The first frost in the Pipe Nebula
  Spectroscopic studies of ices in nearby star-forming regions indicate that
ice mantles form on dust grains in two distinct steps, starting with polar ice
formation (H2O rich) and switching to apolar ice (CO rich). We test how well
the picture applies to more diffuse and quiescent clouds where the formation of
the first layers of ice mantles can be witnessed. Medium-resolution
near-infrared spectra are obtained toward background field stars behind the
Pipe Nebula. The water ice absorption is positively detected at 3.0 micron in
seven lines of sight out of 21 sources for which observed spectra are
successfully reduced. The peak optical depth of the water ice is significantly
lower than those in Taurus with the same visual extinction. The source with the
highest water-ice optical depth shows CO ice absorption at 4.7 micron as well.
The fractional abundance of CO ice with respect to water ice is 16+7-6 %, and
about half as much as the values typically seen in low-mass star-forming
regions. A small fractional abundance of CO ice is consistent with some of the
existing simulations. Observations of CO2 ice in the early diffuse phase of a
cloud play a decisive role in understanding the switching mechanism between
polar and apolar ice formation.
