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Inside the mitochondria is where most of your ATP are created, but some ATP can be made in the cytoplasm through a process called substrate-level phosphorylation. This is a process of forming ATP by the physical addition of a phosphate group to ADP.
Oxidative phosphorylation is a mechanism for ATP synthesis in both plant and animal cells. It involves the chemiosmotic coupling of electron transport and ATP synthesis. Oxidative phosphorylation occurs in the mitochondria. The mitochondrion has two membranes: an inner membrane and an outer membrane. The space defined by the inner membrane is the matrix, and the space between the two membranes is the intermembrane space.