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Coffee itself may not be the cause of bad breath, notes registered nurse Justyna Trzesniowksi on 891 ABC Adelaide. Instead, the real cause may be that the coffee was consumed on an empty stomach. Because coffee is a diuretic, it can cause your mouth to dry out if you drink it without any other food or water. This dry mouth encourages the growth of bacteria, Trzesniowski says.
Although there have been no large-scale studies on this subject, what we do know is that drinking coffee can stimulate movement of the colonic muscles, thus promoting peristalsis (the coordinated contraction and relaxation of intestinal muscles that causes bowel movements).