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Fraulein. 1  Used as a courtesy title in a German-speaking area before the name of an unmarried woman or girl. See Usage Note at miss2. 2  frÃ¤ulein Used as a form of polite address for a girl or young woman in a German-speaking area. 3  Chiefly British A German governess.
Frau is the equivalent of Herr and just means woman which makes it much clearer than in other languages that the married title does not have an inherent meaning of marriage, but of being adult, and that this is the analogous address. Additional remark: Another diminutive of Frau is Frauchen.