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let's give this a shot. *deep breath*. Episode 21 (First appearance) Episode 34 (Forest of Death) Episode 48-50 (Gaara vs Rock Lee) Episode 58 (Hospital) Episode 65-67 (Gaara vs Sasuke) Episode 74-75 (Gaara vs Sasuke cont.)
then you should not go further down from here. Once Naruto fourth shinobi war comes to an end Sasuke wants to destroy leaf village as you all know for avenging his brothers death. As one can remember Naruto says in Chapter 485 that Sasuke has to defeat Naruto before he can destroy Leaf village. In Chapter 698 and 699 Naruto and Sasuke fight against each other and at the end each one of them losses one hand.