For which $n$ are there primitive Pythagorean triples with legs of lengths $a$ and $a+n$? For which n can $a^{2}+(a+n)^{2}=c^{2}$ be solved, where $a,b,c,n$ are positive integers? 
I have found solutions for $n=1,7,17,23,31,41,47,79,89$ and for multiples of $7,17,23$...
Are there infinitely many prime $n$ for which it is solvable?
The general primitive solution to $x^2+y^2 = z^2$ is given by: $x=u^2-v^2$, $y=2uv$, $z=u^2+v^2$, with $u,v$ relatively prime and not both odd.

For $(a,a+n,z)$ to be a primitive triple, we'd have to have a $(u,v)$ such that: $|u^2 - v^2 - 2uv| = n$.  We can rewrite that as: $(u-v)^2 - 2v^2 = \pm n$

So, setting $w = u-v$, we want to find $(w,v)$ which are relatively prime and $w$ is odd, with:

$$w^2-2v^2 = \pm n$$

This means that $n$ must be odd.

In fact, we can use unique factorization in $\mathbb{Z}[\sqrt{2}]$ to show that $n$ can be any product of primes of the form $8k\pm 1$.  Since there are infinitely many primes of the form $8k\pm 1$, the answer to your question is, "yes."

(Oh, and once you find one solution $(w,v)$ for a particular $n$, you can find infinitely many solutions for that $n$.)
If you solve expression for $n$ you get 

$n=\sqrt{c^2-a^2}-a$, let's denote $b=\sqrt{c^2-a^2}$,so we have that $n=b-a$

Now,take look at picture bellow.Note that $AD=a$,and $BD=b-a=n$

If you change value of $b$ and keep $a$ to be constant you will get a infinite number of right triangles,and therefore infinite number of values of $n=b-a$,so answer is yes, there are infinitely many primes $n$ for which equation is solvable.