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When the reactants are heated, the average kinetic energy of the molecules increases. This means that more molecules are moving faster and hitting each other with more energy. If more molecules hit each other with enough energy to react, then the rate of the reaction increases.
Temperature directly influences the kinetic energy -- or energy of motion -- of the molecules in a fluid. The higher the temperature, the higher the kinetic energy and motion of the molecules. When heat energy is added to a system, the molecular kinetic energy increases and the molecules begin to move more quickly. Since they are moving more quickly, the chance of collision with each other and with the sides of the container increases.