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Inside the mitochondria is where most of your ATP are created, but some ATP can be made in the cytoplasm through a process called substrate-level phosphorylation. This is a process of forming ATP by the physical addition of a phosphate group to ADP.
Most of the ATP produced in cellular respiration come from oxidative phosphorylation, in which the energy released from redox reactions in an electron transport chain is used to produce ATP. In substrate level phosphorylation, an enzyme directly transfers a phosphate group to ADP from an intermediate substrate. All ATP production in glycolysis occurs by substrate-level phosphorylation, this form of ATP production also occurs at one step in the citric acid cycle.