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activation energy. activation energy, in chemistry, minimum energy needed to cause a chemical reaction. A chemical reaction between two substances occurs only when an atom, ion, or molecule of one collides with an atom, ion, or molecule of the other.
Tip: The activation energy is the difference between the energy of the reactants and the maximum energy (i.e. the energy of the activated complex). The reaction between \(\text{H}_{2} (\text{g})\) and \(\text{F}_{2} (\text{g})\) (Figure Figure 1) needs energy in order to proceed, and this is the activation energy.