Can neutral and ionized PAHs be carriers of the UV extinction bump and
  the diffuse interstellar bands?
  Up to now, no laboratory-based study has investigated polycyclic aromatic
hydrocarbon (PAH) species as potential carriers of both the diffuse
interstellar bands (DIBs) and the 2175 A UV bump. We examined the proposed
correlation between these two features by applying experimental and theoretical
techniques on two specific medium-sized/large PAHs (dibenzorubicene C30H14 and
hexabenzocoronene C42H18) in their neutral and cationic states. It was already
shown that mixtures of sufficiently large, neutral PAHs can partly or even
completely account for the UV bump. We investigated how the absorption bands
are altered upon ionization of these molecules by interstellar UV photons. The
experimental studies presented here were realized by performing matrix
isolation spectroscopy with subsequent far-UV irradiation. The main effects
were found to be a broadening of the absorption bands in the UV combined with
slight red shifts. The position of the complete pi - pi* absorption structure
around 217.5 nm, however, remains more or less unchanged which could explain
the observed position invariance of the interstellar bump for different lines
of sight. This favors the assignment of this feature to the interstellar PAH
population. As far as the DIBs are concerned, neither our investigations nor
the laboratory studies carried out by other research groups support a possible
connection with this class of molecules. Instead, there are reasonable
arguments that neutral and singly ionized cationic PAHs cannot be made
responsible for the DIBs.
