The nadir (UK: /ËnÃ¦dÉªÉr/), (US: /ËneÉªdÉªÉr/) (from Arabic: ÙØ¸ÙØ±ââ / ALA-LC: naáºÄ«r, meaning counterpart) is the direction pointing directly below a particular location; that is, it is one of two vertical directions at a specified location, orthogonal to a horizontal flat surface there.
Asymmetric hydrogenation is a chemical reaction that adds two atoms of hydrogen preferentially to one of two faces of an unsaturated substrate molecule, such as an alkene or ketone.ne of these is in the asymmetric hydrogenation of N-unfunctionalized imines to give primary amines. Such species can be difficult to selectively reduce because they tend to exist in complex equilibria of imine and enamine tautomers, as well as (E) and (Z) isomers.
Heat of hydrogenation of an alkene in which the double bonds are conjugated is not additive because such an alkene is resonance stabilized, and, therefore, its Lewis structure, which the calculation would be based on, is a poor representation of the molecule.