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Polar substances are likely to dissolve in polar solvents. For example, ionic compounds, which are very polar, are often soluble in the polar solvent water. Nonpolar substances are likely to dissolve in nonpolar solvents.or example, the solution of sodium hydroxide is exothermic, and the solution of sodium chloride is somewhat endothermic. Even if the solution is slightly endothermic, the tendency to shift to the higher entropy solution often makes ionic compounds soluble in water.
Ionic compounds are soluble in water because it a very polar compound. Ionic compounds are also very polar and thus very soluble. The water solvates each ion in the ionic comp â¦ ound. The negative ion of the ionic compound will be surrounded by water molecules with the hydrogen atoms closest.f an organic compound is relatively small, and has a polar end, it may become soluble in water. This depends on how long the carbon-chain is, compared to how polar the polar end of the chain is. I.e. Ethanol is polar and water soluable, while decanol is not.