Analysis of 19F and 13C NMR spectra of tetrafluorophthalic anhydride and its derivatives
Abstract 19 F and 13 C NMR spectra of perfluorinated compounds (i.e., tetrafluorophthalic anhydride, its hydroxyl- and amino-derivatives, N-pentafluorophenyltetrafluorophthalimide, and hexafluoroindan-1,3-dione) were analysed. Different signals in NMR spectra were assigned based on the analysis of spin–spin coupling constants. All assignments made were further confirmed by density functional theory (DFT) calculations of 13 C chemical shifts and J C,F coupling constants.
We study the basic properties of tensor random fields (TRFs) of the wide-sense homogeneous and isotropic kind with generally anisotropic realizations. Working within the constraints of small strains, attention is given to antiplane elasticity, thermal conductivity, classical elasticity and micropolar elasticity, all in quasi-static settings albeit without making any specific statements about the Fourier and Hooke laws. The field equations (such as linear and angular momentum balances and strain–displacement relations) lead to consequences for the respective dependent fields involved. In effect, these consequences are restrictions on the admissible forms of the correlation functions describing the TRFs.