the present inventors have unexpectedly discovered that due to the small molecular size of the fluoride , and its affinity for multiple cross - linking sites , the fluoride can produce cross - linkage in hair and cause temporary or permanent restructuring of the hair ; i . e . causes straightening , smoothing , defrizzing and / or curling of the hair fiber . more particularly , the use of sodium fluoride can be used in hair products for straightening , smoothing , defrizzing and / or curling . sodium fluoride has excellent water solubility . unexpectedly , the present inventors have discovered that the fluoride can be used to crosslink other molecules to the hair to provide long lasting conditioning or volume to the hair . it can also be used to bind hair dye molecules in the hair for longer lasting coloring of the hair . sodium fluoride is an alternative to conventional hair products using formaldehyde . our data show that compositions for hair treatment having about 0 . 1 to about 15 %, preferably about 0 . 1 to about 3 . 0 %, and more preferably about 0 . 60 to about 1 . 25 % sodium fluoride at ph 4 . 8 , along with a polysaccharide thickener ( such as amigel ®) has a perceptible effect on curl reduction , and that smoothening or better alignment of hair fibers is observed for all normal and porous hair types . fig1 to 7 show the effects of a sodium fluoride composition on several hair types , normal and porous hair including 20 volume color treated and bleached hair . the results from examples 1 to 7 below are shown in fig1 to 7 , respectively . in each of the following examples , the hair was treated as follows : the hair was shampooed and blotted dry . the hair was combed and the treatment composition was applied on the hair for 35 minutes at room temperature with a brush and then it was treated as in the directions below for each of examples 1 to 7 . for all hair samples marked “ a ”, the treatment composition was applied for 35 minutes and then the hair was rinsed with tap water . the hair was air - dried naturally . for all hair samples marked “ b ”, the treatment composition was applied for 35 minutes and then the hair was rinsed with tap water . the hair was blow dried to about 90 % and then flat ironed at 430 ° f . the hair was then rinsed with tap water . for all hair samples marked “ c ”, the treatment composition was applied for 35 minutes and then the hair blow dried at a medium setting to about 90 %, and then flat ironed at 430 ° f . the hair was then rinsed with tap water , and the hair was air - dried naturally . for example 1 , shown in fig1 , a composition of the present disclosure containing 1 % sodium fluoride at ph 4 . 8 was applied to very curly normal hair . for example 2 , shown in fig2 , a composition of the present disclosure containing 1 % sodium fluoride at ph 4 . 8 was applied to very curly 20 volume hair . for example 3 , shown in fig3 , a composition of the present disclosure containing 1 % sodium fluoride at ˜ ph 4 . 8 was applied to very curly 40 volume bleached hair . for example 4 , shown in fig4 , a composition of the present disclosure containing 1 % sodium fluoride at ˜ ph 4 . 8 was applied to wavy 20 volume hair . for example 5 , shown in fig5 , a composition of the present disclosure containing 2 % sodium fluoride at a ph of approximately 4 . 8 was applied to very curly normal hair . for example 6 , show in fig6 , a composition of the present disclosure containing 1 . 5 % sodium fluoride at a ph of approximately 4 . 8 was applied to 40 volume bleached hair . for example 7 , samples a , b , and c were treated as follows : the treatment composition was applied to the hair for 35 minutes . the hair was blow dried at medium heat setting to about 90 % dry , and then flat - ironed at 430 ° f . the hair was then rinsed with tap water , and the hair was air dried naturally . samples o and z were treated as follows : the treatment composition was applied to the hair for 35 minutes , and then the hair was blow dried at a medium heat setting to about 90 % dry . the hair was then flat - ironed at 430 ° f ., and then was rinsed with tap water . the hair was then air dried naturally . as used in this application , the word “ about ” for dimensions , weights , and other measures , means a range that is ± 10 % of the stated value , more preferably ± 5 % of the stated value , and most preferably ± 2 % of the stated value , including all sub ranges there between . in practice of the present disclosure one or more other extended cosmetic compositions can be included for their generally acceptable recognized purposes . these can include soothing agents , such as aloe or allantoin gelatin ; auxiliary emollients , such as squalene , mineral oil , argan oil , coconut oil , jojoba oil , walnut oil or liquid silicones ; fatty alcohol based thickeners , such as cetyl alcohol , cetearyl alcohol , or stearic acid ; low to no foaming cationic , nonionic or amphoteric emulsifiers ; or preservatives , such as phenoxyethanol , sorbitol , potassium sorbate , sodium sorbate , methyl paraben , propyl paraben , imidazolidynyl urea , or dmdm hydantoin . the composition may also contain a fragrance to neutralize any malodors of the composition . the hair swatches are shampooed with a clarifying shampoo , towel blot and dried at medium heat with blow dryer . the composition i product was applied liberally to the hair with a tint brush and processed for 35 minutes . the excess product was towel blotted and the hair is dried to about 95 % with a blow dryer at low heat followed with flat ironing @ 430 ° f . using 7 - 8 passes . the hair was rinsed after 48 hours . the performance % curl reduction , shine and smoothness the hair swatches are shampooed with clarifying shampoo , towel blot and dried at medium heat with blow dryer . the composition i product was applied liberally to the hair with a tint brush and processed for 35 minutes . the excess product was towel blotted and hair was blow dried straight at high heat setting using a brush . the hair was rinsed after 48 hrs . the performance % curl reduction , the hair swatches are shampooed with clarifying shampoo , towel blot and dried at medium heat with blow dryer . the composition i product was applied liberally to the hair with a brush and processed for 35 minutes . the excess product was towel blotted and air dried from the hair . the hair was rinsed after 48 hrs . the performance % curl reduction , shine and smoothness was evaluated . the hair swatches are shampooed with clarifying shampoo , towel blot and dried at medium heat with blow dryer . the composition i was applied liberally to the hair with a brush and processed for 35 minutes . the hair was rinsed with luke warm water . the hair is dried to about 95 % with a blow dryer at low heat followed with flat ironing @ 430 ° f . using 7 - 8 passes . the hair was rinsed after 48 hours . the tabulated data of table i above shows that the overall performance of curl reduction , shine and smoothness on hair depends on the ph of composition i and method of application . the performance appears to be dependent on the ph and independent of the type of ph adjustor . the optimum performance of composition i ph range on normal , color treated and bleached hair , appears to be between 4 - 5 . also , the performance effects are dependent on the method of application of composition i . application methods a and d are preferable over methods b and c . both methods a and d have high heat flat ironing greater than 400 f .° with composition i or rinsed off the hair . curl reduction , increase in smoothness and shine of 40 - 80 % have been observed on normal , color treated and bleached hair . the hair swatches are shampooed with clarifying shampoo , towel blot and dried at medium heat with blow dryer . the composition i product was applied liberally to the hair with a tint brush and processed for 35 minutes . the excess product was towel blotted and the hair is dried to about 95 % with a blow dryer at low heat followed with flat ironing @ 430 ° f . using 7 - 8 passes . the hair was rinsed after 48 hours . the hair swatches are shampooed with clarifying shampoo , towel blot and dried at medium heat with blow dryer . the composition i product was applied liberally to the hair with a tint brush and processed for 35 minutes . the excess product was towel blotted and hair was blow dried and straightened at high heat setting using a brush . the hair was rinsed after 48 hrs . the performance % curl reduction , the hair swatches are shampooed with clarifying shampoo , towel blot and dried at medium heat with blow dryer . the composition i product was applied liberally to the hair with a brush and processed for 35 minutes . the excess product was towel blotted and air dried from the hair . the hair was rinsed after 48 hrs . the performance % curl reduction , shine and smoothness was evaluated . the tabulated data on table ia shows that the optimum ph of composition i for maximum performance is about 4 . 50 . this is in agreement with the previous data of table i . exceptional curl reduction , smoothing and shine is observed on all hair types including normal , color treated and multi bleached hair . performance effects of 1 treatment , 1 wash , 5 wash , 10 wash and 2nd treatment with 0 . 75 % naf composition ii - b on very curly / frizzy hair ( normal , color treated and 2x bleached hair type ) process a : the hair swatches were shampooed with an alkaline shampoo ( ph = 8 . 10 ), towel blot and dried at medium heat with blow dryer . the composition ii - b product was applied liberally to the hair with a tint brush and processed for 35 minutes . the excess product was towel blotted and the hair is dried to about 95 % with a blow dryer at low heat followed with flat ironing @ 430 ° f . using 7 - 8 passes . the hair was rinsed after 48 hours . one of the swatch was rinsed and evaluated , the second swatch was washed 1 times and evaluated , the third swatch washed 5 times and evaluated , the fourth swatch was washed 10 times and evaluated and the fifth swatch was washed 10 times and 2nd treatment was repeated and after 48 hours the tabulated data on table ii shows that the performance longevity of a single treatment with composition ii - b can last multiple shampoos . in addition , the performance of repeat or double treatments increases significantly the performance in curl reduction , shine and smoothness . curl reduction study at higher ph range with 0 . 50 % naf composition ii - b on very curly / frizzy hair process a : the measurement of the initial length ( l0 ) and ( l100 ) of each swatch was taken . the hair swatches were shampooed with clarifying shampoo , towel blot and dried at medium heat with blow dryer . the composition ii “ b ” with different ph range was applied liberally to the hair with a tint brush and processed for 35 minutes . the excess product was towel blotted and the hair is dried to about 95 % with a blow dryer at high heat followed by flat ironing @ 430 ° f . using 7 - 8 passes . the hair was rinsed after 48 hours and air dried . % curl reduction was calculated with the final length ( lt ) the data of table iii shows the performance of composition iib , 0 . 50 % naf above ph 8 . 05 shows no advantages . this is probably due to unfavorable crosslinking between unprotonated amino r ′— n — r ″ ( r ′═ h , c ═ o or r ″═ h , c ═ o ) peptide side terminals and the fluoride ion that occurs at high ph . whereas the ph decreases the protonation of the amino group and specifically the peptide side terminals of lysine , arginine r — nh3 + and will favor crosslinking with the fluoride ion . these side terminal crosslinks r — nh3f , — n — h2f , — n — hf or possible amide crosslinks f — n — c ═ o are more favorable at low ph . alternatively , favorable crosslinking may occur with the side oh side terminals of threonine and serine or indirect crosslinking followed by dehydration for threonine side terminal . the hair swatches are shampooed with clarifying shampoo , towel blot and dried at medium heat with blow dryer . the composition ii product was applied liberally to the hair with a tint brush and processed for 35 minutes . the excess product was towel blotted and the hair is dried to about 95 % with a blow dryer at low heat followed with flat ironing @ 430 ° f . using 7 - 8 passes . the hair was rinsed after 48 hours . the hair swatches are shampooed with shampoo , towel blot and dried at medium heat with blow dryer . the composition ii product was applied liberally to the hair with a brush and processed for 35 minutes . the hair was rinsed with luke warm water . the hair is dried to about 95 % with a blow dryer at low heat followed with flat ironing at 430 ° f . using 7 - 8 passes . the hair was rinsed after 48 hours . the performance % curl reduction , shine and smoothness was evaluated . the tabulate data of table iv shows that the performance on normal hair is not affected greatly with the concentration increase of naf from 0 . 5 - 2 . 50 %. however , on porous hair 20 volume and twice 40 volume bleached hair , naf concentration effects are observed . the data shows equivalent performance to 0 . 5 % formaldehyde is obtained with 0 . 23 % f ( 0 . 50 % naf ). this observation can be explained due to the presence of larger number of ionic sites in hair which result in greater crosslinking and overall performance of curl reduction and smoothing effects . it also suggests that the crosslinking reactions of the fluoride and formaldehyde with hair may not entirely be the same . the specificity of crosslinking with the fluoride is greater than formaldehyde , thus more predictable results can be obtained . table v performance evaluation using treatment processes e , f and g ( normal , color treated and 2x bleached hair type ) composition ii - b naf 0 . 75 % amigel thickener 0 . 60 % glycerol 0 . 50 % phenoxyethanol 0 . 20 % 50 % phosphoric acid ph adjustment only qs di water qs . performance ph lo ( cm ) ls ( cm ) lt ( cm ) % curl reduction shine smoothness normal curly process e 4 . 49 13 . 0 20 . 0 14 . 5 21 . 43 % ++ ++ hair process f 4 . 49 13 . 0 20 . 0 15 . 0 28 . 57 % +++ +++ process g 4 . 49 13 . 0 20 . 0 15 . 0 28 . 57 % +++ +++ 20 vol / 6r process e 4 . 49 10 . 0 13 . 5 11 . 0 28 . 57 % ++ ++ color treated process f 4 . 49 10 . 0 13 . 5 11 . 0 28 . 57 % ++++ ++++ hair process g 4 . 49 13 . 0 20 . 0 15 . 0 28 . 57 % ++++ ++++ 2x bleached hair process e 4 . 49 14 . 0 18 . 0 16 . 0 50 . 00 % ++ ++ 40 vol process f 4 . 49 14 . 0 18 . 0 16 . 0 50 . 00 % ++++ ++++ process g 4 . 49 14 . 0 18 . 0 16 . 0 50 . 00 % ++++ ++++ different processes tested process e : wash hair with clarifying shampoo . towel blot excess water and blow dry in medium heat up to 95 % dry . apply the fluoride product thoroughly and comb hair through to ensure that all hair fibers are saturated with the product . process for 35 min . keep the hair straight during process time . rinse with luke warm water and towel blot excess water . apply a moisturizing leave - on conditioner and detangle the hair with the comb . blow dry hair in high heat . take thin sections and flat iron at approximately 430 ° f . with 7 - 8 passes , make sure that all the fibers are passed through the heat evenly . after 48 hours wash hair with sulfate free shampoo and conditioner . process f wash hair with clarifying shampoo . towel blot excess and blow dry in medium heat up to 95 % dry . apply the fluoride product thoroughly and comb hair through to ensure that all hair fibers are saturated with the product . process for 35 min . keep the hair straight during process time . towel blot excess product and apply a deep conditioning masque . comb through so that all the fibers are covered with masque . process for 10 min and rinse with luke warm water . towel blot excess water and blow dry in high heat . take thin sections and flat iron at approximately 430 ° f . with 7 - 8 passes , make sure that all the fibers are passed through the heat evenly . after 48 hours wash hair with sulfate free shampoo and conditioner . process g wash hair with clarifying shampoo . towel blot excess and blow dry in medium heat up to 95 % dry . apply the fluoride product thoroughly with a tint brush . comb hair through to ensure that all hair fibers are saturated with the product . process for 35 min . keep the hair straight during process time . towel blot excess product and apply a leave - on conditioner . comb through so that all the fibers are saturated . towel blot excess and blow dry up to 95 % dry . take very thin sections and flat iron at approximately 430 ° f . with 7 - 8 passes , make sure that all the fibers are passed through the heat evenly . section hair and apply the deep conditioning masque and process for 10 minutes . rinse with luke warm water and style as desired . % curl reduction evaluation : lo = initial length of curly hair ls = length of hair @ 100 % curl reduction lt = length of treated curly hair % ⁢ ⁢ curl ⁢ ⁢ reduction = lt - lo ls - lo ⨯ 100 shine and smoothness evaluation : grading 0 % ± 0 - 20 % + 20 - 40 % ++ 40 - 60 % +++ 60 - 80 % ++++ 80 - 100 % +++++ the data in table v shows the different methods of treatment application to enhance the conditioning effects with the fluoride treatment . all treatment methods e , f and g increase the conditioning and smoothing effects of hair . based on the results it appears that method g is the best where the fluoride is crosslinked first to the hair and the conditioning agents are further crosslinked by the fluoride . this multi - crosslinking effect of fluoride between the hair and the conditioning agent creates longer lasting effects between washes . comparative results with just hair conditioning treatments of masking or rinse off conditioners shows a temporary effect that does not last more than one or two shampoos . the fluoride crosslinked hair will have a strong affinity to bind different molecules , such as conditioning , antistatic , volumizing ingredients , keratin proteins and non - keratinous proteins . the crosslinking of fluoridated keratin reacts with functional groups of strong cationic character , such amino , mono or divalent cations forming strong ligand structures within the air . the formation of these additional structures will restructure hair and produce effects of increased softness , manageability and tensile strength . methods of sodium fluoride application on hair for maximum conditioning / smoothing effects wash the hair with clarifying shampoo . towel blot excess and blow dry in medium heat up to 95 % dry . apply the fluoride composition product on hair thoroughly . and comb through to ensure that all the fibers are saturated with the product . process for 35 min . keep the hair straight during process time . rinse with luke warm water and towel blot excess water . apply a leave - on conditioner and detangle the hair with the comb . blow dry with medium heat . take thin sections and iron hair with a preheated flat iron with a minimum of 7 - 8 passes , making sure that all the fibers are passed through evenly . after 48 hours wash hair with sulfate free shampoo and conditioner . wash the hair with clarifying shampoo . towel blot excess and blow dry in medium heat up to 95 % dry . apply the fluoride composition product on hair thoroughly and comb through to ensure that all the fibers are saturated with the product . process for 35 min . keep the hair straight during process time . towel blot excess product and apply a deep conditioner , reconstructor or conditioning masque with a tint brush . comb through so that all the fibers are covered with deep conditioner , reconstructor or conditioning masque . process for 10 min and rinse with luke warm water . towel blot excess water and blow dry with high heat . take thin sections and iron hair with a pre - heated flat iron with a minimum of 7 - 8 passes , making sure that all the fibers are passed through evenly . after 48 hours wash hair with sulfate free shampoo and conditioner . wash hair with clarifying shampoo . towel blot excess and blow dry hair in medium heat up to 95 % dy . apply the fluoride composition product on hair thoroughly and comb through to ensure that all the fibers are saturated with the product . process for 35 min . keep the hair straight during process time . towel blot excess product and apply a leave - on conditioner . comb through so that all the fibers are saturated . towel blot excess and blow dry up to 95 % dry . take very thin sections and iron hair with a pre heated flat iron with a minimum of 7 - 8 passes , making sure that all the fibers are passed through evenly . section hair and apply a deep conditioner , reconstructor or conditioning masque and process for 10 minutes . rinse with luke warm water and style as desired . detection of fluoride ion in normal , colored and bleached single treated hair fibers with composition ii , 0 . 75 % na f @ ph 4 . 51 analysis of fluoride ion in single treated hair initially and after hair type : normal , 20 vol / 6r color treated and 2x bleached hair . variations : 1 treatment ; 3 wash ; 5 wash ; 10 wash and 15 washes buffer solution : 25 ml . tisab ii + 25 ml . di h 2 o for immersing the hair sample for 48 hours . standards for calibration : 2 , 4 , 6 , 10 , 20 ( μg / ml ) fluoride ion all the hair swatches were washed with an alkaline shampoo at ph 8 . 09 . the controls and the samples to be treated were dried to 95 % with blow dryer , at medium heat setting . the hair swatches ( approximately 5 inch in width ) were treated with composition ii ( 0 . 75 % naf ) ph = 4 . 51 . processed for 35 min . towel blot excess . dried up to 95 % dry with blow dryer at medium heat followed with flat ironing small sections of hair at approximately 430 ° f . with 7 - 8 passes . after 48 hours the hair was rinsed with copious amounts of water and hair was dried at ambient conditions and cut into small 1 / 16 ″ sections . the hair was further equilibrated under ambient conditions for 8 hours and hair samples weighed about 0 . 5 grams and were immersed into 50 ml of buffer solutions 1 : 1 total ionic strength adjustment buffer ( tisab ii ): deionized water for 48 hours . direct analysis of the fluoride ion was carried out in the leached solutions using the fluoride ion selective electrode potentiometric method ( astm d 1179 - 72 ) approved by the american society of testing and materials . the hair swatches were washed 3x , 5x , 10x and 15 x , and the hair was dried with blow dryer between the washes . the multi washed hair samples were analyzed as above . the data in table vi shows that fluoride is detected in normal , colored and bleached hair treated hair . based on the assay results about 3 , 400 μmoles f / g hair is detected in water / buffer leaches of normal and color treated hair . this is compared to 1 , 800 μmoles f / g hair for bleached hair . this detection of fluoride in treated hair even after fifteen washes suggest that stable crosslinking has occurred and it is resistant to conventional shampooing and conditioning . the detection of fluoride in the buffer / water leaches is about 42 - 46 % after fifteen shampoos showing slow rate of depletion or leaching of fluoride from hair . based on these observations long lasting results of up to fifteen or more shampoos should be expected from a single treatment . procedure : hair for tensile testing was prepared with five bundles of twelve hair fibers ( total of 60 fibers ) of similar texture with normal , 20 volume , 2 × bleached hair . the bundles were immersed in water for 1 - 2 hours and the initial wet tensile strength of all the bundles was evaluated at 20 % extension using an instron model 1122c5054 at 0 . 5 inch / minute . the bundles after 24 hours were washed , blow dried with a paddle brush to about 95 % and the naf composition i at ph 4 . 50 was applied with the tint brush and processed for 35 minutes . after the excess product was towel blotted and blow dried to about 95 % with medium heat using a paddle brush , each bundle were flat ironed at approximately 430 ° c . with 7 - 8 passes . after 24 hours , the fibers were soaked in di water and after 45 minutes the tensile strength of bundles was determined under the identical conditions . the tensile strength of bundles was determined versus untreated fibers with composition i . the wet tensile strength of each bundle was calculated as 20 % index given below : the tensile strength studies showed that statistically a single treatment of normal , colored and bleached hair with the fluoride composition i statistically and significantly improved the tensile strength . the wet strength is attributed by adding support to the alpha helical crosslinks of cystine . this is not an expected effect for wet strength since all secondary bonds should be minimized in water . it is interesting that formaldehyde has significantly decreased the tensile strength of hair which suggests the weakening of these crosslinks . this supports our understanding that the crosslinking reactions and mechanism between the fluoride and formaldehyde is different . differential scanning calorimetry ( dsc ) techniques published earlier by cao ( j . cao , melting study of the α crystallites in human hair by dsc , thermody . acta , 335 ( 1999 ) and f . j . wortmann , ( f . j wortmann , c . springob , and g . sendlebach , investigations of cosmetically treated human hair by dsc in water , iffcc . ref 12 ( 2000 ) are used to study the structural changes of hair by measuring the thermal decomposition pattern or behavior . the thermal stability of hair is evaluated by measuring the amount of thermal energy required for denaturation or phase transition . the technique measures the amount of heat transferred into and out of a sample in a comparison to a reference . the heat transfer in ( endothermic ) and out ( exothermic ) is detected and recorded as a thermogram of heat flow versus temperature . the technique gives valuable information on the morphological components of hair of feughelman &# 39 ; s accepted two phase filament matrix model for hair ( m . feugelman , a two phase structure for keratin fibers , text . res . 1 , 29 , 223 - 228 , 1959 ). this two phase model includes the crystalline filaments ( alpha helical proteins ) or traditionally referred to as microfibrils which are embedded in an amorphous matrix . the dsc data technique yields thermogram data on the denaturation temperature t m and the denaturation enthalpy ( delta h ) of hair . it is concluded that the thermogram data of the denaturation temperature t m of hair is dependent on the crosslink density of the matrix in which surrounds the microfibrils or crystalline filaments . also , the denaturation enthalpy ( delta h ) depends on the strength of the crystalline filaments or microfibrils . it has been shown that cosmetic treatments , such as bleaching or perming , effect these morphological components selectively and differently at different rates causing changes in denaturation temperatures and in heat flow . dsc was use to analyze the effects of naf treatment on normal , 20 volume color treated and four times bleached hair . the treatment included process a using composition i at 1 % naf at ph 4 . 50 . the hair after 48 hours was rinsed and dried at ambient temperature conditions and relative humidity ( 20 c .°, 65 % rh ). the hair samples were cut into small pieces of about 2 mm in length and about 4 - 7 mg weighed into aluminum pans followed with capping . the hair samples were analyzed using perkin elmer diamond dsc instrument and a method of 50 c .° to 280 c .° at 20 c .°/ minute using an empty capped aluminum pan as reference . the obtained dsc thermograms for treated and untreated hair samples showed single endothermic ( absorbed thermal energy ) denaturation temperatures t m ranging from 178 to 189 c .° and delta h from 154 to 340 ( j / g ). the comparative tabulated data below for normal untreated and treated hair shows differences in the denaturation temperatures of 178 . 88 and 184 . 33 c .°, respectively , with no differences in the delta h . this is due to changes in the crosslink density of the matrix attributed by an increase in the crosslink density of the matrix proteins with naf . based on the delta h it is assumed that the intermediate filaments or alpha helical protein regions or microfilaments are not affected . the results for 20 volume color treated and untreated hair show significant statistically changes in the delta h ( p = 0 . 00019 ) of 226 . 53 and 270 . 01 ( j / g ) and no changes in the denaturation temperature . this observation suggests that the effects of naf on 20 volume color treated hair are primarily on the alpha helical protein regions with no effect on the matrix proteins . the multi bleached hair fibers show statistically differences in the denaturation temperatures 187 . 76 and 181 . 49 c .° and delta h 260 . 28 and 318 . 16 ( j / g ) between untreated and treated samples . this observation suggests that both the matrix proteins and the alpha - helical proteins are affected by the naf treatment . this data is in good agreement with previously reported data by humphries et al . jscc , 1972 on oxidized and colored dried hair showing higher denaturation temperatures and delta h . the explanation may be explained by an increase in crosslinked bridges between the polypeptide chains giving more structural support . this appears to be the same observation with the naf increasing the overall support for hair through crosslinking on the matrix proteins and alpha helical regions of the hair . it should be understood that the foregoing description is only illustrative of the present disclosure . various alternatives and modifications can be devised by those skilled in the art without departing from the disclosure . accordingly , the present disclosure is intended to embrace all such alternatives , modifications , and variances that fall within the scope of the disclosure .
a hair care composition containing inorganic fluoride for straightening , smoothing , and / or relaxing hair , and a method for using the hair care composition a hair care composition containing an inorganic fluoride for straightening , smoothing , defrizzing , curling and / or relaxing of hair , and its method of use in a variety of hair care products , e . g ., straightener solution , shampoo , conditioner , color binding treatment , volumizing treatment , a combination thereof , etc . the hair care composition is formaldehyde - free , even when heated .