the aromachemicals of the invention may be prepared according to the reaction scheme set forth in the examples which outlines the synthesis of 2 - methoxy - 4 - methylsulfanylphenol . the aromachemicals of the invention possess the odor profile : floral , carnation , spicy , and smoky . examples of suitable articles of manufacture in which the derivatives of the invention may be incorporated include perfumes and colognes , candles , air fresheners , detergent compositions and disinfectants . the compositions , products , preparations and articles in which the compounds and derivatives of the invention may be incorporated include candles , air fresheners , perfumes , fragrances , colognes , soaps , bath or shower gels , shampoos or other hair care products , cosmetic preparations , body odorants , deodorants or antiperspirants , liquid or solid fabric detergents or softeners , bleach products ( hypochlorites ), disinfectants , all - purpose household or industrial cleaners , foods , flavorings , beverages such as beer and soda , denture cleansers ( tablets ), flavored orally - delivered products such as lozenges , candies , chewing gums , matrices , pharmaceuticals and the like . the compounds can be used as perfuming ingredients , as single compounds or as mixture thereof , preferably at a range of at least about 30 % by weight of the perfume composition , more preferably at a range of at least about 60 % by weight of the composition . the compounds can even be used in their pure state or as mixtures , without added components . the olfactive characteristics of the individual compounds are also present in mixtures thereof , and mixtures of these compounds can be used as perfuming ingredients . this may be particularly advantageous where separation and / or purification steps can be avoided by using compound mixtures . the derivatives of the invention can be included in virtually any article of manufacture that can include conventional aromachemicals , or for that matter , other fragrances , whether natural or artificial . examples include bleach , detergents , flavorings and fragrances , beverages , including alcoholic beverages , and the like . the derivatives of the invention can be used in applications like soaps , shampoos , body deodorants and antiperspirants , solid or liquid detergents for treating textiles , fabric softeners , detergent compositions and / or all - purpose cleaners for cleaning dishes or various surfaces , for both household and industrial use . of course , the use of the compounds is not limited to the above - mentioned products , as they be used in other current uses in perfumery , namely the perfuming of soaps and shower gels , hygiene or hair - care products , as well as of body deodorants , air fresheners and cosmetic preparations , and even in fine perfumery , namely in perfumes and colognes . the products of the invention also find utility in foods , flavorings , beverages such as beer and soda , denture cleansers ( tablets ), flavored orally - delivered products such as lozenges , candies , chewing gums , matrices , pharmaceuticals and the like . these uses are described in more detail below . in all cited applications , the derivatives of the invention can be used alone , in admixture with each other , or in admixture with other perfuming ingredients , solvents or adjuvants of current use in the art . the nature and the variety of these co - ingredients do not require a more detailed description here , which , moreover , would not be exhaustive , and the person skilled in the art will be able to choose the latter through its general knowledge and as a function of the nature of the product to be perfumed and of the desired olfactive effect . these perfuming ingredients typically belong to chemical classes as varied as alcohols , aldehydes , ketones , esters , ethers , acetates , nitrites , terpene hydrocarbons , sulfur - and nitrogen containing heterocyclic compounds , as well as essential oils of natural or synthetic origin . a large number of these ingredients described in reference textbooks such as the book of s . arctander , perfume and flavor chemicals , 1969 , montclair , n . j ., usa , the contents of which are hereby incorporated by reference in its entirety , or its more recent versions , or in other works of similar nature . the proportions in which the derivatives of the invention can be incorporated in the various products vary within a large range of values . these values depend on the nature of the article or product that one desires to perfume and the odor effect searched for , as well as on the nature of the co - ingredients in a given composition when the compounds are used in admixture with perfuming co - ingredients , solvents or adjuvants of current use in the art . as an example , the derivatives of the invention are typically present at concentrations between about 0 . 1 and about 10 %, or even more , by weight of these compounds relative to the weight of the perfuming composition in which they are incorporated . far lower concentrations than those mentioned above can be used when the compounds are directly applied for perfuming the various consumer products cited beforehand . the compounds may be used in detergents containing bleaching agents and activators such as , for example , tetraacetylethylenediamine ( taed ), hypohalites , in particular hypochlorite , peroxygenated bleaching agents such as , for example , perborates , etc . the compounds can also be used in body deodorants and antiperspirants , for example , those containing aluminum salts . these embodiments are described in more detail below . in addition to the derivatives described herein , the compositions herein include a detersive surfactant and optionally , one or more additional detergent ingredients , including materials for assisting or enhancing cleaning performance , treatment of the substrate to be cleaned , or to modify the aesthetics of the detergent composition ( e . g ., perfumes , colorants , dyes , etc .). non - limiting examples of synthetic detersive surfactants useful herein typically at levels from about 0 . 5 % to about 90 %, by weight , include the conventional c1 - 18 alkyl benzene sulfonates (“ las ”) and primary , branch - chain and random cio - 20 alkyl sulfates (“ as ”), and the like . preferred compositions incorporating only synthetic detergents have a detergent level of from about 0 . 5 % to 50 %. compositions containing soap preferably comprise from about 10 % to about 90 % soap . the compositions herein can contain other ingredients such as enzymes , bleaches , fabric softening agents , dye transfer inhibitors , suds suppressors , and chelating agents , all well known within the art . the derivatives described herein can be incorporated into beverages and impart various flavorings to the beverages . the beverage composition can be a cola beverage composition , and can also be coffee , tea , dairy beverage , fruit juice drink , orange drink , lemon - lime drink , beer , malt beverages , or other flavored beverage . the beverages can be in liquid or powdered form . the beverage compositions can also include one or more flavoring agents ; artificial colorants ; vitamin additives ; preservatives ; caffeine additives ; water ; acidulants ; thickeners ; buffering agents ; emulsifiers ; and or fruit juice concentrates . artificial colorants which may be used include caramel color , yellow 6 and yellow 5 . useful vitamin additives include vitamin b2 , vitamin b6 , vitamin b12 , vitamin c ( ascorbic acid ), niacin , pantothenic acid , biotin and folic acid . suitable preservatives include sodium or potassium benzoate . salts which may be used include sodium , potassium and magnesium chloride . exemplary emulsifiers are gum arabic and purity gum , and a useful thickener is pectin . suitable acidulants include citric , phosphoric and malic acid , and potential buffering agents include sodium and potassium citrate . in one embodiment , the beverage is a carbonated cola beverage . the ph is generally about 2 . 8 and the following ingredients can be used to make the syrup for these compositions : flavor concentrate , including one or more of the derivatives described herein ( 22 . 22 ml ), 80 % phosphoric acid ( 5 . 55 g ), citric acid ( 0 . 267 g ), caffeine ( 1 . 24 g ), artificial sweetener , sugar or corn syrup ( to taste , depending on the actual sweetener ) and potassium citrate ( 4 . 07 g ). the beverage composition can be prepared , for example , by mixing the foregoing syrup with carbonated water in a proportion of 50 ml syrup to 250 ml of carbonated water . flavored food and pharmaceutical compositions including one or more of the derivatives described herein can also be prepared . the derivatives can be incorporated into conventional foodstuffs using techniques well known to those of skill in the art . alternatively , the derivatives can be incorporated within polymeric particles , which can , in turn , be dispersed within and / or over a surface of an orally - deliverable matrix material , which is usually a solid or semi - solid substrate . when used in chewable compositions , the derivatives can be released into the orally - deliverable polymeric matrix material as the composition is chewed and held in the mouth , thus prolonging the flavor of the composition . in the case of dried powders and mixes , the flavor can be made available as the product is consumed or be released into the matrix material as the composition is further processed . when two flavors are combined with the polymeric particles , the relative amounts of the additives can be selected to provide simultaneous release and exhaustion of the compounds . in one embodiment , the flavored composition includes an orally - deliverable matrix material ; a plurality of water insoluble polymeric particles dispersed in the orally - deliverable matrix material , where the polymeric particles individually define networks of internal pores and are non - degradable in the digestive tract ; and one or more derivatives as described herein entrapped within the internal pore networks . the derivatives are released as the matrix is chewed , dissolved in the mouth , or undergoes further processing selected from the group consisting of liquid addition , dry blending , stirring , mixing , heating , baking , and cooking . the orally - deliverable matrix material can be selected from the group consisting of gums , latex materials , crystallized sugars , amorphous sugars , fondants , nougats , jams , jellies , pastes , powders , dry blends , dehydrated food mixes , baked goods , batters , doughs , tablets , and lozenges . a flavorless gum base can be combined with a derivative of the invention or other suitable derivative as described herein to a desired flavor concentration . typically , a blade mixer is heated to about 11 of , the gum base is preheated so that it is softened , and the gum base is then added to the mixer and allowed to mix for approximately 30 seconds . the flavored derivative is then added to the mixer and mixed for a suitable amount of time . the gum can be then removed from the mixer and rolled to stick thickness on waxed paper while warm . in one embodiment , the derivatives described herein are incorporated into a system which can release a fragrance in a controlled manner . these include substrates such as air fresheners , laundry detergents , fabric softeners , deodorants , lotions , and other household items . the fragrances are generally one or more derivatives of essential oils as described herein , each present in different quantities . u . s . pat . no . 4 , 587 , 129 , the contents of which are hereby incorporated by reference in their entirety , describes a method for preparing gel articles which contain up to 90 % by weight of fragrance or perfume oils . the gels are prepared from a polymer having a hydroxy ( lower alkoxy ) 2 - alkeneoate , a hydroxy ( lower alkoxy ) lower alkyl 2 - alkeneoate , or a hydroxy poly ( lower alkoxy ) lower alkyl 2 - alkeneoate and a polyethylenically unsaturated crosslinking agent . these materials have continuous slow release properties , i . e ., they release the fragrance component continuously over a long period of time . advantageously , all or a portion of those derivatives that include an aldehyde group can be modified to include an acetal group , which can cause the formulations to release fragrance over a period of time as the acetal hydrolyzes to form the aldehyde compound . having hereby disclosed the subject matter of the present invention , it should be apparent that many modifications , substitutions , and variations of the present invention are possible in light thereof . it is to be understood that the present invention can be practiced other than as specifically described . such modifications , substitutions and variations are intended to be within the scope of the present application . a solution of guaiacol sulfonic acid potassium salt ( 1 . 7 g ) in benzene ( 30 ml ) was heated to reflux in a dean - stark apparatus to remove water . the benzene solution was allowed to cool , treated with triphenylphosphine ( 6 . 8 g ) and 18 - crown - 6 ( 0 . 85 g ), fitted with a condenser and degassed . a degassed solution of iodine ( 1 . 23 g ) in benzene ( 10 ml ) was prepared separately , added to the reaction mixture and the solution refluxed overnight . a 10 % mixture of water in dioxane ( 8 ml ) was added to the reaction and reflux continued for a further 1 . 5 hours . the reaction was allowed to cool and the organic solution washed with water ( 2 × 40 ml ), dried over mgso 4 and concentrated to give a colorless solid . flash column chromatography using dichloromethane as eluant gave the title compound as a colorless oil ( 0 . 60 g , 62 %). to a solution of sodium hydroxide ( 0 . 050 g ) in methanol ( 2 ml ) was added 4 - hydroxy - 3 - methoxy - benzene thiol ( 0 . 20 g ) and stirring continued for 20 minutes . methyl iodide ( 0 . 060 ml ) was added slowly and the solution stirred overnight at room temperature . water ( 2 ml ) was added , the solution extracted with dichloromethane , the organic layer dried over mgso 4 and concentrated to give a colorless oil . flash column chromatography using dichloromethane as eluant gave the title compound as a colorless oil ( 0 . 051 g ). having hereby disclosed the subject matter of the present invention , it should be apparent that many modifications , substitutions , and variations of the present invention are possible in light thereof . it is to be understood that the present invention can be practiced other than as specifically described . such modifications , substitutions and variations are intended to be within the scope of the present application .
aromachemical alkoxyalkyl sulfanyl compounds or a mixtures thereof having the formula : r 1 o — c 6 h 5 oh — sr wherein : r is a straight or branched chain , saturated or unsaturated hydrocarbyl group ; preferably , alkyl or alkenyl , having 1 - 8 carbon atoms ; and r 1 is a straight or branched chain , saturated or unsaturated hydrocarbyl group ; preferably , alkyl or alkenyl , having 1 - 8 carbon atoms and their use as aromachemicals and in articles of manufacture .