________________________________                                    
 
    
     
                       TABLE 40                                                    
______________________________________                                    
         acetonitrile + chlorine (Present Invention)                      
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Nitrogen Content                                                          
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
 2.58      177            172 (97)                                        
(Comparative                                                              
Example)                                                                  
 7.2       180            169 (94)                                        
10.5       255            230 (90)                                        
13.5       280            244 (87)                                        
18.3       309            250 (81)                                        
18.9       315            211 (67)                                        
C (Comparative                                                            
           175            170 (97)                                        
Example)                                                                  
______________________________________                                    
 
    
     
                       TABLE 41                                                    
______________________________________                                    
         polyacrylonitrile + chlorine                                     
         (Present Invention)                                              
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Nitrogen Content                                                          
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
 2.58      177            172 (97)                                        
(Comparative                                                              
Example)                                                                  
 7.2       184            175 (95)                                        
10.5       260            242 (93)                                        
13.5       290            258 (89)                                        
18.3       314            261 (83)                                        
18.9       320            224 (70)                                        
C (Comparative                                                            
           175            170 (97)                                        
Example)                                                                  
______________________________________                                    
 
    
     
                       TABLE 42                                                    
______________________________________                                    
         pyridine + chlorine (Present Invention)                          
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Nitrogen Content                                                          
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
 2.58      177            172 (97)                                        
(Comparative                                                              
Example)                                                                  
7.2        180            162 (90)                                        
10.5       252            207 (82)                                        
13.5       283            207 (73)                                        
18.3       310            211 (68)                                        
18.9       318            165 (52)                                        
C (Comparative                                                            
           175            170 (97)                                        
Example)                                                                  
______________________________________                                    
 
    
     As clearly shown in these tables, the batteries configured with the anodes of the carbons having a nitrogen content of 18.9 wt %, synthesized from any of the starting materials, have the largest initial discharge capacity. The charge-discharge performance, which is one of the important characteristics of the secondary battery, was superior in the batteries in accordance with the present invention to that in the battery of the comparative example configured with an anode of the carbon material synthesized from the pyridine and chlorine. The batteries of the present invention demonstrated a larger capacity at the 500th cycle, compared with the battery of the comparative example. 
     Furthermore, the initial capacity of the electrode configured with the material containing nitrogen increases with the increase in the nitrogen content. On the other hand, the capacity maintenance rate decreases with the increase in the nitrogen content. 
     The carbon anode containing nitrogen by only 7.2 wt % which is not sufficiently large, showed a capacity and a capacity maintenance rate substantially equivalent to those of the pyrolyzed carbon anode. 
     In view of the capacity and the charge-discharge performance required for a secondary battery, it is concluded that an electrode configured with the carbon material containing nitrogen by 10.5-18.3 wt % is excellent as an anode for a non-aqueous electrolyte secondary battery. 
     EXAMPLE 8 
     In this example, a carbon material containing nitrogen was synthesized in a reaction vessel by heating the starting material of pyrrole or piperazine, which is a heterocyclic compound containing one or two nitrogen atoms with cupric chloride, or acetonitrile, which is a chain nitrile containing one nitrogen atom with ferric chloride, and the characteristic of an anode configured with the carbon material was investigated. 
     The synthesis of the carbon material containing nitrogen was performed by fixing the reaction temperature at 800° C. 
     As the reaction vessel, a quartz tube was used. After evacuating the reaction tube, the inside pressure of the reaction tube was returned to atmospheric pressure with nitrogen, and each of the starting materials of various proportions was introduced into the quartz tube to synthesize each of the carbon materials containing nitrogen at various proportions as listed in Table 43 through Table 45 below. In this process, pyrrole, piperazine and acetonitrile were vaporized by heating and the resultant vaporized gases were introduced into the reaction tube by using nitrogen as the carrier gas. Further, cupric chloride and ferric chloride were introduced into the central part of the reaction tube in advance. Further, in a case of cuptic chloride, the produced carbon material containing nitrogen was deposited on the surface of the cupric chloride in a molten state. On the other hand, since ferric chloride was in a vaporized state, it reacted with acetonitrile in a gas phase. In either case, only the produced carbon material containing nitrogen was separated from the reaction mixture for configuring the anodes. Table 43 through Table 45 below each list the supplying proportions of pyrrole and cupric chloride of raw materials and the nitrogen content in the produced carbon material. 
     
                       TABLE 43                                                    
______________________________________                                    
Nitrogen Content                                                          
               Supply Amount (mole/hour)                                  
(wt %)         pyrrole   cupric chloride                                  
______________________________________                                    
7.2            0.267     0.200                                            
10.5           0.178     0.200                                            
13.5           0.134     0.200                                            
18.3           0.092     0.200                                            
18.9           0.089     0.200                                            
______________________________________                                    
 
    
     
                       TABLE 44                                                    
______________________________________                                    
Nitrogen Content                                                          
               Supply Amount (mole/hour)                                  
(wt %)         piperazine                                                 
                         cupric chloride                                  
______________________________________                                    
7.2            0.155     0.213                                            
10.5           0.103     0.213                                            
13.5           0.075     0.213                                            
18.3           0.052     0.213                                            
18.9           0.050     0.213                                            
______________________________________                                    
 
    
     
                       TABLE 45                                                    
______________________________________                                    
Nitrogen Content                                                          
               Supply Amount (mole/hour)                                  
(wt %)         acetonitrile                                               
                         ferric chloride                                  
______________________________________                                    
7.2            0.090     0.030                                            
10.5           0.054     0.030                                            
13.5           0.042     0.030                                            
18.3           0.029     0.030                                            
18.9           0.028     0.030                                            
______________________________________                                    
 
    
     By employing each of the synthesized carbon materials, a secondary battery was configured in a manner similar to that of Example 1, and the capacity and the charge-discharge performance were investigated. 
     The electrodes and the configuration of the battery are the same as those of Example 7. Batteries configured with the anodes of the carbon materials each having a nitrogen content of 7.2 wt %, 10.5 wt %, 13.5 wt %, 18.5 wt %, and 18.9 wt % are named &#34;hl&#34;, &#34;il&#34;, &#34;jl&#34;, &#34;kl&#34;, and &#34;ll&#34;, respectively. 
     These batteries have a larger electric capacity in their cathode. The capacity of each of the batteries is determined by the capacity of the respective anodes. Charge-discharge cycles were repeated for each of the batteries by charging at a constant current of 0.5 mA/cm 2  up to 4.4 V and discharging as low as 3.0 V. FIG. 24 through FIG. 26 each show the discharge curve at the first cycle. Further, Table 46 through Table 48 below each list the discharge capacity at the first cycle and the discharge capacity at the 500th cycle, as well as the maintenance rate of the discharge capacity at the 500th cycle to the first cycle. In each table, the discharge capacity represents the capacity for 1 g of the carbon anode containing sulfur. 
     
                       TABLE 46                                                    
______________________________________                                    
         pyrrole + cupric chloride (Present Invention)                    
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Nitrogen Content                                                          
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
7.2        183            165 (90)                                        
10.5       258            214 (83)                                        
13.5       280            221 (79)                                        
18.3       306            233 (76)                                        
18.9       318            181 (57)                                        
______________________________________                                    
 
    
     
                       TABLE 47                                                    
______________________________________                                    
         piperazine + cuprin chloride                                     
         (Present Invention)                                              
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Nitrogen Content                                                          
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
7.2        187            172 (92)                                        
10.5       261            222 (85)                                        
13.5       290            241 (83)                                        
18.3       310            248 (80)                                        
18.9       320            198 (62)                                        
______________________________________                                    
 
    
     
                       TABLE 48                                                    
______________________________________                                    
         acetonitrile + ferric chloride                                   
         (Present Invention)                                              
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Nitrogen Content                                                          
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
7.2        183            168 (92)                                        
10.5       260            218 (84)                                        
13.5       286            232 (81)                                        
18.3       323            252 (78)                                        
18.9       330            198 (60)                                        
______________________________________                                    
 
    
     As clearly shown in these tables, the batteries configured with the anodes of the carbons each having a nitrogen content of 18.9 wt %, synthesized from any of the starting materials, have the largest initial discharge capacity. The charge-discharge performance, which is one of the important characteristics of the secondary battery, was superior in the batteries in accordance with the present invention to the battery of the comparative example configured with an anode of the carbon material synthesized from pyridine and chlorine shown in Example 7. The batteries of the present invention demonstrated a larger capacity at the 500th cycle, compared with the battery of the comparative example. In particular, the battery configured with an anode of the carbon material synthesized from piperazine, which is a heterocyclic compound containing two nitrogen atoms, or the one synthesized from acetonitrile, which is a chain nitrile containing a nitrogen atom, demonstrated a favorable characteristic. 
     While the initial discharge capacity of the carbon electrode containing nitrogen decreased with the decrease in the nitrogen content, the capacity maintenance rate improved with the decrease in the nitrogen content. 
     The carbon anode containing nitrogen by only 7.2 wt %, which is not sufficiently large, showed a capacity and a capacity maintenance rate substantially equivalent to those of the pyrolyzed carbon anode (C) shown in Example 7. 
     In view of the capacity and the charge-discharge performance required for a secondary battery, it is concluded that an electrode configured with the carbon material containing nitrogen by 10.5-18.3 wt % is excellent as an anode for a non-aqueous electrolyte secondary battery. 
     EXAMPLE 9 
     As an alkali metal to be absorbed or intercalated in the anode carbon, in place of Li in Example 7 and Example 8, Na was employed in this example. For each of the anodes of this example, carbon materials each having a nitrogen content of 7.2 wt %, 10.5 wt %, 13.5 wt %, 18.3 wt %, and 18.9 wt % synthesized from polyacrylonitrile and chlorine of Example 7 were used. The procedure identical to that of Example 7 was followed except for the use of NaNiO 2  as the cathode active material and γ-butyrolactone which dissolved sodium perchlorate (NaClO 4 ) by 1 mole/l as the non-aqueous electrolyte. 
     As a comparative example, another anode was prepared by employing the pyrolyzed carbon obtained from benzene similarly, and a battery was configured with this anode. 
     Batteries configured with the anodes of the carbons each having a nitrogen content of 7.2 wt %, 10.5 wt %, 13.5 wt %, 18.3 wt %, and 18.9 wt % are named &#34;ml&#34;, &#34;nl&#34;, &#34;ol&#34;, &#34;pl&#34;, and &#34;ql&#34;, respectively. The battery configured with the anode of thermally decomposed carbon was named &#34;rl&#34;. These batteries have a larger electric capacity in their cathode. The capacity of each of the batteries is determined by the capacity of the respective anodes. 
     Charge-discharge cycles were repeated for each of the batteries by charging it at a constant current of 0.5 mA/cm 2  up to 4.0 V and discharging it as low as 3.0 V. FIG. 27 shows the discharge curve at the first cycle. Further, Table 49 below lists the discharge capacity at the first cycle and the discharge capacity at the 500th cycle, as well as the maintenance rate of the discharge capacity at the 500th cycle to the first cycle. 
     
                       TABLE 49                                                    
______________________________________                                    
         polyacrylonitrile + chlorine                                     
         (Present Invention)                                              
                          Discharge capacity at                           
           Discharge capacity                                             
                          500th cycle (mAh/g)                             
Nitrogen Content                                                          
           at first cycle (capacity maintenance                           
(wt %)     (mAh/g)        rate (%))                                       
______________________________________                                    
 7.2       168            156 (93)                                        
10.5       240            216 (90)                                        
13.5       271            230 (85)                                        
18.3       298            238 (80)                                        
18.9       305            192 (63)                                        
C (Comparative                                                            
           156            147 (94)                                        
Example)                                                                  
______________________________________                                    
 
    
     As clearly shown in the table, the battery configured with the anode of the carbon having a nitrogen content of 18.9 wt % has the largest initial discharge capacity. The charge-discharge performance, which is one of the important characteristics of the secondary battery, is superior in the batteries in accordance with the present invention configured with the carbon material having an nitrogen content of 10.5-18.3 wt % to the other batteries. It was also revealed that, at the 500th cycle, the batteries demonstrated a larger capacity than that of the battery configured with the carbon material having a nitrogen content of 18.9 wt %, not to mention of the battery configured with the carbon material having a nitrogen content of 7.2 wt %. 
     As apparent from the above-mentioned results, even if Na is used as the alkali metal to be absorbed or intercalated in the anode by charging, the electrode configured with the carbon material containing nitrogen in a range of 10.5-18.3 wt % gives an excellent anode for a non-aqueous electrolyte secondary battery. 
     Although the description is limited to the anode configured with the carbon material synthesized from polyacrylonitrile and chlorine of Example 9 as the starting material, it is confirmed that a similar advantage is obtained with any anodes shown in Example 7 and Example 8 in a non-aqueous electrolyte secondary battery, when Na is employed as the alkali metal for the anode. 
     In Example 7 through Example 9, the description has exclusively been made on the anodes configured with the carbon materials synthesized by employing the starting material of aniline, polyaniline, triazine, pyrazine, piperazine, pyrrole, polypyrrole, acetonitrile or polyacrylonitrile. However, it is confirmed that a substantially similar advantage is obtained with any anodes configured with the carbon materials synthesized from any starting material of a heterocyclic compound containing one or more nitrogen atoms such as triazole, pyrazole or melamine, or a chain compound containing one or more nitrogen atoms such as dimethyl formamide, or a chain nitrile represented by acrylonitrile, propionitrile, butyronitrile or pentanonitrile, or derivatives thereof. 
     EXAMPLE 10 
     In this example, each of carbon materials each containing at least two members of sulfur, oxygen and nitrogen was synthesized in a reaction vessel by heating two or three starting materials selected from the group consisting of pyrrole containing a nitrogen atom, or thiophene containing a sulfur atom and furan containing an oxygen atom, together with chlorine, and its characteristic as an anode was investigated. 
     After evacuating a reaction vessel of a quartz tube, its inside pressure was returned to atmospheric pressure with nitrogen, and then each of the starting materials of various proportions was introduced into the reaction tube at a temperature listed in Table 50 below to synthesize each of the carbon materials containing nitrogen and/or sulfur and/or oxygen at various proportions as listed in Table 50 below. In this process, pyrrole, thiophene and furan were vaporized by heating and the resultant vaporized gases were introduced into the reaction tube by using nitrogen as the carrier gas. 
     
                       TABLE 50                                                    
______________________________________                                    
Reaction                                                                  
       Content (wt %)                                                     
                     Supply Amount (mole/hour)                            
tempera-                                                                  
       sul-   oxy-   nitro-                                               
                           thio-       pyr-                               
ture (°C.)                                                         
       fur    gen    gen   phene furan role chlorine                      
______________________________________                                    
1000   9      7      11    0.30  0.25  0.10 0.3                           
1000          7      13          0.35  0.10 0.2                           
1000   8             12    0.528       0.11 0.2                           
900    8      8            0.3   0.225      0.2                           
______________________________________                                    
 
    
     By employing each of the synthesized carbon materials, an anode was prepared and a battery was configured with the thus prepared anode in a manner similar to that of Example 1, and the capacity and the charge-discharge performance were investigated. 
     Charge-discharge cycles were repeated for each of the batteries by charging it at a constant current of 0.5 mA/cm 2  up to 4.4 V and discharging it as low as 3.0 V. Table 51 below lists the discharge capacity at the first cycle and the discharge capacity at the 500th cycle, as well as the maintenance rate of the discharge capacity at the 500th cycle to the first cycle. In these tables, the discharge capacity represents the capacity for 1 g of the carbon anode containing sulfur. 
     
                       TABLE 51                                                    
______________________________________                                    
               Discharge Capacity (mAh/g)                                 
Content (wt %)       At 500th cycle                                       
sul-    oxy-   nitro-    At first                                         
                               (capacity main-                            
fur     gen    gen       cycle tenance rate) (%)                          
______________________________________                                    
9       7      11        332   249 (75)                                   
        7      13        325   267 (82)                                   
8              12        322   267 (83)                                   
8       8                310   248 (80)                                   
______________________________________                                    
 
    
     As clearly shown in these tables, in each of the batteries of this example, the initial discharge capacity and the discharge capacity at 500th cycle are larger and more excellent than those of the battery configured with the anode of pyrolyzed carbon obtained from benzene. 
     As clearly seen from the above-mentioned results, the carbon material containing at least two members of sulfur, oxygen and nitrogen can give an excellent anode, similar to the carbon material containing a single member of sulfur, oxygen or nitrogen. 
     Moreover, although the description is limited to a battery of cylindrical shape in the foregoing examples, the present invention is not limited to this structure of the battery and a similar advantage is obtained with a secondary battery of a coin type, a rectangular type, a flat type, and the like. 
     Although the present invention has been described in terms of the presently preferred embodiments, it is to be understood that such disclosures are not to be interpreted as limiting. Various alterations and modifications will no doubt become apparent to those skilled in the art to which the present invention pertains, after having read the above disclosure. Accordingly, it is intended that the appended claims be interpreted as covering all alterations and modifications as fall within the true spirit and scope of the invention.