In this study, a magnetized polyethylene composite has been prepared using ball milling procedure and employed as an efficient sorbent in magnetic dispersive solid phase extraction combined with dispersive liquid-liquid microextraction. This method has been utilized for the extraction and preconcentration of some pesticides from fruit juices prior to their quantification by gas chromatography-flame ionization detection. The prepared sorbent consisted of the natural iron oxide (obtained from sand) coated with polyethylene. In the present work, first a few mg of the magnetic composite is added into an aqueous solution containing the analytes and vortexed. After that the analytes are eluted with iso-propanol from the surface of the composite particles separated in the presence of a strong external magnetic field. For further enrichment of the analytes, 1,2-dibromoethane (at µL-level) as an extraction solvent is mixed with the obtained eluent and hastily injected into deionized water. The composite was characterized using techniques including vibrating sample magnetometry, X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, Brunauer-Emmett-Teller nitrogen sorption, and Fourier transform infrared spectrophotometry. Under optimal conditions, the method provided low limits of detection (0.94-1.9 μg L-1) and quantification (3.2-5.9 μg L-1), high enrichment factors (570-692), good linearity (r2 ≥ 0.994), and satisfactory repeatabilities (relative standard deviations ≤ 8% for intra- and inter-day precisions at a concentration of 15 μg L-1 of each analyte).
Chemical synthesis-free and facile preparation of magnetized polyethylene composite and its application as an efficient magnetic sorbent for some pesticides.