before exposure , the single - component dental material according to the invention , which can be used as a temporary crown and bridge material , is present in a first , plastic phase , during which the material can be deformed in any desired manner . in connection with the production of temporary crowns and bridges , for example , the dental material according to the invention is repositioned on the patient &# 39 ; s jaw , for example in an impression tray , during the plastic phase , and this takes about 45 seconds . because of the viscosity between 10 and 100 , 000 pa · s provided according to the invention , as well as the consistency ( analogous to iso 4823 ) between 50 and 15 mm provided according to the invention , the dental material is sufficiently capable of flow , during the plastic phase , so that it can reproduce even tiny dental characteristics when repositioned on the jaw . after repositioning on the patient &# 39 ; s jaw , the dental material is exposed with an exposure period and / or exposure intensity that is less than that required for complete activation of the photoinitiator , for example for 10 seconds , after which the material passes through an elastic phase that lasts between 15 and 90 seconds , in which the material demonstrates a modulus of elasticity between 1 and 50 mpa . in this phase , the material can be removed from the patient &# 39 ; s mouth again , without any additional , undesirable deformation occurring due to the great recovery during the elastic phase . in order to assure a sufficiently long working time during the elastic phase , the increase in the modulus of elasticity that begins after photoinitiation should amount to between 0 . 5 and 0 . 0001 mpa / sec , preferably between 0 . 3 and 0 . 001 mpa / sec , particularly preferably between 0 . 25 and 0 . 002 mpa / sec , and very particularly preferably less than or equal to 0 . 21 mpa / sec , during the elastic phase , per time unit . after removal of the temporary from the patient &# 39 ; s mouth , the dental material is exposed a second time , causing the part of the photoinitiator that was not yet activated to be converted to radicals and bringing about final curing to a duroplastic final state . because of the modulus of elasticity provided according to the invention , of at least 1 , 000 mpa , and the bending strength provided according to the invention , of at least 90 mpa , the dental material demonstrates sufficient stability for a crown or bridge in the duroplastic phase . ( light - curing ( temporary ) crown and bridge material according to the invention , having a marked elastic time phase , using a semi - reinforcing silicic acid as filler , and a camphor quinone / dimethylaminobenzoic acid ethyl ester photoinitiator system ) 0 . 28 parts d , l - camphor quinone and 0 . 01 parts dimethylaminobenzoic acid ethyl ester were dissolved , in a light - protected vacuum mixing beaker , in a mixture of 65 parts 2 , 2 - bis -[ 4 - hydroxy - 3 - methacryloyloxy - propoxy ) phenyl ]- propane ( bis - gma ), 20 parts ethoxylated ( 10 eo ) bisphenol a dimethacrylate ( e10badma ), 10 parts triethylene glycol dimethacrylate ( trgdma ), and 5 parts of a 1 : 1 isomer mixture of 7 , 7 , 9 - and 7 , 9 , 9 - trimethyl - 4 , 13 - dioxo - 3 , 14 - dioxa - 5 , 12 - diaza - hexadecane - 1 , 16 - d iol dimethacrylate ( udma ), respectively , and homogeneously mixed with 82 parts of a semi - reinforcing , highly disperse silicic acid surface - treated with methacryloxypropyl trimethoxysilane , having a bet surface of 35 m 2 / g , and a carbon content of 3 %. to produce the tooth colors a1 , a2 , a3 , a5 , b1 , b2 , b3 , and bleaching colors , color pigments as described in european patent no . ep 0 836 845 b1 were used . the total content of hydroxyanisol and di - tert - butyl hydroxytoluene was 0 . 01 parts . a homogeneous , plastically deformable , moderately flowing , translucent paste was obtained , which can be stored in light - protected primary packaging , such as tubes , syringes or cans , and is stable in storage for 24 months . the paste was treated , in various phases , with visible light of an led dental lamp ( 3m - espe freelight 100 mw / cm 2 ), the individual phases through which the material passes up to its final curing were characterized , and the application technology properties of the cured material were determined , whereby the values reproduced in tables 1 and 2 were obtained . as is evident from table 1 , the light - curing single - component crown and bridge material passes through three different phases : before the first exposure , the material was in a plastic time phase and demonstrated a viscosity of 100 pas , i . e . a consistency of 32 mm . therefore the material had an optimal flow capacity during this plastic time phase , which can be terminated at a desired point in time by means of exposure , and therefore can be as long as desired , so that it could be introduced into a shaping support , such as a molding material with an impression tray , or a thermoplastic dental tray , and flow against the prepared teeth or tooth stumps in the mouth . during and after a first exposure that lasted 10 seconds , the material made a transition from the plastic state described above into an elastic , deformable state . this elastic time phase lasted approximately 60 seconds . during the elastic time phase , the moduli of elasticity in the three - point bending test slowly increased at a rate of 0 . 03 mpa / sec , and were in a range between 10 and 30 mpa in this connection . the end of the elastic time phase could be recognized from the fact that the material became susceptible to breaking if additional mechanical stress was applied . after the end of the elastic time phase , the material was subjected to a second exposure having a duration of 160 seconds , whereby the material cured to a hard and impact - resistant composite , as is evident from the values reproduced in tables 1 and 2 . the final mechanical properties were achieved after 24 hours of storage in water at 35 ° c . ( according to din en iso 10477 ). from the above results , it is evident that the dental material according to the invention is excellently suitable for the production of ( temporary ) crowns and bridges . supplemental experiments using the material have shown that its characteristic properties are essentially independent of the exposure source used . thus , the same results were obtained when the material was exposed with other commercially available dental polymerization lamps , such as elipar free lights ( 400 mw / cm 2 ), optilux 501 ( 1500 mw / cm 2 ), elipar tri light ® ( 700 mw / cm 2 ), instead of the led dental lamp ( 3m espe freelight 1000 mw / cm 2 ). ( light - curing ( temporary ) crown and bridge material according to the invention , having a marked elastic time phase , using a filler combination of a semi - reinforcing silicic acid and nanoparticle formulations produced by way of the brine / gel method ) 0 . 21 parts d , l - camphor quinone and 0 . 01 parts dimethylaminobenzoic acid ethyl ester were dissolved , in a light - protected vacuum mixing beaker , in 22 . 7 parts of a nanoparticle formulation produced by way of the brine / gel method , consisting of a mixture of 66 % 2 , 2 - bis -[ 4 - hydroxy - 3 - methacryloyloxy - propoxy ) phenyl ]- propane ( bis - gma ) and 34 % triethylene glycol dimethacrylate ( trgdma ) with 50 % silicon dioxide nanoparticles ( average particle size 20 nm ), as well as 5 . 3 parts of a nanoparticle formulation produced by way of the brine / gel method , of 80 % of a 1 : 1 isomer mixture of 7 , 7 , 9 - and 7 , 9 , 9 - trimethyl - 4 , 13 - dioxo - 3 , 14 - dioxa - 5 , 12 - diaza - hexadecane - 1 , 16 - d iol dimethacrylate ( udma ), respectively , and 20 % triethylene glycol dimethacrylate ( trgdma ) with 50 % silicon dioxide nanoparticles ( average particle size 20 nm ), and 10 . 9 parts ethoxylated ( 10 eo ) bisphenol a dimethacrylate ( e10badma ), and homogeneously mixed with 43 parts of a semi - reinforcing , highly disperse silicic acid surface - treated with methacryloxypropyl trimethoxysilane , having a bet surface of 35 m 2 / g , and a carbon content of 3 %. the total content of hydroxyanisol and di - tert - butyl hydroxytoluene was 0 . 1 parts . a homogeneous , plastically deformable , moderately flowing , translucent , slightly yellowish colored paste was obtained , which can be stored in light - protected primary packaging , such as tubes , syringes or cans , and is stable in storage for 24 months . the paste was treated , in various phases , with visible light of an led dental lamp ( 3m - espe freelight 1000 mw / cm 2 ), the individual phases through which the material passes up to its final curing were characterized , and the application technology properties of the cured material were determined , whereby the values reproduced in table 1 were obtained . as is evident from table 1 , the light - curing single - component crown and bridge material according to the invention passes through the three different phases described in example 1 . during the elastic phase , the moduli of elasticity in the three - point bending test increased slightly more slowly , at a rate of 0 . 02 mpa / sec , than in the case of the material obtained in example 1 , whereby the moduli of elasticity in the three - point bending test were in a range between 15 and 35 mpa . as is evident from the values reproduced in table 1 , the dental material obtained in example 2 is also excellently suitable for the production of ( temporary ) crowns and bridges . ( light - curing ( temporary ) crown and bridge material according to the invention , having a marked elastic time phase , using a semi - reinforcing silicic acid as a filler and a camphor quinone / dimethylaminobenzoic acid ethyl ester / hydroxyanisol photoinitiator system ) a dental material was produced as in example 1 , with the exception that 1 . 0 part instead of 0 . 01 parts dimethylaminobenzoic acid ethyl ester , and 1 . 0 part instead of 0 . 01 parts hydroxyanisol were used . a homogeneous , plastically deformable , moderately flowing , translucent paste was obtained , which can be stored in light - protected primary packaging , such as tubes , syringes or cans , and is stable in storage for 24 months . the paste was treated , in various phases , with visible light of an led dental lamp ( 3m - espe freelight 1000 mw / cm 2 ), the individual phases through which the material passes up to its final curing were characterized , and the application technology properties of the cured material were determined , whereby the values reproduced in table 1 were obtained . as is evident from table 1 , the light - curing single - component crown and bridge material according to the invention passes through the three different phases described in example 1 . during the elastic phase , the moduli of elasticity in the three - point bending test increased slightly more slowly , at a rate of 0 . 01 mpa / sec , as compared to the materials obtained in examples 1 and 2 , whereby the moduli of elasticity in the three - point bending test were in a range between 15 and 35 mpa . as is evident from the values reproduced in table 1 , the dental material obtained in example 3 is also highly suitable for the production of ( temporary ) crowns and bridges . a comparison of the properties of the materials obtained in examples 1 and 3 surprisingly shows that there is an optimum in the particularly preferred ratio of photoinitiator a ), co - photoinitiator b ), and photoretarder c ), at which a sufficiently long elastic phase with a sufficiently high modulus of elasticity is formed , on the one hand , and that in the duroplastic state , an optimum of mechanical / physical values , such as modulus of elasticity and bending strength , is also established . various commercially sold crown and bridge materials or dental composites , specified in greater detail in table 1 , were made to cure in accordance with the manufacturer &# 39 ; s information , the individual phases through which the materials pass until their final curing were characterized , and the application technology properties of the cured materials were determined , whereby the values reproduced in table 1 were obtained . as is evident from the values reproduced in table 1 , the light - curing materials used in comparison examples 1 to 4 demonstrate significantly poorer properties than the masses obtained in examples 1 to 3 . the dental material used in comparison example 1 , for example , has much too high a viscosity / consistency in the plastic phase to be optimally shaped by way of a shape carrier , i . e . not to deform the shape carrier because of the high viscosity / consistency . therefore , an accurate , detailed reproduction of the original tooth shape cannot be guaranteed with this mass . the same also holds true for the product used in comparison example 4 , in which the increase in the modulus of elasticity after the first exposure is furthermore extremely high , so that an elastic phase cannot form over a period of time that allows reasonable working . in the case of the material used in comparison example 1 , in the duroplastic end state , both the modulus of elasticity and the bending strength are furthermore too low to sufficiently withstand daily chewing stress even as a temporary . furthermore , the materials used in the comparison examples demonstrate significantly poorer technical data , such as modulus of elasticity , bending strength , and barcol hardness , than the dental materials obtained in examples 1 to 3 . accordingly , while only a few embodiments of the present invention have been shown and described , it is obvious that many changes and modifications may be made thereunto without departing from the spirit and scope of the invention .
a photopolymerizable single - component dental material , that is useful as a temporary , photopolymerizable single - component crown and bridge material . the material contains at least one compound that can be polymerized by means of photoinitiation , at least one photoinitiator , and filler , if necessary .