Probability of choosing envelopes 
Suppose that you have 20 different letters and 10 distinctly addressed envelopes. The 20 letters consists of 10 pairs, where each pair belongs inside one of the 10 envelopes. Suppose that you place the 20 letters inside the 10 envelopes, two per envelope, but at random.
What is the probability that exactly 3 of the 10 envelopes will contain both of the letters which they should contain?

I have seen similar questions to this one but they always assign only one letter to one envelope. Also, the scenario is usually how to choose AT LEAST one right envelope. I am not too clear as to how to adapt to this new scenario.

Here a way to it.
(At the moment I must leave, so do not have the opportunity to work it out myself)

First let us solve the analogous question where it concerns $7$ enveloppes
and $14$ letters and where we must find the probability that $0$
of the $7$ enveloppes will contain both the letters which they should
contain.
Number the envelopes with $1,2,\dots,7$ and let $E_{i}$ denote the
event that the $i$-th envelop contains the letters which it should
contain.
Then to be found is $P\left(E_{1}^{\complement}\cap\cdots\cap E_{7}^{\complement}\right)=1-P\left(E_{1}\cup\cdots\cup E_{7}\right)$
and for term $P\left(E_{1}\cup\cdots\cup E_{7}\right)$ we can use
inclusion/exclusion and symmetry.
Now in the original problem number the envelopes with $1,2,\dots,10$
and to avoid confusion let here $A_{i}$ denote the event that the
$i$-th envelop contains the letters which it should contain.
Then the probability on exactly $3$ envelopes that contain the correct
letters can be expressed as:
$$\binom{10}{3}P\left(A_{1}^{\complement}\cap\cdots\cap A_{7}^{\complement}\cap A_{8}\cap A_{9}\cap A_{10}\right)=$$$$\binom{10}{3}P\left(A_{1}^{\complement}\cap\cdots\cap A_{7}^{\complement}\mid A_{8}\cap A_{9}\cap A_{10}\right)P\left(A_{8}\cap A_{9}\cap A_{10}\right)$$
Here: $$P\left(A_{8}\cap A_{9}\cap A_{10}\right)=P\left(A_{10}\right)P\left(A_{9}\mid A_{10}\right)P\left(A_{8}\mid A_{9}\cap A_{10}\right)$$
which is not difficult to find, and: $$P\left(A_{1}^{\complement}\cap\cdots\cap A_{7}^{\complement}\mid A_{8}\cap A_{9}\cap A_{10}\right)=P\left(E_{1}\cup\cdots\cup E_{7}\right)$$
where the RHS is found above.

Edit:
Let us choose for a more general approach: $n$ envelopes and $nm$ letters. 
Let $X_{n}$ denote the number of
envelopes containing the $m$ letters that they should contain. 
Our aim is to find an expression for $P\left(X_{n}=k\right)$.
Five the letters the numbers $1,2,\dots,n$ and let $A_i^{(n)}$ denote the event that the $i$-th letter contains the letters that it should contain.
In what follows now $A_i^{(n)}$ is abbreviated as $A_i$.
$\begin{aligned}P\left(X_{n}=k\right) & =\binom{n}{k}P\left(A_{1}\cap\cdots\cap A_{k}\cap A_{k+1}^{\complement}\cap\cdots\cap A_{n}^{\complement}\right)\\
 & =\binom{n}{k}P\left(A_{1}\cap\cdots\cap A_{k}\right)P\left(A_{k+1}^{\complement}\cap\cdots\cap A_{n}^{\complement}\mid A_{1}\cap\cdots\cap A_{k}\right)\\
 & =\binom{n}{k}P\left(A_{1}\cap\cdots\cap A_{k}\right)P\left(X_{n-k}=0\right)
\end{aligned}
$
Here: 
$\begin{aligned}P\left(A_{1}\cap\cdots\cap A_{k}\right) & =P\left(A_{1}\right)P\left(A_{2}\mid A_{1}\right)P\left(A_{3}\mid A_{1}\cap A_{2}\right)\cdots P\left(A_{k}\mid A_{1}\cap\cdots\cap A_{k-1}\right)\\
 & =\left[\frac{m}{nm}\frac{m-1}{nm-1}\cdots\frac{1}{nm-m+1}\right]\left[\frac{m}{nm-m}\frac{m-1}{nm-m-1}\cdots\frac{1}{nm-2m+1}\right]\left[\frac{m}{nm-2m}\frac{m-1}{nm-2m-1}\cdots\frac{1}{nm-3m+1}\right]\cdots\left[\frac{m}{nm-km+m}\frac{m-1}{nm-km+m-1}\cdots\frac{1}{nm-km+1}\right]\\
 & =\frac{\left(nm-km\right)!\left(m!\right)^{k}}{\left(nm\right)!}
\end{aligned}
$
In order to find $P(X_{n-k}=0)$ we now look at the situation where $n$ has changed into $n-k$.
The events $A_1^{(n-k)},\dots,A_{n-k}^{(n-k)}$ are abbreviated as $E_1,\dots,E_{n-k}$ and applying inclusion/exclusion and symmetry we find:
$\begin{aligned}P\left(X_{n-k}=0\right) & =P\left(E_{1}^{\complement}\cap\cdots\cap E_{n-k}^{\complement}\right)\\
 & =1-P\left(E_{1}\cup\cdots\cup E_{n-k}\right)\\
 & =\sum_{i=0}^{n-k}\binom{n-k}{i}\left(-1\right)^{i}P\left(E_{1}\cap\cdots\cap E_{i}\right)\\
 & =\sum_{i=0}^{n-k}\binom{n-k}{i}\left(-1\right)^{i}P\left(E_{1}\cap\cdots\cap E_{i}\right)\\
 & =\sum_{i=0}^{n-k}\binom{n-k}{i}\left(-1\right)^{i}\frac{\left(nm-km-im\right)!\left(m!\right)^{i}}{\left(nm-km\right)!}
\end{aligned}
$
Combining the results we find as final result:

$$P\left(X_{n}=k\right)=\frac{1}{\left(nm\right)!}\binom{n}{k}\sum_{i=0}^{n-k}\binom{n-k}{i}\left(-1\right)^{i}\left(nm-km-im\right)!\left(m!\right)^{k+i}$$

The special case where $n=10$, $m=2$ and $k=3$ gives probability: 

$$\frac{1}{20!}\binom{10}{3}\sum_{i=0}^{7}\binom{7}{i}\left(-1\right)^{i}\left(14-2i\right)!2^{3+i}$$

This agrees with the answer of @jeea.
