Almost sure convergence {Xn} is a sequence of independent random variables each with the same 
Sample Space {0,1} and Probability {1-1/$n^2$ ,1/$n^2$}
 Does this sequence converge with probability one (Almost Sure) to the constant 0?
Essentially the {Xn} will look like this (its random,but just to show that the frequency of ones drops)
   010010000100000000100000000000000001......

Let's elaborate on the answers already given, by considering the more general case where $X_n = 1$ with probability $a_n$ and $X_n = 0$ with probability $1-a_n$, where $a_n \downarrow 0$ (the typical cases being $a_n = 1/n$ and $a_n = 1/n^2$) and the $X_n$ are not necessarily independent.
The most natural approach is to use Borel-Cantelli lemma, as follows. Denote by $E_n$ the event $\lbrace X_n = 1 \rbrace$.
If $\sum\nolimits_{n = 1}^\infty  {{\rm P}(E_n )}  < \infty$, then the probability of $E_n$ occurring for infinitely many $n$ is $0$. Thus, if $\sum\nolimits_{n = 1}^\infty  {a_n}  < \infty$, then $X_n \to 0$ almost surely (that is, with probability $1$), since, almost surely, $X_n = 0$ for all $n$ sufficiently large. If, on the other hand, $\sum\nolimits_{n = 1}^\infty  {{\rm P}(E_n )}  = \infty$ and the events $E_n$ are independent, then the probability of $E_n$ occurring for infinitely many $n$ is $1$. Thus, if $\sum\nolimits_{n = 1}^\infty  {a_n}  = \infty$ and the $X_n$ are independent, then almost surely $X_n$ does not converge to $0$ (even though ${\rm P}(X_n = 0) \to 1$, which only gives that $X_n \to 0$ in probability).
As for chandok's approach, define $Y_n = \sum\nolimits_{k = 1}^n {X_k }$, so that $0 \leq Y_1 \leq Y_2 \leq \cdots$. Since the sequence $Y_n$ is monotone, it converges, say to $Y$ (which might be infinite). By the Monotone Convergence Theorem, ${\rm E}(Y_n) \to {\rm E}(Y)$ (to put it otherwise, $\int_\Omega  {Y_n \,{\rm dP}}  \to \int_\Omega  {Y\,{\rm dP}}$), where the right-hand side might be infinite (and is obviously infinite if $Y$ is). Now, ${\rm E}(Y_n) = \sum\nolimits_{k = 1}^n {a_k }$. Hence, if $\sum\nolimits_{k = 1}^\infty {a_k }$ is finite, then so is ${\rm E}(Y)$, or $\int_\Omega  {Y\,{\rm dP}}$. From measure theory (since $Y$ is nonnegative), it follows that $Y$ is almost everywhere finite, or, in our setting, $Y$ is almost surely finite. But $Y$ is finite if and only if $X_n = 0$ for all $n$ sufficiently large. So, $\sum\nolimits_{k = 1}^\infty {a_k } < \infty$ implies $X_n \to 0$. However, if $\sum\nolimits_{k = 1}^\infty {a_k } = \infty$, then one cannot a priori conclude from ${\rm E}(Y) = \infty$ that $Y$ is almost surely infinite (simply since a random variable can have infinite expectation).
EDIT: With the above notation and assuming that the $X_n$ are independent, the characteristic function $\varphi _{n } (u)$ of $Y_n$ is given by
$$
\varphi _{n } (u) = {\rm E}[e^{{\rm i}uY_n } ] = {\rm E}[e^{{\rm i}u(X_1  +  \cdots  + X_n )} ] = \prod\limits_{k = 1}^n {{\rm E}[e^{{\rm i}uX_k } ]}  = \prod\limits_{k = 1}^n {[(1 - a_k ) + a_k e^{{\rm i}u} ]}. 
$$
Now, $X_n \to 0$ if and only if $Y := \lim _{n \to \infty } Y_n $ is finite. So it is instructive to note here the following (general) result. If $\varphi _{n } (u)$ converges to a function $\varphi(u)$ for every $u \in \mathbb{R}$ and $\varphi(u)$ is continuous at $u=0$, then $\varphi(u)$ is the characteristic function of some distribution.
