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The first school of thought, structuralism, was advocated by the founder of the first psychology lab, Wilhelm Wundt. Almost immediately, other theories began to emerge and vie for dominance in psychology.
So for a quick review, Wilhelm Wundt and William James were some of the first psychologists to study the mind scientifically. Wundt founded the first psychology lab to carry out his structuralist experiments. Structuralism relied mainly on introspection, which William James objected to because it was too subjective.