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let's give this a shot. *deep breath*. Episode 21 (First appearance) Episode 34 (Forest of Death) Episode 48-50 (Gaara vs Rock Lee) Episode 58 (Hospital) Episode 65-67 (Gaara vs Sasuke) Episode 74-75 (Gaara vs Sasuke cont.)
Then itachi and kisame the fake ones fight on episode 12 till like 16 then sasori fights with Granny Chiyo and sakura on Episode 18 till 28 i think . Then you have to wait till episode 70 around there and hidan and kakuzu come in they have a few fights all threw those episodes. Then comes sasuke and Deidara on episode 117 i think then its the Pain vs pervy sage. then sasuke vs itatch. then sasuke vs Killer bee.