Valpolicella Ripasso is a form of Valpolicella Superiore made with partially dried grape skins that have been left over from fermentation of Amarone or recioto. Winemaking in the region has existed since at least the time of the ancient Greeks.
Barium chloride, or any other barium salt, should burn with a green flame. When a barium salt is burned, the thermal energy is transferred to the outer electrons of the barium ions. They gain enough energy to excite them to a higher energy level. They then drop back to their ground state, releasing energy.
(Instructions on how to make strontium chloride appear in the previous post.) Strontium chloride dissolves/suspends pretty well in methanol. When the flame is cool, you get a nice magenta color; when the flame gets hot, you get red/red-orange.