the compositions according to the invention are oil - in - water emulsions . the present invention relates to a composition suitable for use as a calf milk replacer comprising from about 1 wt . % to about 30 wt . % fat phase , from about 70 wt . % to about 99 wt . % aqueous phase , and from about 0 . 05 wt . % to about 5 . 0 wt . % of a membrane separated lecithin having a ratio of alkali metals to alkaline earth metals ranging from greater than 0 to about 10 , preferably greater than 0 to about 5 . in another embodiment , the composition comprises from about 1 wt . % to about 30 wt . % fat phase , from about 70 wt . % to about 99 wt . % of an aqueous phase , and from about 0 . 05 wt . % to about 5 . 0 wt . % of a lecithin having a ratio of alkali metals to alkaline earth metals ranging from about 1 . 6 to about 3 . 0 , preferably about 1 . 8 to about 2 . 8 . the fat phase may comprise any vegetable and / or animal oils or fats that are natural or modified by interesterification , hydrogenation , fractionation , and the like . the composition of the present invention can be produced by any known methods . for example , a fat phase is prepared comprising an oil and a lecithin product of the present invention . the fat phase is mixed with an aqueous phase . in the present composition , the fat phase of about 1 wt . % to about 30 wt . % of any oil is used . in particular , the fat phase suitable for use is about 2 wt . % to about 15 wt . %. any oil , which may be solid or liquid at ambient temperature , can be used in the present food composition . suitable vegetable oils for use include , for example , soybean oil , sunflower oil , rapeseed oil , cottonseed oil , olive oil , corn oil , ground nut oil , safflower oil , linola oil , linseed oil , palm oil , coconut oil , all of which may be partially or completely hydrogenated or modified otherwise , and mixtures thereof . particularly useful are soybean oil and partially hydrogenated soybean oil . suitable oils of animal origin for use include , for example , butterfat and fish oil . in addition to the above - mentioned ingredients , the fat phase may optionally contain further fat - soluble ingredients . examples of these materials are colorants , fat - soluble flavors and vitamins , fat soluble emulsifiers and stabilizers , and the like . the optional aqueous phase of the present composition may comprise water and optionally contain further water - soluble ingredients suitable for use . examples of these materials are proteins , flavors which are water soluble , emulsifiers , thickeners , salt , sugars , dairy ingredients , preservatives , and the like . in the present composition , about 0 . 05 wt . % to about 5 . 0 wt . % of a lecithin having an acetone soluble content of about 35 wt . % to about 40 wt . % and a ratio of greater than 0 to about 10 of alkali metals to alkaline earth metals in monovalent or divalent ionic state , is used . in particular , a membrane separated lecithin having a ratio of 1 . 9 alkali metals to alkaline earth metals is used . the lecithin products of the present invention are in a first embodiment described as membrane separated lecithin having a ratio of alkali metals to alkaline earth metals ranging from greater than 0 to about 10 , and in another embodiment ranging from greater than 0 to about 5 . in a second embodiment the lecithin products of the present invention are described as lecithins having a ratio of alkali metals to alkaline earth metals ranging from about 1 . 6 to about 3 . 0 , and in another embodiment ranging from about 1 . 8 to about 2 . 8 . in determining the content of the alkali metals and alkaline earth metals of the lecithin product , the following test procedure is used : elemental analysis was performed by inductively coupled plasma - emission spectroscopy ( icp - es ) with target elements of aluminum , calcium , chromium , iron , lead , magnesium , nickel , potassium , phosphorus , silicon , sodium , and zinc . this analysis was performed according to the american oil chemists &# 39 ; society ( aocs ) official method ca 20 - 99 . each sample was weighed on an analytical balance to the nearest 0 . 0001 g . because of the range of concentration , two dilution levels are required . approximately 0 . 8 g of sample was weighted out and recorded . to the sample approximately 4 . 2 g of kerosene was weighted and recorded . the sample / kerosene mixture was vortexed until the sample is completely dissolved . approximately 4 . 2 g mineral oil was added to the sample / kerosene solution and recorded . this concentration is used to analyze the lower level elements , al , cr , fe , pb , na , ni , si , and zn . for the higher concentration elements , ca , mg , p and k , another dilution is made by taking approximately 0 . 5 g of the first dilution , recording the weight , and adding approximately 9 . 5 g of a 50 / 50 kerosene / mineral oil and record the total weight . all of the final dilutions are mixed until homogeneous . the samples are placed into a heated , 40 ° c ., sample hot plate along with the standards and allowed to come to temperature , approximately 10 minutes , prior to the introduction into the icp . samples were run in triplicate . the icp data is reported typically as ppm calcium , magnesium , potassium , sodium and phosphorous , along with other metals . the ppm values are divided by the atomic weight of the respective element ( ca : 40 , k : 39 , p : 31 and mg : 24 ) and the atomic equivalents are used to calculate the ratio of monovalent to divalent ( alkali metals to alkaline earth metals ). the lecithin products of the present invention may be prepared by any suitable manner . for example , a vegetable oil miscella may be passed through a membrane , preferably polymeric or semi - permeable , to obtain a retentate and a permeate . the lecithin products are in the retentate . exemplary of such methods are those appearing in u . s . pat . no . 6 , 207 , 209 to jirjis , et al . ; u . s . pat . nos . 4 , 496 , 498 and 4 , 533 , 501 to sen gupta . specific examples describing the preparation of lecithin products of the invention are provided as follows : two samples of miscella were prepared by using the present technique . miscella samples were obtained from two different oil seeds plants . a membrane was conditioned and used for removing phospholipids from each of the two samples of miscella . the membrane purchased was a pan membrane from osmonics , inc . the membrane can be characterized as having an average pore size of 0 . 3 micron , and in the form of a spiral wound 25 inch × 40 inch membrane element . the membrane was conditioned by soaking the membrane in an intermediate solvent ( propanol ) for 24 hours . then the membrane was soaked in mixture of intermediate solvent ( propanol ) and extraction solvent ( hexane ) for 24 hours . finally , the membrane was soaked in extraction solvent ( hexane ) for 24 hours . the two samples of miscella were individually processed . for the soybean oil miscella , the test was conducted at retentate concentration of 10 × of the feed concentration and the permeate rate of 10 × concentration was 100 liter / hour m 2 . for the corn miscella , the test was conducted at retentate concentration of 7 . 4 × of the feed at a permeate rate of 80 liter / hour m 2 . samples of soybean oil miscella were taken on different days and were treated by using the present technique . spiral wound 8 inch × 40 inch qx membranes were purchased from osmonics , inc . the membranes were conditioned and used for removing phospholipids by soaking them in an intermediate solvent ( 100 % isopropanol ) for 12 hours . at 6 hours , the intermediate solvent was recirculated at a flow rate of 15 m3 / hr per element and forced through the membrane pores for about 15 minutes using a pump ( this recirculation or forcing through is referred to as “ forced permeation ” for purposes of this example b ). then the resulting membrane was soaked in a 50 : 50 mixture of intermediate solvent ( 100 % isopropanol ) and extraction solvent ( 100 % commercial hexane ) for 12 hours . after 6 hours this soaking included recirculation at a flow rate of15 m 3 / hour per element and forced permeation for about 15 minutes . finally , the resulting membranes were soaked in extraction solvent ( 100 % commercial hexane ) for 12 hours , also with recirculation and forced permeation of the extraction solvent at 6 hours for about 15 minutes with 15 m 3 / hour recirculation flow . the resulting membranes treated with this process are “ conditioned membranes ” for purposes of this example b . the soybean miscella containing about 75 wt . % hexane , 24 . 3 wt . % crude oil , and 0 . 7 wt . % phospholipids , was passed through the first conditioned membrane at a trans - membrane pressure of 4 kgf / cm 2 at a rate of 0 . 6 m 3 / hour per element . the resulting retentate stream had about 7 wt . % phospholipids and 23 wt . % oil ( i . e ., the test was conducted at retentate concentration of 10 × of the feed concentration ). excess hexane was added to this retentate in the proportion of 2 portions of hexane to 1 portion of retentate resulting in a stream containing 88 wt % hexane . this retentate stream was passed through a second conditioned membrane at a trans - membrane pressure of 4 kgf / cm 2 at a rate of 0 . 35 m 3 / hour per element , resulting in a retentate stream having about 65 wt % hexane , 23 wt . % phospholipids and 12 wt . % oil which is equivalent to lecithin free of hexane with 66 % acetone insolubles . this retentate stream was desolventized at a rate of 1800 kg / hour , 95 ° c . and 260 mmhg absolute pressure . the resulting concentration of hexane was 5 %. the retentate stream was further desolventized at a temperature of 110 ° c . at an absolute pressure of 20 mm hg and sparge steam of 80 kg / hour by using a stripper to produce 600 kg / hour of lecithin product with less than 5 ppm of hexane . the compositions according to the present invention shows low creaming compared to the standard , which indicates the composition is a good emulsifier . the composition suitable for use as a calf milk replacer is supported by the following example . it should be understood that the example is not intended to limit the scope of the invention . the creaming test was used to determine the emulsifying property of the composition of the present invention suitable for use as a calf milk replacer . a fat phase , representative of the milk composition of a cow , was prepared by mixing 60 % refined coconut fat at 50 ° c . and 40 % refined paln oil at 50 ° c . in a glass beaker . 3 . 0 grams of membrane separated lecithin having 62 wt . % acetone insolubles and a ratio of 1 . 9 of alkali metals to alkaline earth metals was placed in a 150 - millimeter glass beaker , and 47 . 0 grams of the fat phase and 5 milligrams of sudan red iii colorant were added to the glass beaker . the beaker was then placed in a warm water bath to maintain the temperature at 50 ° c . 400 millimeter of demineralized water at 50 ° c . was placed in a 600 - millimeter glass beaker and the mixture of fat phase and lecithin was added to the water and mixed using a mixer ( ultraturrax comprised of a module by kinematica gmbh , switzerland , type reco 20t , and a polytron mixer type pt 10 / 35 by kinematica gmbh , switzerland ) for 2 minutes at 9900 rpm , which formed small droplets of an emulsino . this resulting emulsion was poured into a 500 - millimeter graduated cylinder . the creaming of a dark red layer at the top of the cylinder was measured every 10 minutes for 1 hour . the results are shown in table 1 . a standard of less than 15 millimeter creaming at 60 minutes indicates a good calf milk replacer . therefore , the composition of the present invention is suitable for use as a calf milk replacer . the invention has been described with reference to various specific and illustrative embodiments and techniques . however , one skilled in the art will recognize that many variations and modifications may be made while remaining within the spirit and scope of the invention .
there are disclosed compositions containing specified lecithins that are suitable for many applications , particularly as a calf milk replacer .