Evidence for phase separation of ethanol-water mixtures at the hydrogen terminated nanocrystalline diamond surface
Interactions between ethanol-water mixtures and a hydrophobic hydrogen terminated nanocrystalline diamond surface, are investigated by sessile drop contact angle measurements. The surface free energy of the hydrophobic surface, obtained with pure liquids, differs strongly from values obtained by ethanol-water mixtures. Here, a model which explains this difference is presented. The model suggests that, due to a higher affinity of ethanol for the hydrophobic surface, when compared to water, a phase separation occurs when a mixture of both liquids is in contact with the H-terminated diamond surface. These results are supported by a computational study giving insight in the affinity and related interaction at the liquid-solid interface.
Abstract Bubbles of inviscid fluid surrounded by a viscous fluid in a Hele–Shaw cell can merge and break off. During the process of break-off, a thinning neck pinches off to a universal self-similar singularity. We describe this process and reveal its integrable structure: it is a solution of the dispersionless limit of the AKNS hierarchy. The singular break-off patterns are universal, not sensitive to details of the process and can be seen experimentally. We briefly discuss the dispersive regularization of the Hele–Shaw problem and the emergence of the Painleve II equation at the break-off.