Reactivity of OH and CH3OH between 22 and 64 K: Modelling the gas phase
  production of CH3O in Barnard 1b
  In the last years, ultra-low temperature chemical kinetic experiments have
demonstrated that some gas-phase reactions are much faster than previously
thought. One example is the reaction between OH and CH3OH, which has been
recently found to be accelerated at low temperatures yielding CH3O as main
product. This finding opened the question of whether the CH3O observed in the
dense core Barnard 1b could be formed by the gas-phase reaction of CH3OH and
OH. Several chemical models including this reaction and grain-surface processes
have been developed to explain the observed abundance of CH$_3$O with little
success. Here we report for the first time rate coefficients for the gas-phase
reaction of OH and CH3OH down to a temperature of 22 K, very close to those in
cold interstellar clouds. Two independent experimental set-ups based on the
supersonic gas expansion technique coupled to the pulsed laser photolysis-laser
induced fluorescence technique were used to determine rate coefficients in the
temperature range 22-64 K. The temperature dependence obtained in this work can
be expressed as k(22-64 K) = (3.6+/-0.1)e-12 (T/ 300)^(-1.0+/-0.2) cm3
molecule-1 s-1. Implementing this expression in a chemical model of a cold
dense cloud results in CH3O/CH3OH abundance ratios similar or slightly lower
than the value of 3e-3 observed in Barnard 1b. This finding confirms that the
gas-phase reaction between OH and CH3OH is an important contributor to the
formation of interstellar CH3O. The role of grain-surface processes in the
formation of CH3O, although it cannot be fully neglected, remains
controversial.
