Vector space structure on extensions of vector bundles Let $F, G$ be vector bundles on a scheme over the field of complex numbers. I know that the set $V:=Ext^1(F, G)$ has the structure of an additive group given by the Baer sum of extensions. But $V$ also has the vector space structure. Namely, if $a\in\mathbb{C}^*$ and $\xi\in Ext^1(F, G)$ is given by
$$0\longrightarrow G\stackrel{g}\longrightarrow E\stackrel{f}\longrightarrow F\longrightarrow 0$$
is it true that $a\cdot\xi$ is given by an extension
$$0\longrightarrow G\stackrel{g}\longrightarrow E\stackrel{a\cdot f}\longrightarrow F\longrightarrow 0?$$

In fact, $\operatorname{Ext}^1(F,G)$ admits two vector spaces structures. One which comes from $F$ and another one which comes from $G$. But you can show that these two structures are identical here.
The construction of the first one is as follow : let $a\in\mathbb{C}$ and consider the multiplication by $a$ map $a:F\to F$. You can form the pullback if $E\to F$ along $a$. This gives a commutative diagram :
$$
\require{AMScd}
\begin{CD}
0@>>> G@>>> E\times_{F,a} F@>>> F@>>>0\\
@.@|@VVV@VVaV\\
0@>>> G@>>> E@>>>F@>>>0
\end{CD}
$$
If $a=0$, then $E\times_{F,a} F$ is isomorphic to $G\oplus F$. Now if $a\neq 0$, then $a$ is an isomorphism so $E\times_{F,a} F$ is isomorphic to $E$. Modulo this isomorphism, the pullback diagram looks like :
$$
\require{AMScd}
\begin{CD}
0@>>> G@>>> E @>a^{-1}f>> F@>>>0\\
@.@|@|@VVaV\\
0@>>> G@>>> E@>>f>F@>>>0
\end{CD}
$$
Hence, the extension $a\xi$ is actually given by 
$$0\longrightarrow G\longrightarrow E\overset{a^{-1}f}\longrightarrow F\longrightarrow 0$$

For sake of completness, lets have a look at the other possible construction : we use instead the structure on $G$. Let $a\in\mathbb{C}$ and consider the multiplication by $a$ as a map $a:G\to G$. We can form the pushout diagram of $G\to E$ along $a$. This gives a commutative diagram :
$$
\require{AMScd}
\begin{CD}
0@>>> G@>>> E @>>> F@>>>0\\
@.@VaVV@VVV@|\\
0@>>> G@>>> G\coprod_{a,G} E @>>>F@>>>0
\end{CD}
$$
Again, if $a=0$ then $G\coprod_{a,G} E=G\oplus F$ and the extension splits. If $a\neq 0$, then $G\coprod_{a,G} E\simeq E$ and modulo this isomorphism the pushout looks like :
$$
\require{AMScd}
\begin{CD}
0@>>> G@>g>> E @>>> F@>>>0\\
@.@VaVV@|@|\\
0@>>> G@>a^{-1}g>> E @>>>F@>>>0
\end{CD}
$$
So for the second vector space structure, the class $a\xi$ is reprensented by 
$$0\longrightarrow G\overset{a^{-1}g}\longrightarrow E\longrightarrow F\longrightarrow 0$$

It remains to show that these two structures are identical, but this follows from the commutativity of :
$$
\require{AMScd}
\begin{CD}
0@>>> G@>a^{-1}g>> E @>f>> F@>>>0\\
@.@|@VaVV@|\\
0@>>> G@>>g> E @>>a^{-1}f>F@>>>0
\end{CD}
$$
