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When the reactants are heated, the average kinetic energy of the molecules increases. This means that more molecules are moving faster and hitting each other with more energy. If more molecules hit each other with enough energy to react, then the rate of the reaction increases.
The dangerous thing about the chemical reactions in fire is the fact that they are self-perpetuating. The heat of the flame itself keeps the fuel at the ignition temperature, so it continues to burn as long as there is fuel and oxygen around it. The flame heats any surrounding fuel so it releases gases as well.