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1 Ratio of the salt to the acid or base. 2  The buffer capacity is optimal when the ratio is 1:1; that is, when pH = pKa. 3  Total buffer concentration. 4  For example, it will take more acid or base to deplete a 0.5 M buffer than a 0.05 M buffer.
Calculation of the pH of a Buffer Solution after Addition of a Small Amount of Strong Base. When a strong base (OH -) is added to a buffer solution, the hydroxide ions are consumed by the weak acid forming water and the weaker conjugate base of the acid. The amount of the weak acid decreases while the amount of the conjugate base increases.