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Any form of aluminum sulfate could be called alum, including toxic versions of the chemical. However, the type of alum you find used for pickling and in deodorant is potassium alum, KAl(SO 4) 2 Â·12H 2 O. Sodium aluminum sulfate is a type of alum that is used in commercial baking powder.
Bismuth metal is not considered toxic and poses minimum threat to the environment. Bismuth compounds generally have very low solubility but they should be handled with care, as there is only limited information on their effects and fate in the environment.