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Adding foods like potatoes, pasta, or oats to a rich and savory sauce will also naturally thicken the sauce because of the starch present in the food. 3 Adjust the seasoning as necessary.
I've never seen it marketed as flour, just Arrowroot. and for some recipes there is no substitute. Although there are other excellent thickeners (potato starch, corn starch, tapioca) arrowroot thickens but the sauce stays translucent. That doesn't happen with the other thickeners.