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Inside the mitochondria is where most of your ATP are created, but some ATP can be made in the cytoplasm through a process called substrate-level phosphorylation. This is a process of forming ATP by the physical addition of a phosphate group to ADP.
Ree Let us first define synthesis of ATP is = Phosphorylation. In biological kingdom phosphoryltaion which occurs is three kinds : 1. Photophosphorylation 2. Substrate level of phosphorylation 3. Oxidative phosphorylation. As your question relates to cellular respiration so we should pick up points 2 and 3. As you have not mentioned which cell so I have to cover both, aerobic and anaerobic cellular respiration. 2. Substrate level of respiraion occurs in cytoplasm (= Glycolysis) for both aerobic and anerobic respiration 3. Oxidative phosphorylation involves matrix of mitochondria and its inner membrane. You can hear few lectures on cellular respiration recorded at http://bisbio.in Good luck