Related literature   {#sec1}
====================

For background to the coordination chemistry and bio-activity of hydrazinecarbodithio­ates, see: Khoo *et al.* (2005[@bb5]); Chan *et al.* (2008[@bb3]); Ravoof *et al.* (2010[@bb8]). For related structures, see: Paulus *et al.* (2011[@bb7]); Manan *et al.* (2012[@bb6]). For the synthesis, see: Tarafder *et al.* (2002[@bb10]).

Experimental   {#sec2}
==============

 {#sec2.1}

### Crystal data   {#sec2.1.1}

C~15~H~16~N~2~S~2~*M* *~r~* = 288.42Monoclinic,*a* = 5.7000 (1) Å*b* = 11.0136 (2) Å*c* = 22.7545 (4) Åβ = 95.198 (2)°*V* = 1422.60 (4) Å^3^*Z* = 4Cu *K*α radiationμ = 3.27 mm^−1^*T* = 100 K0.22 × 0.14 × 0.08 mm

### Data collection   {#sec2.1.2}

Oxford Diffraction Xcaliber Eos Gemini diffractometerAbsorption correction: multi-scan (*CrysAlis PRO*; Agilent, 2011[@bb1]) *T* ~min~ = 0.63, *T* ~max~ = 0.7715011 measured reflections2725 independent reflections2560 reflections with *I* \> 2σ(*I*)*R* ~int~ = 0.022

### Refinement   {#sec2.1.3}

*R*\[*F* ^2^ \> 2σ(*F* ^2^)\] = 0.035*wR*(*F* ^2^) = 0.097*S* = 1.032725 reflections179 parameters2 restraintsH atoms treated by a mixture of independent and constrained refinementΔρ~max~ = 0.44 e Å^−3^Δρ~min~ = −0.23 e Å^−3^

 {#d5e517}

Data collection: *CrysAlis PRO* (Agilent, 2011[@bb1]); cell refinement: *CrysAlis PRO*; data reduction: *CrysAlis PRO*; program(s) used to solve structure: *SHELXS97* (Sheldrick, 2008[@bb9]); program(s) used to refine structure: *SHELXL97* (Sheldrick, 2008[@bb9]); molecular graphics: *ORTEP-3* (Farrugia, 1997[@bb4]) and *DIAMOND* (Brandenburg, 2006[@bb2]); software used to prepare material for publication: *publCIF* (Westrip, 2010[@bb11]).

Supplementary Material
======================

Crystal structure: contains datablock(s) global, I. DOI: [10.1107/S160053681201567X/hg5209sup1.cif](http://dx.doi.org/10.1107/S160053681201567X/hg5209sup1.cif)

Structure factors: contains datablock(s) I. DOI: [10.1107/S160053681201567X/hg5209Isup2.hkl](http://dx.doi.org/10.1107/S160053681201567X/hg5209Isup2.hkl)

Supplementary material file. DOI: [10.1107/S160053681201567X/hg5209Isup3.cml](http://dx.doi.org/10.1107/S160053681201567X/hg5209Isup3.cml)

Additional supplementary materials: [crystallographic information](http://scripts.iucr.org/cgi-bin/sendsupfiles?hg5209&file=hg5209sup0.html&mime=text/html); [3D view](http://scripts.iucr.org/cgi-bin/sendcif?hg5209sup1&Qmime=cif); [checkCIF report](http://scripts.iucr.org/cgi-bin/paper?hg5209&checkcif=yes)

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: [HG5209](http://scripts.iucr.org/cgi-bin/sendsup?hg5209)).

Support for the project came from Universiti Putra Malaysia under their Research University Grant Scheme (grant No. 9174000) and from the Malaysian Ministry of Science, Technology and Innovation (grant No. 09--02-04--0752-EA001). We also thank the Ministry of Higher Education (Malaysia) for funding structural studies through the High-Impact Research scheme (UM.C/HIR/MOHE/SC/12).

Comment
=======

The study of hydrazinecarbodithioate derivatives, their coordination chemistry and bio-activities has been carried out in our laboratory for a number of years (Khoo *et al.* 2005; Chan *et al.* 2008; Ravoof *et al.*, 2010; Paulus *et al.*, 2011; Manan *et al.*, 2012). In our efforts to expand the scope of these investigations, the title compound (I) was synthesized and characterized crystallographically.

In (I), Fig. 1, the central moiety is essentially planar with a r.m.s. deviation of the fitted atoms (S1,S2,N1,N2,C1 and C8) of 0.047 Å with the maximum deviations being 0.0709 (8) and -0.0711 (11) Å for the N2 and N1 atoms, respectively. The phenyl and *o*-tolyl rings lie out of this plane forming dihedral angles of 68.26 (4) and 65.99 (4)°, respectively. The *o*-tolyl ring is orientated to one side of the central plane as seen in the C8---N1---N2---C9 torsion angle of 111.24 (16)°, whereas the plane through the central atoms almost bisects the phenyl ring with the C8---S1---C1---C2 torsion angle being 176.89 (11)°.

The most prominent feature of the crystal packing is the formation of supramolecular chains along \[100\]. These are mediated through N---H···S hydrogen bonds involving the thione-S2 atom, Table 1. Thus, centrosymmetrically related molecules are connected into dimeric aggregates *via* eight-membered {···HNCS}~2~ synthons. These are connected to translationally related dimeric aggregates *via* weaker N---H···S hydrogen bonds leading to 10-membered {···HNNH···S}~2~ synthons. The chain has a step topology and comprises alternating {···HNCS}~2~ and {···HNNH···S}~2~ synthons, Fig. 2. The chains are consolidated into a three-dimensional architecture by C---H···π interactions, Fig. 3 and Table 1.

Experimental {#experimental}
============

The compound was prepared by adapting the synthetic procedure for *S*-benzyldithiocarbazate (Tarafder *et al.*, 2002). *o*-Tolylhydrazine hydrochloride (0.1 mol) in absolute ethanol (70 ml) was added to a solution of potassium hydroxide (0.1 mol) in absolute ethanol (40 ml). The mixture was cooled in an ice-salt bath and carbon disulfide (0.1 mol) was added drop-wise with constant stirring over one hour, during which a yellow-orange solution was formed. The temperature of reaction was kept below 278 K. Benzyl chloride (0.1 mol) was added drop-wise to the above solution with vigorous stirring while continuing to maintain the temperature below 278 K. The pale product was filtered off, dried briefly in a vacuum desiccator over anhydrous silica gel, recrystallized from absolute ethanol and kept in a freezer overnight. Dark-yellow crystals were grown from its ethanol solution. Yield 89%. *M*.pt: 392 K. Anal. Found (Calc.): C, 62.03 (62.46); H, 5.34 (5.59); N: 10.26 (9.71)%.

Refinement {#refinement}
==========

Carbon-bound H-atoms were placed in calculated positions (C---H = 0.95 to 0.99 Å) and were included in the refinement in the riding model approximation with *U*~iso~(H) set to 1.2 to 1.5*U*~equiv~(C). The amino H-atoms were refined with a distance restraint of N---H = 0.88±0.01 Å, and with *U*~iso~(H) = 1.2*U*~eq~(N).

Figures
=======

![The molecular structure of (I) showing the atom-labelling scheme and displacement ellipsoids at the 50% probability level.](e-68-o1402-fig1){#Fap1}

![A view of the supramolecular chain in (I) mediated by N---H···S hydrogen bonding, shown as blue dashed lines.](e-68-o1402-fig2){#Fap2}

![A view in projection down the a axis of the unit-cell contents for (I). The N---H···S hydrogen bonding and C---H···π interactions are shown as blue and purple dashed lines, respectively.](e-68-o1402-fig3){#Fap3}

Crystal data {#tablewrapcrystaldatalong}
============

  ------------------------- ---------------------------------------
  C~15~H~16~N~2~S~2~        *F*(000) = 608
  *M~r~* = 288.42           *D*~x~ = 1.347 Mg m^−3^
  Monoclinic, *P*2~1~/*n*   Cu *K*α radiation, λ = 1.54180 Å
  Hall symbol: -P 2yn       Cell parameters from 8863 reflections
  *a* = 5.7000 (1) Å        θ = 4--71°
  *b* = 11.0136 (2) Å       µ = 3.27 mm^−1^
  *c* = 22.7545 (4) Å       *T* = 100 K
  β = 95.198 (2)°           Prism, dark-yellow
  *V* = 1422.60 (4) Å^3^    0.22 × 0.14 × 0.08 mm
  *Z* = 4                   
  ------------------------- ---------------------------------------

Data collection {#tablewrapdatacollectionlong}
===============

  ------------------------------------------------------------------- --------------------------------------
  Oxford Diffraction Xcaliber Eos Gemini diffractometer               2725 independent reflections
  Radiation source: fine-focus sealed tube                            2560 reflections with *I* \> 2σ(*I*)
  Graphite monochromator                                              *R*~int~ = 0.022
  Detector resolution: 16.1952 pixels mm^-1^                          θ~max~ = 71.5°, θ~min~ = 3.9°
  ω/2θ scans                                                          *h* = −6→6
  Absorption correction: multi-scan (*CrysAlis PRO*; Agilent, 2011)   *k* = −13→13
  *T*~min~ = 0.63, *T*~max~ = 0.77                                    *l* = −27→25
  15011 measured reflections                                          
  ------------------------------------------------------------------- --------------------------------------

Refinement {#tablewraprefinementdatalong}
==========

  ------------------------------------- -------------------------------------------------------------------------------------------------
  Refinement on *F*^2^                  Primary atom site location: structure-invariant direct methods
  Least-squares matrix: full            Secondary atom site location: difference Fourier map
  *R*\[*F*^2^ \> 2σ(*F*^2^)\] = 0.035   Hydrogen site location: inferred from neighbouring sites
  *wR*(*F*^2^) = 0.097                  H atoms treated by a mixture of independent and constrained refinement
  *S* = 1.03                            *w* = 1/\[σ^2^(*F*~o~^2^) + (0.0646*P*)^2^ + 0.6201*P*\] where *P* = (*F*~o~^2^ + 2*F*~c~^2^)/3
  2725 reflections                      (Δ/σ)~max~ = 0.001
  179 parameters                        Δρ~max~ = 0.44 e Å^−3^
  2 restraints                          Δρ~min~ = −0.23 e Å^−3^
  ------------------------------------- -------------------------------------------------------------------------------------------------

Special details {#specialdetails}
===============

  ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
  Geometry. All s.u.\'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.\'s are taken into account individually in the estimation of s.u.\'s in distances, angles and torsion angles; correlations between s.u.\'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.\'s is used for estimating s.u.\'s involving l.s. planes.
  Refinement. Refinement of *F*^2^ against ALL reflections. The weighted *R*-factor *wR* and goodness of fit *S* are based on *F*^2^, conventional *R*-factors *R* are based on *F*, with *F* set to zero for negative *F*^2^. The threshold expression of *F*^2^ \> 2σ(*F*^2^) is used only for calculating *R*-factors(gt) *etc*. and is not relevant to the choice of reflections for refinement. *R*-factors based on *F*^2^ are statistically about twice as large as those based on *F*, and *R*- factors based on ALL data will be even larger.
  ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å^2^) {#tablewrapcoords}
==================================================================================================

  ------ ------------- -------------- --------------- -------------------- --
         *x*           *y*            *z*             *U*~iso~\*/*U*~eq~   
  S1     0.96691 (6)   0.83305 (3)    0.582743 (16)   0.02154 (13)         
  S2     0.73047 (7)   0.64766 (4)    0.498745 (16)   0.02497 (14)         
  N1     1.1403 (2)    0.62113 (12)   0.56054 (6)     0.0234 (3)           
  H1n    1.153 (3)     0.5503 (11)    0.5436 (8)      0.028\*              
  N2     1.3086 (2)    0.65256 (12)   0.60680 (6)     0.0226 (3)           
  H2n    1.446 (2)     0.6572 (17)    0.5924 (8)      0.027\*              
  C1     0.6928 (3)    0.90389 (14)   0.55250 (7)     0.0247 (3)           
  H1A    0.6944        0.9153         0.5094          0.030\*              
  H1B    0.5571        0.8516         0.5597          0.030\*              
  C2     0.6713 (3)    1.02493 (14)   0.58237 (6)     0.0216 (3)           
  C3     0.8217 (3)    1.12038 (16)   0.57225 (7)     0.0277 (4)           
  H3     0.9444        1.1086         0.5472          0.033\*              
  C4     0.7947 (3)    1.23226 (16)   0.59816 (8)     0.0314 (4)           
  H4     0.8989        1.2967         0.5908          0.038\*              
  C5     0.6166 (3)    1.25144 (15)   0.63490 (7)     0.0285 (4)           
  H5     0.5978        1.3288         0.6524          0.034\*              
  C6     0.4669 (3)    1.15700 (15)   0.64578 (8)     0.0279 (4)           
  H6     0.3445        1.1693         0.6709          0.033\*              
  C7     0.4950 (3)    1.04384 (15)   0.62004 (7)     0.0252 (3)           
  H7     0.3931        0.9789         0.6282          0.030\*              
  C8     0.9545 (3)    0.69201 (14)   0.54650 (6)     0.0206 (3)           
  C9     1.3110 (3)    0.57463 (14)   0.65724 (7)     0.0211 (3)           
  C10    1.4934 (3)    0.59097 (14)   0.70252 (7)     0.0231 (3)           
  C11    1.4978 (3)    0.51509 (15)   0.75165 (7)     0.0272 (3)           
  H11    1.6205        0.5243         0.7825          0.033\*              
  C12    1.3278 (3)    0.42639 (16)   0.75675 (7)     0.0294 (4)           
  H12    1.3361        0.3745         0.7902          0.035\*              
  C13    1.1459 (3)    0.41438 (16)   0.71253 (7)     0.0288 (4)           
  H13    1.0267        0.3553         0.7161          0.035\*              
  C14    1.1371 (3)    0.48843 (15)   0.66296 (7)     0.0250 (3)           
  H14    1.0114        0.4800         0.6328          0.030\*              
  C15    1.6766 (3)    0.68749 (16)   0.69763 (7)     0.0288 (4)           
  H15A   1.7773        0.6925         0.7348          0.043\*              
  H15B   1.5991        0.7659         0.6894          0.043\*              
  H15C   1.7730        0.6670         0.6655          0.043\*              
  ------ ------------- -------------- --------------- -------------------- --

Atomic displacement parameters (Å^2^) {#tablewrapadps}
=====================================

  ----- ------------- ------------ ------------ --------------- --------------- ---------------
        *U*^11^       *U*^22^      *U*^33^      *U*^12^         *U*^13^         *U*^23^
  S1    0.0220 (2)    0.0224 (2)   0.0195 (2)   0.00052 (13)    −0.00217 (14)   −0.00249 (13)
  S2    0.0232 (2)    0.0274 (2)   0.0232 (2)   −0.00015 (14)   −0.00370 (15)   −0.00584 (14)
  N1    0.0266 (7)    0.0216 (6)   0.0210 (6)   0.0004 (5)      −0.0032 (5)     −0.0029 (5)
  N2    0.0217 (7)    0.0245 (7)   0.0207 (7)   −0.0005 (5)     −0.0028 (5)     0.0004 (5)
  C1    0.0217 (8)    0.0261 (8)   0.0253 (8)   0.0019 (6)      −0.0035 (6)     −0.0019 (6)
  C2    0.0209 (7)    0.0242 (8)   0.0188 (7)   0.0017 (6)      −0.0030 (5)     0.0008 (6)
  C3    0.0288 (8)    0.0312 (8)   0.0241 (8)   −0.0025 (7)     0.0065 (6)      −0.0002 (6)
  C4    0.0372 (10)   0.0252 (8)   0.0323 (9)   −0.0060 (7)     0.0055 (7)      0.0007 (7)
  C5    0.0320 (9)    0.0256 (8)   0.0268 (8)   0.0048 (6)      −0.0037 (6)     −0.0036 (6)
  C6    0.0214 (8)    0.0359 (9)   0.0263 (8)   0.0047 (6)      0.0019 (6)      −0.0026 (7)
  C7    0.0207 (7)    0.0287 (8)   0.0260 (8)   −0.0021 (6)     0.0003 (6)      0.0016 (6)
  C8    0.0230 (7)    0.0233 (7)   0.0157 (7)   −0.0025 (6)     0.0026 (5)      0.0008 (6)
  C9    0.0217 (7)    0.0214 (7)   0.0203 (7)   0.0037 (6)      0.0030 (6)      −0.0018 (6)
  C10   0.0218 (8)    0.0269 (8)   0.0208 (7)   0.0033 (6)      0.0024 (6)      −0.0049 (6)
  C11   0.0255 (8)    0.0366 (9)   0.0192 (7)   0.0045 (7)      0.0000 (6)      −0.0025 (6)
  C12   0.0343 (9)    0.0339 (9)   0.0205 (8)   0.0048 (7)      0.0062 (6)      0.0034 (6)
  C13   0.0283 (8)    0.0298 (8)   0.0289 (8)   −0.0017 (7)     0.0067 (6)      0.0010 (7)
  C14   0.0234 (8)    0.0263 (8)   0.0247 (8)   0.0004 (6)      −0.0004 (6)     −0.0019 (6)
  C15   0.0249 (8)    0.0355 (9)   0.0254 (8)   −0.0024 (7)     −0.0016 (6)     −0.0024 (7)
  ----- ------------- ------------ ------------ --------------- --------------- ---------------

Geometric parameters (Å, º) {#tablewrapgeomlong}
===========================

  ------------------- -------------- ----------------------- --------------
  S1---C8             1.7571 (15)    C5---H5                 0.9500
  S1---C1             1.8247 (16)    C6---C7                 1.392 (2)
  S2---C8             1.6729 (15)    C6---H6                 0.9500
  N1---C8             1.331 (2)      C7---H7                 0.9500
  N1---N2             1.4020 (17)    C9---C14                1.387 (2)
  N1---H1n            0.877 (9)      C9---C10                1.407 (2)
  N2---C9             1.432 (2)      C10---C11               1.394 (2)
  N2---H2n            0.878 (9)      C10---C15               1.501 (2)
  C1---C2             1.506 (2)      C11---C12               1.388 (2)
  C1---H1A            0.9900         C11---H11               0.9500
  C1---H1B            0.9900         C12---C13               1.384 (2)
  C2---C3             1.389 (2)      C12---H12               0.9500
  C2---C7             1.394 (2)      C13---C14               1.389 (2)
  C3---C4             1.381 (2)      C13---H13               0.9500
  C3---H3             0.9500         C14---H14               0.9500
  C4---C5             1.389 (3)      C15---H15A              0.9800
  C4---H4             0.9500         C15---H15B              0.9800
  C5---C6             1.382 (2)      C15---H15C              0.9800
                                                             
  C8---S1---C1        101.79 (7)     C2---C7---H7            119.7
  C8---N1---N2        120.74 (13)    C6---C7---H7            119.7
  C8---N1---H1n       120.8 (13)     N1---C8---S2            121.91 (12)
  N2---N1---H1n       118.2 (13)     N1---C8---S1            114.11 (11)
  N1---N2---C9        114.19 (12)    S2---C8---S1            123.98 (9)
  N1---N2---H2n       108.0 (13)     C14---C9---C10          120.37 (14)
  C9---N2---H2n       112.9 (13)     C14---C9---N2           122.02 (14)
  C2---C1---S1        108.06 (10)    C10---C9---N2           117.57 (14)
  C2---C1---H1A       110.1          C11---C10---C9          117.97 (15)
  S1---C1---H1A       110.1          C11---C10---C15         121.44 (14)
  C2---C1---H1B       110.1          C9---C10---C15          120.59 (14)
  S1---C1---H1B       110.1          C12---C11---C10         121.78 (15)
  H1A---C1---H1B      108.4          C12---C11---H11         119.1
  C3---C2---C7        118.62 (15)    C10---C11---H11         119.1
  C3---C2---C1        121.22 (14)    C13---C12---C11         119.28 (15)
  C7---C2---C1        120.15 (14)    C13---C12---H12         120.4
  C4---C3---C2        120.69 (15)    C11---C12---H12         120.4
  C4---C3---H3        119.7          C12---C13---C14         120.25 (16)
  C2---C3---H3        119.7          C12---C13---H13         119.9
  C3---C4---C5        120.58 (16)    C14---C13---H13         119.9
  C3---C4---H4        119.7          C9---C14---C13          120.29 (15)
  C5---C4---H4        119.7          C9---C14---H14          119.9
  C6---C5---C4        119.37 (15)    C13---C14---H14         119.9
  C6---C5---H5        120.3          C10---C15---H15A        109.5
  C4---C5---H5        120.3          C10---C15---H15B        109.5
  C5---C6---C7        120.12 (16)    H15A---C15---H15B       109.5
  C5---C6---H6        119.9          C10---C15---H15C        109.5
  C7---C6---H6        119.9          H15A---C15---H15C       109.5
  C2---C7---C6        120.61 (15)    H15B---C15---H15C       109.5
                                                             
  C8---N1---N2---C9   111.24 (16)    C1---S1---C8---S2       −1.24 (12)
  C8---S1---C1---C2   176.89 (11)    N1---N2---C9---C14      −9.7 (2)
  S1---C1---C2---C3   68.74 (16)     N1---N2---C9---C10      172.43 (13)
  S1---C1---C2---C7   −112.65 (14)   C14---C9---C10---C11    2.4 (2)
  C7---C2---C3---C4   −1.1 (2)       N2---C9---C10---C11     −179.66 (14)
  C1---C2---C3---C4   177.55 (15)    C14---C9---C10---C15    −177.54 (14)
  C2---C3---C4---C5   0.0 (3)        N2---C9---C10---C15     0.4 (2)
  C3---C4---C5---C6   0.5 (3)        C9---C10---C11---C12    −0.6 (2)
  C4---C5---C6---C7   0.0 (2)        C15---C10---C11---C12   179.38 (15)
  C3---C2---C7---C6   1.6 (2)        C10---C11---C12---C13   −1.4 (2)
  C1---C2---C7---C6   −177.07 (14)   C11---C12---C13---C14   1.5 (2)
  C5---C6---C7---C2   −1.0 (2)       C10---C9---C14---C13    −2.3 (2)
  N2---N1---C8---S2   −170.63 (11)   N2---C9---C14---C13     179.88 (14)
  N2---N1---C8---S1   8.92 (19)      C12---C13---C14---C9    0.3 (2)
  C1---S1---C8---N1   179.22 (12)                            
  ------------------- -------------- ----------------------- --------------

Hydrogen-bond geometry (Å, º) {#tablewraphbondslong}
=============================

Cg1 and Cg2 are the centroids of the C2--C7 and C9--C14 rings, respectively.

  ------------------------ ---------- ---------- ------------- ---------------
  *D*---H···*A*            *D*---H    H···*A*    *D*···*A*     *D*---H···*A*
  N1---H1*n*···S2^i^       0.88 (1)   2.50 (1)   3.3625 (14)   169 (2)
  N2---H2*n*···S2^ii^      0.88 (1)   2.79 (2)   3.5919 (13)   152 (1)
  C11---H11···*Cg*1^iii^   0.95       2.98       3.8594 (18)   155
  C5---H5···*Cg*2^iv^      0.95       2.84       3.7005 (18)   151
  ------------------------ ---------- ---------- ------------- ---------------

Symmetry codes: (i) −*x*+2, −*y*+1, −*z*+1; (ii) *x*+1, *y*, *z*; (iii) −*x*+5/2, *y*−1/2, −*z*+3/2; (iv) *x*−1, *y*+1, *z*.

###### Hydrogen-bond geometry (Å, °)

*Cg*1 and *Cg*2 are the centroids of the C2--C7 and C9--C14 rings, respectively.

  *D*---H⋯*A*            *D*---H    H⋯*A*      *D*⋯*A*       *D*---H⋯*A*
  ---------------------- ---------- ---------- ------------- -------------
  N1---H1*n*⋯S2^i^       0.88 (1)   2.50 (1)   3.3625 (14)   169 (2)
  N2---H2*n*⋯S2^ii^      0.88 (1)   2.79 (2)   3.5919 (13)   152 (1)
  C11---H11⋯*Cg*1^iii^   0.95       2.98       3.8594 (18)   155
  C5---H5⋯*Cg*2^iv^      0.95       2.84       3.7005 (18)   151

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) .

[^1]: Additional correspondence author, e-mail: kacrouse\@gmail.com.
