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1 Note that in chair cyclohexane, there are two different types of C-H bonds, and thus two chemically different types of hydrogens. 2  The C-H bonds which point vertically upward or downward are called axial. 3  There are 6 of these, 3 upward and 3 downward bonds, and they alternate up/down/up, etc., around the ring. The ground state conformation of cyclohexane is a fully staggered conformation which is shaped somewhat like a chair. 2  In this conformation there is no torsional strain at all, and as we shall see later, no strain of any kind.
1 The ground state conformation of cyclohexane is a fully staggered conformation which is shaped somewhat like a chair. 2  In this conformation there is no torsional strain at all, and as we shall see later, no strain of any kind.3  Cyclohexane is unique in being the only cyclic hydrocarbon which is completely strain-free. Another conformation which is important in any conformational analysis is the transition state, or maximum energy conformation on the rotational path.For cyclohexane this is the so-called half-chair conformation, in which now 5 carbons are co-planar, and only one is puckered out of the plane.