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Polar substances are likely to dissolve in polar solvents. For example, ionic compounds, which are very polar, are often soluble in the polar solvent water. Nonpolar substances are likely to dissolve in nonpolar solvents.or example, the solution of sodium hydroxide is exothermic, and the solution of sodium chloride is somewhat endothermic. Even if the solution is slightly endothermic, the tendency to shift to the higher entropy solution often makes ionic compounds soluble in water.
Polar compounds are generally soluble in other polar compounds; non-polar compounds are generally soluble in other non-polar compounds. Molecules that can form hydrogen bonds are generally soluble with other molecules that can form hydrogen bonds (see picture below), and so forth.Oil and water don't mix.nowing the different effects that determine solubility between compounds is of great importance in organic chemistry since solvent choice can directly determine recrystallization and reaction yields.