Sets and subsets: What is the difference between these two statements? Would it be correct to say that $\emptyset \subseteq \emptyset$ or $\emptyset \subseteq \{\emptyset\}$? To my understanding, the null set is just an empty set, so a null set is a subset of a set that contains the null set as an element, hence $\emptyset \subseteq \{\emptyset\}$ would be true. But wouldn't the first statement also be true? 

They are both true but mean different things altogether.
$\emptyset \subset \emptyset$ is true.
It is true for any of the following reasons and maybe more.
1) Every set is a subset of itself.
2) The emptyset is a subset of any set
3) The emptyset has no elements so every element is in the emptyset is vacuuously in the emptyset
4) there are no elements in the emptyset that are not in the emptyset.
$\emptyset \subset \{\emptyset\}$ is also true but it means something entirely different.
It is true because
1) The emptyset is a subset of any set.
2) The emptyset has no elements at all so every element it has is vacuously an element of $\{\emptyset\}$.
3) The emptyset doesn't have any elements not in $\{\emptyset\}$.
etc.
However the reason you gave:
"so a null set is a subset of a set that contains the null set as an element, hence ∅⊆{∅} would be true."
is completely wrong.
A set, $A$ is NOT as subset of a set containing it.
$A\not \subset \{A\}=B$
$A$ is an element of $B$ but the elements within $A$ are not elements of $B$ at all.  We never consider the elements within elements when determining subsets.
That $A\in B$ is no more relevant and has no more bearing on whether $A$ is subset of $B$ then whether $froofroothedog \in B$.
