Chemistry in a gravitationally unstable protoplanetary disc
  Until now, axisymmetric, alpha-disc models have been adopted for calculations
of the chemical composition of protoplanetary discs. While this approach is
reasonable for many discs, it is not appropriate when self-gravity is
important. In this case, spiral waves and shocks cause temperature and density
variations that affect the chemistry. We have adopted a dynamical model of a
solar-mass star surrounded by a massive (0.39 Msun), self-gravitating disc,
similar to those that may be found around Class 0 and early Class I protostars,
in a study of disc chemistry. We find that for each of a number of species,
e.g. H2O, adsorption and desorption dominate the changes in the gas-phase
fractional abundance; because the desorption rates are very sensitive to
temperature, maps of the emissions from such species should reveal the
locations of shocks of varying strengths. The gas-phase fractional abundances
of some other species, e.g. CS, are also affected by gas-phase reactions,
particularly in warm shocked regions. We conclude that the dynamics of massive
discs have a strong impact on how they appear when imaged in the emission lines
of various molecular species.
