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Lower the high pH in pool water. Adding an acid to the pool water reduces the pH. The most common chemicals used to reduce high pool water pH are: muriatic acid - typically 30% - 35% liquid hydrochloric acid; sodium bisulfate - granule or powder pH reducer, dry acid.
To put it another way, the more Alkaline your water is, the more it will resist a drop in pH. If your Alkalinity is low, your pH will be less stable and more difficult to control. However, too much Alkalinity can cause scaling and other problems. The best way to raise Alkalinity is to add baking soda to your water.