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When the reactants are heated, the average kinetic energy of the molecules increases. This means that more molecules are moving faster and hitting each other with more energy. If more molecules hit each other with enough energy to react, then the rate of the reaction increases.
The reaction is spontaneous at low and high temperatures but at room temperature its rate is so slow that it is negligible. The increase in temperature, as created by a match, allows the reaction to start and then it heats itself, because it is exothermic. That is valid for many other fuels, such as methane, butane, hydrogen... 4) Solvent: Many reactions take place in solution and the properties of the solvent affect the reaction rate.