Watching nucleation pathways in calcite
Crystal Nucleation ::: The initial stage of crystallization, the formation of nuclei, is a critical process, but because of the length and time scales involved, is hard to observe. Nielsen et al. explored the crystallization of calcium carbonate, a well-studied material but one with multiple nucleation theories. Different calcium and carbonate solutions were mixed inside a fluid cell and imaged using a liquid cell inside a transmission electron microscope. Competing pathways operated during nucleation, with both the direct association of ions into nuclei from solution and the transformation of amorphous calcium carbonate into and between different crystalline polymorphs. ::: ::: Science , this issue p. [1158][1] ::: ::: [1]: /lookup/doi/10.1126/science.1254051
We report the yield and D/H of water released by stepped heating of bulk Shergotty, Zagami, Chassigny, and the newest martian meteorite, ALH 84001. For comparison, we also report data from Nakhla using the same procedure since the heating steps in this study are slightly different than our previously reported nakhlite analyses.