The simple view of the bonding in methane You will be familiar with drawing methane using dots and crosses diagrams, but it is worth looking at its structure a bit more closely. There is a serious mis-match between this structure and the modern electronic structure of carbon, 1s 2 2s 2 2p x 1 2p y 1.
The second reason for a low vitamin D is that you have primary hyperparathyroidism due to a small tumor in your neck and the body converts all the vitamin D-25 (that your doctor is measuring) to the active Vitamin D-1-25 (that doctors do not measure). This is the blue blob on the graph.
The other reasons that low levels of vitamin D may relate to anxiety have nothing to do with the vitamin at all. Rather, they have to do with lifestyles. There is a considerable amount of evidence that those that don't exercise are more likely to develop anxiety.