On the Energetics of the HCO$^+$ + C $\to$ CH$^+$ + CO Reaction and Some
  Astrochemical Implications
  We explore the energetics of the titular reaction, which current
astrochemical databases consider open at typical dense molecular (i.e., dark)
cloud conditions. As is common for reactions involving the transfer of light
particles, we assume that there are no intersystem crossings of the potential
energy surfaces involved. In the absence of any such crossings, we find that
this reaction is endoergic and will be suppressed at dark cloud temperatures.
Updating accordingly a generic astrochemical model for dark clouds changes the
predicted gas-phase abundances of 224 species by greater than a factor of 2. Of
these species, 43 have been observed in the interstellar medium. Our findings
demonstrate the astrochemical importance of determining the role of intersystem
crossings, if any, in the titular reaction.
