in the practice of the present invention , the compounds of the present invention are manufactured by reacting the properly selected 2 , 4 disubstituted aniline with an alkyl orthoformate and then reacting the resulting alkylformimidate with 1 - methyl - amino - 1 - methylpropin - 2 as shown by the following reaction scheme : ## str3 ## after the compounds of the present invention are formed , they can be applied to the habitat in an effective amount to control respective mites and insects . into a round - bottom flask fitted with a stirrer , was placed 4 . 0 g ( 0 . 02 mole ) of o - ethyl - n -( 2 - methyl - 4 - chlorophenyl )- formimidate , 10 ml ch 2 cl 2 and 6 ml of 1 - methylamino - 1 - methylpropin - 2 . the reacting solution was refluxed for 4 hours . after cooling the mixture was stripped by high vacuum . the reaction yielded 4 . 5 g of a solid product . structure confirmation was by n . m . r . other compounds can be prepared in an anologous manner starting with the appropriate materials as outlined above . following is a table of compounds representative of those embodied in the present invention . compound numbers have been assigned to them and are used for identification throughout the balance of this specification . insecticidal activity of the above compounds were evaluated for efficacy on various insect species as follows : a . leaf dip assay to determine efficacy against first instar salt - marsh caterpillar larvae kidney bean leaves are dipped in a 50 - 50 acetonewater solution of the test chemical . when the leaves have dried , egg masses of the salt - marsh caterpillars are placed on the leaf surface . mortality of the newly hatched larvae is determined after one week . test concentrations range from 0 . 05 % down to that at which approximately 50 % of the larvae are dead . egg masses of the salt - marsh caterpillar are dipped in acetone solutions of the test chemicals and placed in petri dishes containing a portion of larval rearing medium . efficacy is determined after seven days by observing the number of newly emerged larvae . test concentrations range from 0 . 05 % down to that at which approximately 50 % of the eggs do not hatch . nasturtium ( tropaeolum sp .) plants , approximately 2 - 3 inches tall , are transplanted into sandy loam soil in 3 - inch clay pots and infested with 50 - 75 aphids of mixed ages . twenty - four hours later they are sprayed , to the point of runoff , with aqueous suspensions of the toxicant . the suspensions are prepared by diluting aliquots of the toxicant , dissolved in an appropriate solvent , with water to which has been added 0 . 0002 % of a conventional wetting agent such as polyoxy - ethylene sorbitan monolaurate ether of alkylated phenol blended with organic sulfonate . test concentrations ranged from 0 . 05 % to that at which 50 % mortality is obtained . mortality is recorded after 48 hours and the ld - 50 values are expressed as percent active ingredient in the aqueous suspensions . pinto beans ( phaseolus sp .) plants , approximately 2 - 3 inches tall , are transplanted into sandy loam soil in 3 - inch clay pots and infested with 50 - 75 mites of mixed ages . twenty - four hours later they are sprayed , to the point of runoff , with aqueous suspensions of the toxicant . the suspensions are prepared as in previously described tests ( i and ii ). test concentrations ranged from 0 . 05 % to that at which 50 % mortality is obtained . mortality of adults , nymphs and eggs is recorded after 7 days and the ld - 50 values are expressed as percent active ingredient in the aqueous suspensions . aliquots of toxicant dissolved in an appropriate solvent are diluted in water and placed in glass bottles . concentrations of active ingredient range from 10 ppm to that at which 50 % mortality is obtained . kidney beans ( phaseolus vulgaris ), supported by cotton plugs , are inserted into the solution so that the roots and major portion of the stem are completely immersed . masses of caterpillar eggs which are nearly ready to hatch are fastened to the bean leaves . one week later mortality of the newly hatched larvae is recorded . ld - 50 values are expressed as ppm of toxicant in the aqueous suspensions . preparation of the test solution and concentrations is the same as for the salt - marsh caterpillar test ( iv - a ). pinto bean ( phaseolus sp .) plants with expanded primary leaves are placed in the solution so that the roots and major portions of the stem are completely immersed . immediately after , the leaves are infested with 75 - 100 mites of various ages . mortality of adults , nymphs and eggs is recorded after one week , and ld - 50 values are expressed as ppm of toxicant in the aqueous suspensions . the results of the above test procedures indicate in table ii the effective concentration at which ld - 50 control effect was achieved on the various species of insects . table ii______________________________________ smc leaf 2smcompound ba dip ovicide sys pe eggs sysnumber % % % ppm % % ppm______________________________________1 . 05 . 0003 . 03 . 3 . 01 . 05 10______________________________________ smc = salt - marsh caterpillar sys = systemic 2sm = two - spotted mite ba = bean aphid & gt ; = greater than & lt ; = less than pe = post - embryonic the compounds of this invention are generally embodied into a form suitable for convenient application . for example , the compounds can be embodied into pesticidal compositions which are provided in the form of emulsion , suspension , solutions , dusts and aerosol sprays . in general , such compositions will contain , in addition to the active compound , the adjuvants which are normally found in pesticide preparations . in these compositions , the active compounds of this invention can be employed as a sole pesticide component or they can be used in a mixture with other compounds having similar utility . the pesticide compositions of this invention can contain as adjuvants organic solvents such as sesame oil ; xylene solvents ; heavy petroleum , etc ; water ; emulsifying agents ; surface active agents ; talc , pyrophyllite ; diatomite ; gypsum ; clays ; propellents ; such as dichlorodifluormethane , etc . if desired , however , the active compounds can be applied directly to feedstuffs , seeds , etc . upon which these pests feed . when applied in such a manner , it will be advantageous to use a compound which is not volatile . in connection with the activity of the presently disclosed pesticidal compounds , it should be fully understood that it is not necessary that they be active as such . the purposes of this invention will be fully served to the compound as rendered active by external influences , such as light or by some physiological action which occurs when the compound is ingested into the body of the pests . the precise manner in which the pesticidal composition of this invention are used in any particular instance , will be readily apparent to a person skilled in the art . generally , the active pesticide compound will be embodied in the form of a liquid composition . for example , an emulsion , suspension or aerosol spray . while the concentration of the active pesticide in the present compositions can vary within rather wide limits , ordinarily the pesticide compound will comprise not more than about 15 . 0 % by weight of the pesticidal composition . preferably , however , the pesticide compositions of this invention will be in the form of solutions or suspensions containing from about 0 . 1 to about 1 . 0 % by weight of the active pesticide compound .
a composition of matter is described herein which has insecticidal and miticidal activity and methods of use . the composition may be defined by the following generic formula : ## str1 ## wherein r 1 and r 2 are independently methyl or halogen , preferably methyl or chlorine .