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Binary files are usually thought of as being a sequence of bytes, which means the binary digits (bits) are grouped in eights. Binary files typically contain bytes that are intended to be interpreted as something other than text characters.
The zero bin is the Null or DC subcarrierIn an orthogonal frequency division multiplexing (OFDM) or orthogonal frequency division multiple access (OFDMA) signal, the subcarrier whose frequency would be equal to the RF center frequency of the station. and is not used; it contains a 0 value (0+j0).