It seems strange to think that something that affects a joint in the jaw can lead to anxiety, but TMJ is actually a fascinating disorder, and causes a host of different symptoms that can lead to the development of anxiety. However, it should be noted that TMJ often doesn't cause anxiety-instead, it makes anxiety worse.
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In general, backfiring on deceleration (as opposed to acceleration) is generally caused by a lean condition in the pilot circuit. What happens is that the mixture leans out enough to where is fails to ignite consistently. This, in turn allows some un-burnt fuel to get into the exhaust pipes. Then when the engine does fire, these un-burnt gasses are ignited in the exhaust pipe, causing the backfire. Newer Virago carbs have an 'enricher circuit' which cuts in on deceleration to help this problem. Earlier carbs do not have this.