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The rate law is an expression for the reaction rate in terms of concentrations of chemical species involved in the reaction. For example, Rate = k [A]m [B]n. where k is a rate constant, m is reaction order with respect to A, n is the reaction order with respect to B, and m+n is the overall reaction order. The rate constant is independent of the concentrations of the chemical species involved in the reaction.
â¢ Rate laws show the dependence of reaction rates on concentration. â¢ Know the general form of a rate law: rate = k[A]x[B]y. â¢ You should know what is meant by orders of reaction with respect to reactants and overall, including being able to. identify a reaction order from a rate law, and being able to write a rate law given the orders. â¢ Determination of reaction order and rate law by the method of initial rates.