s amount may seem small, and is comparable to the concentration of radioactive potassium naturally present in bananas. Combined over the entire mass of the Earth's core, however, it can be enough to provide one-fifth of the heat given off by the Earth."
Lee and Jeanloz will report their findings on Dec. 10, at the American Geophysical Union meeting in San Francisco, and in an article accepted for publication in Geophysical Research Letters.
"With one experiment, Lee and Jeanloz demonstrated that potassium may be an important heat source for the geodynamo, provided a way out of some troublesome aspects of the core's thermal evolution, and further demonstrated that modern computational mineral physics not only complements experimental work, but that it can provide guidance to fruitful experimental explorations," said Mark Bukowinski, professor of earth and planetary science at UC Berkeley, who predicted the unusual alloy in the mid-1970s.
Geophysicist Bruce Buffett of the University of Chicago cautions that more experiments need to be done to show that iron can actually pull potassium away from the silicate rocks that dominate in the Earth's mantle.
"They proved it would be possible to dissolve potassium into liquid iron," Buffet said. "Modelers need heat, so this is one source, because the radiogenic isotope of potassium can produce heat and that can help power convection in the core and drive the magnetic field. They proved it could go in. What's important is how much is pulled out of the silicate. There's still work to be done "
If a significant amount of potassium does reside in the Earth's core, this would clear up a lingering question - why the ratio of potassium to uranium in stony meteorites (chondrites), which presumably coalesced to form the Earth, is eight times greater than the observed ratio in the Earth's crust. Though some geologists have asserted that the missing potassium resides in the core, there was no mechanism by which it could have reached the core. Other elements like oxygen and carbon form compounds or alloys with iron and presumably were dragged down by iron as it sank to the core. But at normal temperature and pressure, potassium does not associate with iron.
Others have argued that the missing potassium boiled away during the early, molten stage of Earth's evolution.
The demonstration by Lee and Jeanloz that potassium can dissolve in iron to form an alloy provides an explanation for the missing potassium.
"Early in Earth's history, the interior temperature and pressure would not have been high enough to make this alloy," Lee said. "But as more and more meteorites piled on, the pressure and temperature would have increased to the point where this alloy could form."
The existence of this high-pressure alloy was predicted by Bukowinski in the mid-1970s. Using quantum mechanical arguments, he suggested that high pressure would squeeze potassium's lone outer electron into a lower shell, making the atom resemble iron and thus more likely to alloy with iron.
More recent quantum mechanical calculations using improved techniques, conducted with Gerd Steinle-Neumann at the Universität Bayreuth's Bayerisches Geoinstitüt, confirmed the new experimental measurements.
"This really replicates and verifies the earlier calculations 26 years ago and provides a physical explanation for our experimental results," Jeanloz said.
The Earth is thought to have formed from the collision of many rocky asteroids, perhaps hundreds of kilometers in diameter, in the early solar system. As the proto-Earth gradually bulked up, continuing asteroid collisions and gravitational collapse kept the planet molten. Heavier elements – in particular iron - would have sunk to the core in 10 to 100 million years' time, carrying with it other elements that bind to iron.
Gradually, however, the Earth would have cooled off and become a dead rocky globe with a cold iron ball at the core if not for the continued release of heat by the decay of radioactive elements like potassium-40, uranium-238 and thorium-232, which have half-lives of 1.25 bil