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Polar substances are likely to dissolve in polar solvents. For example, ionic compounds, which are very polar, are often soluble in the polar solvent water. Nonpolar substances are likely to dissolve in nonpolar solvents.or example, the solution of sodium hydroxide is exothermic, and the solution of sodium chloride is somewhat endothermic. Even if the solution is slightly endothermic, the tendency to shift to the higher entropy solution often makes ionic compounds soluble in water.
But 1-hexanol (C6H14O) is only partially soluble in water. Compounds that are less polar, like diethyl ether (C4H10O) aren't soluble at all in water. When two compounds are mutually insoluble they're immiscible with each other: water is not miscible with diethyl ether.So when you mix hydrocarbons with water, they tend to form layers.Water is more dense than more hydrocarbons, so it is usually the bottom layer.The organic (hydrocarbon) layer is usually on top.ecause what is polar and more hydrocarbons are non-polar. The rule rule like dissolves in like.. Hydroxyl (-OH) groups are very polar. But alkyl (-CH3, -CH2CH3 etc.) groups are non-polar.