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Painting Metal Surface. Make sure the primer coat is completely dry. Apply top coat suitable metal paint (Gloss Enamel, Satin Enamel or Synthetic Enamel) using the recommended thinner. Allow 8 â 10 hours for the first coat to dry. When the first coat is dry, it should be wet sanded with waterproof emery paper.
Here's how to paint galvanized metal: 1  Wash the metal thoroughly with hot soapy water. 2  Rinse the metal and let it dry completely for several hours. 3  Rinse the metal with a weak solution of water and ammonia and allow it to dry.4  Remove any handles or other attachments from the metal.ere's what you'll need to paint galvanized metal so that the paint won't peel off: 1  Ammonia. 2  Heavy duty sandpaper, 240 girt. 3  Metal primer. 4  Metal paint, preferably the same brand as the primer. 5  Tack cloths [source: Do It Yourself ].