d enhanced light-matter interaction such as surface-enhanced Raman spectroscopy (SERS). A few of the more interesting applications from the literature and industry are outlined below.
Surface plasmon resonance sensors based on Kretschmann couplers can be used to make precise optical measurements at a metal-dielectric interface. The basic idea behind these detectors is encapsulated in the coupling condition discussed above for the Kretschmann geometry: k|| = nkosin(&theta) = kspp. Since the surface plasmon is tightly bound to the metal-dielectric interface, any changes in that interface will translate directly into changes in the surface plasmon wave-vector kspp. This will cause a corresponding change in the optimal excitation angle for the Kretschmann coupler; by measuring this angle, the change in kspp can be deduced, allowing for the change in the refractive index to be computed. These detectors are sensitive enough that they can measure a change in film thickness of just a single monolayer, or refraction index changes (for example, due to chemical binding events on a bio-functionalized gold surface) as small as 10-6 RIU (refractive index units). For example, the commercial sensiQ detector from Nomadics is capable of measuring binding events of just one picogram of protein/mm2.
More recently, there has been an explosion of interest in surface plasmons on nanoscale patterned surfaces. Using modern nanofabrication facilities, it is possible to make structures with feature sizes much smaller than the wavelength of visible light (&sim 500nm). For example, enhanced transmission through arrays of sub-wavelength slits has been experimentally demonstrated and has promising applications in photolithography and high-density optical data storage. Because surface plasmons can be launched at optical frequencies with much smaller wavelengths, it is possible to manipulate the flow of light on the scale of tens of nanometers. This has led to the coining of the term "plasmonics", where surface plasmons are used to manipulate an