Difference between Null set and empty set One of my friend asked this doubt.Even in lower class we use both as synonyms,he says that these two concepts have difference.Empty set $\{ \}$ is a set which does not contain any elements,while null set ,$\emptyset$ says about a set which does not contain any elements.

I could not make out that...is his argument correct ? if so how ?
In measure theory, a null set refers to a set of measure zero. For example, in the reals, $\mathbb R$ with its standard measure (Lebesgue measure), the set of rationals $\mathbb Q$ has measure $0$, so $\mathbb Q$ is a null set in $\mathbb R$. Actually, all finite and countably infinite subsets of $\mathbb R$ have measure $0$. In contrast, the empty set always refers to the unique set with no elements, denoted $\left\{ \right\}$, $\varnothing$ or $\emptyset$.
I would call "null sets" in the Measure Theory sense "sets of measure 0" just to avoid any confusion. In many parts of mathematics, "null set" and "empty set" are synonyms.