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Binary files are usually thought of as being a sequence of bytes, which means the binary digits (bits) are grouped in eights. Binary files typically contain bytes that are intended to be interpreted as something other than text characters.
A .bin file is sort of a universal file for binary file. So it can be anything from a rom for an emulator, to image/sound data for a game. There are a few widely used utilizations for .bin files. One of them is CD images.