1. Field of Invention
The present invention relates to the use of radiation measurements for determining the elemental content of bulk material in an on-line process, and to the fusion of sensor technologies, specifically Prompt Gamma Neutron Activation Analysis (PGNAA) and Dual-Energy Gamma Attenuation (DGA), to make this measurement possible.
2. Description of the Related Art
Several technologies exist to determine the composition of bulk materials. Two that are specifically important to the present invention are Prompt Gamma Neutron Activation Analysis (PGNAA) and Dual-Energy Gamma Attenuation (DGA) analysis.
The PGNAA technique involves bombarding a bulk material sample with neutrons from a neutron emitter (typically Cf-252). The neutrons collide with atoms/elements in the sample, emitter housing, and/or an external moderator and are captured by the nuclei of atoms/elements present in the sample. The capture process often involves the release of gamma rays at energies specific to the captured atom/element. These gamma rays are detected typically by a scintillation crystal (typically NaI). The sum of the detected gamma energy at these specific energies is referred to as an energy spectrum. Analysis of the energy spectrum provides analytical information on the proportion of the various elements present in the bulk material.
Various PGNAA based sensor systems are known. One such analyzer is that described in U.S. Pat. No. 4,582,992, titled “Self-Contained, On-Line, Real-time Bulk Material Analyzer,” issued to Atwell, et al., on Apr. 15, 1986, which uses PGNAA technology in an attempt to determine the elemental content of the bulk material. The described analyzer uses an arrangement of neutron sources and gamma ray detectors in an enclosed assembly to perform its analysis. Additionally, a similar device, described in U.S. Pat. No. 6,362,477, titled “Bulk Material Analyser for On-Conveyor Belt Analysis,” issued to Sowerby, et al., on Mar. 26, 2002, uses PGNAA technology in a bulk material on-conveyor belt arrangement to analyze bulk material. Again, this analyzer uses a neutron source and gamma ray detectors in an enclosed assembly to perform its analysis.
The DGA analysis technique involves bombarding a bulk material with gamma rays from two gamma ray emitters of sufficiently different energies. The gamma rays interact with the bulk material resulting in the attenuation of the number of gamma rays transmitted through the bulk material. The gamma rays are typically detected by a scintillation crystal (typically NaI). The sum of these released gamma rays at these specific energies is referred to as an energy spectrum. The technology relies on the fact that elements with different atomic numbers attenuate gamma rays at specific energies in different ways. Thus, for low-energy gamma rays (i.e., those generated by a low energy gamma emitter such as Am-241), the attenuation of gamma rays is largely dependent on the atomic number of the atoms/elements present in the bulk material. For high-energy gamma rays (i.e., those generated by a high-energy gamma emitter such as Cs-137), attenuation is independent of the atoms/elements in the bulk material. Analysis of the energy spectrum leads to a determination of the bulk elemental composition of the bulk material.
DGA based sensors are known in the art. DGA devices are based on the premise that analyzed material will attenuate different energy gamma rays in fixed repeatable ways. A DGA device consists of a gamma energy source arrangement consisting of dual energy gamma emitters. The gamma emitters are chosen in such a way that the material to be analyzed will attenuate the different energy gamma rays in ways that are conducive to measuring one or more specific properties of the material being measured. One such application of DGA technology uses gamma ray sources to interrogate coal, with the assumption that the material that coal is composed of will attenuate the differing energy gamma rays to produce a measurement that is conducive to determining coal ash content and density.