A Superhydrophobic Smart Coating for Flexible and Wearable Sensing Electronics.
Superhydrophobic surfaces have shown versatile applications in waterproofing, self-cleaning, drag reduction, selective absorption, etc. The most convenient and universally applicable approach to forming superhydrophobic surfaces is by coating; however, currently, superhydrophobic, smart coatings with flexibility and multiple functions for wearable sensing electronics are not yet reported. Here, a highly flexible multifunctional smart coating is fabricated by spray-coating multiwalled carbon nanotubes dispersed in a thermoplastic elastomer solution, followed by treatment with ethanol. The coatings not only endow various substrate materials with superhydrophobic surfaces, but can also respond to stretching, bending, and torsion-a property useful for flexible sensor applications. The coatings show superior sensitivity (gauge factor of 5.4-80), high resolution (1° of bending), a fast response time (<8 ms), a stable response over 5000 stretching-relaxing cycles, and wide sensing ranges (stretching: over 76%, bending: 0°-140°, torsion: 0-350 rad m-1 ). Moreover, multifunctional coatings with thicknesses of only 1 µm can be directly applied to clothing for full-range and real-time detection of human motions, which also show extreme repellency to water, acid, and alkali, which helps the sensors to work under wet and corrosive conditions.