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Nonmetals also have high electron affinity. This means that it is energetically favorable to add an electron to a nonmetal. So, nonmetals can be easily reduced. Metals tend to have low electron affinity so it is more difficult to add electrons (or reduce them). In short: Metals have low ionization energies and low electron affinities so they are readily oxidized. Nonmetals have high ionization energies and high electron affinities so they are readily reduced.
Reduction at cathode. The cell potential (often called the electromotive force or emf) has a contribution from the anode which is a measure of its ability to lose electrons-it will be called its oxidation potential. The cathode has a contribution based on its ability to gain electeons, its reduction potential.ince the tabulated standard electrode potentials are reduction potentials, the one which is most negative will need to be reversed in sign to get its oxidation potential. When that is done, it is clear that the theoretical standard cell potential for the zinc-copper cell is 1.10 volts.