lion, 4 billion and 14 billion years, respectively. About one in every thousand potassium atoms is radioactive.
The heat generated in the core turns the iron into a convecting dynamo that maintains a magnetic field strong enough to shield the planet from the solar wind. This heat leaks out into the mantle, causing convection in the rock that moves crustal plates and fuels volcanoes.
Balancing the heat generated in the core with the known concentrations of radiogenic isotopes has been difficult, however, and the missing potassium has been a big part of the problem. One researcher proposed earlier this year that sulfur could help potassium associate with iron and provide a means by which potassium could reach the core.
The experiment by Lee and Jeanloz shows that sulfur is not necessary. Lee combined pure iron and pure potassium in a diamond anvil cell and squeezed the small sample to 26 gigapascals of pressure while heating the sample with a laser above 2,500 Kelvin (4,000 degrees Fahrenheit), which is above the melting points of both potassium and iron. She conducted this experiment six times in the high-intensity X-ray beams of two different accelerators - Lawrence Berkeley National Laboratory's Advanced Light Source and the Stanford Synchrotron Radiation Laboratory - to obtain X-ray diffraction images of the samples' internal structure. The images confirmed that potassium and iron had mixed evenly to form an alloy, much as iron and carbon mix to form steel alloy.
In the theoretical magma ocean of a proto-Earth, the pressure at a depth of 400-1,000 kilometers (270-670 miles) would be between 15 and 35 gigapascals and the temperature would be 2,200-3,000 Kelvin, Jeanloz said.
"At these temperatures and pressures, the underlying physics changes and the electron density shifts, making potassium look more like iron," Jeanloz said. "At high pressure, the periodic table looks totally different."
"The work by Lee and Jeanloz provides the first proof that potassium is indeed miscible in iron at high pressures and, perhaps as significantly, it further vindicates the computational physics that underlies the original prediction," Bukowinski said. "If it can be further demonstrated that potassium would enter iron in significant amounts in the presence of silicate minerals, conditions representative of likely core formation processes, then potassium could provide the extra heat needed to explain why the Earth's inner core hasn't frozen to as large a size as the thermal history of the core suggests it should."
Jeanloz is excited by the fact that theoretical calculations are now not only explaining experimental findings at high pressure, but also predicting structures.
"We need theorists to identify interesting problems, not only check our results after the experiment," he said. "That's happening now. In the past half a dozen years, theorists have been making predictions that experimentalists are willing to spend a few years to demonstrate."
The work was funded by the National Science Foundation and the Department of Energy.