SUMMARY. 1. A new experimental method for the study of kinetics and mechanism of reactions at the solid-liquid interface has shown that the dissolution of calcite in acidic waters is, under conditions of high mass transport, controlled by the first order heterogeneous reaction of H+ at the interface and not by diffusion as previously thought. ::: ::: ::: ::: 2. The implications of this for lake liming strategies (aimed at countering the effects of ‘acid rain’) are significant in that under typical liming conditions, the rate of calcite dissolution will be surface controlled and consequently appreciably slower than previously considered.
[1] This investigation focuses on the use of microbially induced calcium carbonate precipitation (MICP) to set up subsurface hydraulic barriers to potentially increase storage security near wellbores of CO2 storage sites. A numerical model is developed, capable of accounting for carbonate precipitation due to ureolytic bacterial activity as well as the flow of two fluid phases in the subsurface. The model is compared to experiments involving saturated flow through sand-packed columns to understand and optimize the processes involved as well as to validate the numerical model. It is then used to predict the effect of dense-phase CO2 and CO2-saturated water on carbonate precipitates in a porous medium.
Let R be an exchange ring in which all regular elements are one-sided unit-regular. Then every regular element in R is the sum of an idempotent and a one-sided unit. Furthermore, we extend this result to exchange rings satisfying related comparability.